Search

We present the results of the ALMA Large Program Early Planet Formation in Embedded disks observations of the Class 0 protostar GSS30 IRS3. Our observations included 1.3 mm continuum with a resolution of 0.''05 (7.8 au) and several molecular species including $^{12}$CO, $^{13}$CO, C$^{18}$O, H$_{2}$CO and c-C$_{3}$H$_{2}$. The dust continuum analysis unveiled a disk-shaped structure with a major axis size of $\sim$200 au. We observed an asymmetry in the minor axis of the continuum emission suggesting that the emission is optically thick and the disk is flared. On the other hand, we identified two prominent bumps along the major axis located at distances of 26 and 50 au from the central protostar. The origin of the bumps remains uncertain and might be due to an embedded substructure within the disk or the result of the temperature distribution instead of surface density due to optically thick continuum emission. The $^{12}$CO emission reveals a molecular outflow consisting of three distinct components: a collimated one, an intermediate velocity component exhibiting an hourglass shape, and a wider angle low-velocity component. We associate these components with the coexistence of a jet and a disk-wind. The C$^{18}$O emission traces both a Keplerian rotating circumstellar disk and the infall of the rotating envelope. We measured a stellar dynamical mass of 0.35$\pm$0.09 M$_{\odot}$., Comment: 25 pages, 19 figures. Accepted for publication in A&A

We present Atacama Large Millimeter/submillimeter Array (ALMA) observations of the binary Class 0 protostellar system BHR 71 IRS1 and IRS2 as part of the Early Planet Formation in Embedded Disks (eDisk) ALMA Large Program. We describe the $^{12}$CO ($J$=2--1), $^{13}$CO ($J$=2--1), C$^{18}$O ($J$=2--1), H$_2$CO ($J=3_{2,1}$--$2_{2,0}$), and SiO ($J$=5--4) molecular lines along with the 1.3 mm continuum at high spatial resolution ($\sim$0.08" or $\sim$5 au). Dust continuum emission is detected toward BHR 71 IRS1 and IRS2, with a central compact component and extended continuum emission. The compact components are smooth and show no sign of substructures such as spirals, rings or gaps. However, there is a brightness asymmetry along the minor axis of the presumed disk in IRS1, possibly indicative of an inclined geometrically and optically thick disk-like component. Using a position-velocity diagram analysis of the C$^{18}$O line, clear Keplerian motions were not detected toward either source. If Keplerian rotationally-supported disks are present, they are likely deeply embedded in their envelope. However, we can set upper limits of the central protostellar mass of 0.46 M$_\odot$ and 0.26 M$_\odot$ for BHR 71 IRS1 and BHR 71 IRS2, respectively. Outflows traced by $^{12}$CO and SiO are detected in both sources. The outflows can be divided into two components, a wide-angle outflow and a jet. In IRS1, the jet exhibits a double helical structure, reflecting the removal of angular momentum from the system. In IRS2, the jet is very collimated and shows a chain of knots, suggesting episodic accretion events., Comment: 38 pages, 29 figures, accepted in ApJ

Context. The carbamoyl radical (H2NCO) is believed to play a central role in the ice-grain chemistry of crucial interstellar complex organic molecules as formamide and acetamide. Yet, little is known about this radical that remains elusive in laboratory gas-phase experiments. Aims. In order to enable interstellar searches of H2NCO, we have undertaken a mandatory laboratory characterisation of its pure rotational spectrum. Methods. We report the gas-phase laboratory detection of H2NCO, produced by H-atom abstraction from formamide, using pure rotational spectroscopy at millimetre and submillimetre wavelengths. Millimetre-wave data were acquired using chirped-pulse Fourier-transform spectroscopy while submillimetre-wave ones were obtained using Zeeman-modulated spectroscopy. Experimental measurements were guided by quantum-chemical calculations at the $\omega$B97X-D/cc-pVQZ level of theory. Interstellar searches for the radical have been undertaken on the Protostellar Interferometric Line Survey (PILS) towards the solar-type protostar IRAS 16293-2422. Results. From the assignment and fit of experimental transitions up to 660 GHz, reliable spectroscopic parameters for H2NCO in its ground vibrational state have been derived, enabling accurate spectral predictions. No transitions of the radical were detected on the PILS survey. The inferred upper limit shows that H2NCO abundance is at least 60 times below that of formamide and 160 times below that of HNCO in this source; a value that is in agreement with predictions from a physico-chemical model of this young protostar., Comment: Accepted in A&A

Infrared emission features toward interstellar gas of the IC 348 star cluster in Perseus have been recently proposed to originate from the amino acid tryptophan. The assignment was based on laboratory infrared spectra of tryptophan pressed into pellets, a method which is known to cause large frequency shifts compared to the gas phase. We assess the validity of the assignment based on the original Spitzer data as well as new data from JWST. In addition, we report new spectra of tryptophan condensed in para-hydrogen matrices to compare with the observed spectra. The JWST MIRI data do not show evidence for tryptophan, despite deeper integration toward IC 348. In addition, we show that several of the lines attributed to tryptophan are likely due to instrumental artifacts. This, combined with the new laboratory data, allows us to conclude that there is no compelling evidence for the tryptophan assignment.

The low carbon content of Earth and primitive meteorites compared to the Sun and interstellar grains suggests that carbon-rich grains were destroyed in the inner few astronomical units of the young solar system. A promising mechanism to selectively destroy carbonaceous grains is thermal sublimation within the soot line at $\gtrsim$ 300 K. To address whether such hot conditions are common amongst low-mass protostars, we observe CH$_3$CN transitions at 1, 2 and 3 mm with the NOrthern Extended Millimeter Array (NOEMA) toward seven low-mass and one intermediate-mass protostar ($L_{\rm{bol}} \sim2-300 L_\odot$), as CH$_3$CN is an excellent temperature tracer. We find $>$ 300 K gas toward all sources, indicating that hot gas may be prevalent. Moreover, the excitation temperature for CH$_3$OH obtained with the same observations is always lower ($\sim$135-250 K), suggesting that CH$_3$CN and CH$_3$OH have a different spatial distribution. A comparison of the column densities at 1 and 3 mm shows a stronger increase at 3 mm for CH$_3$CN than for CH$_3$OH. Since the dust opacity is lower at longer wavelengths, this indicates that CH$_3$CN is enhanced in the hot gas compared to CH$_3$OH. If this CH$_3$CN enhancement is the result of carbon-grain sublimation, these results suggests that Earth's initial formation conditions may not be rare., Comment: 19 pages, 9 figures, 4 tables (plus 13 pages appendix with 10 figures, 4 tables). Accepted for publication in ApJ

The magnetic field of a molecular cloud core may play a role in the formation of circumstellar disks in the core. We present magnetic field morphologies in protostellar cores of 16 targets in the Atacama Large Millimeter/submillimeter Array large program "Early Planet Formation in Embedded Disks (eDisk)", which resolved their disks with 7 au resolutions. The 0.1-pc scale magnetic field morphologies were inferred from the James Clerk Maxwell Telescope (JCMT) POL-2 observations. The mean orientations and angular dispersions of the magnetic fields in the dense cores are measured and compared with the radii of the 1.3 mm continuum disks and the dynamically determined protostellar masses from the eDisk program. We observe a significant correlation between the disk radii and the stellar masses. We do not find any statistically significant dependence of the disk radii on the projected misalignment angles between the rotational axes of the disks and the magnetic fields in the dense cores, nor on the angular dispersions of the magnetic fields within these cores. However, when considering the projection effect, we cannot rule out a positive correlation between disk radii and misalignment angles in three-dimensional space. Our results suggest that the morphologies of magnetic fields in dense cores do not play a dominant role in the disk formation process. Instead, the sizes of protostellar disks may be more strongly affected by the amount of mass that has been accreted onto star+disk systems, and possibly other parameters, for example, magnetic field strength, core rotation, and magnetic diffusivity., Comment: 14 pages, 4 figures, accepted by ApJ

We use both chirped-pulse Fourier transform and frequency modulated absorption spectroscopy to study the rotational spectrum of 2-methoxyethanol in several frequency regions ranging from 8.7-500 GHz. The resulting rotational parameters permitted a search for this molecule in Atacama Large Millimeter/submillimeter Array (ALMA) observations toward the massive protocluster NGC 6334I as well as source B of the low-mass protostellar system IRAS 16293-2422. 25 rotational transitions are observed in the ALMA Band 4 data toward NGC 6334I, resulting in the first interstellar detection of 2-methoxyethanol. A column density of $1.3_{-0.9}^{+1.4} \times 10^{17}$ cm$^{-2}$ is derived at an excitation temperature of $143_{-39}^{+31}$ K. However, molecular signal is not observed in the Band 7 data toward IRAS 16293-2422B and an upper limit column density of $2.5 \times 10^{15}$ cm$^{-2}$ is determined. Various possible formation pathways--including radical recombination and insertion reactions--are discussed. We also investigate physical differences between the two interstellar sources that could result in the observed abundance variations., Comment: Accepted for publication in The Astrophysical Journal Letters

