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The direct carbonate procedure for accelerator mass spectrometry radiocarbon (AMS 14C) dating of submilligram samples of biogenic carbonate without graphitization is becoming widely used in a variety of studies. We compare the results of 153 paired direct carbonate and standard graphite 14C determinations on single specimens of an assortment of biogenic carbonates. A reduced major axis regression shows a strong relationship between direct carbonate and graphite percent Modern Carbon (pMC) values (m = 0.996; 95% CI [0.991–1.001]). An analysis of differences and a 95% confidence interval on pMC values reveals that there is no significant difference between direct carbonate and graphite pMC values for 76% of analyzed specimens, although variation in direct carbonate pMC is underestimated. The difference between the two methods is typically within 2 pMC, with 61% of direct carbonate pMC measurements being higher than their paired graphite counterpart. Of the 36 specimens that did yield significant differences, all but three missed the 95% significance threshold by 1.2 pMC or less. These results show that direct carbonate 14C dating of biogenic carbonates is a cost-effective and efficient complement to standard graphite 14C dating.

Neogene deposits of the lower Colorado River valley, especially the Miocene(?) and early Pliocene Bouse Formation, have been the focus of intense debate regarding the early paleoenvironmental history of this important continental-scale river system in southwestern North America and its integration with the proto-Gulf of California. Fine-grained units within these Neogene deposits also hold a promising archive of Pliocene paleoclimate history for this part of the world. Because the depocenter deposits of the Bouse Formation and the deposits that overlie and underlie it are poorly exposed and highly weathered, the formation is ripe for study through collection of drill cores. A workshop was held 28 February–3 March 2019 in Parker, AZ, USA, to discuss how scientific drilling might be employed to help resolve the Bouse controversies and improve our understanding of paleoclimate history in the region.

Newark Valley lies between the two largest pluvial lake systems in the Great Basin, Lake Lahontan and Lake Bonneville. Soils and geomorphology, stratigraphic interpretations, radiocarbon ages, and amino acid racemization geochronology analyses were employed to interpret the relative and numerical ages of lacustrine deposits in the valley. The marine oxygen isotope stage (MIS) 2 beach barriers are characterized by well-preserved morphology and deposits with youthful soil development, with Bwk horizons and maximum stage I+ carbonate morphology. Radiocarbon ages of gastropods and tufas within these MIS 2–age deposits permit construction of a latest Pleistocene lake-level curve for Newark Valley, including a maximum limiting age of 13,780 ± 50 14C yr B.P. for the most recent highstand, and they provide a calibration point for soil development in lacustrine deposits in the central Great Basin. The MIS 8–age to MIS 4–age beach barriers are higher in elevation and represent a larger lake than existed during MIS 2. The beach barriers have subdued morphology, are only preserved in short segments, and have stronger soil development, with Bkm and/or Bkmt horizons and maximum stage III+ to IV carbonate morphology. Newark Lake reached elevations higher than the MIS 2 highstand during at least two additional pluvial periods, MIS 16 and MIS 12, 10, or 8. These oldest lacustrine deposits do not have preserved shoreline features and are represented only by gravel lags, buried deposits, and buried soils with similar strong soil development. This sequence of middle and latest Pleistocene shorelines records a long-term pluvial history in this basin that remained internally drained for the last four or more pluvial cycles. Obtaining numerical ages from material within lacustrine deposits in the Great Basin can be challenging. Amino acid D/L values from gastropod shells and mollusk valves proved to be a valuable tool to correlate lacustrine deposits within Newark Valley. Comparison of soils and geomorphology results to independent 36Cl cosmogenic nuclide ages from a different study indicated unexpected changes in rates of soil development during the past ~200,000 yr and suggested that common stratigraphic changes in lake stratigraphy could obscure incremental changes in soil development and/or complicate 36Cl cosmogenic nuclide age estimates.

