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Helium isotopes are unrivalled tracers of the origins of melts in the Earth's convecting mantle but their role in determining melt contributions from the shallower and rigid lithospheric mantle is more ambiguous. We have acquired new 3He/4He data for olivine and pyroxene separates from 47 well-characterised mantle xenoliths from global on- and off-craton settings. When combined with existing data they demonstrate a new systematic relationship between fluid-hosted 3He/4He and major and trace element composition of host minerals and whole rock. We show that a significant proportion (>70 %) of mantle peridotites from continental off-craton settings with depleted major element compositions (e.g., olivine Mg# ≥ 89.5) have 3He/4He in the range of modern-day mid-ocean ridge basalt (MORB) source mantle (7–9 R a) and we propose that they represent underplated melt residues, which initially formed in the convecting upper mantle. Furthermore, we observe that off-craton mantle xenoliths with signatures often attributed to enrichment by melts or fluids from 'ancient' subducted oceanic lithosphere have lower 3He/4He (<7 R a). Modest correlations between 3He/4He and whole rock incompatible trace element signatures commonly used as proxies for metasomatism by small-fraction carbonatite and silicate melts or C-O-H fluids characterise lithospheric mantle with 3He/4He ranging from 5 to 8 R a. Using a numerical model that integrates temperature-dependent melt extraction from the upper mantle with in-situ radiogenic ingrowth of 4He in the continental mantle we show that the initial 3He/4He of continental lithosphere mantle has decreased over time. This is consistent with previous observations demonstrating that ancient (2.5–3.5 Ga) cratonic mantle has a depleted mineral chemistry (e.g., olivine Mg# = 91–94) and low 3He/4He (0.5–6.7 R a), while continental off-craton mantle (<2.5 Ga) is more fertile (olivine Mg# = 88–92) and has less radiogenic 3He/4He (4–8.8 R a). This relationship defines a 'global lithospheric mantle array' for intraplate peridotites on plots of 3He/4He vs olivine Mg#. Peridotites influenced by past and present subduction fluids, including those that contain amphibole, plot off this array. Our findings have broad implications for the 3He/4He signatures observed in continental magmas. Many of Earth's deepest melts, i.e. proto-kimberlites, are characterised by relatively low 3He/4He. We attribute this to assimilation and incorporation of low 3He/4He cratonic mantle material during ascent of carbonate-rich melts through thick lithosphere, which overprints the original signatures. Moreover, our findings suggests that the lithospheric mantle acts as a long-term reservoir for other fluid-hosted volatiles (e.g., CO 2 , CH 4 , H 2 O), and in some cases able to sequester these over billion-year timescales until physio-chemical perturbation (e.g., during major rifting or heating events). [ABSTRACT FROM AUTHOR]

The Pipe 200 kimberlite in northern Lesotho on the southeast margin of the Kaapvaal Craton is a diamond-poor deposit despite its proximity to economically viable kimberlites like the Liqhobong kimberlite. We study harzburgite xenoliths' mineral composition, geochemistry, and pressure–temperature evolution to understand factors influencing diamond destruction. The xenoliths are classified into five types based on their petrography and geochemistry. The diversity in the mineral assemblage correlates with a sampling depth of ~ 100 to 175 km (~ 2.8 to < 5.0 GPa). The signatures of metasomatism are evident in type 3 and 4 xenoliths, where garnet breaks down to form a cluster (henceforth assemblage) of phlogopite, chromite, and diopside. Fine-grained melts associated with an uplift in the mantle to shallower depths of < 90 km (< 2.3 GPa) encompass the minerals in the assemblage, which display resorption at the boundaries. Water contents (structural hydroxyl) of olivine and possibly orthopyroxene are lower in the xenoliths with metasomatism-induced breakdown of garnet. The structural hydroxyl distribution in the nominally anhydrous minerals shows flat distribution profiles of re-equilibration due to residence in the kimberlite magma. It is supported by the disruption of the inter-mineral water partition coefficient due to olivine water diffusion during residence in the kimberlite magma. The barren nature of the Pipe 200 kimberlite is attributed to the signatures of mantle metasomatism and residence in kimberlite magma, which led to the diamond destruction. [ABSTRACT FROM AUTHOR]

This article describes a novel dataset on non‐diamondiferous eclogite and garnet pyroxenite xenoliths from four kimberlite pipes of the Ekati Diamond Mine (Central Slave Craton, Canada). Xenoliths brought to the surface by kimberlite eruptions are direct sources of information on the composition and evolution of the Earth's mantle. Eclogite and garnet pyroxenite xenoliths, specifically, are testimony of subduction into, and metasomatism of, the mantle beneath cratons. Furthermore, these rocks are major hosts for diamond and thus an important part of the deep carbon cycle. The sample suite consists of 41 small xenoliths (2–5 cm) recovered from drill cores. The dataset includes major and trace element concentrations for garnet, clinopyroxene and ilmenite, as well as stable oxygen isotope compositions of garnets. Strontium and neodymium isotopic compositions are reported for garnet and clinopyroxene for four samples which were large enough to allow for analysis. Overall, this dataset significantly expands and complements existing datasets on diamondiferous and non‐diamondiferous xenoliths from the Slave Craton in Canada, furthering our understanding of the composition of the Slave subcratonic lithosphere. The dataset includes several samples with rare mineral assemblages, including an olivine‐bearing eclogite as well as ilmenite and apatite‐bearing garnet‐pyroxenites, and thus provides data shedding light on rarely reported compositional nuances in xenolith suites found in kimberlites. [ABSTRACT FROM AUTHOR]

Melt inclusions trapped in minerals inside xenoliths from kimberlites can help to examine the composition of kimberlite melt and/or metasomatic processes in the subcratonic lithospheric mantle as well as shed more light on the role of these melts in diamond destruction. In this study, confocal Raman spectroscopy of secondary melt inclusions in olivine from xenoliths in five different Kaapvaal Craton kimberlites was used for testing any compositional differences between melt inclusions from economically productive (Bultfontein and Frank Smit) and uneconomic diamond barren (Matsoku, Thaba Putsoa, and Pipe 200) kimberlite pipes. The xenoliths represent a range of pressures (37–45 kbar) and temperatures (1000–1300°C). The 26 daughter minerals identified within melt inclusions include Ca–Mg (±Na, K, P, Cl)‐bearing carbonates, alkali (±Ca, Ba, Cl, F, H2O, CO2)‐bearing sulfates, phosphates, oxides, silicates, and a rare nitrate. The mineral assemblages in melt inclusions are similar in both economic and barren kimberlite pipes from the interior and the edge of the craton, indicating the similar composition of the entrapped melts in all studied samples. However, the petrographic study revealed different metasomatic processes recorded by xenoliths from barren and economic kimberlites. Metasomatism by a melt enriched in K, Ca, and H2O could be instrumental in diamond destruction and the low diamond grade of the three barren kimberlites from Lesotho. Our study revealed no effect of kimberlite melt composition on diamond preservation in the studied kimberlites: instead, diamond grade is most likely affected by diamond destruction in the mantle source prior to kimberlite emplacement with kimberlite ascent. [ABSTRACT FROM AUTHOR]

40Ar/39Ar ages of phlogopite from kimberlite-hosted mantle xenoliths are commonly older than the kimberlite eruption, despite the fact that argon is supposed not to be retained by phlogopite at temperatures above hydrothermally-derived Ar closure temperatures (< 500 ° C). Combining Molecular Dynamics (MD) with Nudged Elastic Band (NEB) and Transition State Theory (TST), we investigate 40Ar − P V T (Pressure − Volume − Temperature) relationships in pristine, defect-free, phlogopite and show that 40Ar diffusivity is several orders of magnitude slower than existing estimates with a strong effect of pressure on diffusion rates and retention of 40Ar at mantle conditions. These results imply to fundamentally revise residence- and transit-time estimates based on Ar kinetics in phlogopite assuming simple diffusive relaxation during upwelling. When accounting for pressure, 40Ar retention trends in phlogopite predict substantially slower kimberlite ascent rates than documented by independent chronometers, indicating that 40Ar resetting during ascent in phlogopite does not result from simple decompression-driven diffusive relaxation. We argue that 40Ar remobilization probably involves secondary structural–textural modifications induced by reaction-driven recrystallization or rim overgrowth. These findings have far-reaching consequences in terms of argon isotopic mobility at mantle depths as well as for dating and tracing metasomatic events during crust − mantle interactions in the evolution of the subcontinental mantle. [ABSTRACT FROM AUTHOR]

