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We review the evolution of our understanding of the planetary nebulae phenomenon and their place in the scheme of stellar evolution. The historical steps leading to our current understanding of central star evolution and nebular formation are discussed. Recent optical imaging, X-ray, ultraviolet, infrared, millimeter wave, radio observations have led to a much more complex picture of the structure of planetary nebulae. The optically bright regions have multiple shell structures (rims, shells, crowns, and haloes), which can be understood within the interacting winds framework. However, the physical mechanism responsible for bipolar and multipolar structures that emerged during the proto-planetary nebulae phase is yet to be identified. Our morphological classifications of planetary nebulae are hampered by the effects of sensitivity, orientation, and field-of-view coverage, and the fraction of bipolar or multipolar nebulae may be much higher than commonly assumed. The optically bright bipolar lobes may represent low-density, ionization-bounded cavities carved out of a neutral envelope by collimated fast winds. Planetary nebulae are sites of active synthesis of complex organic compounds, suggesting that planetary nebulae play a major role in the chemical enrichment of the Galaxy. Possible avenues of future advancement are discussed.

Mid-infrared emission features probe the properties of ionized gas, and hot or warm molecular gas. The Orion Bar is a frequently studied photodissociation region (PDR) containing large amounts of gas under these conditions, and was observed with the MIRI IFU aboard JWST as part of the "PDRs4All" program. The resulting IR spectroscopic images of high angular resolution (0.2") reveal a rich observational inventory of mid-IR emission lines, and spatially resolve the substructure of the PDR, with a mosaic cutting perpendicularly across the ionization front and three dissociation fronts. We extracted five spectra that represent the ionized, atomic, and molecular gas layers, and measured the most prominent gas emission lines. An initial analysis summarizes the physical conditions of the gas and the potential of these data. We identified around 100 lines, report an additional 18 lines that remain unidentified, and measured the line intensities and central wavelengths. The H I recombination lines originating from the ionized gas layer bordering the PDR, have intensity ratios that are well matched by emissivity coefficients from H recombination theory, but deviate up to 10% due contamination by He I lines. We report the observed emission lines of various ionization stages of Ne, P, S, Cl, Ar, Fe, and Ni, and show how certain line ratios vary between the five regions. We observe the pure-rotational H$_2$ lines in the vibrational ground state from 0-0 S(1) to 0-0 S(8), and in the first vibrationally excited state from 1-1 S(5) to 1-1 S(9). We derive H$_2$ excitation diagrams, and approximate the excitation with one thermal (~700 K) component representative of an average gas temperature, and one non-thermal component (~2700 K) probing the effect of UV pumping. We compare these results to an existing model for the Orion Bar PDR and highlight the differences with the observations., Comment: 26 pages, 12 figures, 3 tables. Submitted to A&A, under review (1st revision)

Most low-mass stars form in stellar clusters that also contain massive stars, which are sources of far-ultraviolet (FUV) radiation. Theoretical models predict that this FUV radiation produces photo-dissociation regions (PDRs) on the surfaces of protoplanetary disks around low-mass stars, impacting planet formation within the disks. We report JWST and Atacama Large Millimetere Array observations of a FUV-irradiated protoplanetary disk in the Orion Nebula. Emission lines are detected from the PDR; modelling their kinematics and excitation allows us to constrain the physical conditions within the gas. We quantify the mass-loss rate induced by the FUV irradiation, finding it is sufficient to remove gas from the disk in less than a million years. This is rapid enough to affect giant planet formation in the disk.

(Abridged) We investigate the impact of radiative feedback from massive stars on their natal cloud and focus on the transition from the HII region to the atomic PDR (crossing the ionisation front (IF)), and the subsequent transition to the molecular PDR (crossing the dissociation front (DF)). We use high-resolution near-IR integral field spectroscopic data from NIRSpec on JWST to observe the Orion Bar PDR as part of the PDRs4All JWST Early Release Science Program. The NIRSpec data reveal a forest of lines including, but not limited to, HeI, HI, and CI recombination lines, ionic lines, OI and NI fluorescence lines, Aromatic Infrared Bands (AIBs including aromatic CH, aliphatic CH, and their CD counterparts), CO2 ice, pure rotational and ro-vibrational lines from H2, and ro-vibrational lines HD, CO, and CH+, most of them detected for the first time towards a PDR. Their spatial distribution resolves the H and He ionisation structure in the Huygens region, gives insight into the geometry of the Bar, and confirms the large-scale stratification of PDRs. We observe numerous smaller scale structures whose typical size decreases with distance from Ori C and IR lines from CI, if solely arising from radiative recombination and cascade, reveal very high gas temperatures consistent with the hot irradiated surface of small-scale dense clumps deep inside the PDR. The H2 lines reveal multiple, prominent filaments which exhibit different characteristics. This leaves the impression of a "terraced" transition from the predominantly atomic surface region to the CO-rich molecular zone deeper in. This study showcases the discovery space created by JWST to further our understanding of the impact radiation from young stars has on their natal molecular cloud and proto-planetary disk, which touches on star- and planet formation as well as galaxy evolution., Comment: 52 pages, 30 figures, submitted to A&A

