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Major and trace element composition of silicate melt inclusions (SMI) and their rock-forming minerals were studied in mafic garnet granulite xenoliths from the Bakony–Balaton Highland Volcanic Field (Western-Hungary). Primary SMIs occur in clinopyroxene and plagioclase in the plagioclase-rich domains of mafic garnet granulites and in ilmenite in the vicinity of these domains in the wall rock. Based on major and trace elements, we demonstrated that the SMIs have no connection with the xenolith-hosting alkaline basalt as they have rhyodacitic composition with a distinct REE pattern, negative Sr anomaly, and HFSE depletion. The trace element characteristics suggest that the clinopyroxene hosted SMIs are the closest representation of the original melt percolated in the lower crust. In contrast, the plagioclase and ilmenite hosted SMIs are products of interaction between the silicic melt and the wall rock garnet granulite. A further product of this interaction is the clinopyroxene–ilmenite±plagioclase symplectite. Textural observations and mass ­balance calculations reveal that the reaction between titanite and the silicate melt led to the formation of these assemblages. We propose that a tectonic mélange of metapelites and (MOR-related) metabasalts partially melted at 0.3–0.5 GPa to form a dacitic–rhyodacitic melt leaving behind a garnet-free, plagioclase+clinopyroxene+orthopyroxene+ilmenite residuum. The composition of the SMIs (both major and trace elements) is similar to those from the middle Miocene calc-alkaline magmas, widely known from the northern Pannonian Basin (Börzsöny and Visegrád Mts., Cserhát and Mátra volcanic areas and Central Slovakian VF), but the SMIs are probably the result of a later, local process. The study of these SMIs also highlights how crustal contamination changes magma compositions during asthenospheric Miocene ascent.

A composite xenolith composed of a zircon-bearing, apatite-rich olivine-pyroxene hornblendite and an amphibole harzburgite part was found in an outcrop of Neogene alkali basalt at Szigliget, Bakony-Balaton Highland Volcanic Field, Western Hungary. The hornblendite is composed dominantly of amphibole that is strongly enriched in incompatible trace elements along with apatite, orthopyroxene and olivine. Zircon, rutile, ilmenite and sulphide occur as inclusions in the silicate minerals as accessory phases. On the basis of the chemical composition of the minerals, we estimate that the hornblendite crystallized at ~1000–1015 °C and 1.2–1.4 GPa pressure in the uppermost mantle under oxidising conditions (ΔlogfO2(FMQ)~ + 1.3). The hornblendite precipitated from a volatile and incompatible element-rich silicate melt with trachyte or phonolite composition, which might be derived from an alkali basalt melt by high-degree (>70%) fractional crystallisation.

Tourmaline-rich pegmatitic orthogneisses, tourmalinites, kyanite-chlorite-muscovite schists and quartzites crosscut by subordinate quartz-tourmaline veins and layers were newly described from the Sopron area, Western Hungary. The orthogneisses mainly consist of quartz, plagioclase, tourmaline, garnet and white mica. In smaller amounts K-feldspar, beryl, Mg-rich chlorite, kyanite, lazulite, florencite, monazite and apatite also are present. Magmatic cores and two generations of metamorphic tourmaline (Fe-rich and Mg-rich) were distinguished. Tourmaline in tourmalinites is generally large (several cm), deformed, contains chlorite inclusions and shows oscillatory zoning or polygonal fabric. Large tourmaline crystals often contain dark brown mica-shaped relic areas with higher amount of Ti and Fe than the adjacent parts, interpreted as relics of micas from the protolith. Besides tourmaline, quartz, white mica, plagioclase, apatite, garnet, rutile, ilmenite, scheelite, zircon and monazite are also present in the tourmalinites. Deformed tourmaline-quartz bands and veins occur in kyanite-chlorite-muscovite schists and quartzites. Euhedral, zoned and deformed schorl-dravite is accompanied with kyanite, Mg-chlorite (leuchtenbergite), rutile muscovite and sillimanite. Narrow colorless tourmaline rims enriched exclusively in Mg (FeO < 1 wt. %) can be identified. Coarse-grained orthogneisses with a significant amount of primary tourmaline-beryl assemblage indicates a fluid-rich, B-Be-bearing environment during the final crystallization of the Variscan peraluminous leucogranite. The formation of tourmalinites can be explained by the related boron metasomatism. Phengitic white mica rims and calcic garnet rims in orthogneisses and tourmalinites indicate high-pressure Alpine metamorphic overprint. The presence of REE-rich phosphate mineralisation and leuchtenbergite in the orthogneisses imply that high salinity fluids metasomatized the orthogneisses along the pre-existing shear zones after the Alpine metamorphic peak. Tourmaline grains in kyanite-bearing quartzites and schists may have originated from a micaschist that underwent a strong Mg-metasomatism during the formation of leucophyllites described from the area.