Magma fragmentation is an essential process driving explosive volcanic eruptions, generating a distribution of pyroclasts with characteristic shape and grain size. These characteristics are often used to inform on the energetics of magma fragmentation and the associated eruption style and intensity. However, a portion of these pyroclasts, droplets when still in the molten state, are likely to be generated through impact mechanisms (i.e., collisions), and subsequent secondary fragmentation (i.e., splashing). Here, we successfully apply and dynamically scale concepts and findings of liquid droplet impacts in engineering to magma fragmentation processes in volcanology. We compile and model physical data for two mafic melt compositions (kimberlite and basalt) and use specific eruption examples from Igwisi Hills, Kīlauea and Stromboli volcanoes to define composition‐specific impact dynamics. Pyroclast impact dynamics have a direct control on in‐conduit processes, eruption dynamics, and ash dispersal. For low viscosity mafic melts such as kimberlite and basalt, pyroclast impacts can lead to both splash and deposition on the conduit wall, resulting either in conduit clearing or conduit narrowing, respectively. In both cases, shifting the impact regime toward surface deposition will lead to an inexorable decay in explosiveness, potentially switching the eruption style to effusive behavior. This has direct consequences for the transport of volcanic ash at the surface and inferring magma fragmentation processes (e.g., energies) from the depositional record. Plain Language Summary: During explosive eruptions, magma is ripped apart to form a distribution of incandescent fragments, termed pyroclasts, of different sizes and shapes. These characteristics are often used to forensically reconstruct eruption dynamics. For explosive volcanic eruptions of low viscosity magmas, fragmentation dynamics often resemble water spraying with the generation of droplets. In volcanoes, and under certain conditions, magma droplets can impact a surface or each other and further fragment, splashing into finer droplets. Such liquid impact dynamics have been long researched in engineering but seldom considered in volcanology. Here, we apply and scale the concepts of liquid impacts from engineering to volcanic processes. We compiled data for ultramafic and mafic magma compositions, which are characterized by different physical properties that influence the impact outcomes (e.g., splash vs. surface deposition). Droplet impacts may lead to splashing or sticking against the conduit wall. For example, under prolonged deposition conditions, progressive narrowing of the conduit could lead to eruption termination or switch to pure lava effusion. Finally, we show that droplet impacts are likely to control the final size of pyroclasts produced during ultramafic and mafic explosive eruptions, and therefore must be considered when interpreting the rock record from related past events. Key Points: Liquid droplet impacts are relevant to magma fragmentation processes in volcanologyMagma composition and ejection velocity are the main factors controlling pyroclast impact dynamicsTransitions between pyroclast splash and deposition can contribute to eruption style transitions and eruption dynamics [ABSTRACT FROM AUTHOR]

The eruption of deeply sourced kimberlite magma offers the fastest route to bring deep-seated volatiles back to the Earth's surface. However, the viscosity of kimberlite magma, a factor governing its migration and eruption dynamics within Earth, remains poorly constrained. We conducted synchrotron in situ falling sphere viscometry experiments to examine kimberlite magma with different volatile contents (0 to 5 wt % H2O and 2 to 8 wt % CO2) under high pressure-temperature conditions. The results reveal that the viscosity of volatile-rich kimberlite magma is ~1 to 2 orders lower than that of mid-ocean ridge basalt (MORB) and comparable to the ultramobile pure carbonate melt. Using the measured viscosity values, we simulated the ascent and eruption process of kimberlite magma. We found that a minimum content of ~0.5 wt % water in the primitive magma is necessary to allow the ultrafast eruption process of kimberlite, thereby enabling the preservation of diamonds and high-pressure mineral inclusions transported by the magma. [ABSTRACT FROM AUTHOR]

The destruction of the cratonic root has been documented for multiple cratons worldwide and is characterized by severe lithospheric thinning, extensive extensional deformation, and intense thermal activity. Here, we present detailed petrography accompanied by comprehensive geochemical and isotopic data for peridotites, pyroxenites, and eclogites from the SW margin of the São Francisco Craton that has also been severely thinned. The diamond-bearing Canastra-1 kimberlite represents a Cretaceous intrusion from the Alto Paranaíba Igneous Province and hosts garnet-bearing mantle xenoliths from different mantle sources, revealing a complex history of metasomatism/refertilization related to superimposed tectonic events since the cratonic consolidation. Eclogites (T = 978–982°C; P ~ 4.0 GPa) and pargasite-bearing websterites (T = 875–926°C; P = 2.0–3.0 GPa) represent the shallower and colder cratonic lithosphere. Mantle-derived high-MgO eclogitic clinopyroxenes show a light rare earth element (LREE)-enriched pattern (Ce/YbN = 60.90–93.63) while both clinopyroxene and garnet present high 87Sr/86Sr ratios (0.70842–0.70912) and negative εNd values (−5.6 to −7.3). These features, supported by the reconstructed whole-rock composition, suggest a mafic protolith probably metasomatized by fluid/melt derived from the overlying sedimentary rocks. Pargasite websterites are cumulates from an evolved (SiO2-rich) and hydrated basaltic andesitic magma. These xenoliths are characterized by high concentration of LREE relative to heavy-REE (HREE) in clinopyroxene (Ce/YbN = 10.52–50.61) and pargasite (Ce/YbN = 10.26–57.06), and by the presence of Al-rich orthopyroxene. As observed in eclogites, clinopyroxene and garnet from pargasite websterites display high 87Sr/86Sr ratios (0.70894–0.71094) and strong negative εNd values (−7.2 to −13.3). Trace elements (i.e. Zr, Ti, and Y) in garnets of both rock types indicate the role of a depleted component affected by a metasomatic agent. Although we were unable to date the formation of these rocks or the metasomatic events, we suggest a possible relationship with the consolidation of Gondwana during the Neoproterozoic. Sheared lherzolites, clinopyroxenites, anhydrous websterites, and dunite are deeper fragments from the lithosphere-asthenosphere boundary (LAB: 1191–1290°C; 5.3–5.6 GPa). They have abundant kelyphitic rims around garnet grains, which indicate metasomatism promoted by the percolation of a high-temperature proto-kimberlite melt enriched in Ti, Zr, and Y. The presence of kelyphitic phlogopite with high-Ti-Cr contents reinforces this assumption. LREE-enriched clinopyroxenes (Ce/YbN = 12.06–48.02) confirm the enriched character of the silicate melt responsible for the refertilization process within the cratonic root. The proto-kimberlite metasomatism is further supported by the preferential enrichment of 87Sr/86Sr ratios (0.70560–0.70869) accompanied by positive εNd values (+1.8 to +10.10). Two-point clinopyroxene-garnet Sm–Nd isochrons yielded an average age of 120 ± 5 Ma, representing the kimberlite eruption/emplacement age of the host kimberlite. These deeper LAB xenoliths reveal intense lithospheric thinning triggered by percolation of a high-temperature proto-kimberlite melt since the early stages of Gondwana break-up during the Cretaceous, shortly before the kimberlite emplacement at 120 Ma. Therefore, they provide remarkable evidence of the destruction of the São Francisco Craton through thermal-mechanical erosion that triggered its rejuvenation. [ABSTRACT FROM AUTHOR]

This paper describes secondary crystallized melt inclusions trapped in magnesiochromite of lherzolite xenolith from the V. Grib kimberlite pipe (Arkhangelsk diamondiferous province). It is shown that the inclusions are microportions of melt related to magmatism, which was further formed this pipe. Daughter minerals assemblage of inclusions in magnesiochromite contain Na‒K‒Ca-, Na‒Mg-, Ca‒Mg-, Mg-, and Ca-bearing carbonates; Na–Mg carbonates with additional PO , Cl–, and SO anions; chlorides; sulfate; phosphate; and silicate. The mineral assemblage of daughter phases, the amount of carbonates (77 vol %) and silicates (tetraferriphlogopite) (15 vol %) and Ca : Na : K ratios within the inclusions indicate that this melt was an alkali-enriched carbonate liquid with a low content of SiO2 (≤6 wt %) and H2O (≤0.6 wt %). As is known, serpentine in kimberlites is a major H2O-bearing mineral, but the problem of water sources during serpentinization of kimberlites and an actual H2O content in kimberlite melts is a controversial issue. The absence of serpentine and the low H2O content (≤0.6 wt %) of the studied melt inclusions in comparison with those of kimberlites of the V. Grib kimberlite pipe (10‒14 wt %) indicate the key role of external fluids during serpentinization of these kimberlites. [ABSTRACT FROM AUTHOR]

This paper presents the reconstruction of the architecture of the lithospheric mantle, including its thermal state and thickness, as well as the scale and efficiency of its sampling by four kimberlites from the Arkhangelsk diamondiferous province: Arkhangelskaya, Lomonosovskaya, V. Grib, and TSNIGRI-Arkhangelskaya. These kimberlites differ in terms of their composition, diamond content, and location. Data presented include the major-element composition of clinopyroxene xenocrysts (>2000 grains), P–T calculations from compositionally filtered Cr-diopside grains, and the reconstruction of local paleogeotherms. Additionally, we used available data on Ni content in peridotitic garnet xenocrysts to calculate their T values and project them onto local Cr-diopside-derived geotherms to reconstruct the vertical distribution of mantle xenocrysts and assess the efficiency of lithospheric mantle sampling by different kimberlites. We identified the presence of a >200 km-thick lithospheric mantle beneath the region at the time of kimberlite emplacement. We also found that the diamond content of the studied pipes was, to some extent, dependent on the following set of factors: (1) the thermal state of the lithospheric mantle; (2) the width of the real "diamond window" marked by mantle xenocrysts, especially by diamond-associated garnets; and (3) the efficiency of lithospheric mantle sampling by kimberlite. The results of this study can be used to inform diamond exploration programs within the region. [ABSTRACT FROM AUTHOR]