The JWST has captured the most detailed and sharpest infrared images ever taken of the inner region of the Orion Nebula, the nearest massive star formation region, and a prototypical highly irradiated dense photo-dissociation region (PDR). We investigate the fundamental interaction of far-ultraviolet photons with molecular clouds. The transitions across the ionization front (IF), dissociation front (DF), and the molecular cloud are studied at high-angular resolution. These transitions are relevant to understanding the effects of radiative feedback from massive stars and the dominant physical and chemical processes that lead to the IR emission that JWST will detect in many Galactic and extragalactic environments. Due to the proximity of the Orion Nebula and the unprecedented angular resolution of JWST, these data reveal that the molecular cloud borders are hyper structured at small angular scales of 0.1-1" (0.0002-0.002 pc or 40-400 au at 414 pc). A diverse set of features are observed such as ridges, waves, globules and photoevaporated protoplanetary disks. At the PDR atomic to molecular transition, several bright features are detected that are associated with the highly irradiated surroundings of the dense molecular condensations and embedded young star. Toward the Orion Bar PDR, a highly sculpted interface is detected with sharp edges and density increases near the IF and DF. This was predicted by previous modeling studies, but the fronts were unresolved in most tracers. A complex, structured, and folded DF surface was traced by the H2 lines. This dataset was used to revisit the commonly adopted 2D PDR structure of the Orion Bar. JWST provides us with a complete view of the PDR, all the way from the PDR edge to the substructured dense region, and this allowed us to determine, in detail, where the emission of the atomic and molecular lines, aromatic bands, and dust originate.

(Abridged) Mid-infrared observations of photodissociation regions (PDRs) are dominated by strong emission features called aromatic infrared bands (AIBs). The most prominent AIBs are found at 3.3, 6.2, 7.7, 8.6, and 11.2 $\mu$m. The most sensitive, highest-resolution infrared spectral imaging data ever taken of the prototypical PDR, the Orion Bar, have been captured by JWST. We provide an inventory of the AIBs found in the Orion Bar, along with mid-IR template spectra from five distinct regions in the Bar: the molecular PDR, the atomic PDR, and the HII region. We use JWST NIRSpec IFU and MIRI MRS observations of the Orion Bar from the JWST Early Release Science Program, PDRs4All (ID: 1288). We extract five template spectra to represent the morphology and environment of the Orion Bar PDR. The superb sensitivity and the spectral and spatial resolution of these JWST observations reveal many details of the AIB emission and enable an improved characterization of their detailed profile shapes and sub-components. While the spectra are dominated by the well-known AIBs at 3.3, 6.2, 7.7, 8.6, 11.2, and 12.7 $\mu$m, a wealth of weaker features and sub-components are present. We report trends in the widths and relative strengths of AIBs across the five template spectra. These trends yield valuable insight into the photochemical evolution of PAHs, such as the evolution responsible for the shift of 11.2 $\mu$m AIB emission from class B$_{11.2}$ in the molecular PDR to class A$_{11.2}$ in the PDR surface layers. This photochemical evolution is driven by the increased importance of FUV processing in the PDR surface layers, resulting in a "weeding out" of the weakest links of the PAH family in these layers. For now, these JWST observations are consistent with a model in which the underlying PAH family is composed of a few species: the so-called 'grandPAHs'., Comment: 25 pages, 10 figures, to appear in A&A