The Tecopa basin in eastern California was a terminal basin that episodically held lakes during most of the Quaternary until the basin and its modern stream, the Amargosa River, became tributary to Death Valley. Although long studied for its sedimentology, diagenesis, and paleomagnetism, the basin’s lacustrine and paleoclimate history has not been well understood, and conflicting interpretations exist concerning the relations of Tecopa basin to the Amargosa River and to pluvial Lake Manly in Death Valley. Previous studies also did not recognize basinwide tectonic effects on lake-level history. In this study, we focused on: (1) establishing a chronology of shoreline deposits, as the primary indicator of lake-level history, utilizing well-known ash beds and new uranium-series and luminescence dating; (2) using ostracodes as indicators of water chemistry and water source(s); and (3) correlating lake transgressions to well-preserved fluvial-deltaic sequences. During the early Pleistocene, the Tecopa basin hosted small shallow lakes primarily fed by low-alkalinity water sourced mainly from runoff and (or) a groundwater source chemically unlike the modern springs. The first lake that filled the basin occurred just prior and up to the eruption of the 765 ka Bishop ash during marine isotope stage (MIS) 19; this lake heralded the arrival of the Amargosa River, delivering high-alkalinity water. Two subsequent lake cycles, coeval with MIS 16 (leading up to eruption of 631 ka Lava Creek B ash) and MIS 14 and (or) MIS 12, are marked by prominent accumulations of nearshore and beach deposits. The timing of the youngest of these three lakes, the High lake, is constrained by a uranium-series age of ca. 580 ± 120 ka on tufa-cemented beach gravel and by estimates from sedimentation rates. Highstand deposits of the Lava Creek and High lakes at the north end of the basin are stratigraphically tied to distinct sequences of fluvial-deltaic deposits fed by alkaline waters of the Amargosa River. The High lake reached the highest level achieved in the Tecopa basin, and it may have briefly discharged southward but did not significantly erode its threshold. The High lake was followed by a long hiatus of as much as 300 k.y., during which there is evidence for alluvial, eolian, and groundwater-discharge deposition, but no lakes. We attribute this hiatus, as have others, to blockage of the Amargosa River by an alluvial fan upstream near Eagle Mountain. A final lake, the Terminal lake, formed when the river once again flowed south into Tecopa basin, but it was likely short-lived due to rapid incision of the former threshold south of Tecopa. Deposits of the Terminal lake are inset below, and are locally unconformable on, deposits of the High lake and the nonlacustrine deposits of the hiatus. The Terminal lake reached its highstand at ca. 185 ± 21 ka, as dated by infrared-stimulated luminescence on feldspar in beach sand, a time coincident with perennial lake mud and alkaline-tolerant ostracodes in the Badwater core of Lake Manly during MIS 6. A period of stillstand occurred as the Terminal lake drained when the incising river encountered resistant Stirling Quartzite near the head of present-day Amargosa Canyon. Our studies significantly revise the lacustrine and drainage history of the Tecopa basin, show that the MIS 6 highstand was not the largest lake in the basin as previously published (with implications for potential nuclear waste storage at Yucca Mountain, Nevada), and provide evidence from shoreline elevations for ∼20 m of tectonic uplift in the northern part of the basin across an ENE-trending monoclinal flexure.

Sediment cores taken near extant springs along the western margin of Soda Lake playa, as well as from the playa center, reveal dramatic hydrologic changes that occurred in the central Mojave Desert during the late Quaternary. Results of stratigraphic, chronologic, physical, chemical, and microfossil analyses of seven cores, ranging in length from 5 to 23 m, help refine the timing and character of the final stages of pluvial Lake Mojave during the late Pleistocene and define distinct periods of wetland development in the early and late Holocene. Evidence shows that an incipient lake occupied the central Soda Lake basin by at least 25.0 ka (ka = thousands of calibrated 14 C years before present), and a fully developed Lake Mojave was present between 20.5 and 12.8 ka, before receding and ultimately yielding to playa conditions by 11.0 ka. Organic-rich “black mats” appear in several cores along the playa margin between 10.7 and 9.0 ka, suggesting that spring-fed wetlands persisted in this area long after the lake had regressed. The basin remained relatively dry throughout most of the Holocene until wetland ecosystems expanded along the margins between 0.73 and 0.18 ka, coincident with part of the Medieval Climate Anomaly and Little Ice Age. Overall, our results demonstrate that buried sediments surrounding extant and extinct springs can be used to reconstruct past hydrologic conditions in desert environments on a variety of spatial and temporal scales, and provide important baseline information for effective management of limited desert resources.