Abstract This article describes a novel dataset on non‐diamondiferous eclogite and garnet pyroxenite xenoliths from four kimberlite pipes of the Ekati Diamond Mine (Central Slave Craton, Canada). Xenoliths brought to the surface by kimberlite eruptions are direct sources of information on the composition and evolution of the Earth's mantle. Eclogite and garnet pyroxenite xenoliths, specifically, are testimony of subduction into, and metasomatism of, the mantle beneath cratons. Furthermore, these rocks are major hosts for diamond and thus an important part of the deep carbon cycle. The sample suite consists of 41 small xenoliths (2–5 cm) recovered from drill cores. The dataset includes major and trace element concentrations for garnet, clinopyroxene and ilmenite, as well as stable oxygen isotope compositions of garnets. Strontium and neodymium isotopic compositions are reported for garnet and clinopyroxene for four samples which were large enough to allow for analysis. Overall, this dataset significantly expands and complements existing datasets on diamondiferous and non‐diamondiferous xenoliths from the Slave Craton in Canada, furthering our understanding of the composition of the Slave subcratonic lithosphere. The dataset includes several samples with rare mineral assemblages, including an olivine‐bearing eclogite as well as ilmenite and apatite‐bearing garnet‐pyroxenites, and thus provides data shedding light on rarely reported compositional nuances in xenolith suites found in kimberlites.

The ∼ 1.15-billion-year-old (Ga) Premier kimberlite pipe (Cullinan diamond mine), South Africa, is composed of several distinct kimberlite facies (Grey, Brown, Pale Piebald, Dark Piebald, Black Coherent [Type 3C], Blue/Brown Transitional, and Fawn). We report bulk rock Re-Os isotope data for Premier kimberlite facies, as well as for a suite of entrained peridotite and mafic xenoliths. These data are complemented by bulk rock highly siderophile element (HSE: Re, Pd, Pt, Ru, Ir, Os), major- and trace-element abundances. Measured 187Os/188Os for the kimberlite facies range from 0.1223 to 0.1672 (γOs i of −2.5 to + 17.4), peridotite xenoliths range from 0.1096 to 0.1244 (γOs i of −13.3 to −1.1), and pyroxenite xenoliths range from 0.1796 to 0.938 (γOs i of + 27 to + 419). A single measured amphibolite xenolith has the most radiogenic measured 187Os/188Os of 2.86 (γOs i of + 43). Harzburgite xenoliths yield time of rhenium depletion model ages (T RD) of ∼ 1.5 to 2.8 Ga, consistent with average T RD ages for Premier peridotites (2.4 ± 0.4 Ga). With these and published data, we considered the relationships between kimberlite and mantle xenoliths, compare estimates of relative peridotite incorporation to sampled diamond grade, and explore recratonization versus refertilization arguments with regards to T RD model ages. Kimberlite melt infiltration into Premier peridotite xenoliths is evident from melt veins accounting for ∼ 2 and ∼ 14 modal % of samples, and has led to incompatible element enrichment, including elevated Re. In turn, kimberlites show geochemical evidence for addition of peridotite xenolith fragments, with Type 3C having > 30 % more peridotite contribution than the Brown volcaniclastic facies. Kimberlites and peridotites plot on a 187Re/188Os versus 187Os/188Os mixing line (R2 = 0.92), with kimberlites having older apparent ages than the true age of crystallization. This mixing line provides estimates of lithospheric incorporation into the kimberlites, where the units with higher peridotite incorporation do not correlate with diamond grade. This is likely due to lithological and post-emplacement alteration heterogeneity within the kimberlite units, perhaps also reflecting the eclogitic paragenesis of many Premier diamonds. The peridotites provide evidence for the nature of the lithosphere beneath Premier prior to ∼ 1.15 Ga. Metasomatism of the peridotites is possibly linked to the Bushveld Igneous Event at ∼ 2 Ga, as well as to other magmatic events that affected the Kaapvaal craton from the Archean to the Mesoproterozoic. Premier peridotites do not suggest that the cratonic lithosphere beneath the region was completely replaced. Samples with Proterozoic T RD eruption model ages may represent Archean lithosphere that experienced alteration by metasomatism and modification, such as during the Bushveld Igneous Event. [ABSTRACT FROM AUTHOR]

The lamprophyric rocks are uncommon volatile-rich melanocratic porphyritic rocks which contain only mafic phenocrysts. The felsic minerals are confined in the groundmass. They occur as dikes, sills and diatremes. The lamprophyric rocks are sometimes associated with diamond deposits. This review article discusses the ongoing debate in igneous petrology regarding the classification of lamprophyric rocks, specifically the Lamprophyre clan vs Lamprophyre facies problem. The background of this debate is rooted in conflicting interpretations of the classification of these rocks, with some researchers grouping them into a super-group called the “Lamprophyre clan” while others emphasize the distinction between the different types of these rocks (Lamprophyre facies). The aim of this study is to provide a comprehensive analysis of relevant literature and propose a more inclusive petrological classification system for lamprophyric rocks by considering the geological setting, petrography, texture, mineralogy, whole-rock geochemistry and isotopic analysis of the various kimberlites, orangeites, lamproites, para-lamproites, calc-alkaline, alkaline and ultramafic lamprophyres. Lastly, the diamond potential is also taken into account. The implications of this study are significant for the international geological community. It proposes the adoption by the IUGS TGIR of both the Lamprophyre clan (as updated by Kamvisis & Phani, 2022, i.e. genetically interrelated rocks) and Lamprophyre facies (as suggested by Mitchell, 1994, i.e. rocks that formed under volatile-rich conditions) concepts to achieve a more widespread consensus among igneous petrologists. Both terms can be correct but they represent different perspectives in the study of these exotic rocks.

The first results of mineralogical and geochemical studies of a unique xenolith of lithospheric mantle are presented illustrating the earlier non-described mineral association of quartz, Cr-pyrope and Cr-diopside. Structural and textural features of the sample suggest a joint formation of these minerals. The calculated P-T-parameters of the formation of Cr-diopside indicate the capture of xenolith from the depth interval ~ 95-105 km (31-35 kbar) corresponding to the stability field of coesite. This suggests that quartz in the studied xenolith can represent paramorphs after coesite. It was shown that quartz in this rock is not a product of postmagmatic processes. The transformation stage of the source lherzolite into garnet- and clinopyroxene-enriched rock/garnet pyroxenite as a result of exposure to a high-temperature silicate melt was reconstructed. Subsequent stages of the influence of metasomatic agents were identified by the presence of a negative Eu-anomaly in some garnet grains, which could result from the impact of subduction-related fluid and the enrichment of rock-forming minerals with light rare earth elements, Sr, Th, U, Nb and Ta as a consequence of fluid saturated with these incompatible elements. Several models for the formation of SiO2 phase (quartz/coesite) in association with high-chromium mantle minerals are considered including carbonatization of mantle peridotites/eclogites and melting of carbonate-containing eclogites at the stage of subduction and the impact of SiO2-enriched melt/fluid of subduction genesis with peridotites of the lithospheric mantle.

Abstract—The capabilities of a combination of passive seismic methods to study the geological structure of the upper part of the Earth's crust compared to active methods are analyzed using case examples. The passive methods include microseismic sounding, Nakamura's horizontal-to-vertical spectral ratio method (HVSR), seismic interferometry, and, for anthropogenic sites, ambient vibration testing using industrial signals. Three examples are considered: a zone of a platform tectonic earthquake, a kimberlite pipe, and a hydroelectric dam with foundation site. The results of the passive and active seismic methods agree well. Passive methods give more diffuse horizontal boundaries but clearly identify near-vertical heterogeneities. Combining passive methods is effective for reconnaissance studies and in the remote regions that are difficult to access by active observation techniques. Combination of passive methods enables simultaneous processing of seismic records obtained through different passive methods, with a minimum of two sensors required. [ABSTRACT FROM AUTHOR]

The results of U–Pb Isotope Dilution Thermal Ionization Mass Spectrometry (ID-TIMS) geochronological studies of perovskite from kimberlite rocks of the Manchary pipe (Khompu-Maya kimberlite field, Central Yakutia) are reported. The obtained U–Pb age (472 ± 1 Ma) indicates the Early Paleozoic age of the formation of the Khompu-Maya field kimberlites and allows us to identify a new Aldan kimberlite subprovince within the Aldan anteclise. [ABSTRACT FROM AUTHOR]