Young protostellar binary systems, with expected ages less than $\sim$10$^5$ years, are little modified since birth, providing key clues to binary formation and evolution. We present a first look at the young, Class 0 binary protostellar system R CrA IRAS 32 from the Early Planet Formation in Embedded Disks (eDisk) ALMA large program, which observed the system in the 1.3 mm continuum emission, $^{12}$CO (2-1), $^{13}$CO (2-1), C$^{18}$O (2-1), SO (6$_5$-5$_4$), and nine other molecular lines that trace disk, envelope, shocks, and outflows. With a continuum resolution of $\sim$0.03$^{\prime\prime}$ ($\sim$5 au, at a distance of 150 pc), we characterize the newly discovered binary system with a separation of 207 au, their circumstellar disks, and a circumbinary disk-like structure. The circumstellar disk radii are 26.9$\pm$0.3 and 22.8$\pm$0.3 au for sources A and B, respectively, and their circumstellar disk dust masses are estimated as 22.5$\pm$1.1 and 12.4$\pm$0.6 M$_{\Earth}$. The circumstellar disks and the circumbinary structure have well aligned position angles and inclinations, indicating formation in a smooth, ordered process such as disk fragmentation. In addition, the circumstellar disks have a near/far-side asymmetry in the continuum emission suggesting that the dust has yet to settle into a thin layer near the midplane. Spectral analysis of CO isotopologues reveals outflows that originate from both of the sources and possibly from the circumbinary disk-like structure. Furthermore, we detect Keplerian rotation in the $^{13}$CO isotopologues toward both circumstellar disks and likely Keplerian rotation in the circumbinary structure; the latter suggests that it is probably a circumbinary disk., Comment: 33 pages, 29 figures, 6 tables

We present ALMA observations of the Class I source Oph IRS63 in the context of the Early Planet Formation in Embedded Disks (eDisk) large program. Our ALMA observations of Oph IRS63 show a myriad of protostellar features, such as a shell-like bipolar outflow (in $^{12}$CO), an extended rotating envelope structure (in $^{13}$CO), a streamer connecting the envelope to the disk (in C$^{18}$O), and several small-scale spiral structures seen towards the edge of the dust continuum (in SO). By analyzing the velocity pattern of $^{13}$CO and C$^{18}$O, we measure a protostellar mass of $\rm M_\star = 0.5 \pm 0.2 $~$\rm M_\odot$ and confirm the presence of a disk rotating at almost Keplerian velocity that extends up to $\sim260$ au. These calculations also show that the gaseous disk is about four times larger than the dust disk, which could indicate dust evolution and radial drift. Furthermore, we model the C$^{18}$O streamer and SO spiral structures as features originating from an infalling rotating structure that continuously feeds the young protostellar disk. We compute an envelope-to-disk mass infall rate of $\sim 10^{-6}$~$\rm M_\odot \, yr^{-1}$ and compare it to the disk-to-star mass accretion rate of $\sim 10^{-8}$~$\rm M_\odot \, yr^{-1}$, from which we infer that the protostellar disk is in a mass build-up phase. At the current mass infall rate, we speculate that soon the disk will become too massive to be gravitationally stable., Comment: 26 pages and 17 figures

We present the first results from the Early Planet Formation in Embedded Disks (eDisk) ALMA Large Program toward Oph IRS43, a binary system of solar mass protostars. The 1.3 mm dust continuum observations resolve a compact disk, ~6au radius, around the northern component and show that the disk around the southern component is even smaller, <~3 au. CO, 13CO, and C18O maps reveal a large cavity in a low mass envelope that shows kinematic signatures of rotation and infall extending out to ~ 2000au. An expanding CO bubble centered on the extrapolated location of the source ~130 years ago suggests a recent outburst. Despite the small size of the disks, the overall picture is of a remarkably large and dynamically active region., Comment: Paper 10 of the ALMA eDisk Large Program. Accepted for publication in ApJ

Protostellar disks are a ubiquitous part of the star formation process and the future sites of planet formation. As part of the Early Planet Formation in Embedded Disks (eDisk) large program, we present high-angular resolution dust continuum ($\sim40\,$mas) and molecular line ($\sim150\,$mas) observations of the Class 0 protostar, IRAS 15398-3359. The dust continuum is small, compact, and centrally peaked, while more extended dust structures are found in the outflow directions. We perform a 2D Gaussian fitting to find the deconvolved size and $2\sigma$ radius of the dust disk to be $4.5\times2.8\,\mathrm{au}$ and $3.8\,\mathrm{au}$, respectively. We estimate the gas+dust disk mass assuming optically thin continuum emission to be $0.6-1.8\,M_\mathrm{jup}$, indicating a very low-mass disk. The CO isotopologues trace components of the outflows and inner envelope, while SO traces a compact, rotating disk-like component. Using several rotation curve fittings on the PV diagram of the SO emission, the lower limits of the protostellar mass and gas disk radius are $0.022\,M_\odot$ and $31.2\,\mathrm{au}$ from our Modified 2 single power-law fitting. A conservative upper limit of the protostellar mass is inferred to be $0.1\,M_\odot$. The protostellar mass-accretion rate and the specific angular momentum at the protostellar disk edge are found to be between $1.3-6.1\times10^{-6}\,M_\odot\,\mathrm{yr^{-1}}$ and $1.2-3.8\times10^{-4}\,\mathrm{km\,s^{-1}\,pc}$, respectively, with an age estimated between $0.4-7.5\times10^{4}\,$yr. At this young age with no clear substructures in the disk, planet formation would likely not yet have started. This study highlights the importance of high-resolution observations and systematic fitting procedures when deriving dynamical properties of deeply embedded Class 0 protostars., Comment: 28 pages, 16 figures. Accepted for publication in ApJ as one of the first-look papers of the eDisk ALMA Large Program

Precise estimates of protostellar masses are crucial to characterize the formation of stars of low masses down to brown-dwarfs (BDs; M* < 0.08 Msun). The most accurate estimation of protostellar mass uses the Keplerian rotation in the circumstellar disk around the protostar. To apply the Keplerian rotation method to a protostar at the low-mass end, we have observed the Class 0 protostar IRAS 16253-2429 using the Atacama Large Millimeter/submillimeter Array (ALMA) in the 1.3 mm continuum at an angular resolution of 0.07" (10 au), and in the 12CO, C18O, 13CO (J=2-1), and SO (J_N = 6_5-5_4) molecular lines, as part of the ALMA Large Program Early Planet Formation in Embedded Disks (eDisk). The continuum emission traces a non-axisymmetric, disk-like structure perpendicular to the associated 12CO outflow. The position-velocity (PV) diagrams in the C18O and 13CO lines can be interpreted as infalling and rotating motions. In contrast, the PV diagram along the major axis of the disk-like structure in the 12CO line allows us to identify Keplerian rotation. The central stellar mass and the disk radius are estimated to be ~0.12-0.17 Msun and ~13-19 au, respectively. The SO line suggests the existence of an accretion shock at a ring (r~28 au) surrounding the disk and a streamer from the eastern side of the envelope. IRAS 16253-2429 is not a proto-BD but has a central stellar mass close to the BD mass regime, and our results provide a typical picture of such very low-mass protostars., Comment: 41 pages, 14 figures

Water is a very abundant molecule in star-forming regions. Its deuterium fractionation is an important tool for understanding its formation and evolution during the star and planet formation processes. While the HDO/H$_2$O ratio has been determined toward several Class 0 protostars and comets, the number of studies toward Class I protostars is limited. We aim to study the water deuteration toward the Class I binary protostar L1551 IRS5 and to investigate the effect of evolutionary stage and environment on variations in the water D/H ratio. Observations were made using the NOEMA interferometer. The HDO 3$_{1,2}$-2$_{2,1}$ transition at 225.9 GHz and the H$_2^{18}$O 3$_{1,3}$-2$_{2,0}$ transition at 203.4 GHz were covered with a spatial resolution of 0.5'' $\times$ 0.8'', while the HDO 4$_{2,2}$-4$_{2,3}$ transition at 143.7 GHz was observed with a resolution of 2.0'' $\times$ 2.5''. We used both LTE and non-LTE models. The three transitions are detected. The line profiles display two peaks, one at $\sim$6 km s$^{-1}$ and one at $\sim$9 km s$^{-1}$. We derive an HDO/H$_2$O ratio of (2.1 $\pm$ 0.8) $\times$ 10$^{-3}$ for the redshifted component and a lower limit of $>$ 0.3 $\times$ 10$^{-3}$ for the blueshifted component due to the blending with the redshifted CH$_3$OCH$_3$ emission. The HDO/H$_2$O in L1551 IRS5 is similar to the ratios in isolated Class 0 sources and to the Class I V883 Ori, while it is significantly higher than in the clustered Class 0 sources and the comets. This suggests that the chemistry of protostars in low source densities clouds share more similarities with the isolated sources than the protostars of very dense clusters. If Class 0 protostars with few sources around and isolated Class 0 objects are comparable in the HDO/H$_2$O ratio, it would mean that there is little water reprocessing from the Class 0 to Class I protostellar stage., Comment: Accepted in A&A, 10 pages, 8 figures