Fluid inclusions (FIs) ( n = 34) in spinel lherzolite xenoliths derived from the subcontinental lithospheric mantle from Jeju Island (S. Korea), the Rio Grande Rift (New-Mexico, USA) and Mt. Quincan (Australia) were analysed using confocal Raman spectroscopy. Despite the significant geographical distances, the studied rocks and their FIs show similar petrographic features. We show evidence for the presence of small amounts of nitrogen in extreme high density (≥1 g/cm 3 ) FIs from the deep lithospheric mantle using Raman spectroscopy with a spectral resolution between 0.6 and 0.7 cm −1 . The only nitrogen-bearing species found in the inclusions was N 2 . The N 2 Raman signal appeared as two adjacent, partially overlapping bands. The band at higher Raman shift is identical with the nitrogen-in-air (N 2 air ) band. The band at lower Raman shift is therefore nitrogen within the FIs (N 2 fluid ). The relative amounts of CO 2 and N 2 within the FIs were calculated using the integrated band areas. In the studied ultramafic xenoliths, N 2 concentrations varied between 0.2 and 1.8 mol%, with one exceptionally high concentration of 3.1 mol%. We believe that microthermometric measurements and/or Raman spectroscopy with an inferior spectral resolution may leave N 2 undetected in CO 2- rich upper mantle FIs. Based on our observations, we propose that N 2 may be a minor but common component in subcontinental lithospheric upper-mantle fluids.

Four fluid migration events were recorded during the Alpine metamorphism in the Sopron micaschist from the Grob gneiss series of the Lower Austroalpine Unit of the Eastern Alps near Sopron, using mineral chemistry data, geothermo-barometry and fluid inclusion studies.1. Tourmaline mineralisation in quartz veins and to some extent in the host rock. Similar mineral compositions in the quartz-tourmaline veins and in the host rock show equilibrium between fluid and the host rock. Geothermo-barometry gives 560-610oC temperature and 950-1230 MPa pressure for the formation of quartz-tourmaline veins which is the same as the determined P-T peak (T=560 and 600°C p= 840-1230 MPa).2. Fluids causing Mg-metasomatism in the shear zones. The result of this fluid invasion was the formation of leucophyllite in the shear zones and Mg-enrichment of some minerals (chlorite, muscovite, garnet) in the close vicinity of the shear zone. The effect of this fluid was confined to the shear zones and the neighbouring host rock.3. The rock was infiltrated along the shear zones and quartz veins with CO2-bearing hypersaline fluids during retrograde metamorphism. The presence of this fluid is evidenced by secondary CO2 inclusions and hypersaline aqueous fluid inclusions ± CO2. The aqueous fluid had high concentrations of Na, Ca, Fe, Al, Cl and contained moderate amounts of Mg, Zn, Ti, K, Mn, S and P. This fluid was the carrier of the REE and Th and locally precipitated florencite, monazite, allanite, apatite, thorite and thorianite in the shear zone. Traces of this mineralisation are found in quartz-tourmaline veins, postdating the tourmaline mineralisation.4. Late retrograde metamorphic fluid represented by two phase (liquid+vapor) aqueous inclusions of the NaCl-CaCl2-H2O system with total salinity between 25 and 28.5% and homogenisation temperatures between 229.6 and 322oC

Radioactive minerals of the gneiss of Sopron Mountains were analysed by micro-PIXE method at the Debrecen scanning nuclear microprobe. Zircon and monazite minerals were identified with detectable amount of U and Th. Qualitative elemental maps and quantitative concentration data were obtained on 20 minerals. U and Th concentrations were between few 100 ppm and 10 wt%. The size of the minerals varied between few micrometers and 100 microns, the distribution of U and Th within the grains was inhomogeneous. These radioactive minerals occurred in veins enriched with Fe.

Plio-Pleistocene alkali basalt hosted mafic garnet granulite xenoliths were studied from the Bakony-Balaton Highland Volcanic Field (BBHVF) to trace fluid-melt-rock interactions in the lower crust. Two unique mafic garnet granulite samples were selected for analyses (optical microscopy, microthermometry, electron microprobe, Raman and IR spectroscopy), which contain a clinopyroxene-plagioclase vein and patches with primary silicate melt inclusions (SMI). The samples have non-equilibrium microtexture in contrast with the overwhelming majority of previously studied mafic garnet granulite xenoliths. Primary silicate-melt inclusions were observed in plagioclase, clinopyroxene and ilmenite in both xenoliths. The SMI-bearing minerals located randomly in Mi26 and in a clinopyroxene-plagioclase vein on the edge of Sab38 granulites. Petrography and the fluid and melt inclusion study suggest that at least three fluid events occurred in the deep crust represented by these xenoliths. 1. Primary CO2-dominated ± CO ± H2S fluid inclusions were observed in the wall-rock part of Sab38 xenolith. 2. The crystallization of new clinopyroxene from melt, with CO2 + H2O fluid. 3. The crystallization of new plagioclase occurred in a heterogeneous fluid-melt system with additional N2 and CH4 during crystallization. A local reaction was observed between sphene and acidic melt, which formed ilmenite + clinopyroxene + plagioclase ± orthopyroxene. The ‘water’ content of the rock forming minerals was determined by infrared spectroscopy. The calculated bulk ‘water’ content of the Mi26 xenolith is 171 ± 51 ppm wt. %. The bulk wall rock part of the Sab38 granulite contains 55 ± 17 ppm wt. % of ‘water’, whereas the bulk plagioclase-clinopyroxene vein contains 278 ± 83 ppm wt. %. These results imply a very dry lower crust, locally hydrated by percolating fluids and melts.