The observation of photosynthetic biofilms growing on the Fine Residue Deposit (FRD) kimberlite produced by the Venetia Diamond Mine, Limpopo, South Africa suggests that processed kimberlite supports bacterial growth. The presence of this biofilm may aid in the acceleration of weathering of this ultra-mafic host material - a process that can sequester CO2 via carbon mineralization. Laboratory and field trial experiments were undertaken to understand the microbe-mineral interactions occurring in these systems, and how these interactions impact geochemical cycling and carbonate precipitation. At laboratory scale it was discovered that using kimberlite as a growth supplement increased biomass production (up to 25-fold) and promoted microbiome diversity, while the inoculation of FRD systems aided in the aggregation, settling, and dewatering of kimberlitic slurries. Field trial studies combining photosynthetic biofilms (cultured in 3 × 1,000 L bioreactors) with FRD material were initiated to better understand microbially enhanced mineral carbonation across different depths, and under field environmental conditions. Over the 15-month experiment the microbial populations shifted with the kimberlitic environmental pressure, with the control and inoculated systems converging. The natural endogenous biosphere (control) and the inoculum accelerated carbonate precipitation across the entire 40 cm bioreactor depth, producing average 15-month carbonation rates of 0.57 wt.% and 1.17 wt.%, respectively. This corresponds to an annual CO2e mine offset of ~4.48% and ~ 9.2%, respectively. Millimetre-centimetre scale secondary carbonate that formed in the inoculated bioreactors was determined to be biogenic in nature (i.e., possessing microbial fossils) and took the form of radiating colloform precipitates with the addition of new, mineralized colonies. Surficial conditions resulted in the largest production of secondary carbonate, consistent with a ca. 12% mine site CO2e annual offset after a 15-month incubation period. [ABSTRACT FROM AUTHOR]

Textural, mineralogical and mineral compositional observations in a suite of Neoproterozoic aillikite and calcite kimberlite dykes from southern West Greenland point to consistent variations in melt major element compositions amongst these silica-undersaturated magma types. The aillikites have notably higher bulk SiO2/CO2, H2O/CO2 and K2O compared to calcite kimberlite. Bulk rock arrays, together with field and petrographic observations, emphasize that flow sorting of olivine and other crystalline phases during magma emplacement is important in controlling the compositions of individual samples from these ultramafic dykes. Flow sorting together with variable overall proportions of entrained lithospheric mantle material result in scatter on element–element plots, which makes the interpretation of regional scale major and trace element geochemical datasets difficult. We argue that a significant proportion of the regional Ni–MgO variation in the ultramafic dyke suite of SW Greenland is due to variation in the proportion of an entrained refractory lithospheric mantle component. Therefore, ratios of elements to MgO can be used as proxies for melt compositions. Ratios of SiO2, TiO2, Al2O3, FeO and K2O over MgO are systematically higher, and CO2/MgO lower, in aillikites compared to calcite kimberlites. The trace element patterns of the calcite kimberlite and aillikite dykes show strong similarities in incompatible element concentrations, resulting in overlapping ratios for the highly to moderately incompatible elements. However, differences in Zr-Hf concentrations between rock types imply differences in mantle source mineralogy. Guided by our observations, we present mixing models that demonstrate that partial flux-melting of phlogopite–ilmenite metasomes within the cratonic mantle lithosphere is capable of produce the geochemical characteristics of aillikites and mela-aillikites in West Greenland. Fusion of cratonic metasomes was initiated by infiltrating asthenosphere-derived carbonatitic melts previously identified as the parental liquids to calcite kimberlite. [ABSTRACT FROM AUTHOR]

Estimates of oxygen fugacity of eclogitic rocks are linked to the redox evolution of the oceanic protolith during subduction and its residence in the lithospheric mantle, and, based on knowledge of pressures and temperatures, allow modelling of the speciation of volatile elements and diamond (or graphite) versus carbonate stability. To date, the oxygen fugacity of mantle eclogites has been shown to vary between −6 (Kasai, Congo and Udachnaya, Siberia) and −0.1 (Udachnaya, Siberia) log units (relative to the fayalite–magnetite–quartz buffer, FMQ), linked to the low Fe3+ contents of garnets. In this study, we investigated the Fe oxidation state of coexisting garnet and clinopyroxene hand-picked out of 17 diamond-free high-MgO and low-MgO mantle eclogites (dated at 2.84 Ga) from the Grib kimberlite pipe (East-European platform). Measured Fe3+/∑Fe values range between 0.03 and 0.19 for garnet and 0.18–0.38 for clinopyroxene, the former being higher than what was measured previously in garnets equilibrated at mantle conditions. The Fe3+/∑Fe of the reconstructed bulk rock ranges between 0.10 and 0.15 for high-MgO eclogites and 0.10 and 0.24 for low-MgO eclogites (with uncertainties of ± 0.02 and ± 0.03 in both cases). Thermobarometric calculations result in equilibration pressures and temperatures of 3.0–5.2 (± 0.4) GPa and 720–1050 (± 60) °C for both high-MgO and low-MgO eclogites, slightly lower than previous P–T estimates of mantle eclogites from the Udachnaya kimberlite pipe (Siberian craton). At these conditions, ∆log f o2 (FMQ) calculated using the available oxythermobarometric model varies from −1.7 to −0.6 log units for high-MgO eclogites and from −2.9 to 0.9 log units for low-MgO eclogites. Samples recording ∆log f o2 (FMQ) ≤ −1 log units overlap with North Slave, West Africa and Udachnaya eclogites, with no difference among eclogite types. The average values of −1.2 (± 0.4) log units for high-MgO and −0.6 (± 1.1) log units for low-MgO eclogites suggest different redox conditions of basaltic protoliths during subduction worldwide. Previous geochemical studies on the same rock samples reported evidence of cryptic metasomatism in both garnet and clinopyroxene that we demonstrate being not recorded by their major elements, while modal metasomatism evidenced by the presence of phlogopite as a product of interaction with a kimberlitic melt only affects the MgO of the bulk rock. Therefore, we suggest that high Fe3+/∑Fe ratios for garnet (> 0.10) and for reconstructed bulk rocks in the case of both low-MgO and high-MgO samples cannot be due to metasomatic interaction with an oxidized fluid, but rather are the consequence of Fe3+ redistribution in an unusually oxidized mafic protolith upon metamorphism. Our results highlight the redox variability of eclogites of Archaean age at conditions more oxidized than present-day mid-ocean ridge basalts (MORBs) and imply an oxidizing nature of the convective mantle source where magma was formed with consequent speciation of C in the form of carbonate fluid explaining, therefore, the lack of eclogitic diamonds in V. Grib kimberlite pipe. [ABSTRACT FROM AUTHOR]

Koh-i-Noor and other world-famous diamonds such as Hope, Orloff, Great Mogul, Nizam, and Pitt, well-known in the industry as 'Golkonda Diamonds' are very well recognised for their rare colours, large carat sizes, and because of the paucity of nitrogen atoms majority of them have been classified as Type IIa diamonds. These renowned Golkonda diamonds were recovered from placers mined on the banks of the Krishna River in southern India; however, their primary source rocks (either kimberlites or lamproites) remain questioned and untraced. Precise identification of the primary sources of such large-sized, dominantly Type IIa diamonds (i.e., CLIPPIRS) is crucial for understanding their deep mantle origin, nature and timing of magmatism carrying them and essential from economic and geological perspectives. We employed a multidisciplinary approach incorporating xenocrystic mineral composition and bulk-rock geochemistry, field geological and remote sensing (GIS) studies to locate the probable primary sources of these renowned diamonds, know the origin of Type IIa Golkonda diamonds in southern India, and to understand the mechanism and timing of diamond transport and dispersal as placers in the Krishna River basin. Our study rules out the possibility of various lamproite occurrences of the Eastern Dharwar Craton and Banganapalle conglomerates as being sources of Koh-i-Noor and other Golkonda diamonds. The absence of Type IIa diamonds in the highly diamondiferous Late Cretaceous kimberlites of Wajrakarur likewise excludes them as source of Golkonda diamonds. Among southern India's two significant kimberlite fields, i.e., Wajrakarur and Narayanpet, compositions of indicator minerals from the Wajrakarur Kimberlite Field (WKF) reveal their ultimate diamond preservation potential, presence of strong diamondiferous mantle roots and deeper source regions, hence recognising them to be the potential sources of Golkonda diamonds. GIS and remote sensing tools were used to calculate moisture content, vegetation indices, and to locate paleo-channel of the Penner River, which was primarily responsible for the transportation of diamonds from their Mesoproterozoic (ca. 1.1 Ga) source rocks at Wajrakarur to their final sites of recovery, i.e., Kolluru and other mines situated on the banks of the Krishna River. The occurrence of alluvial placer deposits in Krishna River drainage system is analogous to the Orange River drainage system in South Africa. Both areas have diamonds sourced from primary kimberlite pipes, transported by rivers, and deposited in specific areas. Similarities in the origin, mechanism of diamond transport, dispersal and deposition have played a crucial role in significant diamond production from alluvial deposits in Krishna and Orange Rivers. [ABSTRACT FROM AUTHOR]