We present high-resolution, high-sensitivity observations of the Class 0 protostar RCrA IRS5N as part of the Atacama Large Milimeter/submilimeter Array (ALMA) large program Early Planet Formation in Embedded Disks (eDisk). The 1.3 mm continuum emission reveals a flattened continuum structure around IRS5N, consistent with a protostellar disk in the early phases of evolution. The continuum emission appears smooth and shows no substructures. However, a brightness asymmetry is observed along the minor axis of the disk, suggesting the disk is optically and geometrically thick. We estimate the disk mass to be between 0.007 and 0.02 M$_{\odot}$. Furthermore, molecular emission has been detected from various species, including C$^{18}$O (2$-$1), $^{12}$CO (2$-$1), $^{13}$CO (2$-$1), and H$_2$CO (3$_{0,3}-2_{0,2}$, 3$_{2,1}-2_{2,0}$, and 3$_{2,2}-2_{2,1}$). By conducting a position-velocity analysis of the C$^{18}$O (2$-$1) emission, we find that the disk of IRS5N exhibits characteristics consistent with Keplerian rotation around a central protostar with a mass of approximately 0.3 M$_{\odot}$. Additionally, we observe dust continuum emission from the nearby binary source, IRS5a/b. The emission in $^{12}$CO toward IRS5a/b seems to emanate from IRS5b and flow into IRS5a, suggesting material transport between their mutual orbits. The lack of a detected outflow and large-scale negatives in \tlvco~observed toward IRS5N suggests that much of the flux from IRS5N is being resolved out. Due to this substantial surrounding envelope, the central IRS5N protostar is expected to be significantly more massive in the future., Comment: 25 pages, 24 figures. Accepted for publication in ApJ

We report the detection of the millimeter CH$_3$OH masers including a new detection of class I (11$_{0,11}$-10$_{1,10}$A) and class II (6$_{1,5}$-5$_{2,4}$E) maser transitions toward the high-mass protostar S255IR NIRS3 in post-burst phase. The CH$_3$OH emissions were detected as a mixture of maser and thermal characteristics. We examine the detected transitions using an excitation diagram and LTE model spectra and compare the observed properties with those of thermal lines. Class II CH$_3$OH maser transitions showed distinctive intensity and velocity distributions from those of thermal transitions. Bright distinct emission components in addition to the fragmented and arc-shaped emissions are only detected in class I CH$_3$OH maser transitions toward southern and western directions from the protostellar position, implying the presence of the slow outflow shocks., Comment: 9 pages, 4 Figures, 1 Table, Accepted for publication in ApJL

We have observed the Class 0/I protostellar system Ced110 IRS4 at an angular resolution of $0.05''$ ($\sim$10 au) as a part of the ALMA large program; Early Planet Formation in the Embedded Disks (eDisk). The 1.3 mm dust continuum emission reveals that Ced110 IRS4 is a binary system with a projected separation of $\sim$250 au. The continuum emissions associated with the main source and its companion, named Ced110 IRS4A and IRS4B respectively, exhibit disk-like shapes and likely arise from dust disks around the protostars. The continuum emission of Ced110 IRS4A has a radius of $\sim$91.7 au ($\sim0.485''$), and shows bumps along its major axis with an asymmetry. The bumps can be interpreted as an shallow, ring-like structure at a radius of $\sim$40 au ($\sim0.2''$) in the continuum emission, as demonstrated from two-dimensional intensity distribution models. A rotation curve analysis on the C$^{18}$O and $^{13}$CO $J=2$-1 lines reveals the presence of a Keplerian disk within a radius of 120 au around Ced110 IRS4A, which supports the interpretation that the dust continuum emission arises from a disk. The ring-like structure in the dust continuum emission might indicate a possible, annular substructure in the surface density of the embedded disk, although the possibility that it is an apparent structure due to the optically thick continuum emission cannot be ruled out., Comment: 32 pages, 23 figures. Accepted for publication in ApJ as one of the first-look papers of the eDisk ALMA Large Program

Constraining the physical and chemical structure of young embedded disks is crucial to understanding the earliest stages of planet formation. As part of the Early Planet Formation in Embedded Disks Atacama Large Millimeter/submillimeter Array Large Program, we present high spatial resolution ($\sim$0$.\!\!^{\prime\prime}$1 or $\sim$15 au) observations of the 1.3 mm continuum and $^{13}$CO $J=$ 2-1, C$^{18}$O $J=$ 2-1, and SO $J_N=$ $6_5$-$5_4$ molecular lines toward the disk around the Class I protostar L1489 IRS. The continuum emission shows a ring-like structure at 56 au from the central protostar and a tenuous, optically thin emission extending beyond $\sim$300 au. The $^{13}$CO emission traces the warm disk surface, while the C$^{18}$O emission originates from near the disk midplane. The coincidence of the radial emission peak of C$^{18}$O with the dust ring may indicate a gap-ring structure in the gaseous disk as well. The SO emission shows a highly complex distribution, including a compact, prominent component at $\lesssim$30 au, which is likely to originate from thermally sublimated SO molecules. The compact SO emission also shows a velocity gradient along a slightly ($\sim15^\circ$) tilted direction with respect to the major axis of the dust disk, which we interpret as an inner warped disk in addition to the warp around $\sim$200 au suggested by previous work. These warped structures may be formed by a planet or companion with an inclined orbit, or by a gradual change in the angular momentum axis during gas infall., Comment: 24 pages, 12 figures. Accepted for publication in The Astrophysical Journal as one of the first-look papers of the eDisk ALMA Large Program

Studying the physical and chemical conditions of young embedded disks is crucial to constrain the initial conditions for planet formation. Here, we present Atacama Large Millimeter/submillimeter Array (ALMA) observations of dust continuum at $\sim$0.06" (8 au) resolution and molecular line emission at $\sim$0.17" (24 au) resolution toward the Class 0 protostar L1527 IRS from the Large Program eDisk (Early Planet Formation in Embedded Disks). The continuum emission is smooth without substructures, but asymmetric along both the major and minor axes of the disk as previously observed. The detected lines of $^{12}$CO, $^{13}$CO, C$^{18}$O, H$_2$CO, c-C$_3$H$_2$, SO, SiO, and DCN trace different components of the protostellar system, with a disk wind potentially visible in $^{12}$CO. The $^{13}$CO brightness temperature and the H$_2$CO line ratio confirm that the disk is too warm for CO freeze out, with the snowline located at $\sim$350 au in the envelope. Both molecules show potential evidence of a temperature increase around the disk-envelope interface. SO seems to originate predominantly in UV-irradiated regions such as the disk surface and the outflow cavity walls rather than at the disk-envelope interface as previously suggested. Finally, the continuum asymmetry along the minor axis is consistent with the inclination derived from the large-scale (100" or 14,000 au) outflow, but opposite to that based on the molecular jet and envelope emission, suggesting a misalignment in the system. Overall, these results highlight the importance of observing multiple molecular species in multiple transitions to characterize the physical and chemical environment of young disks., Comment: 27 pages, 16 figures, 2 tables, 10 pages appendix with 12 figures. Accepted for publication in ApJ as one of the first-look papers of the eDisk ALMA Large Program

We present an overview of the Large Program, ``Early Planet Formation in Embedded Disks (eDisk)'', conducted with the Atacama Large Millimeter/submillimeter Array (ALMA). The ubiquitous detections of substructures, particularly rings and gaps, in protoplanetary disks around T Tauri stars raise the possibility that at least some planet formation may have already started during the embedded stages of star formation. In order to address exactly how and when planet formation is initiated, the program focuses on searching for substructures in disks around 12 Class 0 and 7 Class I protostars in nearby ($< $200 pc) star-forming regions through 1.3 mm continuum observations at a resolution of $\sim7$ au (0.04"). The initial results show that the continuum emission, mostly arising from dust disks around the sample protostars, has relatively few distinctive substructures, such as rings and spirals, in marked contrast to Class II disks. The dramatic difference may suggest that substructures quickly develop in disks when the systems evolve from protostars to Class II sources or alternatively that high optical depth of the continuum emission could obscure internal structures. Kinematic information obtained through CO isotopologue lines and other lines reveals the presence of Keplerian disks around protostars, providing us with crucial physical parameters, in particular, the dynamical mass of the central protostars. We describe the background of the eDisk program, the sample selection and their ALMA observations, the data reduction, and also highlight representative first-look results., Comment: This is a publication of a series of eDisk ALMA large program first-look papers