Radon gas is the largest natural source of human exposure to ionizing radiation and most of that exposure occurs in indoor air. Bedrock geology is an important factor in radon hazard evaluation of an area. The presence of rock types usually rich in uranium can be considered an indication of a potential radon hazard. In this study the average 226Ra activity concentration of the main rock types (orthogneiss, micaschist, leucophyllite) in the Sopron Mountains was measured by gamma-spectroscopy, to reveal the uranium rich areas. This work is focusing on the distribution of 226Ra among the different rock types of the Sopron Mountains with similar geological origin. The effect of different retrograde processes such as mylonitisation, fluid migration and argillitic–limonitic alteration on 226Ra activity concentration was investigated. A few anomalies occurred in these metamorphic rocks. One explanation of the high uranium concentration is the high radioactive level of the rocks before the metamorphosis, but we demonstrated the significance of the above mentioned secondary processes as well. At Nandormagaslat quarry the presence of radium anomaly we found in the limonitic alteration of weathered gneiss (range: 131–726 Bq kg−1) in fractures explains the high air concentration nearby in houses (96–2,051 Bq m−3) and in a corresponding tunnel (maximum 600 kBq m−3).

Felsic to mafic granulite xenoliths from late Neogene basalt pyroclastics in four localities of the western Pannonian Basin (Beistein, Kapfenstein, Szigliget and Kaptalantoti (Sabar-hegy) were studied to find out their metamorphic and fluid history. The characteristic mineral assemblage of the granulites consists of Pl + Opx + Qtz ± Cpx ± Bt ± Grt ± Kfs. Based on abundant magmatic relic microstructural domains occurring in these rocks, the potential precursors might have been predominantly felsic igneous or high to ultrahigh temperature rocks. Ternary feldspar thermometry provides a rough estimate of temperatures of about 920–1070 °C. The first fluid invasion event, which is linked with this early high to ultrahigh temperature stage is characterised by primary pure CO2 inclusions in apatite and zircon. The densest primary CO2 inclusions indicate 0.52–0.64 GPa pressure at the estimated temperature range of crystallization. According to mineral equilibria and geothermobarometry, the high to ultrahigh temperature rock cooled and crystallized to granulite of predominantly felsic composition at about 750–870 °C and 0.50–0.75 GPa in the middle crust, between 20 and 29 km depths. The second fluid invasion event is recorded by primary CO2-rich fluid inclusions hosted in the granulitic mineral assemblage (plagioclase, quartz and orthopyroxene). In addition to CO2, Raman spectroscopy revealed the presence of minor N2, H2S, CO and H2O in these inclusions. Partial melting of biotite-bearing assemblages could be connected to the next fluid invasion shown by secondary CO2-rich fluids recorded along with healed fractures in plagioclase, clinopyroxene and orthopyroxene. This event could have happened at depths similar to the previous ones. The final step in the granulite evolution was the sampling in the middle crust and transportation to the surface in form of xenoliths by mafic melt. This event generated temperature increase and pressure decrease and thus, limited melting of the xenoliths. The youngest fluid inclusion generation, observed mostly in healed fractures of felsic minerals, could be associated with this event.

The aim of this study was to determine both ‘water’ contents (as OH− and H2O) and δD values of several clinopyroxene samples from alkaline basalts. These parameters were first obtained from five clinopyroxene samples using both the classical ‘off-line’ vacuum extraction technique and the ‘on-line’ high-temperature pyrolysis technique. Blanks measured with the ‘on-line’ gas extraction techniques were low enough to prevent any contamination by atmospheric water vapour. The comparison of data has revealed that our ‘on-line’ procedure is more effective for the extraction of ‘water’ from clinopyroxenes and, consequently, this ‘on-line’ technique was applied to ten additional clinopyroxene samples. Sample δD values cover a similar range from −95 to −45 ‰ (VSMOW) regardless of the studied locations, whereas the total ‘water’ content varies from ~115 to ~2570 ppm. The structural hydroxyl content of clinopyroxene samples measured by micro-FTIR spectrometry varies from ~0 to 476 ppm expressed in molecular water equivalent. The total ‘water’ concentrations determined by mass spectrometry differ considerably from structural hydroxyl contents constrained by micro-FTIR, thus indicating that considerable proportion of the ‘water’ may be present in (nano)-inclusions. The structural hydroxyl concentration—apart from clinopyroxenes separated from amphibole clinopyroxenite xenoliths—correlates positively with the δD values of clinopyroxene megacrysts for each locality, indicating that structurally bond hydrogen in clinopyroxenes may have δD values higher than molecular water in inclusions. This implies that there may be a significant hydrogen isotope fractionation for structural hydroxyl during crystallization of clinopyroxene, while for molecular water there may be no or only negligible isotope fractionation.