[Display omitted] • Definition of the thermal structure of the Brazilian SCLM using geothermobarometers. • Ultra-alkaline silicate metasomatism involved in deep Brazilian SCLM. • Shallow portion of Brazilian SCLM affected by silicate metasomatism. • Definition of hotter SCLM under Três Ranchos than Osvaldo França/Canastra. The thermal structure and chemical composition of the subcontinental lithospheric mantle beneath the Alto Paranaíba Igneous Province defined by the major and trace element compositions of garnet and clinopyroxene xenocrysts and mantle peridotite xenoliths entrained in the Cretaceous Três Ranchos kimberlite. Estimated temperatures and pressures indicate a typical cratonic geotherm, with a surface heat flow of ∼ 40 mW/m2 slightly hotter than that at the São Francisco Craton margin (35–36 mW/m2), suggesting lateral heterogeneities in the geothermal gradients. A deep mantle portion (160 km) is recorded by a lherzolite xenolith (5 GPa and 1200 °C). This portion has undergone pervasive interstitial melt percolation of an ultra-alkaline silicate melt and late injection of small silicate melt fractions such as the host carbonated kimberlite. This pervasive migration extended into shallower SCLM sectors at 124–100 km (3.9–3.1 GPa and ∼ 940–810 °C) as evidenced by metasomatized (±phlogopite) peridotite identified by sinusoidal REE garnet compositions. This portion is apparently intercalated at 120–110 km depth (3.7–3.3 GPa and ∼ 850 °C) with strongly depleted peridotites showing garnet and clinopyroxene compositions extremely impoverished in moderately incompatible elements, as a result of extreme ancient, melt extraction. Atop the metasomatized and depleted peridotites, at 100 km depth, a layer of fertile lherzolite is identified by garnet xenocrysts, with 'normal', HREE-enriched, steadily fractionated LREE-depleted patterns. Combining our data with those of the Osvaldo França SCLM points to the occurrence of a deeper sector (>100 km depth beneath Trȇs Ranchos) originally formed by extremely depleted peridotites, successively metasomatized by ultra-alkaline melts; and a shallower sector of the São Francisco craton composed of fertile lherzolites unrelated to ultra-alkaline magmatism. Similar fertile lherzolites are found in the uppermost sectors of the Siberian and Kaapval SCLM, suggesting that they may be a ubiquitous, primary feature, possibly related to the stabilization of the Archean cratons. [ABSTRACT FROM AUTHOR]

The "National Diamond Exploration Field Seminar" held by China Geological Survey in Suzhou, Anhui in 2013 kicked off a new round of primary diamond deposits exploration in China. In the past decade, a series of new progress in the exploration and research of primary diamond deposits have been made: the new batch of primary diamond resources identified in Langan, Anhui and Wafangdian, Liaoning further enhanced domestic supply ability of diamond resources. The VI diamond mineralization belt in Liaoning, the Pingyi-Feixian diamond mineralization belt in Shandong and new prospecting clues in Other regions will expand the exploration spaces of primary diamond deposits. The comprehensive exploration methods such as tectonic analysis-3D modeling-engineering verification, and high-resolution remote sensing information extraction are new exploring ideas for deep exploration and the discovery of hidden rock bodies. New insights in the genesis of diamond-bearing rock bodies, the emplacement model of kimberlite (potassium magnesium lamprophyre), and the study of diamond source area have been acquired. The chronological studies have shown that the mineralization of diamond-bearing parent rock in China extends from the Paleozoic to the late Mesozoic, which embodies the feature of multi-stage metallogenesis. Based on the progress and new problems in diamond exploration and research in the past decade, the suggestions for future exploration and research of primary diamond deposits is also proposed in the paper. [ABSTRACT FROM AUTHOR]

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Rare-Earth Elements (REE) are key geochemical tracers of crust–mantle differentiation, but there are few direct data on REE-rich minerals in mantle rocks. Here, we report the combined petrography and comprehensive chemical and isotopic characterization of three coesite- and kyanite-bearing eclogite xenoliths from the Udachnaya kimberlite pipe (Siberian craton), which are unusual in that two xenoliths (one with diamond and graphite) contain discrete, idiomorphic crystals of allanite at the grain boundaries of garnet and omphacite. Another xenolith contains allanite as part of a complex aggregate of calcite, apatite, barite, and celestine hosted by serpentine, which is a low-temperature secondary minerals likely result from metasomatic reaction at shallower depths during the transport of eclogite by the erupting kimberlite melt. The bulk rock composition reconstructed from the trace element composition of garnet and omphacite show marked depletion in LREE, precluding equilibration with kimberlite melt, whereas the measured bulk compositions show chondrite-normalized REE patterns with conspicuous depletions of Ce–Pr–Nd relative to La and Sm. The presence of 0.005 to 0.008 wt % of allanite, texturally and chemically out of equilibrium with the rock-forming minerals, allows balancing the LREE and Sm–Nd budget of the rock, whereas Th and U require additional hosts. This not only highlights the utility of measuring bulk eclogite xenoliths in bringing this unusual component to light, but also demonstrates that the long-known incompatible element enrichment in bulk eclogites reflects the deposition of discrete phases rather than merely bulk kimberlite melt addition. Although allanite is stable in metabasalts at the pressure–temperature conditions of 1025°C to 1080°C and 3.6 to 4.8 GPa recorded by the eclogite xenoliths, its association with Ba-Sr minerals suggests its formation via reaction of the host eclogites with kimberlite melt. This is supported by the similarity in 143Nd/144Nd ratios between bulk eclogite (0.51227–0.51249) and the host kimberlite at eruption, whereas clinopyroxene in part retains unradiogenic Sr (87Sr/86Sr = 0.70205 ± 0.00011) related to ancient depletion. The discovery of allanite in the Udachnaya eclogites demonstrates that this REE mineral can form when omphacite and grossular-rich garnet in eclogite breakdown in contact with REE- and alkali-rich carbonatite/kimberlite melt, and may be more common than hitherto recognized. Crystallization of allanite in the cratonic mantle eclogite reservoir may also help explain the difference in LREE abundances between the more strongly enriched carbonatite/kimberlite at depth and the final erupted product. It is likely that allanite is overlooked at eclogites xenoliths, while it is common accessory mineral, hosting REE in orogenic UHP/HP eclogites. Further studies are required to deciphered the peculiarities in metamorphic history recorded in eclogites xenoliths and orogenic eclogites, as well as the differences ancient (Archean/Proterozoic) and Phanerozoic subduction processes. [ABSTRACT FROM AUTHOR]

This study presents the first comprehensive investigation of perovskite from its type locality (Mineral Mines of Southern Urals, Russia), where this mineral was first described by Gustav Rose in 1839. The new data includes results from precise chemical analyses (electron-probe microanalyzer, LA-ICP-MS) and U-Pb ages (SHRIMP-II) of perovskite. Perovskite occurs in silicate-carbonate veins that transect the marginal parts of the Middle Riphaean Kusinsko-Kopanskaya layered intrusion, previously thought to be skarns. The perovskite crystals range from micrometer-scale grains to up to 11 cm in size. Chemical investigations revealed a low content of trace elements (rare earth elements, Y, Nd, U, Th) compared to perovskites from alkaline ultramafic rocks, silica-undersaturated basic rocks, carbonatites, and kimberlites. The determined age of the perovskite, 535 ± 43 Ma, significantly differs from the 1379 ± 8 Ma age of the Kusinsko-Kopanskaya intrusion, challenging the skarn-origin hypothesis for perovskite. Instead, the findings suggest a carbonatite origin for the perovskite mineralization. This timing indicates a previously unknown stage of endogenic activity on the Western Slope of the Southern Urals. [ABSTRACT FROM AUTHOR]

Syn-emplacement serpentine is one of the most abundant late minerals in kimberlites; its multiple generations can be distinguished by various textural positions and parageneses. Composition of the primary kimberlite melt cannot be accurately determined if we do not recognize distinct origins for several textural varieties of serpentine. This study aims to find compositional indicators of the serpentine origin by characterizing millimetre-sized serpentine domains in hypabyssal kimberlites. Serpentine forms as segregations in the groundmass or when serpentine replaces olivine or metasomatized silicate xenoliths. The latter textural variety of serpentine has not been recognized previously; it develops in Si-rich basement xenoliths ranging from basalt to granite. This serpentine is associated with abundant diopside, pectolite, phlogopite and chlorite and less prominent amphibole, hydrogarnet, wollastonite, xonotlite and other rare Ca hydrosilicates. We report petrography and textures of reacted silicate xenoliths in Renard 65, Orapa AK15, BK1, Gahcho Kué 5034 and Jericho kimberlites and provide a global summary of the phase compositions in the xenoliths. This study discovered that NiO content < 0.05 wt %, Al2O3 content > 1.3 wt % and MnO > 0.3 wt % in serpentine are clear signs of formation after felsic xenoliths. Serpentine/chlorite replacing olivine always have 1.5–4 wt % more FeO than serpentine after silicate xenoliths. The compositional contrast results from the immobile behaviour of conserved Al, Ni and Mn. The proposed criteria were tested on a pyroclastic kimberlite with an enigmatic origin of round serpentinized clasts overgrown by fibrous clinopyroxene and identified the precursor of these clasts as felsic. We also determined mineralogical characteristics of serpentine parageneses that can be used for reconstruction of the initial xenolith lithology. Serpentine coexists with the more abundant calcic hydrosilicates (hydrogarnet, xonotlite, amphiboles) in reacted mafic xenoliths. There, serpentine and chlorite crystal structures show less ideal stoichiometry indicative of a higher volume of nanometre-scale interstratification with smectites. Serpentine-rich assemblages in reacted xenoliths formed metasomatically at T < 600°C due to skarn-like mass transfer with the host kimberlite that controlled the gain of Ca and Mg and desilication. These metasomatic assemblages are remarkably identical to rodingites. Serpentine production appeared to be limited by the availability of Si in and around silicate xenoliths, but by the H2O availability in pseudomorphed olivine/monticellite. [ABSTRACT FROM AUTHOR]