A new sediment core from Padul, Padul-15-05, provides a long and continuous sedimentary and paleoenvironmental record of the last ∼200 kyr. Here we present a detailed palynological study from this sedimentary sequence with new vegetation and paleoenvironmental data and a climatic interpretation for the last two climatic cycles from the southern Iberian Peninsula in the western Mediterranean region. Pollen analysis from this core shows orbital-scale vegetation oscillations (mainly forced by precession and eccentricity) pointing into insolation as the principal factor controlling vegetation changes at this latitude. The last two glacial-interglacial cycles (from MIS 6 to the present) as well as stadial and interstadial phases are well represented and characterized by significant oscillations in Mediterranean forest in the area, but several differences with respect to other Mediterranean long pollen records can be recognized. Some of these disparities between regions seem to be more related to different precipitation rates linked to the specific geographical features (e.g. strong topographic relief) than to latitudinal differences between the sites. In addition, a lake level reconstruction based on palynological data was developed and compared with the previous reconstruction from this record, representing local environmental changes in the Padul wetland that seems to be related to precipitation/evapotranspiration balance, and therefore, to changes in regional climate conditions. During glacial/stadial conditions recorded by maxima in xerophytes, the p/e increased due to very low evapotranspiration, resulting in high lake levels, while during warmer interglacial/interstadial phases (except for the MIS 5e), mainly represented in this record by maxima in the Mediterranean forest, water level decreased as a result of high evapotranspiration exceeding precipitation input. The comparison of the new Padul-15-05 pollen record with the two previous palynological studies from Padul shows significant differences mainly due to disagreements in the age control of the sequences. This study shows that an accurate age-depth model becomes essential when interpreting long paleoenvironmental and paleoclimate records., This research is supported by the projects CGL2013-47038-R and CGL-2017-85415-R funded by Ministerio de Economía y Competitividad of the Spanish Government, project P11-RNM-7332 from the Junta de Andalucía and the research group RNM0190 (Junta de Andalucía). Jon Camuera acknowledges the PhD funding (BES-2014-069117) provided by the Ministerio de Economía y Competitividad of the Spanish Government under the project CGL2013-47038-R. María J. Ramos-Román also acknowledges the PhD and post-PhD fellowship (P11-RNM-7332) from the Conserjería de Economía, Innovación, Ciencia y Empleo of the Junta de Andalucía. Antonio García-Alix was supported by a Ramón y Cajal fellowship (RYC-2015-18966) from the Ministerio de Economía y Competitividad of the Spanish Government. Thanks to Javier Jaimez for helping with the coring (CIC-UGR). José Carrión thanks the Ministerio de Economía y Competitividad of the Spanish Government (grant number CGL-BOS-2012-34717 and CGL-BOS 2015-68604) and Fundación Séneca (grant number 19434/PI/14).

Padul is one of the few wetland sites in southern Europe and the Mediterranean region that exhibits an unusually large temporal span (>100 kyr) and continuous Quaternary sedimentary record. Previous core-based studies from Padul yielded paleoecological datasets (i.e., pollen and organic geochemistry), but with a poor age control that resulted in rather arbitrary climate inferences. Therefore, precise age control and a multidisciplinary approach is necessary to understand long-term regional environmental and climate change and the associated local response of the Padul wetland environment. Here we present a new long sediment record (Padul-15-05) from this wetland in the southern Iberian Peninsula with the aim of improving the age control of the sedimentary sequence and carrying out up-to-date high-resolution multiproxy analyses. In this study the age control is based on 61 AMS radiocarbon dates for the last ca. 50 kyr BP and on the extent of amino acid racemization (AAR) in mollusc shells extending back ∼118 kyr BP. No numerical ages are available for the bottom part of the core but the sediment accumulation rates (SAR) and the cyclostratigraphic analysis of the multiproxy data suggest that the core preserves a continuous record of the last ∼197 kyr (from late MIS 7 to present) with millennial-scale time resolution. Sedimentological (lithology, magnetic susceptibility, XRD, color), geochemical (XRF, TOC, C/N, % carbonate content) and paleontological (pollen, charophytes, gastropods) data show co-varying cyclical paleoenvironmental changes linked to orbital-scale climatic variability. Silicon, magnetic susceptibility (MS) and total organic carbon (TOC) data show periodicities between ∼26.2–19.6 kyr linked to insolation, which is strongly dominated by precession cycles at this latitude. High values of Si and MS data have been related to high siliciclastic/detrital input from Sierra Nevada range during minima in insolation due to enhanced soil weathering/erosion during regional aridity and lower forest cover recorded by the arboreal pollen, which could also be favored by a minor biogenic productivity. In addition, warm climate conditions during maxima in insolation mostly resulted in negative precipitation/evapotranspiration balance and low lake levels, while cold glacial and stadial periods were mainly characterized by positive precipitation/evapotranspiration balance, and therefore, high lake levels. The improved chronology of the Padul sedimentary sequence along with a multiproxy study permitted us to better relate environmental and vegetation changes to climatic events and to demonstrate how both local (i.e., lake level, sedimentation) and regional (i.e., vegetation) environments responded to orbital-scale climate changes.