Previous observations of B335 have presented evidence of ongoing infall in various molecular lines, e.g., HCO$^+$, HCN, CO. There have been no confirmed observations of a rotationally supported disk on scales greater than ~12~au. The presence of an outflow in B335 suggests that also a disk should be present or in formation. To constrain the earliest stages of protostellar evolution and disk formation, we aim to map the region where gas falls inwards and observationally constrain its kinematics. Furthermore, we aim to put strong limits on the size and orientation of any disk-like structure in B335. We use high angular resolution $^{13}$CO data from ALMA, and combine it with shorter-baseline archival data to produce a high-fidelity image of the infall in B335. We also revisit the imaging of high-angular resolution Band 6 continuum data to study the dust distribution in the immediate vicinity of B335. Continuum emission shows an elliptical structure (10 by 7 au) with a position angle 5 degrees east of north, consistent with the expectation for a forming disk in B335. A map of the infall velocity (as estimated from the $^{13}$CO emission), shows evidence of asymmetric infall, predominantly from the north and south. Close to the protostar, infall velocities appear to exceed free-fall velocities. 3D radiative transfer models, where the infall velocity is allowed to vary within the infall region, can explain the observed kinematics. The data suggests that a disk has started to form in B335 and that gas is falling towards that disk. However, kinematically-resolved line data towards the disk itself is needed to confirm the presence of a rotationally supported disk around this young protostar. The measured high infall velocities are not easily reconcilable with a magnetic braking scenario and suggest that there is a pressure gradient that allows the infall velocity to vary in the region., Comment: 14 pages, 11 figures

We prepared a sample of oxirane doubly deuterated at one C atom and studied its rotational spectrum in the laboratory for the first time between 120~GHz and 1094~GHz. Accurate spectroscopic parameters up to eighth order were determined, and the calculated rest frequencies were used to identify $c$-CD$_2$CH$_2$O tentatively in the interstellar medium in the Atacama Large Millimeter/submillimeter Array Protostellar Interferometric Line Survey (PILS) of the Class 0 protostellar system IRAS 16293$-$2422. The $c$-CD$_2$CH$_2$O to $c$-C$_2$H$_4$O ratio was estimated to be $\sim$0.054 with $T_{\rm rot} = 125$ K. This value translates to a D-to-H ratio of $\sim$0.16 per H atom which is higher by a factor of 4.5 than the $\sim$0.036 per H atom obtained for $c$-C$_2$H$_3$DO. Such increase in the degree of deuteration referenced to one H atom in multiply deuterated isotopologs compared to their singly deuterated variants have been observed commonly in recent years., Comment: Journal of Molecular Spectroscopy, in press; Per Jensen special issue. 12 pages here

Up to date, only 6 imines have been detected in the interstellar medium. The 3-carbon imine, 2-propanimine ((CH$_3$)$_2$C=NH), is predicted to be the structural isomer with the lowest energy in the C$_3$H$_7$N group, and appears to be a good candidate for astronomical searches. Unexpectedly, no microwave or millimeter wave spectrum is available for 2-propanimine. In this work, we provide the first high resolution millimeter wave spectrum of 2-propanimine and its analysis. With the guide of this laboratory measurement, we aim to search for 2-propanimine in two molecule-rich sources Sgr B2(N) and IRAS 16293-2422 using observations from the Atacama Large Millimeter/submillimeter Array (ALMA). Starting from a synthesized sample, we measured the spectrum of 2-propanimine from 50 to 500 GHz, and the ground state lines are successfully assigned and fitted using XIAM and ERHAM programs with the aid of theoretical calculations. The barriers to internal rotation of the two CH$_3$ tops are determined to be 531.956(64) cm$^{-1}$ and 465.013(26) cm$^{-1}$. These data are able to provide reliable prediction of transition frequencies for astronomical search. Although a few line matches exist, no confirmed detection of 2-propanimine has been found in the hot molecular core Sgr B2(N1S) and the Class 0 protostar IRAS 16293B. Upper-limits of its column density have been derived, and indicate that 2-propanimine is at least 18 times less abundant than methanimine in Sgr B2(N1S), and is at most 50-83 % of methanimine in IRAS 16293B., Comment: 14 pages, 10 figures

Models of the protostellar source, B335, are developed using axisymmetric three-dimensional models to resolve conflicts found in one-dimensional models. The models are constrained by a large number of observations, including ALMA, Herschel, and Spitzer data. Observations of the protostellar source B335 with ALMA show red-shifted absorption against a central continuum source indicative of infall in the HCO$^+$ and HCN $J = 4\rightarrow 3$ transitions. The data are combined with a new estimate of the distance to provide strong constraints to three-dimensional radiative transfer models including a rotating, infalling envelope, outflow cavities, and a very small disk. The models favor ages since the initiation of collapse between $3 \times 10^4$ and $4 \times 10^4$ yr for both the continuum and the lines, resolving a conflict found in one-dimensional models. The models under-predict the continuum emission seen by ALMA, suggesting an additional component such as a pseudo-disk. The best-fitting model is used to convert variations in the 4.5 $\mu m$ flux in recent years into a model for a variation of a factor of 5-7 in luminosity over the last 8 years., Comment: 22 pages, 20 figures, in press ApJ

The nitrogen chemical evolution during star and planet formation is still not fully understood. Ammonia (NH$_3$) is a key specie in the understanding of the molecular evolution in star-forming clouds and nitrogen isotope fractionation. In this paper, we present high spatial resolution observations of multiple emission lines of NH$_3$ toward the protobinary system NGC1333 IRAS4A with Karl G. Jansky Very Large Array (VLA). We spatially resolved the binary (hereafter 4A1 and 4A2) and detected compact emission of NH$_3$ transitions with high excitation energies ($\gtrsim$100 K) from the vicinity of the protostars, indicating the NH$_3$ ice has sublimated at the inner hot region. The NH$_3$ column density is estimated to be $\sim 10^{17}-10^{18}$ cm$^{-2}$. We also detected two NH$_2$D transitions, allowing us to constrain the deuterium fractionation of ammonia. The NH$_2$D/NH$_3$ ratios are as high as $\sim 0.3-1$ in both 4A1 and 4A2. From the comparisons with the astrochemical models in the literature, the high NH$_2$D/NH$_3$ ratios suggest that the formation of NH$_3$ ices mainly started in the prestellar phase after the formation of bulk water ice finished, and that the primary nitrogen reservoir in the star-forming cloud could be atomic nitrogen (or N atoms) rather than nitrogen-bearing species such as N$_2$ and NH$_3$. The implications on the physical properties of IRAS4A cores are discussed as well., Comment: 20 pages, 7 figures, accepted for publication in ApJ

We prepared a sample of mono-deuterated oxirane and studied its rotational spectrum in the laboratory between 490 GHz and 1060 GHz in order to improve its spectroscopic parameters and consequently the calculated rest frequencies of its rotational transitions. The updated rest frequencies were employed to detect $c$-C$_2$H$_3$DO for the first time in the interstellar medium in the Atacama Large Millimetre/submillimetre Array (ALMA) Protostellar Interferometric Line Survey (PILS) of the Class 0 protostellar system IRAS 16293$-$2422. Fits of the detected lines using the rotation diagrams yield a temperature of $T_{\rm rot} = 103 \pm 19$ K, which in turn agrees well with 125 K derived for the $c$-C$_2$H$_4$O main isotopologue previously. The $c$-C$_2$H$_3$DO to $c$-C$_2$H$_4$O ratio is found to be $\sim$0.15 corresponding to a D-to-H ratio of $\sim$0.036 per H atom which is slightly higher than the D-to-H ratio of species such as methanol, formaldehyde, ketene and but lower than those of the larger complex organic species such as ethanol, methylformate and glycolaldehyde. This may reflect that oxirane is formed fairly early in the evolution of the prestellar cores. The identification of doubly deuterated oxirane isotopomers in the PILS data may be possible judged by the amount of mono-deuterated oxirane and the observed trend that multiply deuterated isotopologues have higher deuteration rates than their mono-deuterated variants., Comment: 10 pages total; Mon. Not. R. Astron. Soc., accepted

We present high resolution Karl G. Jansky Very Large Array (VLA) observations of the protostar L1527 IRS at 7 mm, 1.3 cm, and 2 cm wavelengths. We detect the edge-on dust disk at all three wavelengths and find that it is asymmetric, with the southern side of the disk brighter than the northern side. We confirm this asymmetry through analytic modeling and also find that the disk is flared at 7 mm. We test the data against models including gap features in the intensity profile, and though we cannot rule such models out, they do not provide a statistically significant improvement in the quality of fit to the data. From these fits, we can however place constraints on allowed properties of any gaps that could be present in the true, underlying intensity profile. The physical nature of the asymmetry is difficult to associate with physical features due to the edge-on nature of the disk, but could be related to spiral arms or asymmetries seen in other imaging of more face-on disks., Comment: 20 pages, 5 figures, 3 tables; accepted for publication in the Astrophysical Journal