[Display omitted] • Diamondiferous kimberlites in the southern part of Siberian craton characterized by high TiO 2 and high mg# values in garnet xenocrysts. • Titanium in garnets is indicator of inhomogeneous composition of sub-continental lithospheric mantle. • High-Ti in garnets and high-Ti in kimberlites are result of asthenosphere activity SCLM under northern part of Siberian craton is generally poor in Ti. This contribution reports some 16,000 major and minor element analyses of garnet xenocrysts derived from 18 (out of the 21 known) kimberlite fields of the Yakutian Kimberlite Province (YaKP) on the Siberian craton in Russia. Using TiO 2 –in–garnet as an indicator of heterogeneity within the subcontinental lithospheric mantle (SCLM), as well as garnet mg# (mg#=Mg2+/(Mg2++Fe2+)*100), we distinguish three subpopulations of garnet: 1) high content of TiO 2 (0.26–0.50 wt%) and high mg# (80.6–82.6) garnet xenocrysts are common in the southern diamondiferous kimberlite fields; 2) garnet xenocrysts with low content of TiO 2 (0.06–0.26 wt%) and relatively high values of mg# (78.8–81.7), which prevail in the northern 'barren' kimberlite fields; and 3) three anomalous northern kimberlite fields (Chomurdakh, Ogoner-Yuryakh, Toluopka) characterized by the predominance of garnet xenocrysts with high TiO 2 content (0.53–0.78 wt%) at relatively low mg# (76.9–78.3). It is reasonable to assume that relatively thin cratonic mantle lithosphere beneath the three anomalous kimberlite fields underwent intense metasomatic overprinting by melts and fluids injected from the underlying asthenosphere, which changed the compositions of peridotitic garnets significantly. An interpretation of the data presented in this study is that the generally high TiO 2 contents of kimberlites in the northern YaKP (>1.5 wt% TiO 2) are a primary magmatic feature of asthenospheric origin because the lithospheric mantle traversed by these kimberlite magmas is TiO 2 depleted. We propose a model in which the relatively thin SCLM of the northern Siberian craton provided less opportunity for high-TiO 2 asthenospheric kimberlite melts to interact and change compositions on their way to the Earth's surface. The high-TiO 2 kimberlites of the northern YaKP may thus represent a good approximation of the primary compositions of natural kimberlite melts. [ABSTRACT FROM AUTHOR]

Rehabilitation strategies for degraded mine dumps have generally seen limited success due to different complications associated with mining biophysical disturbance. In this study, we tested a combination of two methods to expedite revegetation of kimberlite tailings at Letseng Diamond Mine (i.e., in the Afro‐alpine areas of Lesotho). We ran trials on different growth media located on fine and coarse kimberlite tailings (i.e. sites) mixed with different substrate combinations and topsoil and sowing a seed mix comprised of native plant species. Overall, as predicted, fine kimberlite tailings displayed significantly higher plant abundance than coarse kimberlite tailings, and sown seeds performed significantly better than spontaneous colonisation by emerging species. Kimberlite tailings mixed with topsoil (100 mm) showed significantly greater plant abundance, and similarly, when coarse kimberlite tailings were introduced to fine tailings. Physicochemical analyses of growth media components suggested that topsoil provided additional nutrients and that plants could readily access available nutrients in the fine kimberlite tailings. We noted a gradual significant increase in plant abundance over 5 years, enhanced by new plant species emerging from the topsoil seed bank or by natural seed dispersal. Although plant abundance differed significantly, both fine and coarse kimberlite tailings displayed high plant species diversity (H = 3.4 and D = 0.95 and H = 3.5 and D = 0.95, respectively). Out of 36 emerging plant species, 15 species spontaneously colonised both growth media. The significant variation in abundance among plant species between treatments was mostly attributed to dominant forb species, namely Chrysocoma ciliata, Glumicalyx montanus, Oxalis obliquifolia, Senecio inaequidens and Trifolium burchellianum. We have identified suitable growth media for plant community restoration on kimberlite tailings in the Drakensberg alpine area using a seed mix of native plant species in combination with natural seed dispersal from the surrounding pristine environment. We provide evidence for using two complementary approaches to optimise native plant community development during restoration in the Drakensberg alpine area. [ABSTRACT FROM AUTHOR]

With the diversification of remote sensing sensors and the improvement of remote sensing data processing, the in-situ, fast, and effective characteristics of remote sensing technology make it an important technical means for mineral exploration. Remote sensing ore-prospecting model is used to construct the prospecting information and geological prospecting by remote sensing data, which is widely used in mineral resources exploration, but seldom applied in diamond deposits. Diamond deposit of Xiyu kimberlite belt in Mengy in area of Shandong, was taken as a case study, and the samples of kimberlite body(vein)in Hongqiminning area were tested by short-wave infrared spectroscopy, the composition and spectral characteristics of altered minerals were analyzed.The results show that there are absorption valley at the wavelength 1391, 1912, 2318 and 2393n min Hongqimining area. The principal component analysis(PCA)is used to extract alteration information from ASTER remote sensing data, according to the characteristics of alteration minerals. So the abnormal information of magnesium hydroxyl, aluminum hydroxyl and iron staining from ASTER remotesensing data is extracted. The structure, lithology and water system are interpreted by using PALSAR radar remote sensing data and WorldView-2 high-resolution remote sensing data. Kimberlite is distributed at the intersection of northeast and northwest structures. False alteration remote sensing anomalies caused by erosion and sedimentation through water system could be excluded. Boundaries of lithological differences could be tighten through remote sensing lithological enhancement. By the comprehensive analysis of alteration information, structures, regional geology, geochemical and heavy sand anomaly, etc., the ore-prospecting model is constructed and six exploration targets are figured out, which provide a basis for diamond prospecting and mineral resources evaluation. [ABSTRACT FROM AUTHOR]

Diamondiferous kimberlites occur in the Wafangdian area in the eastern part of the North China Craton (NCC). In order to better constrain their magmatic source and emplacement time, we have investigated apatite from two kimberlites, i.e., the #110 dike kimberlite and the #50 root-zone kimberlite by measuring in situ their U–Pb and Sr–Nd isotopic compositions. The crystallization ages of the #110 and #50 apatites are 460.9 ± 16.8 Ma and 455.4 ± 19.3 Ma, respectively. For the #50 apatite, 87Sr/86Sr = 0.70453–0.70613 and εNd(t) = −2.74 to −4.52. For the #110 apatite, 87Sr/86Sr = 0.70394–0.70478 and εNd(t) = −3.46 to −5.65. Based on the similar distribution patterns of the rare earth elements (REEs) and the similar Sr-Nd isotope compositions of the apatite, it is believed that the #110 and #50 kimberlites have the same source region and the kimberlite magmas in Wafangdian were derived from an enriched mantle source (EMI). The primary magmatic composition has little effect on the emplacement pattern. It is more likely that the geological environment played an important role in controlling the retention and removal of volatile components (H2O and CO2). This led to the different evolutionary paths of the kimberlite magma in the later period, resulting in differences in the major element compositions of the apatite. High Sr concentrations may be associated with hydrothermal (H2O-rich fluid) overprinting events in the later magmatic period; the higher light rare earth element (LREE) concentration of the #50 apatite reflects the involvement of the REE3+ + SiO44− ⇔ Ca2+ + PO43− replacement mechanism. Two emplacement patterns of the #110 dike kimberlite (#110 apatite, low Sr, and high Si) and the #50 root-zone (#50 apatite, high Sr, and low Si) kimberlites were identified via major element analysis of the #110 apatite and #50 apatite. [ABSTRACT FROM AUTHOR]