Rarely occurring clinopyroxene-plagioclase bearing, felsic granulite and skarn xenoliths were studied from the mantle and crustal xenolith-bearing alkaline basaltic and pyroclastic localities of the Bakony–Balaton Highland Volcanic Field (W-Hungary). Geobarometry and geothermometry of the xenoliths made it possible to categorise them in three groups according to their depth of formation. The first group formed in the lower crust together with mafic and metasedimentary granulites. The second group represents magmatic intrusions of the middle crust, and the third one comprises contact metamorphic rocks of relatively shallow origin. The calculated pressure difference from the core and rim compositions of plagioclase and clinopyroxene as well as garnet breakdown reactions in some xenoliths show evidence for pressure decrease due to crustal thinning both in lower crustal and middle crustal xenoliths during formation of the Pannonian Basin. Fluid inclusion studies reveal the dominance of the CO2-rich fluids in the whole crustal section in contrast with fluids found in mafic garnet-bearing xenoliths. Crustal stratigraphy was constructed for the periods prior to the extension and after the extension on the basis of geobarometry and geophysical data. On the basis of mineral stabilities and geothermo-barometry, we estimated that the pre-extensional thickness of the lower and upper crust may have been 27–34 and 26–28 km, respectively. Comparison of pre-extensional and present-day thickness of the lower and upper crust indicate that thinning affected both the lower and the upper portion of the crust but on a different scale. The calculated thinning factors are between 2.25 and 3.4 for the lower crust and 1.3–1.56 for the upper crust.

Silicate melt inclusions containing rhonite Ca2(Mg,Fe2+)4Fe3+Ti[Al3Si3O20] were studied in olivine phenocrysts from alkali basalts of six different volcanic regions: Udokan Plateau, North Minusa Depression, Tsagan-Khurtei Ridge (Russia), Bakony-Balaton Highland, Nograd-Gomor Region (Hungary) and Makhtesh Ramon (Israel). Rhonite-bearing silicate melt inclusions are relatively common phenomena in alkali basalts and usually coexist with inclusions containing no rhonite. Inclusions with rhonite generally occur in the core of the olivine phenocrysts. According to heating experiments and CO2 microthermometry, all the rhonite-bearing inclusions in core of the olivine phenocrysts were trapped as silicate melt at T > 1300 °C and P > 3–5 kbar. Rhonite crystallized in a narrow temperature range (1180–1260 °C) and P < 0.5 kbar. The petrography and thermometry of rhonite-bearing silicate melt inclusions show a general crystallization sequence: Al-spinel → rhonite → clinopyroxene → apatite → ± amphibole, Fe-Ti oxide (ilmenite or Ti-magnetite) → glass. Majority of rhonites from melt inclusions have Mg/(Mg + Fe2+) > 0.5 and belong to Mg-rich species Ca2Mg4Fe3+Ti[Al3Si3O20]. There are no essential differences in chemistry among rhonites from olivine-hosted silicate melt inclusions from phenocryst, from groundmass of alkali basalts, from alteration products of kaersutitic amphibole mega/xenocrysts and of kaersutite in deep-seated xenoliths in alkali basalts. The rare occurrence of rhonite as essential constituent in rocks may be explained from its microstructural peculiarities. This mineral is an intermediate member of the polysomatic spinel-pyroxene series. Possibly, the structural feature of rhonite does explain why it is an unstable mineral in under changing crystallization conditions. In general, the presence and chemistry of rhonite may be used for rough estimation of temperature, pressure and oxygen fugacity during crystallization of alkali basalts.

In this paper we present a detailed textural and geochemical study of two equigranular textured amphibole-bearing spinel lherzolite xenoliths from Szigliget, Bakony–Balaton Highland Volcanic Field (BBHVF, western Hungary) containing abundant primary silicate melt inclusions (SMIs) in clinopyroxene rims and secondary SMIs in orthopyroxene (and rarely spinel) along healed fractures. The SMIs are dominantly composed of silicate glass and CO2-rich bubbles. Clinopyroxene and orthopyroxene are zoned in both studied xenoliths, especially with respect to Fe, Mg, Na, and Al contents. Cores of clinopyroxenes in both xenoliths show trace element distribution close to primitive mantle. Rims of clinopyroxenes are enriched in Th, U, light rare earth elements (LREEs) and medium REEs (MREEs). Amphiboles in the Szg08 xenolith exhibit elevated Rb, Ba, Nb, Ta, LREE, and MREE contents. The composition of silicate glass in the SMIs covers a wide range from the basaltic trachyandesite and andesite to phonolitic compositions. The glasses are particularly rich in P2O5. Both primary and secondary SMIs are strongly enriched in incompatible trace elements (mostly U, Th, La, Zr) and display a slight negative Hf anomaly. The development of zoned pyroxenes, as well as the entrapment of primary SMIs in the clinopyroxene rims, happened after partial melting and subsequent crystallization of clinopyroxenes, most probably due to an interaction between hot volatile-bearing evolved melt and mantle wall-rocks. This silicate melt filled microfractures in orthopyroxenes (and rarely spinels) resulting in secondary SMIs.