The water snowline in circumstellar disks is a crucial component in planet formation, but direct observational constraints on its location remain sparse due to the difficulty of observing water in both young embedded and mature protoplanetary disks. Chemical imaging provides an alternative route to locate the snowline, and HCO$^+$ isotopologues have been shown to be good tracers in protostellar envelopes and Herbig disks. Here we present $\sim$0.5$^{\prime\prime}$ resolution ($\sim$35 au radius) Atacama Large Millimeter/submillimeter Array (ALMA) observations of HCO$^+$ $J=4-3$ and H$^{13}$CO$^+$ $J=3-2$ toward the young (Class 0/I) disk L1527 IRS. Using a source-specific physical model with the midplane snowline at 3.4 au and a small chemical network, we are able to reproduce the HCO$^+$ and H$^{13}$CO$^+$ emission, but for HCO$^+$ only when the cosmic ray ionization rate is lowered to $10^{-18}$ s$^{-1}$. Even though the observations are not sensitive to the expected HCO$^+$ abundance drop across the snowline, the reduction in HCO$^+$ above the snow surface and the global temperature structure allow us to constrain a snowline location between 1.8 and 4.1 au. Deep observations are required to eliminate the envelope contribution to the emission and to derive more stringent constraints on the snowline location. Locating the snowline in young disks directly with observations of H$_2$O isotopologues may therefore still be an alternative option. With a direct snowline measurement, HCO$^+$ will be able to provide constraints on the ionization rate., Comment: Accepted for publication in ApJ, 15 pages, 6 figures and appendix

This work aims to constrain the abundances of interstellar amides, by searching for this group of prebiotic molecules in the intermediate-mass protostar Serpens SMM1-a. ALMA observations are conducted toward Serpens SMM1. A spectrum is extracted toward the SMM1-a position and analyzed with the CASSIS line analysis software for the presence of characteristic rotational lines of a number of amides and other molecules. NH$_{2}$CHO, NH$_{2}$CHO $\nu_{12}$=1, NH$_{2}^{13}$CHO, CH$_{3}$C(O)NH$_{2}$ $\nu$=0,1, CH$_{2}$DOH, CH$_{3}$CHO, and CH$_{3}$C(O)CH$_{3}$ are securely detected, while trans-NHDCHO, NH$_{2}$CDO, CH$_{3}$NHCHO $\nu$=0,1, CH$_{3}$COOH, and HOCH$_{2}$CHO are tentatively identified. The results of this work are compared with detections presented in the literature. A uniform CH$_{3}$C(O)NH$_{2}$/NH$_{2}$CHO ratio is found for a group of interstellar sources with vast physical differences. A similar ratio is seen for CH$_{3}$NHCHO, based on a smaller data sample. The D/H ratio of NH$_{2}$CHO is about 1--3\% and is close to values found in the low-mass source IRAS~16293--2422B. The formation of CH$_{3}$C(O)NH$_{2}$ and NH$_{2}$CHO is likely linked. Formation of these molecules on grain surfaces during the dark cloud stage is a likely scenario. The high D/H ratio of NH$_{2}$CHO is also seen as an indication that these molecules are formed on icy dust grains. As a direct consequence, amides are expected to be present in the most pristine material from which planetary systems form, thus providing a reservoir of prebiotic material., Comment: Accepted for publication in ACS Earth and Space Chemistry; 59 pages, 10 figures

Accurate quantification of the column density of di-deuterated methanol is a key missing puzzle piece in the otherwise thoroughly constrained family of D-bearing methanol in the deeply embedded low-mass protostellar system and astrochemical template source IRAS16293-2422. A spectroscopic dataset for astrophysical purposes is built for CHD$_{2}$OH and made publicly available to facilitate accurate characterization of this species in astrochemical surveys. The newly computed line list and partition function are used to search for CHD$_{2}$OH towards IRAS16293-2422 A and B in data from ALMA-PILS. Only non-blended, optically thin lines of CHD$_{2}$OH are used for the synthetic spectral fitting. The constructed spectroscopic database contains line frequencies and strengths for 7417 transitions in the 0 to 500 GHz frequency range. ALMA-PILS observations in the 329-363 GHz range are used to identify 105 unique, non-blended, optically thin line frequencies of CHD$_{2}$OH for synthetic spectral fitting. The derived excitation temperatures and column densities yield high D/H ratios of CHD$_{2}$OH in IRAS 16293-2422 A and B of 7.5$\pm$1.1% and 7.7$\pm$1.2%, respectively. Deuteration in IRAS 16293-2422 is not higher than in other low-mass star-forming regions. Di-deuterated molecules consistently have higher D/H ratios than their monodeuterated counterparts in all low-mass protostars, which may be a natural consequence of H-D substitution reactions as seen in laboratory experiments. The Solar System's natal cloud, as traced by comet 67P/Churyumov-Gerasimenko, may have had a lower initial abundance of D, been warmer than the cloud of IRAS16293-2422, or been partially reprocessed. In combination with accurate spectroscopy, a careful spectral analysis, and a consideration of the underlying assumptions, successive deuteration is a robust window on the physicochemical provenance of star-forming systems., Comment: Accepted for publication in A&A; 24 pages, 18 figures, 3 tables; the full line list is made available as an electronic Table at the Centre de Donn\'ees astronomiques de Strasbourg (CDS) with association to this A&A article

Chemistry along the star- and planet-formation sequence regulates how prebiotic building blocks -- carriers of the elements CHNOPS -- are incorporated into nascent planetesimals and planets. Spectral line observations across the electromagnetic spectrum are needed to fully characterize interstellar CHNOPS chemistry, yet to date there are only limited astrochemical constraints at THz frequencies. Here, we highlight advances to the study of CHNOPS astrochemistry that will be possible with the Orbiting Astronomical Satellite for Investigating Stellar Systems (OASIS). OASIS is a NASA mission concept for a space-based observatory that will utilize an inflatable 14-m reflector along with a heterodyne receiver system to observe at THz frequencies with unprecedented sensitivity and angular resolution. As part of a survey of H2O and HD towards ~100 protostellar and protoplanetary disk systems, OASIS will also obtain statistical constraints on the inventories of light hydrides including NH3 and H2S towards protoplanetary disks, as well as complex organics in protostellar hot corinos and envelopes. Line surveys of additional star-forming regions, including high-mass hot cores, protostellar outflow shocks, and prestellar cores, will also leverage the unique capabilities of OASIS to probe high-excitation organics and small hydrides, as is needed to fully understand the chemistry of these objects., Comment: Accepted to Frontiers in Astronomy and Space Sciences

Context: Gas accretion flows transport material from the cloud core onto the protostar. In multiple protostellar systems, it is not clear if the delivery mechanism is preferential or evenly distributed among the components. Aims: Gas accretion flows within IRAS16293 is explored out to 6000 AU. Methods: ALMA Band 3 observations of low-$J$ transitions of HNC, cyanopolyynes (HC$_3$N, HC$_5$N), and N$_2$H$^+$ are used to probe the cloud core structure at ~100 AU resolution. Additional Band 3 archival data provide low-$J$ HCN and SiO lines. These data are compared with the corresponding higher-$J$ lines from the PILS Band 7 data for excitation analysis. The HNC/HCN ratio is used as a temperature tracer. Results: The low-$J$ transitions of HC$_3$N, HC$_5$N, HNC and N$_2$H$^+$ trace extended and elongated structures from 6000 AU down to ~100 AU, without accompanying dust continuum emission. Two structures are identified: one traces a flow that is likely accreting toward the most luminous component of the system IRAS16293 A. Temperatures inferred from the HCN/HNC ratio suggest that the gas in this flow is cold, between 10 and 30 K. The other structure is part of an UV-irradiated cavity wall entrained by one of the outflows. The two outflows driven by IRAS16293 A present different molecular gas distributions. Conclusions: Accretion of cold gas is seen from 6000 AU scales onto IRAS16293 A, but not onto source B, indicates that cloud core material accretion is competitive due to feedback onto a dominant component in an embedded multiple protostellar system. The preferential delivery of material could explain the higher luminosity and multiplicity of source A compared to source B. The results of this work demonstrate that several different molecular species, and multiple transitions of each species, are needed to confirm and characterize accretion flows in protostellar cloud cores., Comment: 17 pages, 10 figures, accepted for publication in A&A