Juína is the second-largest diamond-producing municipality in Brazil and is globally known for its outstanding sublithospheric diamond occurrences in both placer and kimberlite-hosted deposits. However, the scarcity of petrological data for Juína kimberlite pipes hampers understanding the nature and mantle source of these primary diamond sources in this region. Here, we present a textural and mineralogical study of ten kimberlite pipes from the Juína area. Based on petrographic features and mineral compositions, we interpret the studied Juína pipes as archetypal kimberlites with pyroclastic emplacement styles filled with resedimented volcaniclastic kimberlite and Kimberley-type pyroclastic kimberlite variants. The composition and texture of the magmatic phases, particularly spinel and phlogopite, suggest crystallisation from kimberlite sensu stricto magmas. The presence of high-Na eclogitic garnets and the absence of high-Cr low-Ca G10 garnets within the mantle xenocryst suite suggest the likelihood of eclogitic diamonds among Juína's lithospheric diamond populations. The Zr and Y contents, Ti/Eu and Zr/Hf ratios in the peridotite garnets, and Zr contents, Ca/Al, LaN/YbN (primitive-mantle normalised), Ti/Eu, and Zr/Hf ratios in the clinopyroxenes suggest a solid connection to kimberlite melt-related mantle metasomatism. Thermobarometry calculations indicate a relatively narrow stability window (825–936 ºC and 32–36 kbar) for lithospheric diamonds in the Juína region. Our findings have important implications for regional diamond exploration programs, shedding light on the primary sources of Juína's diamonds and contributing to understanding the deep geological processes in the underlying lithospheric mantle beneath the Amazonian craton. [ABSTRACT FROM AUTHOR]

The observation of photosynthetic biofilms growing on the Fine Residue Deposit (FRD) kimberlite produced by the Venetia Diamond Mine, Limpopo, South Africa suggests that processed kimberlite supports bacterial growth. The presence of this biofilm may aid in the acceleration of weathering of this ultra-mafic host material – a process that can sequester CO2 via carbon mineralization. Laboratory and field trial experiments were undertaken to understand the microbe–mineral interactions occurring in these systems, and how these interactions impact geochemical cycling and carbonate precipitation. At laboratory scale it was discovered that using kimberlite as a growth supplement increased biomass production (up to 25-fold) and promoted microbiome diversity, while the inoculation of FRD systems aided in the aggregation, settling, and dewatering of kimberlitic slurries. Field trial studies combining photosynthetic biofilms (cultured in 3 × 1,000 L bioreactors) with FRD material were initiated to better understand microbially enhanced mineral carbonation across different depths, and under field environmental conditions. Over the 15-month experiment the microbial populations shifted with the kimberlitic environmental pressure, with the control and inoculated systems converging. The natural endogenous biosphere (control) and the inoculum accelerated carbonate precipitation across the entire 40 cm bioreactor depth, producing average 15-month carbonation rates of 0.57 wt.% and 1.17 wt.%, respectively. This corresponds to an annual CO2e mine offset of ~4.48% and ~ 9.2%, respectively. Millimetre-centimetre scale secondary carbonate that formed in the inoculated bioreactors was determined to be biogenic in nature (i.e., possessing microbial fossils) and took the form of radiating colloform precipitates with the addition of new, mineralized colonies. Surficial conditions resulted in the largest production of secondary carbonate, consistent with a ca. 12% mine site CO2e annual offset after a 15-month incubation period.

One of the research areas focused on improving the efficiency of diamond-bearing kimberlite beneficiation processes involves the utilization of technology aimed at enhancing the recovery of weakly and anomalously luminescent diamonds during the X-ray luminescence separation process using luminophore-containing chemical agents. The objective of this research was to select the optimal composition of agents that modify the spectral characteristics of minerals and the conditions for their application. A crucial factor for process efficiency is the effective attachment of modifying agents to diamond crystals while avoiding similar attachment to kimberlite mineral surfaces. This is achieved through the use of organic collectors with an optimal composition, characterized by their ability to both adhere to the diamond surface and retain inorganic luminophore grains. The evaluation of luminophore attachment efficiency was performed using visiometric analysis in the UV range. The capability of diamonds to retain luminophore collector droplets or films on their surfaces was evaluated using a technique to measure the three-phase limiting wetting angle. The spectral and kinetic characteristics of diamonds and their recovery during the X-ray luminescence separation process were determined using a separator “Polyus-M”. The feasibility of purposefully modifying the spectral characteristics of weakly and anomalously luminescent diamonds through luminophore-containing compositions based on zinc sulfides and zinc orthosilicate has been confirmed through the conducted studies. By considering the criterion of selectivity in the attachment of luminophore emulsion to diamonds and kimberlite minerals, calculated based on the measured surface concentrations of luminophores on the minerals, the optimal ratios between the masses of inorganic luminophore, organic collector, and the aqueous phase of the emulsion were determined. Dispersing agents that offer selective binding of luminophores to diamond crystals were identified, and rational parameters for the composition of the organic collector were established. The temperature range for treating diamond-containing material was defined. As a result of bench testing the modifying agents with the selected composition and conditions for their application in the diamond-containing material treatment cycle before XRF separation, it was confirmed that the recovery of anomalously and weakly luminescent diamonds could exceed 90%, while keeping the yield of kimberlite minerals in the concentrate below 1%.

Phlogopite is a crucial indicator for effectively constraining the magmatic evolution and emplacement mechanism of kimberlite. In this study, samples were collected from the No. 110 kimberlite pipe within diamond belt I and the No. 50 kimberlite pipe within diamond belt II in the southern Liaoning diamond mining area in the eastern North China Craton (NCC). Zonation is highly developed in the phlogopite; the major and trace element compositions of the phlogopite zonation in the samples were analyzed. In this study, phlogopite from the No. 50 pipe kimberlite (#50 phlogopite) zonation is divided into the following components: (1) The cores, low Ti-Cr xenocryst, average Mg# = 90.6, has a resorption structure, the presence of serpentine and talc minerals in low Ti-Cr cores (xenocrysts) can be used as evidence for hydrothermal metasomatism; (2) cores/inner rims (between core and outer rim), high Ti-Cr, it is thought to be related to the assimilation of mantle materials by deep kimberlite magma, average Mg# = 88.2; (3) outer rims, low-Cr/Cr-poor, average Mg# = 82.4, Fe, Al and Ba contents increased, and there was a trend of evolution to biotite composition believed to be related to the metasomatic metamorphism of melt and wall rock during the late magmatic evolution or ascent; (4) rinds, it is characterized by re-enrichment of Mg, rind I (low-Ti-Cr, average Mg# = 88.4), rind II (high-Ti-Cr, Mg# = 88.6), rind II may be formed earlier than rind I. Rind is very rare and has been reported for the first time in southern Liaoning kimberlite. This study was only accidentally found in the outermost part of #50 phlogopite, the Mg-rich feature represents an environment in which oxygen fugacity has increased. The phlogopite in samples from pipe No. 110 (#110 phlogopite) exhibits relatively homogeneous characteristics across different zones and is more enriched in Al and Ba, which is likely the result of mantle metasomatism. Due to its euhedral characteristics and limited composition variation, it is considered that #110 phlogopite is more likely to be derived from direct crystallization from magma than from xenocrysts. In addition, based on the simultaneous enrichment of Al and Fe in phlogopite from the core to the outer rim, pipe No. 50 was determined to be a micaceous kimberlite, while pipe No. 110 more closely resembles group I kimberlites. This paper proposes that successive pulses of kimberlite magma emplacement gradually metasomatized the conduit, and subsequent kimberlite magma ascended along the metasomatized conduit, thereby minimizing the interaction between the later magma and the surrounding mantle lithosphere. [ABSTRACT FROM AUTHOR]

The continental lithospheric mantle (CLM) beneath the southern margin of the Congo craton has remained elusive, mainly because of the thick Phanerozoic sedimentary cover concealing possible kimberlite and lamproite diatremes. In this study, we explore this lithospheric mantle section using major and trace element compositions of mantle-derived clinopyroxene and garnet xenocrysts from kimberlites of the ca. 84 Ma Nxau Nxau cluster in northwest (NW) Botswana, which is part of the poorly known Xaudum kimberlite province extending into northern Namibia. We utilize these data to better understand the thermal and compositional evolution of the lithospheric mantle at the southern margin of the Congo craton. The clinopyroxene population (83 individual grains) comprises Cr-rich and Cr-poor diopsides with variable major (Al2O3, Na2O, Mg#) and incompatible trace element (U, Th, Zr, Hf, Nb, Ta, REEs) compositions. The large garnet population studied (496 individual grains) is dominated by lherzolitic G9 (38%) and 'megacrystic' G1 (41%) compositions, with minor contributions from Ti-metasomatized G11 (7%) and eclogitic G3 (6%) cratonic mantle sources. Harzburgitic G10 garnet is very rare (two grains only), consistent with a lherzolite-dominated CLM section in a craton margin position. The eclogitic garnet population has compositions similar to garnet from high-Mg cratonic mantle eclogite xenoliths, and such compositions have recently been interpreted as metasomatic in origin within the mantle xenoliths literature. Pressure–temperature calculations using the single-grain clinopyroxene technique reveal a relatively cold cratonic geotherm of 37–38 mW/m2 for the study region during the Late Mesozoic. For peridotitic garnets, projections of calculated Ni-in-garnet temperatures onto the independently constrained regional conductive geotherm suggest that lherzolite dominates at <145 km depth, whereas high-Ti lherzolitic G11 garnets and 'megacrystic' G1 garnets originate mostly from greater depths, reaching down to the lithosphere base at 150 to 210 km depth. The apparent confinement of 'megacrystic' G1 garnet to the bottom of the lithosphere suggests formation from infiltrating asthenosphere-derived proto-kimberlite liquids during melt–rock interactions. In general, the data suggest that the CLM beneath NW Botswana is depleted to about 145 km depth, and between 145 and 210 km depth, a thick metasomatized layer is identified, representing the transition into the underlying asthenosphere. A relatively thin lithosphere beneath NW Botswana is consistent with the proposed craton margin setting, especially when compared with the thicker cratonic roots beneath the central regions of the Congo and Kalahari cratons in Angola and South Africa, respectively, reaching down to 250 km depth and possibly even deeper. The compositional dissimilarity between the deepest-derived garnets from kimberlites in NW Botswana (i.e. from the diamond stability field) and garnets that occur as inclusions in diamond from cratons worldwide suggests extensive overprinting of the lowermost cratonic lithosphere by oxidative melt-related metasomatism. This finding, together with the very low diamond grades of the Xaudum kimberlites, points to a diminished diamond potential of the large and mostly unexposed 'cratonic' region (e.g. covered by thick desert sand) located between the major diamond mining districts of the Congo craton to the north (e.g. Catoca) and the Kalahari craton to the south (e.g. Orapa and Jwaneng). [ABSTRACT FROM AUTHOR]