We investigate the effects of xenolith–host basalt interaction on lower crustal mafic granulite xenoliths from the Central Pannonian Basin. The xenoliths are devoid of any signs of melting, nevertheless various phenomena are identified, which indicate that the original mineralogy and chemistry of the xenoliths was modified during interaction with the host basalt. The rock-forming silicates are only slightly affected by alteration, but the Fe–Ti-oxides are overprinted to a significant extent. Complex chemical zoning patterns are detected using high-resolution element mapping in ilmenites and in lamellar titanomagnetite–ilmenite intergrowths. The chemical alteration of the Fe–Ti-oxides was diffusion-controlled and, hence, time and temperature dependent. On the basis of diffusion profiles in titanomagnetite we estimate the duration of xenolith–host basalt interaction to be at least 9–20 h. This is comparable to the time necessary for the ascent of the host basalt to the surface. It is too short to reflect alteration during granulite facies metamorphism in the deep crust. The chemical alteration of the titanomagnetite thus reflects the total duration of the xenolith–host basalt interaction.

An unusual quartz-bearing orthopyroxene-rich websterite xenolith has been found in an alkali basaltic tuff at Szigliget, Bakony-Balaton Highland Volcanic Field (BBHVF), western Hungary. Ortho- and clinopyroxenes are enriched in light rare earth elements (LREE), middle REE and Ni, and depleted in Nb, Ta, Sr and Ti compared with ortho- and clinopyroxenes occurring in either peridotite or lower crustal granulite xenoliths from the BBHVF. Both ortho- and clinopyroxenes in the xenolith contain primary and secondary silicate melt inclusions, and needle-shaped or rounded quartz inclusions. The melt inclusions are rich in SiO 2 and alkalis and poor in MgO, FeO and CaO. They are strongly enriched in LREE and large ion lithophile elements, and display negative Nb, Ta and Sr anomalies, and slightly positive Pb anomalies. The xenolith is interpreted to represent a fragment of an orthopyroxene-rich body that crystallized in the upper mantle from a hybrid melt that formed by interaction of mantle peridotite with a quartz-saturated silicate melt that was released from a subducted oceanic slab. Although the exact composition of the slab melt cannot be determined, model calculations on major and trace elements suggest involvement of a metasedimentary component.

We examined the Csaloka Spring, which has the highest radon concentration in the Sopron Mountains (West Hungary) (, yearly average of 227 ± 10 Bq L(-1)). The main rock types here are gneiss and micaschist, formed from metamorphism of former granitic and clastic sedimentary rocks respectively. The aim of the study was to find a likely source of the high radon concentration in water. During two periods (2007-2008 and 2012-2013) water samples were taken from the Csaloka Spring to measure its radon concentration (from 153 ± 9 Bq L(-1) to 291 ± 15 Bq L(-1)). Soil and rock samples were taken within a 10-m radius of the spring from debrish and from a deformed gneiss outcrop 500 m away from the spring. The radium activity concentration of the samples (between 24.3 ± 2.9 Bq kg(-1) and 145 ± 6.0 Bq kg(-1)) was measured by gamma-spectroscopy, and the specific radon exhalation was determined using radon-chamber measurements (between 1.32 ± 0.5 Bq kg(-1) and 37.1 ± 2.2 Bq kg(-1)). Based on these results a model calculation was used to determine the maximum potential radon concentration, which the soil or the rock may provide into the water. We showed that the maximum potential radon concentration of these mylonitic gneissic rocks (cpot = 2020 Bq L(-1)) is about eight times higher than the measured radon concentration in the water. However the maximum potential radon concentration for soils are significantly lower (41.3 Bq L(-1)) Based on measurements of radon exhalation and porosity of rock and soil samples we concluded that the source material can be the gneiss rock around the spring rather than the soil there. We determined the average radon concentration and the time dependence of the radon concentration over these years in the spring water. We obtained a strong negative correlation (-0.94 in period of 2007-2008 and -0.91 in 2012-2013) between precipitation and radon concentration.