The water snowline location in protostellar envelopes provides crucial information about the thermal structure and the mass accretion process as it can inform about the occurrence of recent ($\lesssim$1,000 yr) accretion bursts. In addition, the ability to image water emission makes these sources excellent laboratories to test indirect snowline tracers such as H$^{13}$CO$^+$. We study the water snowline in five protostellar envelopes in Perseus using a suite of molecular line observations taken with the Atacama Large Millimeter/submillimeter Array (ALMA) at $\sim$0.2$^{\prime\prime}-$0.7$^{\prime\prime}$ (60--210 au) resolution. B1-c provides a textbook example of compact H$_2^{18}$O ($3_{1,3}-2_{2,0}$) and HDO ($3_{1,2}-2_{2,1}$) emission surrounded by a ring of H$^{13}$CO$^+$ ($J=2-1$) and HC$^{18}$O$^+$ ($J=3-2$). Compact HDO surrounded by H$^{13}$CO$^+$ is also detected toward B1-bS. The optically thick main isotopologue HCO$^+$ is not suited to trace the snowline and HC$^{18}$O$^+$ is a better tracer than H$^{13}$CO$^+$ due to a lower contribution from the outer envelope. However, since a detailed analysis is needed to derive a snowline location from H$^{13}$CO$^+$ or HC$^{18}$O$^+$ emission, their true value as snowline tracer will lie in the application in sources where water cannot be readily detected. For protostellar envelopes, the most straightforward way to locate the water snowline is through observations of H$_2^{18}$O or HDO. Including all sub-arcsecond resolution water observations from the literature, we derive an average burst interval of $\sim$10,000 yr, but high-resolution water observations of a larger number of protostars is required to better constrain the burst frequency., Comment: Accepted for publication in ApJ

We report the detection of more than 120 emission lines corresponding to 8 complex organic molecules (CH3OH, CH3CH2OH, CH3OCH3, CH3OCHO, CH3COCH3, NH2CHO, CH2DCN, and CH3CH2CN) and 3 isotopologues (CH2DOH, 13CH3CN, and CH3C15N) toward the western component of the Ser-emb 11 binary young stellar object (YSO) using observations with the Atacama Large Millimeter/submillimeter Array at ~1 mm. The complex organic emission was unresolved with a ~0.5" beam (~220 au) in a compact region around the central protostar, and a population diagram analysis revealed excitation temperatures above 100 K for all COMs, indicating the presence of a hot corino. The estimated column densities were in the range of 10^17 - 10^18 cm^-2 for the O-bearing COMs, and three orders of magnitude lower for the N-bearing species. We also report the detection of H2CO and CH3OH emission in a nearby millimeter source that had not been previously catalogued. Ser-emb 11 is classified in the literature as a Class I source near the Class 0/I cutoff. The estimated COM relative abundances in Ser-emb 11 W and the other three Class I hot corino sources reported in the literature are consistent with those of Class 0 hot corinos, suggesting a continuity in the chemical composition of hot corinos during protostellar evolution.

Context. A variety of laboratory ice spectra simulating different chemical environments, ice morphology as well as thermal and energetic processing are demanded to provide an accurate interpretation of the infrared spectra of protostars. To answer which combination of laboratory data best fit the observations, an automated statistically-based computational approach becomes necessary. Aims. To introduce a new approach, based on evolutionary algorithms, to search for molecules in ice mantles via spectral decomposition of infrared observational data with laboratory ice spectra. Methods. A publicly available and open-source fitting tool, called ENIIGMA (dEcompositioN of Infrared Ice features using Genetic Modelling Algorithms), is introduced. The tool has dedicated Python functions to carry out continuum determination of the protostellar spectra, silicate extraction, spectral decomposition and statistical analysis to calculate confidence intervals and quantify degeneracy. As an assessment of the code, several tests were conducted with known ice samples and constructed mixtures. A complete analysis of the Elias 29 spectrum was performed as well. Results. The ENIIGMA fitting tool can identify the correct ice samples and their fractions in all checks with known samples tested in this paper. Concerning the Elias 29 spectrum, the broad spectral range between 2.5-20 $\mu$m was successfully decomposed after continuum determination and silicate extraction. This analysis allowed the identification of different molecules in the ice mantle, including a tentative detection of CH$_3$CH$_2$OH. Conclusions. The ENIIGMA is a toolbox for spectroscopy analysis of infrared spectra that is well-timed with the launch of the James Webb Space Telescope. Additionally, it allows for exploring the different chemical environments and irradiation fields in order to correctly interpret astronomical observations., Comment: 23 pages, 19 figures, 3 tables. Accepted for publication in A&A

We present observations toward HOPS 383, the first known outbursting Class 0 protostar located within the Orion molecular cloud using ALMA, VLA, and SMA. The SMA observations reveal envelope scale continuum and molecular line emission surrounding HOPS 383 at 0.85 mm, 1.1 mm, and 1.3 mm. The images show that HCO$^+$ and H$^{13}$CO$^+$ peaks on or near the continuum, while N$_2$H$^+$ is reduced at the same position. This reflects the underlying chemistry where CO evaporating close to the protostar destroys N$_2$H$^+$ while forming HCO$^+$. We also observe the molecular outflow traced by $^{12}$CO ($J = 2 \rightarrow 1$) and ($J = 3 \rightarrow 2$). A disk is resolved in the ALMA 0.87 mm dust continuum, orthogonal to the outflow direction, with an apparent radius of $\sim$62 AU. Radiative transfer modeling of the continuum gives disk masses of 0.02 M$_{\odot}$ when fit to the ALMA visibilities. The models including VLA 8 mm data indicate that the disk mass could be up to a factor of 10 larger due to lower dust opacity at longer wavelengths. The disk temperature and surface density profiles from the modeling, and an assumed protostar mass of 0.5 M$_{\odot}$ suggest that the Toomre $Q$ parameter $< 1$ before the outburst, making gravitational instability a viable mechanism to explain outbursts at an early age if the disk is sufficiently massive., Comment: Accepted by ApJ

The chemical composition of gas and ice in disks around young stars set the bulk composition of planets. In contrast to protoplanetary disks (Class II), young disks that are still embedded in their natal envelope (Class 0 and I) are predicted to be too warm for CO to freeze out, as has been confirmed observationally for L1527 IRS. To establish whether young disks are generally warmer than their more evolved counterparts, we observed five young (Class 0/I and Class I) disks in Taurus with the Atacama Large Millimeter/submillimeter Array (ALMA), targeting C$^{17}$O $2-1$, H$_2$CO $3_{1,2}-2_{1,1}$, HDO $3_{1,2}-2_{2,1}$ and CH$_3$OH $5_K-4_K$ transitions at $0.48^{\prime\prime} \times 0.31^{\prime\prime}$ resolution. The different freeze-out temperatures of these species allow us to derive a global temperature structure. C$^{17}$O and H$_2$CO are detected in all disks, with no signs of CO freeze-out in the inner $\sim$100 au, and a CO abundance close to $\sim$10$^{-4}$. H$_2$CO emission originates in the surface layers of the two edge-on disks, as witnessed by the especially beautiful V-shaped emission pattern in IRAS~04302+2247. HDO and CH$_3$OH are not detected, with column density upper limits more than 100 times lower than for hot cores. Young disks are thus found to be warmer than more evolved protoplanetary disks around solar analogues, with no CO freeze-out (or only in the outermost part of $\gtrsim$100 au disks) or CO processing. However, they are not as warm as hot cores or disks around outbursting sources, and therefore do not have a large gas-phase reservoir of complex molecules., Comment: Accepted for publication in ApJ. 19 pages, 11 figures, 3 tables (+ appendix)

Earth's carbon deficit has been an outstanding problem in our understanding of the formation of our Solar System. A possible solution would be the sublimation of carbon grains at the so-called soot line (~300 K) early in the planet-formation process. Here, we argue that the most likely signatures of this process are an excess of hydrocarbons and nitriles inside the soot line, and a higher excitation temperature for these molecules compared to oxygen-bearing complex organics that desorb around the water snowline (~100 K). Such characteristics have been reported in the literature, for example, in Orion KL, although not uniformly, potentially due to differences in observational settings and analysis methods of different studies or related to the episodic nature of protostellar accretion. If this process is active, this would mean that there is a heretofore unknown component to the carbon chemistry during the protostellar phase that is acting from the top down - starting from the destruction of larger species - instead of from the bottom up from atoms. In the presence of such a top-down component, the origin of organic molecules needs to be re-explored., Comment: Accepted for publication in ApJL. 14 pages, 2 figures, 1 table (4 pages)

The volatile composition of a planet is determined by the inventory of gas and ice in the parent disk. The volatile chemistry in the disk is expected to evolve over time, though this evolution is poorly constrained observationally. We present ALMA observations of C18O, C2H, and the isotopologues H13CN, HC15N, and DCN towards five Class 0/I disk candidates. Combined with a sample of fourteen Class II disks presented in Bergner et al. (2019b), this data set offers a view of volatile chemical evolution over the disk lifetime. Our estimates of C18O abundances are consistent with a rapid depletion of CO in the first ~0.5-1 Myr of the disk lifetime. We do not see evidence that C2H and HCN formation are enhanced by CO depletion, possibly because the gas is already quite under-abundant in CO. Further CO depletion may actually hinder their production by limiting the gas-phase carbon supply. The embedded sources show several chemical differences compared to the Class II stage, which seem to arise from shielding of radiation by the envelope (impacting C2H formation and HC15N fractionation) and sublimation of ices from infalling material (impacting HCN and C18O abundances). Such chemical differences between Class 0/I and Class II sources may affect the volatile composition of planet-forming material at different stages in the disk lifetime., Comment: Accepted to ApJ