The 40Ar/39Ar age is determined for K-bearing minerals from high-K nepheline syenite (rischorrites), liebenerite and carbonatized nepheline syenite, and pseudoleucite syenite of the Bogdo alkaline massif (Arctic Siberia). The polychronous formation of alkaline complexes of the Tomtor type at the Paleozoic stage is revealed from summarizing and analysis of the 40Ar/39Ar age data on the thermochronological diagram for minerals of rocks of the Tomtor massif, Udachnaya–Vostochnaya kimberlite pipe, and alkaline rocks of the Bogdo massif. The isotopic data indicate a complex three-stage evolution of rocks of the massif with the most productive Late Devonian–Early Carboniferous rare metal–rare earth element mineralization. The Devonian stage of the formation of the Tomtor and Bogdo massifs is related to the impact of the Vilyui plume on the eastern margin of the Siberian Craton. A similar age range is registered during the formation of rocks of the Kola alkaline province. [ABSTRACT FROM AUTHOR]

Ancient orogens within the supercontinent like Columbia can remain stable evolution as long as the cratons. What kind of lithospheric mantle was beneath those orogens and how it evolved into a stable state are still enigmatic. The Trans‐North China orogen (TNCO) is one of the typical collisional orogens within the Columbia supercontinent and was formed at ca. 1.85 Ga. Our work reveals that a cluster of kimberlites intruded the orogenic belt at ca. 1.54 Ga. These rocks were originally generated under a thick lithosphere (>200 km). Their entrained olivine cores show a composition of overlapping olivines from refractory mantle peridotites. The results suggest a thick and refractory lithospheric mantle beneath the TNCO at ca. 1.54 Ga. Such craton‐like property may result from large volume melt extraction from the lithospheric mantle, possibly caused by the ca. 1.78 Ga large igneous event, which eventually induces the long‐term stability of the TNCO during the subsequent supercontinent cycle. [ABSTRACT FROM AUTHOR]

Xenoliths in kimberlites are the most promising material for studying the composition and structure of the lower levels of the continental crust. This study is aimed at the estimation of P–T parameters and fluid regime of metamorphism for garnet–biotite–feldspar and orthopyroxene–garnet–biotite–feldspar rocks found as xenoliths in kimberlites of the Yubileynaya and Sytykanskaya pipes, Yakutian kimberlite province. The seven studied samples show inverse dependences of relative contents of garnet and orthopyroxene, orthopyroxene and biotite, garnet and plagioclase, plagioclase and potassium feldspar. This indicates a consistent series of transformations of the assemblage garnet + plagioclase + orthopyroxene ± quartz to the assemblage garnet + biotite + potassium feldspar. In this process, the replacement of plagioclase by potassium feldspar was the leading reaction. Evidence of this reaction is specific reaction textures in the rocks, negative correlations between the contents of the minerals, and petrochemical characteristics of the rocks. Modeling of the mineral assemblages of the xenoliths using the pseudosection approach (PERPLE_X) revealed two groups of rocks corresponding to different depth levels of the Siberian cratonic crust. For rocks without orthopyroxene or with this mineral as single relics, the pressure was estimated at 9.5–10 kbar, and it is 6–7 kbar for orthopyroxene-bearing samples. The xenolith rocks have close metamorphic peak temperatures of 750–800°C. They experienced 200–250°C cooling and 3–4 kbar decompression, regardless of the level of the crust at which they had initially occurred. This indicates that the metamorphic evolution of the rocks during their exhumation was probably associated with collisional processes during the amalgamation of individual terrains of the Siberian craton. Xenoliths enriched in K-feldspar might have been products of metamorphic reactions with participation of aqueous–(carbonic)–salt fluids, which were sourced from basaltic magmas in the lower crust. The most strongly metasomatized rocks were located closest to the place of accumulation of crystallizing magmas. [ABSTRACT FROM AUTHOR]

In the field, kimberlites are characterized by high electrical conductivities (about 0.1 S m−1) compared to most igneous rocks. The reason for these high conductivities has not been fully elucidated to date. We investigate here the spectral induced polarization of seven core samples of kimberlites in the frequency range 1.43 mHz–20 kHz. The measurements are made at pore water conductivities ranging from 0.07 to 2.4 S m−1 (NaCl, 25 °C). We also measured the cation exchange capacity (CEC), the specific surface area (SSA) and the magnetic susceptibility of the core samples. We characterized the samples by optical microscopy as well as the X-ray diffraction and thermogravimetric analyses. Based on the electrical measurements, we obtained values of the surface conductivity produced by the double electrical layer coating the solid particles, and the normalized chargeability values characterizing the polarization magnitude of these materials. Mineralogical analyses show significant amount of magnetite (from 2 to 9 wt. per cent, approximately 1 to 4 per cent in vol. content) and smectite (from 1 to 44 wt. per cent) in the core samples. The main contributor of the CEC is smectite because of its very high CEC. The quadrature conductivity, the normalized chargeability, and the surface conductivity are controlled by the CEC normalized by the tortuosity of the pore space (product of the formation factor by the porosity). Our data demonstrate that the conduction and polarization of kimberlites are both controlled by the presence of smectite rather than associated with magnetite. Comparing the new data set and data recently obtained with volcanic rocks from both shield and strato-volcanoes in the previous papers of this series, we show that the model of polarization of the dynamic Stern layer correctly describes the complex electrical conductivity of kimberlites as well. Our results also explain the cause of electrical conductivity anomalies detected at kimberlite pipes and offer new perspectives in using induced polarization method for the exploration of kimberlites around the world. [ABSTRACT FROM AUTHOR]

Kimberlite indicator minerals (KIMs) are distributed unevenly within the Voronezh anteclise (VA) both along the section and over its area. The Aptian rocks are characterized by a VA record content of small diamonds and chrome spinelids. Small diamond crystals were found in nine sections, and maximum concentrations were characteristic of the Volchinskaya placer (320 signs). Chrome spinelids reached several thousand signs per sample in a number of localities. In N.V. Sobolev's diagram, some grains (from 8 to 32%) occur in terms of their chemical composition in the diamond assemblage composition field. The sections contain "mantle"-type chrome spinelid grains as combination crystals and octahedra with vicinal faces. Continental deposits in the section make it possible to determine relatively reliably the drift direction as SE-to-NW in the Aptian. The identified KIMs are indicative of diamond-bearing bodies within the Voronezh anteclise to the southeast of the sections studied. [ABSTRACT FROM AUTHOR]

A rostrum fragment of a representative of the Toarcian–Early Aalenian (the latest Early Jurassic–the earliest Middle Jurassic) belemnites Arcobelus cf. krimholzi (Sachs, 1970) was found for the first time in kimberlites of the Obnazhennaya pipe of the Kuoika kimberlite field (northeastern Siberian Platform, Olenek Uplift). It was shown that the belemnite records previously known here and dated to the Late Jurassic or Early Cretaceous may be of Bajocian–Bathonian (Middle Jurassic) age. The stage of kimberlite magmatism of 177 ± 1.5 Ma, recently established in the northeastern part of the Siberian craton according to U–Pb geochronological data, falls on the time of the existence of belemnites of the genus Arcobelus. The estimated Late Bajocian–Early Bathonian age of the representative of the genus Pachyteuthis, previously found in kimberlites of the Obnazhennaya pipe, is consistent with the 40Ar/39Ar age (167 Ma), as well as with the age based on some paleomagnetic data (168 ± 11 Ma) reported for the pipe. Taking into consideration the new data on belemnites, the internal part of the shelf should be extended to the territory of the Kuoika kimberlite field in the paleogeographic schemes of the northeastern part of the Siberian Platform during the Toarcian–Early Bathonian. [ABSTRACT FROM AUTHOR]