Amphibole-bearing and amphibole-free garnet granulite xenoliths (clinopyroxene, plagioclase, garnet ± orthopyroxene, ± amphibole) from two localities of the Bakony–Balaton Highland Volcanic Field (Sabar-hegy and Szentbekkalla) were investigated by means of textural analysis, mineral chemistry, mineral equilibria, geothermobarometry and fluid inclusion studies. We have determined the P–T path of these lower crustal xenoliths, which begins at peak pressure between 0.9 and 1.4 GPa. The peak pressure was followed by temperature increase of about 200–300 °C and 0.3–0.7 GPa pressure decrease which is marked by breakdown reactions of garnet and pargasitic amphibole. Garnet broke down first to orthopyroxene–anorthite–spinel (type 1) then to olivine–plagioclase ± spinel (type 2) symplectite. Amphibole broke down to form clinopyroxene–plagioclase–Fe–Ti oxide-melt ± orthopyroxene ± olivine mineral assemblage. These changes in P–T conditions were caused by crustal thinning. The present day crustal thickness (max. 32 km) indicates that garnet granulites are no longer stable in the lower crust of the Pannonian Basin. The calculated crustal thinning factor is between 1.6 and 1.8 in accordance with the values calculated from tectonic methods. A unique CO2–CO–C fluid system—which has not been described from the lower crust so far—occurs in inclusions of the rock-forming minerals, mainly in plagioclase and clinopyroxene. A primary and two secondary fluid inclusion (FI) generations were identified on the basis of textural analyses and distribution of homogenization temperatures. Primary FIs are connected to the formation of garnet granulite. The older secondary generation was trapped after the main temperature increase and some pressure decrease during crustal thinning. The younger secondary generation trapped within the depth limits of the present lower crust at pressures between 0.6–0.7 GPa. The overall composition of the fluid system has not changed during crustal thinning. The calculated oxygen fugacity values are slightly above and under QFM (between 10–8.5 and 10–10.1 at 1200 °C).

This paper is devoted to the description of spessartine-almandine garnet (Sps: 39.8-60.2%; Alm: 29.1-56.76%; Grs

High-pressure metapelites with the assemblage kyanite-staurolite-garnet ′ chloritoid-biotite-muscovite-plagioclase-quartz and crosscutting gneiss veins were studied in the Sopron Mountains near Obrennberg (Hungary, Eastern Alps). Different garnet generations were investigated by textural analysis and study of garnet zoning from different textural domains from both the micaschist and the gneiss veins. Thermobarometry of subsequent garnet generations and the surrounding mineral assemblage was used to reconstruct the Alpine P-T path of the metamorphic rocks during the Alpine orogenesis. Peak pressure conditions (1390-1470 MPa) are recorded by high-Si phengites (Si = 7.03 a.p.f.u.) and temperatures by white mica-garnet-albite-quartz assemblage at about 550-600 °C. This is in good agreement with the peak pressures obtained from the massive orthogneisses of the area. Gneiss veins crosscutting the micaschist show slightly lower peak pressures between 1230 and 1280 MPa at similar temperatures (575-590 °C). Subsequent garnet generations and associated mineral assemblages show decreasing pressure with slightly decreasing temperature. Textural observations, white mica chemistry and comparison of garnet zoning trends provided additional evidence on the formation of leucophyllites during retrograde metamorphism.

A unique occurrence of strontian barite droplets associated with oriented planes of primary sulfide blebs in several clinopyroxene megacrysts was found in the Plio-Pleistocene basaltic tuff of Szentbekkalla (Bakony–Balaton Highland, western Hungary). The barite droplets contain 3.22–14.7 wt.% SrO, variable amount of FeO (up to 3.25 wt.%), minor CaO, CuO and NiO. Textural arrangements of oriented sulfide planes show that they were trapped as immiscible sulfide melt during crystallization of the clinopyroxene. Temperature and pressure estimation (978–1094 °C and 1.0–1.1 GPa) of the host clinopyroxenes indicate that formation of clinopyroxene megacrysts and entrapment of sulfide blebs happened under upper mantle conditions. A genetic relationship between the sulfate and sulfide blebs is doubtful. Textural features suggest that the barite droplets might have been trapped together with the sulfide blebs from immiscible sulfide melts. However, it cannot be excluded that the barite formed during metasomatic event following the sulfide formation.

¶Fluid inclusions from two Mesoproterozoic, metamorphosed layered intrusive complexes, Niquelândia and Barro Alto, Goias State, Brazil record multiple fluid influx events from the magmatic to granulitic and retrograde metamorphic stages.

A partially molten buchite xenolith containing quartz, glass, mullite/sillimanite, corundum, Al-rich orthopyroxene, spinel, Mg-Al-bearing Fe-Ti oxides, ilmenite and rutile was found in the basaltic tuff of Szigliget (Balaton Highlands, Hungary). The pre-existing rock may have been a quartz-rich micaschist or phyllite from the wall of the magma vent. Minerals like mullite, Al-mullite and Al-rich orthopyroxene with Al2O3 between 7.62 to 11.54 wt% show ultrahigh-temperature (UHT) metamorphism of the xenolith with temperatures in excess of 1080 °C, which means that the temperature of metamorphism approached that of the enclosing alkaline basaltic melt. CO2 fluid inclusions with homogenization temperatures between +26.5 and +29.7 °C and mineral equilibria indicate pressure of buchitization between 310 and 390 MPa. Glass compositions are similar to a peraluminous leucogranite which is in accordance with melting experiments when metagreywackes, pelites and orthogneisses are involved. The presence of glass sugge...