Star-forming regions show a rich and varied chemistry, including the presence of complex organic molecules - both in the cold gas distributed on large scales, and in the hot regions close to young stars where protoplanetary disks arise. Recent advances in observational techniques have opened new possibilities for studying this chemistry. In particular, the Atacama Large Millimeter/submillimeter Array (ALMA) has made it possible to study astrochemistry down to Solar System size scales, while also revealing molecules of increasing variety and complexity. In this review, we discuss recent observations of the chemistry of star-forming environments, with a particular focus on complex organic molecules, taking context from the laboratory experiments and chemical models that they have stimulated. The key takeaway points are: The physical evolution of individual sources plays a crucial role in their inferred chemical signatures, and remains an important area for observations and models to elucidate. Comparisons of the abundances measured toward different star-forming environments (high-mass versus low-mass, Galactic center versus Galactic disk) reveal a remarkable similarity, an indication that the underlying chemistry is relatively independent of variations in their physical conditions. Studies of molecular isotopologs in star-forming regions provide a link with measurements in our own Solar System, and thus may shed light on the chemical similarities and differences expected in other planetary systems., Comment: Invited review to be published in Annual Reviews of Astronomy and Astrophysics; 55 pages, 10 figures

H$_2$CO is one of the most abundant organic molecules in protoplanetary disks and can serve as a precursor to more complex organic chemistry. We present an ALMA survey of H$_2$CO towards 15 disks covering a range of stellar spectral types, stellar ages, and dust continuum morphologies. H$_2$CO is detected towards 13 disks and tentatively detected towards a 14th. We find both centrally-peaked and centrally-depressed emission morphologies, and half of the disks show ring-like structures at or beyond expected CO snowline locations. Together these morphologies suggest that H$_2$CO in disks is commonly produced through both gas-phase and CO-ice-regulated grain-surface chemistry. We extract disk-averaged and azimuthally-averaged H$_2$CO excitation temperatures and column densities for four disks with multiple H$_2$CO line detections. The temperatures are between 20-50K, with the exception of colder temperatures in the DM Tau disk. These temperatures suggest that H$_2$CO emission in disks is generally emerging from the warm molecular layer, with some contributions from the colder midplane. Applying the same H$_2$CO excitation temperatures to all disks in the survey, we find that H$_2$CO column densities span almost three orders of magnitude ($\sim 5 \times 10^{11} - 5 \times 10^{14} \mathrm{cm}^{-2}$). The column densities appear uncorrelated with disk size and stellar age, but Herbig Ae disks may have less H$_2$CO compared to T Tauri disks, possibly because of less CO freeze-out. More H$_2$CO observations towards Herbig Ae disks are needed to confirm this tentative trend, and to better constrain under which disk conditions H$_2$CO and other oxygen-bearing organics efficiently form during planet formation., Comment: 20 pages, 14 figures, 3 figure sets, 9 tables. Published in ApJ (February 2020)

We present and release the full dataset for the Mass Assembly of Stellar Systems and their Evolution with the SMA (MASSES) survey. This survey used the Submillimeter Array (SMA) to image the 74 known protostars within the Perseus molecular cloud. The SMA was used in two array configurations to capture outflows for scales $>$30$^{\prime\prime}$ ($>$9000 au) and to probe scales down to $\sim$1$^{\prime\prime}$ ($\sim$300 au). The protostars were observed with the 1.3 mm and 850 $\mu$m receivers simultaneously to detect continuum at both wavelengths and molecular line emission from CO(2-1), $^{13}$CO(2-1), C$^{18}$O(2-1), N$_2$D$^+$(3-2), CO(3-2), HCO$^+$(4-3), and H$^{13}$CO$^+$(4-3). Some of the observations also used the SMA's recently upgraded correlator, SWARM, whose broader bandwidth allowed for several more spectral lines to be observed (e.g., SO, H$_2$CO, DCO$^+$, DCN, CS, CN). Of the main continuum and spectral tracers observed, 84% of the images and cubes had emission detected. The median C$^{18}$O(2-1) linewidth is $\sim$1.0 km s$^{-1}$, which is slightly higher than those measured with single-dish telescopes at scales of 3000-20000 au. Of the 74 targets, six are suggested to be first hydrostatic core candidates, and we suggest that L1451-mm is the best candidate. We question a previous continuum detection toward L1448 IRS2E. In the SVS13 system, SVS13A certainly appears to be the most evolved source, while SVS13C appears to be hotter and more evolved than SVS13B. The MASSES survey is the largest publicly available interferometric continuum and spectral line protostellar survey to date, and is largely unbiased as it only targets protostars in Perseus. All visibility ($uv$) data and imaged data are publicly available at https://dataverse.harvard.edu/dataverse/full_MASSES/., Comment: Accepted to ApJS

Temperature is a crucial parameter in circumstellar disk evolution and planet formation, because it governs the resistance of the gas to gravitational instability and sets the chemical composition of the planet-forming material. We set out to determine the gas temperature of the young disk-like structure around the Class 0 protostar IRAS 16293$-$2422A. We use Atacama Large Millimeter/submillimeter Array (ALMA) observations of multiple H$_2$CS $J=7-6$ and $J=10-9$ lines from the Protostellar Interferometric Line Survey (PILS) to create a temperature map for the inner $\sim$200 AU of the disk-like structure. This molecule is a particularly useful temperature probe because transitions between energy levels with different $K_{\rm{a}}$ quantum numbers operate only through collisions. Based on the H$_2$CS line ratios, the temperature is between $\sim$100$-$175 K in the inner $\sim$150 AU, and drops to $\sim$75 K at $\sim$200 AU. At the current resolution (0.5$^{\prime\prime} \sim$70 AU), no jump is seen in the temperature at the disk-envelope interface. The temperature structure derived from H$_2$CS is consistent with envelope temperature profiles that constrain the temperature from 1000 AU scales down to $\sim$100 AU, but does not follow the temperature rise seen in these profiles at smaller radii. Higher angular resolution observations of optically thin temperature tracers are needed to establish whether cooling by gas-phase water, the presence of a putative disk or the dust optical depth influences the gas temperature at $\lesssim$100 AU scales. The temperature at 100 AU is higher in IRAS 16293A than in the embedded Class 0/I disk L1527, consistent with the higher luminosity of the former., Comment: 10 pages, 9 figures (+ 7 pages appendix with 9 figures and 1 table). Accepted for publication in A&A

Methanol is a key species in astrochemistry since it is the most abundant organic molecule in the ISM and is thought to be the mother molecule of many complex organic species. Estimating the deuteration of methanol around young protostars is of crucial importance because it highly depends on its formation mechanisms and the physical conditions during its moment of formation. We analyse dozens of transitions from deuterated methanol isotopologues coming from various existing observational datasets from the IRAM-PdBI and ALMA sub-mm interferometers to estimate the methanol deuteration surrounding three low-mass protostars on Solar System scales. A population diagram analysis allows us to derive a [CH$_2$DOH]/[CH$_3$OH] abundance ratio of 3-6 % and a [CH$_3$OD]/[CH$_3$OH] ratio of 0.4-1.6 % in the warm inner protostellar regions. These values are ten times lower than those derived with previous single-dish observations towards these sources but they are 10-100 times higher than the methanol deuteration measured in massive hot cores. Dust temperature maps obtained from Herschel and Planck observations show that massive hot cores are located in warmer molecular clouds than low-mass sources, with temperature differences of $\sim$10 K. Comparison with the predictions of the gas-grain astrochemical model GRAINOBLE shows that such a temperature difference is sufficient to explain the different deuteration observed in low- to high-mass sources, suggesting that the physical conditions of the molecular cloud at the origin of the protostars mostly govern the present observed deuteration of methanol. The methanol deuteration measured in this work is higher by a factor of 5 than the upper limit in methanol deuteration estimated in comet Hale-Bopp, implying that an important reprocessing of the organic material would have occurred in the solar nebula during the formation of the Solar System., Comment: 16 pages, 10 figures, accepted for publication in Astronomy & Astrophysics