Planetary nebulae (PNe), the ejected envelopes of red giant stars, provide us with a history of the last, mass-losing phases of 90 percent of stars initially more massive than the Sun. Here, we analyse James Webb Space Telescope (JWST) Early Release Observation (ERO) images of the PN NGC3132. A structured, extended H2 halo surrounding an ionised central bubble is imprinted with spiral structures, likely shaped by a low-mass companion orbiting the central star at 40-60 AU. The images also reveal a mid-IR excess at the central star interpreted as a dusty disk, indicative of an interaction with another, closer companion. Including the previously known, A-type visual companion, the progenitor of the NGC3132 PN must have been at least a stellar quartet. The JWST images allow us to generate a model of the illumination, ionisation and hydrodynamics of the molecular halo, demonstrating the power of JWST to investigate complex stellar outflows. Further, new measurements of the A-type visual companion allow us to derive the value for the mass of the progenitor of a central star to date with excellent precision: 2.86+/-0.06 Mo. These results serve as path finders for future JWST observations of PNe providing unique insight into fundamental astrophysical processes including colliding winds, and binary star interactions, with implications for supernovae and gravitational wave systems., Comment: 32 pages, 5 figures for the main article. 12 pages 8 figures for the supplementary material

Chemical kinetics plays an important role in governing the thermal evolution in reactive flows problems. The possible interactions between chemical species increase drastically with the number of species considered in the system. Various ways have been proposed before to simplify chemical networks with an aim to reduce the computational complexity of the chemical network. These techniques oftentimes require domain-knowledge experts to handcraftedly identify important reaction pathways and possible simplifications. Here, we propose a combination of autoencoder and neural ordinary differential equation to model the temporal evolution of chemical kinetics in a reduced subspace. We demonstrated that our model has achieved a close-to 10-fold speed-up compared to commonly used astro-chemistry solver for a 9-species primordial network, while maintaining 1 percent accuracy across a wide-range of density and temperature., Comment: 10 pages, 8 figures, accepted to the ICML 2022 Machine Learning for Astrophysics workshop

A key yet unresolved question in modern-day astronomy is how galaxies formed and evolved under the paradigm of the $\Lambda$CDM model. A critical limiting factor lies in the lack of robust tools to describe the merger history through a statistical model. In this work, we employ a generative graph network, E(n) Equivariant Graph Normalizing Flows Model. We demonstrate that, by treating the progenitors as a graph, our model robustly recovers their distributions, including their masses, merging redshifts and pairwise distances at redshift z=2 conditioned on their z=0 properties. The generative nature of the model enables other downstream tasks, including likelihood-free inference, detecting anomalies and identifying subtle correlations of progenitor features., Comment: 6 pages, 3 figures, accepted to the ICML 2022 Machine Learning for Astrophysics workshop

Massive stars disrupt their natal molecular cloud material through radiative and mechanical feedback processes. These processes have profound effects on the evolution of interstellar matter in our Galaxy and throughout the Universe, from the era of vigorous star formation at redshifts of 1-3 to the present day. The dominant feedback processes can be probed by observations of the Photo-Dissociation Regions (PDRs) where the far-ultraviolet photons of massive stars create warm regions of gas and dust in the neutral atomic and molecular gas. PDR emission provides a unique tool to study in detail the physical and chemical processes that are relevant for most of the mass in inter- and circumstellar media including diffuse clouds, proto-planetary disks and molecular cloud surfaces, globules, planetary nebulae, and star-forming regions. PDR emission dominates the infrared (IR) spectra of star-forming galaxies. Most of the Galactic and extragalactic observations obtained with the James Webb Space Telescope (JWST) will therefore arise in PDR emission. In this paper we present an Early Release Science program using the MIRI, NIRSpec, and NIRCam instruments dedicated to the observations of an emblematic and nearby PDR: the Orion Bar. These early JWST observations will provide template datasets designed to identify key PDR characteristics in JWST observations. These data will serve to benchmark PDR models and extend them into the JWST era. We also present the Science-Enabling products that we will provide to the community. These template datasets and Science-Enabling products will guide the preparation of future proposals on star-forming regions in our Galaxy and beyond and will facilitate data analysis and interpretation of forthcoming JWST observations., Comment: Submitted to PASP

A family of unidentified infrared emission (UIE) bands has been observed throughout the Universe. The current observed spectral properties of the UIE bands are summarized. These properties are discussed in the frameworks of different models of the chemical carriers of these bands. The UIE carriers represent a large reservoir of carbon in the Universe, and play a significant role in the physical and chemical processes in the interstellar medium and galactic environment. A correct identification of the carrier of the UIE bands is needed to use these bands as probes of galactic evolution.