Silicate melt pockets with or without carbonate occur in 10% of upper mantle xenoliths from the alkali basalts of the Bakony–Balaton Highland Volcanic Field (BBHVF), Western Hungary. Based on the estimated bulk composition of the melt pockets, both the carbonate-free and the carbonate-bearing ones are considered to be the result of the reaction between primary mantle clinopyroxene and/or amphibole and external CaO, Al2O3, alkali-rich and MgO-poor fluids/melts, as metasomatic agents, migrating in the upper mantle. The metasomatic melt that produced the carbonate-bearing melt pockets was extremely rich in volatiles, whereas metasomatic melt that contributed to the formation of the carbonate-free melt pockets was particularly rich in silica and relatively poor in volatiles. These metasomatizing melts could have originated from the melting of the previously metasomatized upper mantle due to Middle Miocene mantle diapirism.

Microthermometric investigations of silicate-melt inclusions and electron microprobe analyses were conducted on experimentally homogenized silicate-melt inclusions and on the host clinopyroxenes from 4 scoria samples of different layers from the Mt. Somma-Vesuvius medieval eruption (Formazione di Terzigno, 893 A.D.). The temperature of homogenization, considered the minimum trapping temperature, ranges from 1190 to 1260 ± 5 °C for all clinopyroxene-hosted silicate melt inclusions. The major and minor-element compositional trends shown by Terzigno scoria and matrix glass chemical analysis are largely compatible with fractional crystallization of clinopyroxene and Fe-Ti oxides. Sulfur contents of the homogenized silicate-melt inclusions in clinopyroxene phenocrysts compared with that in the host scoria show that S has been significantly degassed in the erupted products; whereas, Cl has about the same abundance in the inclusions and in host scoria. Fluorine is low (infrequently up to 800 ppm) in the silicate-melt inclusions compared to 2400 ppm in the bulk scoria. Electron microprobe analyses of silicate-melt inclusions show that they have primitive magma compositions (Mg# = 75-91). The composition of the host clinopyroxene phenocrysts varies from typical plinian-related (Mg#≥85) to non plinian related (Mg#≤85). The mixed source of the host clinopyroxenes and primitive nature of the silicate-melt inclusions implies that these phenocrysts, in part, may be residual and/or have a polygenetic origin. The similar variation trends of major and minor-elements between homogenized silicate-melt inclusions from the Terzigno scoria, and silicate-melt inclusions in olivine and diopside phenocrysts from plinian eruptions (Marianelli et al., 1995) suggest that the trapped inclusions represent melts similar to those that supplied the plinian and sub-plinian magma chambers. These geochemical characteristics suggest that the Vesuvius magmatic system retained a vestige of the most recent plinian event.

Nodules (coarse-grain “plutonic” rocks) were collected from the ca. 20 ka Pomici di Base (PB)-Sarno eruption of Mt. Somma-Vesuvius, Italy. The nodules are classified as monzonite-monzogabbro based on their modal composition. The nodules have porphyrogranular texture, and consist of An-rich plagioclase, K-feldspar, clinopyroxene (ferroan-diopside), mica (phlogopite-biotite) ± olivine and amphibole. Aggregates of irregular intergrowths of mostly alkali feldspar and plagioclase, along with mica, Fe-Ti-oxides and clinopyroxene, in the nodules are interpreted as crystallized melt pockets. Crystallized silicate melt inclusions (MI) are common in the nodules, especially in clinopyroxenes. Two types of MI have been identified. Type I consists of mica, Fe-Ti-oxides and/or dark green spinel, clinopyroxene, feldspar and a vapor bubble. Volatiles (CO2, H2O) could not be detected in the vapor bubbles by Raman spectroscopy. Type II inclusions are generally lighter in color and contain subhedral feldspar and/or glass and several opaque phases, most of which are confirmed to be oxide minerals by SEM analysis. Some of the opaque-appearing phases that are below the surface may be tiny vapor bubbles. The two types of MI have different chemical compositions. Type I MI are classified as phono-tephrite — tephri-phonolite — basaltic trachy-andesite, while Type II MI have basaltic composition. The petrography and MI geochemistry led us to conclude that the nodules represent samples of the crystal mush zone in the active plumbing system of Mt. Somma-Vesuvius that were entrained into the upwelling magma during the PB-Sarno eruption. PhD Programme (XXV Cycle, Coordinated by B. De Vivo) “Internal dynamics of volcanic systems and hydrogeological-environmental risks” of the University of Naples Federico II Virginia Tech Published version former journal title: Central European Journal of Geosciences