Context. The relationship between outflow launching and formation of accretion disks around young stellar objects is still not entirely understood, which is why spectrally and spatially resolved observations are needed. Recently, the Atacama Large Millimetre/sub-millimetre Array (ALMA) has carried out long-baseline observations towards a handful of sources, revealing connections between outflows and the inner regions of disks. Aims. Here we aim to determine the small-scale kinematic and morphological properties of the outflow from the isolated protostar B335 for which no Keplerian disk has, so far, been observed on scales down to 10 au. Methods. We use ALMA in its longest-baseline configuration to observe emission from CO isotopologs, SiO, SO$_2$ and CH$_3$OH. The proximity of B335 provides a resolution of ~3 au (0.03''). We also combine our long-baseline data with archival data to produce a high-fidelity image covering scales up to 700 au (7''). Results. $^{12}$CO has a X-shaped morphology with arms ~50 au in width that we associate with the walls of an outflow cavity, similar to what is observed on larger scales. Long-baseline continuum emission is confined to <7 au of the protostar, while short-baseline continuum emission follows the $^{12}$CO outflow and cavity walls. Methanol is detected within ~30 au of the protostar. SiO is also detected in the vicinity of the protostar, but extended along the outflow. Conclusions. The $^{12}$CO outflow shows no clear signs of rotation at distances $\gtrsim$30 au from the protostar. SiO traces the protostellar jet on small scales, but without obvious rotation. CH$_3$OH and SO$_2$ trace a region <16 au in diameter, centred on the continuum peak, which is clearly rotating. Using episodic, high-velocity, $^{12}$CO features, we estimate the launching radius of the outflow to be <0.1 au and dynamical timescales on the order of a few years., Comment: Abstract very slightly abridged. 15 pages, 13 figures, accepted for publication in A&A

Our modern day Solar System has $4.6\times10^9$ yrs of evolution behind it with just a few relics of its birth conditions remaining. Comets are thought to be some of the most pristine tracers of the initial ingredients that were combined to produce the Earth and the other planets. Other low-mass protostars may be analogous to our proto-Sun and hence, could be used to study the building blocks necessary to form Solar-like systems. This study tests this idea on the basis of new high sensitivity, high spatial resolution ALMA data on the protoplanetary disc-scales (~70 au) of IRAS 16293-2422 and the bulk composition of comet 67P/Churyumov-Gerasimenko, as determined for the first time with the unique in situ monitoring carried out by Rosetta. The comparative analysis of the observations from the Protostellar Interferometric Line Survey (PILS) and the measurements made with Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA) shows that the relative abundances of CHO-, N-, and S-bearing molecules correlate, with some scatter, between protostellar and cometary data. A tentative correlation is seen for the first time for P- and Cl-bearing compounds. The results imply that the volatile composition of cometesimals and planetesimals is partially inherited from the pre- and protostellar phases of evolution., Comment: Accepted for publication in MNRAS; 36 pages, 15 figures, 4 tables

We present ALMA observations of organic molecules towards five low-mass Class 0/I protostellar disk candidates in the Serpens cluster. Three sources (Ser-emb 1, Ser-emb 8, and Ser-emb 17) present emission of CH3OH as well as CH3OCH3, CH3OCHO, and CH2CO, while NH2CHO is detected in just Ser-emb 8 and Ser-emb 17. Detecting hot corino-type chemistry in three of five sources represents a high occurrence rate given the relative sparsity of these sources in the literature, and this suggests a possible link between protostellar disk formation and hot corino formation. For sources with CH3OH detections, we derive column densities of 10^{17}-10^{18} cm^{-2} and rotational temperatures of ~200-250 K. The CH3OH-normalized column density ratios of large, oxygen-bearing COMs in the Serpens sources and other hot corinos span two orders of magnitude, demonstrating a high degree of chemical diversity at the hot corino stage. Resolved observations of a larger sample of objects are needed to understand the origins of chemical diversity in hot corinos, and the relationship between different protostellar structural elements on disk-forming scales., Comment: Accepted to ACS Earth & Space Chemistry

In the standard picture for low-mass star formation, a dense molecular cloud undergoes gravitational collapse to form a protostellar system consisting of a new central star, a circumstellar disk, and a surrounding envelope of remaining material. The mass distribution of the system evolves as matter accretes from the large-scale envelope through the disk and onto the protostar. While this general picture is supported by simulations and indirect observational measurements, the specific timescales related to disk growth and envelope dissipation remain poorly constrained. In this paper we conduct a rigorous test of a method introduced by J{\o}rgensen et al. (2009) to obtain mass measurements of disks and envelopes around embedded protostars with observations that do not resolve the disk (resolution of $\sim$1000\,AU). Using unresolved data from the recent Mass Assembly of Stellar Systems and their Evolution with the SMA (MASSES) survey, we derive disk and envelope mass estimates for $59$ protostellar systems in the Perseus molecular cloud. We compare our results to independent disk mass measurements from the VLA Nascent Disk and Multiplicity (VANDAM) survey and find a strong linear correlation, suggesting that accurate disk masses can be measured from unresolved observations. Then, leveraging the size of the MASSES sample, we find no significant trend in protostellar mass distribution as a function of age, as approximated from bolometric temperatures. These results may indicate that the disk mass of a protostar is set near the onset of the Class 0 protostellar stage and remains roughly constant throughout the Class I protostellar stage., Comment: Accepted to ApJ

Methyl mercaptan (also known as methanethiol), CH3SH, has been found in the warm and dense parts of high -- as well as low -- mass star-forming regions. The aim of the present study is to obtain accurate spectroscopic parameters of the S-deuterated methyl mercaptan CH$_3$SD to facilitate astronomical observations by radio telescope arrays at (sub)millimeter wavelengths. We have measured the rotational spectrum associated with the large-amplitude internal rotation of the methyl group of methyl mercaptan using an isotopically enriched sample in the 150-510 GHz frequency range using the K\"oln millimeter wave spectrometer. The analysis of the spectra has been performed up to the second excited torsional state. We present modeling results of these data with the RAM36 program. CH$_3$SD was searched for, but not detected, in data from the Atacama Large Millimeter/submillimeter Array (ALMA) Protostellar Interferometric Line Survey (PILS) of the deeply embedded protostar IRAS 16293-2422. The derived upper limit corresponds to a degree of deuteration of at most ~18%., Comment: Astron. Astrophys., 8 pages; article appeared; CDMS links updated

We present Atacama Large Millimeter/submillimeter Array (ALMA) observations of 1.1 mm dust continuum and CO 2-1 emission toward six dense cores within the Ophiuchus molecular cloud. We detect compact, sub-arcsecond continuum structures toward three targets, two of which (Oph A N6 and SM1) are located in the Ophiuchus A ridge. Two targets, SM1 and GSS 30, contain two compact sources within the ALMA primary beam. We argue that several of the compact structures are small ($R \lesssim 80$ au) accretion disks around young protostars, due to their resolved, elongated structures, coincident radio and x-ray detections, or bipolar outflow detections. While CO line wings extend to $\pm 10-20$ km s$^{-1}$ for the more evolved sources GSS 30 IRS3 and IRS1, CO emission toward other sources, where detected, only extends a few km s$^{-1}$ from the cloud $v_\mathrm{LSR}$. The dust spectral index toward the compact objects suggests that the disks are either optically thick at 1.1 mm, or that significant grain growth has already occurred. We identify, for the first time, a single compact continuum source ($R \sim 100$ au) toward N6 embedded within a larger continuum structure. SM1N is extended in the continuum but is highly centrally concentrated, with a density profile that follows a $r^{-1.3}$ power law within 200 au, and additional structure suggested by the uv-data. Both N6 and SM1N show no clear bipolar outflows with velocities greater than a few km s$^{-1}$ from the cloud velocity. These sources are candidates to be the youngest protostars or first hydrostatic cores in the Ophiuchus molecular cloud., Comment: 19 pages, 10 figures, accepted to ApJ

It is not known whether the original carriers of Earth's nitrogen were molecular ices or refractory dust. To investigate this question, we have used data and results of Herschel observations towards two protostellar sources: the high-mass hot core of Orion KL, and the low-mass protostar IRAS 16293-2422. Towards Orion KL, our analysis of the molecular inventory of Crockett et al. (2014) indicates that HCN is the organic molecule that contains by far the most nitrogen, carrying $74_{-9}^{+5}\%$ of nitrogen-in-organics. Following this evidence, we explore HCN towards IRAS 16293-2422, which we consider a solar analog. Towards IRAS 16293-2422, we have reduced and analyzed Herschel spectra of HCN, and fit these observations against "jump" abundance models of IRAS 16293-2422's protostellar envelope. We find an inner-envelope HCN abundance $X_{\textrm{in}} = 5.9\pm0.7 \times 10^{-8}$ and an outer-envelope HCN abundance $X_{\textrm{out}} = 1.3 \pm 0.1 \times 10^{-9}$. We also find the sublimation temperature of HCN to be $T_{\textrm{jump}} = 71 \pm 3$~K; this measured $T_{\textrm{jump}}$ enables us to predict an HCN binding energy $E_{\textrm{B}}/k = 3840 \pm 140$~K. Based on a comparison of the HCN/H2O ratio in these protostars to N/H2O ratios in comets, we find that HCN (and, by extension, other organics) in these protostars is incapable of providing the total bulk N/H2O in comets. We suggest that refractory dust, not molecular ices, was the bulk provider of nitrogen to comets. However, interstellar dust is not known to have 15N enrichment, while high 15N enrichment is seen in both nitrogen-bearing ices and in cometary nitrogen. This may indicate that these 15N-enriched ices were an important contributor to the nitrogen in planetesimals and likely to the Earth., Comment: Accepted to ApJ; 21 pages, 4 figures