There exists a number of astronomical spectral phenomena that have remained unidentified after decades of extensive observations. The diffuse interstellar bands, the 220 nm feature, unidentified infrared emission bands, extended red emissions, and 21 and 30 $\mu$m emission features are seen in a wide variety of astrophysical environments. The strengths of these features suggest that they originate from chemical compounds made of common elements, possibly organic in nature. The quest to understand how such organic materials are synthesized and distributed across the Galaxy represents a major challenge to our understanding of the chemical content of the Universe.

We present QUOTAS, a novel research platform for the data-driven investigation of super-massive black hole (SMBH) populations. While SMBH data sets -- observations and simulations -- have grown rapidly in complexity and abundance, our computational environments and analysis tools have not matured commensurately to exhaust opportunities for discovery. Motivated to explore BH host galaxy and the parent dark matter halo connection, in this pilot version of QUOTAS, we assemble and co-locate the high-redshift, luminous quasar population at $z \geq 3$ alongside simulated data of the same epochs. Leveraging machine learning algorithms (ML) we expand simulation volumes that successfully replicate halo populations beyond the training set. Training ML on the Illustris-TNG300 simulation that includes baryonic physics, we populate the larger LEGACY Expanse dark matter-only box with quasars. Our first science results comparing observational and ML simulated quasars at $z \sim 3$, reveal that while the recovered Black Hole Mass Functions and clustering are in good agreement, simulated SMBHs fail to accrete, shine and grow at high enough rates to match observed quasars. We conclude that sub-grid models of mass accretion and SMBH feedback implemented in Illustris-TNG300 do not reproduce their observed mass growth. QUOTAS, demonstrates the power of ML, both for analyzing large complex datasets, and offering a unique opportunity to interrogate our theoretical model assumptions. We deploy ML again to derive and devise an optimal survey strategy for bringing the undetected lower luminosity quasar population into view. QUOTAS, and all related materials are publicly available at the Google Kaggle platform., Comment: Revised version: 38 pages, 4 tables and 14 figures, accepted for publication in ApJ

Although automated pathology classification using deep learning (DL) has proved to be predictively efficient, DL methods are found to be data and compute cost intensive. In this work, we aim to reduce DL training costs by pre-training a Resnet feature extractor using SimCLR contrastive loss for latent encoding of OCT images. We propose a novel active learning framework that identifies a minimal sub-sampled dataset containing the most uncertain OCT image samples using label propagation on the SimCLR latent encodings. The pre-trained Resnet model is then fine-tuned with the labelled minimal sub-sampled data and the underlying pathological sites are visually explained. Our framework identifies upto 2% of OCT images to be most uncertain that need prioritized specialist attention and that can fine-tune a Resnet model to achieve upto 97% classification accuracy. The proposed method can be extended to other medical images to minimize prediction costs., Comment: 4 pages, 6 images, 2 tables, submitted to IEEE EMBC 2021

We report an unbiased radio line survey towards the circumstellar envelopes of evolved stars at the frequency range from 20 to 25 GHz, aiming to obtain a more complete unbiased picture of the chemical evolution in the final stages of stellar evolution. The observation sample includes the asymptotic giant branch (AGB) star IRC+10216, the proto-planetary nebulae (PPNs) CRL\,2688 and CRL\,618, and the young planetary nebula (PN) NGC\,7027, representing an evolutionary sequence spanning about 10,000 years. Rotational transitions from cyanopolyyne chains and inversion lines from ammonia are detected in the AGB star and PPNs, while the PN displays several recombination lines. The different spectral behaviors of these evolved stars clearly reflect the evolution of circumstellar chemistry during the AGB-PPN-PN transitions., Comment: 37 pages. 8 figures, Accepted for publication in PASJ

Astronomical infrared spectral features at ~6.6, 9.8 and 20 micronm have recently been suggested as being due to the planar graphene form of C24 carbon cluster. Here we report density functional theory and coupled cluster calculations on wavefunctions stability, relative energies, and infrared spectra of four different types of C24 isomers, including the graphene and fullerene forms. The types of vibrational motions under these bands are also discussed. Among the four isomers, we find that the astronomical data are best approximated by the graphene form of C24., Comment: 15 pages, 4 figures