The complex microstructure of kelyphitic rims around garnet in lower crustal garnet granulite xenoliths from the Bakony–Balaton Highland Volcanic Field, Central Pannonian Basin has been studied in order to identify controls on garnet breakdown. Symplectites comprised of a vermicular intergrowth of submicron sized anorthite, orthopyroxene and spinel replace garnet at a sharp reaction front. Based on element distribution maps the transformation of garnet to symplectite is isochemical. Phase diagram calculations indicate that this reaction was induced by a pressure decrease and/or a temperature increase. In site-specific TEM foils prepared by focused ion beam technique and oriented parallel and perpendicular to the reaction front 200 nm wide rods of anorthite and 20 nm wide rods of spinel are identified. The rods are oriented approximately perpendicular to the replacement front and are embedded in an orthopyroxene matrix. The regular spacing of the symplectite phases along the reaction front suggests that their growth is controlled by diffusion. The kinetics of symplectite formation has been modelled based on irreversible thermodynamics. During interaction of the xenolith with the host basalt the microstructure and chemistry of the An–Opx–Spl symplectite was significantly modified and it was partially replaced by an olivine bearing symplectite. In contrast to primary symplectite formation, these processes were metasomatic in nature including addition of sodium, titanium and some trace elements from the basaltic melt and can clearly be discerned from the garnet breakdown. Based on these observations it is inferred that symplectite formation took place within the deep crust during the extension of the Pannonian Basin between 15 and 30 km depth at high temperature (850–1,050°C) prior to the volcanic transport to the surface.

Polymetamorphic cordierite andalusite-bearing micaschist from the Garabonc-1 borehole has been affected by three metamorphic episodes: Medium-pressure (800-900 Mpa), medium-grade (500-550 C ) Barrovian-type metamorphism occurred first, defined by the appearance of staurolite and kyanite. There are no geochronologic data concerning the age of this episode. Based on certain assumptions it is most probably related to the Caledonian or Early Hercynian orogenies. The second metamorphic episode was low-pressure/medium-grade in character (200-300 Mpa and 560 to 580 o C). Finally, contact metamorphism (100-150 Mpa and 600-640 o C) was caused by an intruding granitoid body. The characteristic minerals are andalusite, cordierite, fibrolite and spinel. The age of the granite intrusion is Carboniferous (Balogh et al., 1981). The most dense CO 2 ±CH 4 ±N e inclusions formed well after the peak P-T conditions. This inclusion type was sealed during all the three stages of metamorphism. There is no significant change in the fluid composition during the second phase. In addition to the pre-existing CO 2 ±CH 4 ±N 2 fluid hypersaline brine was trapped in connection with the third stage. The cooling and uplift of the terrain is recorded by low- to intermediate-salinity aqueous and gaseous CH 4 ±CO 2 inclusions

Fluid and melt inclusions and geochemical features of alkali syenite, mafic, and ultramafic cumulate xenoliths in the last ignimbritic event (volcanism up to 300 ky.b.P.) at the island of Ventotene in the Pontine archipelago (Gaeta Gulf) were investigated to establish the genesis and evolution of the fluids trapped in the inclusions. Ranges in lead isotopic compositions of the xenoliths as a group are narrow: 206Pb/204Pb:18.778–18.864; 207Pb/204Pb:15.641–15.701; 208Pb/204Pb:38.858–39.090; the values overlap among the groups, implying that the xenoliths are closely related. The xenoliths straddle the best-fit line describing the regional NW-SE variation of values for uranogenic Pb in volcanic rocks from the Roman alkaline province. The similarity between the xenoliths and volcanic rocks permits the interpretation that the xenoliths are representative of the source region of the volcanic rocks, residues after partial melting of the source region or fractional crystallization of the volcanic rocks, or even that the xenoliths represent assimilants obtained during the evolution of the magmas that produced the volcanic rocks. Xenoliths belonging to the ultramafic-mafic cumulate group contain only silicate melt inclusions ± vapor bubble ± droplets of an opaque phase and rarely some CO2 trapped in silicate melt inclusions. Xenoliths in the alkali syenite group have three types of fluid inclusions: (1) single phase vapor and silicate melt inclusions; (2) two-phase silicate melt + salt, silicate melt + CO2 (V), aqueous (L + V), and silicate melt + vapor inclusions, and (3) three-phase and multiphase inclusions: CO2 (L) + CO2 (V) + H2O; silicate melt + saline melt + H2O ± birefringent or opaque trapped minerals; H2O + salt + silicate glass ± birefringent trapped minerals. During heating experiments, melting of salt occurs at temperatures from 565 to 815°C, depending on the water content of the inclusions. Homogenization of the vapor bubble occurs from 850–1160°C, and complete melting of the silicate glass at about 950°C. The highly variable proportions of the individual phases in the silicate melt + salt + H2O inclusions and the coexistence of silicate melt + CO2 inclusions indicates immiscibility during the crystallization of the magma. Primary and secondary CO2 inclusions in the alkali syenite suite indicate lower densities (from 0.10 to 0.22 g/cm3) than those resulting from primary CO2 inclusions in the gabbroic suite (from 0.34 to 0.42 g/cm3). The P-T trajectory of the probable fluid evolution path shows that the crystallization of gabbro occurred between ∼1 and 1.4 kbars, whereas alkali syenite crystallized between ∼200 and 400 bars. The secondary H2O inclusions in alkali syenite were trapped in the later stages of the hydrothermal process and at much lower temperatures (130–290°C), but at pressures relatively close to those of alkali syenite crystallization. The almost isobaric conditions during the final stage of the fluid evolution path are explained by the very shallow emplacement of the alkali syenite intrusive body.