We have studied the high-mass star-forming complex NGC 6334 with ALMA in the continuum emission at a frequency of 87.6 GHz, achieving a spatial resolution of 1300 au. Detecting 142 compact sources distributed over the whole observed area, we then used machine learning algorithms to group the compact cores in different clusters. A total of four main clusters were identified: NGC 6334-E, NGC 6334-I, NGC 6334-I(N) and NGC 6334-I(NW). The typical separations between cluster members (4000-12000 au) together with the core masses (0.2-100 $M_{\odot}$) are in agreement with turbulent fragmentation at scales of 0.1 pc. We find that the CMFs (core mass functions) show an excess of massive cores compared to the IMF. Typical uncertainties in temperature or unresolved multiplicity may mimic the observed excess of massive cores. Evidence of mass segregation in NGC 6334-I and NGC 6334-I(N), with the most massive cores located closer to the center, was found. Correlations between the physical properties of the clusters and their evolutionary stage were searched for, and found to show a larger separation between cores in the more evolved clusters, favouring the role of gas expulsion and stellar ejection over time. From these results, we suggest that NGC 6334-I(N) was primordially segregated, while NGC 6334-I may have become mass-segregated over time due to dynamical effects. Finally, the lack of massive cores in the most evolved cluster suggests that the gas reservoir may be already exhausted, while the less evolved clusters still have access to a larger gas mass reservoir. In general, the fragmentation in NGC 6334 at large scales (about 1 pc) is governed by turbulent pressure, while at smaller scales (a few hundred au), thermal pressure regulates the fragmentation process., Comment: Accepted for publication in Astronomy & Astrophysics. 20 pages with 15 figures and 3 tables, plus Appendices with extra figures and tables. (Abstract modified)

The late stages of stellar evolution from asymptotic giant branch stars to planetary nebulae are now known to be an active phase of molecular synthesis. Over 80 gas-phase molecules have been detected through rotational transitions in the mm/submm region. Infrared spectroscopy has also detected inorganic minerals, fullerenes, and organic solids. The synthesis of these molecules and solids take place over very low density ($<10^6$ cm$^{-3}$) and short ($\sim10^3$ yr) time scales. The complex organics are observed to have mixed aromatic/aliphatic structures and may be related to the complex organics found in meteorites, comets, interplanetary dust particles, and planetary satellites. The possible links between stellar and solar system organics is discussed., Comment: 22 pages, 10 figures

We present high-angular-resolution {\it Hubble Space Telescope (HST)} optical and near-infrared imaging of the compact planetary nebula (PN) IRAS 21282+5050. Optical images of this object reveal several complex morphological structures including three pairs of bipolar lobes and an elliptical shell lying close to the plane of the sky. From near-infrared observations, we found a dust torus oriented nearly perpendicular to the major axis of elliptical shell. The results suggest that IRAS 21282+5050 is a multipolar PN, and these structures developed early during the post asymptotic-giant-branch (AGB) evolution. From a three-dimensional (3-D) model, we derived the physical dimensions of these apparent structures. When the 3-D model is viewed from different orientations, IRAS 21282+5050 shows similar apparent structures as other multipolar PNs. Analysis of the spectral energy distribution and optical spectroscopic observations of the nebula suggests the presence of a cool companion to the hot central star responsible for the ionization of the nebula. Whether the binary nature of the central star has any relations with the multipolar structure of the nebula needs to be further investigated.

The linewidth of ions has been observed to be systematically narrower than that of the coexisting neutrals in molecular clouds (Houde et al. 2000) and been interpreted as the signature of the decoupling of the neutral turbulence from magnetic fields in partially ionized medium (Li & Houde 2008; Paper I, hereafter). As a sequel of Paper I, here we present further observational evidence that lend support to these earlier proposals with the velocity coordinate spectrum analysis (Lazarian & Pogosyan 2006). We recover the turbulent energy spectra of HCN and HCO+(4-3) in a starless molecular filament in NGC 6334 where magnetic fields play a dynamically important role (Li et al. 2015). Our analysis showed that the neutral spectrum is consistent with Kolmogorov-type (k^-5/3, where k is the wave number), while that of the ions is the same on the large scale but steeper (k^-2) for scales smaller than 0.404pc. We carefully ruled out the possibilities that the spectrum difference can stem from the differences of ion and neutral optical depth and hyper-fine structures.

Complex organics are now commonly found in meteorites, comets, asteroids, planetary satellites, and interplanetary dust particles. The chemical composition and possible origin of these organics are presented. Specifically, we discuss the possible link between Solar System organics and the complex organics synthesized during the late stages of stellar evolution. Implications of extraterrestrial organics on the origin of life on Earth and the possibility of existence of primordial organics on Earth are also discussed.