Brackish marine and brackish continental environments are fundamentally different from a compositional perspective. Brackish water is often defined as having salinity lower than that of standard seawater but higher than that of freshwater, but less regard is given to the origin of the salts involved. The simple dilution of standard seawater by freshwater in a coastal or estuarine setting constitutes a brackish environment, but so do lakes where continental fresh water is impounded and becomes more saline through a variety of solute evolution pathways. The range of potential compositions of brackish lake water is diverse and includes water with “seawater-like” compositions. Isolated brackish lake environments located hundreds of kilometers inland can evolve towards sodium chloride-dominated, low alkalinity environments that mimic the composition of brackish seawater environments. These types of lakes can harbor a variety of continentally invasive but typically marine organisms, including but not limited to algae, foraminifers, mollusks, diatoms, and crustaceans. Distinguishing brackish marine from brackish lake environments in the geologic record can be difficult. In this paper, the enigmatic late Miocene and early Pliocene southern Bouse Formation of southern Arizona and California, USA, considered by many to represent a marine transgression along the lower Colorado River corridor, is discussed within a broad framework that incorporates hydrochemical, biogeographical, and species niche concepts. A brackish lake interpretation provides a powerful platform that can comprehensively account for the enigmatic mixed marine and continental fossil assemblage and possible tidal rhythmites that feature prominently in the southern Bouse Formation controversy. A review of the broader regional (paleo)environmental context for the southern Bouse supports a sodium chloride-dominated, low alkalinity, mildly brackish (10-5 ppt) Colorado River-fed lake depositional environment that was populated by an intriguing but predictable array of euryhaline, opportunistic, and continentally invasive marginal marine organisms.

Pluvial lake deposits in the Basin and Range province have long been exploited for records of hydrologic and climatic change. To obtain the most accurate reconstructions, a thorough understanding of the geomorphic evolution of such lake basins must be grounded in field stratigraphy and mapping, which are often lacking or are not well integrated with core studies. We conducted extensive stratigraphic investigation, mapping, and dating of exposed strata in the Lake Manix basin, former terminus of the Mojave River, California, during the Pleistocene to provide such a background and to supplement interpretations from a 45-m-long core. In this paper, we emphasize the geomorphic and tectonic processes that shaped the evolution of the Manix basin after the arrival of the Mojave River in the early-middle Pleistocene. The main processes include (1) sedimentary infilling of the lake basin, (2) interaction among the subbasins as controlled by internal sills and sill failures, (3) tectonics, and (4) climate change. From about 500 to 190 ka, Lake Manix was confined to its western subbasins, and fluctuated in response to climate change and perhaps to brief diversions of the river into the upstream Harper Lake basin. During this time, about 24 m of sediment accumulated near the confluence of the Mojave River and Manix Wash, and a 15-km-long clastic wedge built into the western basins, gradually filling the accommodation space. Two basin-integration events subsequently occurred, both caused by failure of sills that lay on sheared deposits along the Manix fault zone. When Lake Manix rose at the onset of glacial marine isotope stage 6, the sill on the south flank of Buwalda Ridge failed and triggered a catastrophic flood that entered the new, lower elevation, previously endorheic Afton subbasin. Subsequent lake-level changes affected both subbasins, but the thickest deposits after the flood are preserved in the Afton subbasin. The area upstream of Buwalda Ridge was only submerged during relatively high lake levels. Thus, sediment records interpreted from the core site and nearby outcrops in part reflect a geomorphic event (basin integration) rather than climatic conditions. The sill of Lake Manix after the integration event lay at the northeast end of the Afton subbasin, athwart strands of the Manix fault zone. At about 25 ka, this eastern sill was rapidly incised, and the river advanced to terminate in Lake Mojave in the Soda and Silver Lake basins. Recognition and dating of integration events, common for lake-river interactions in active tectonic settings, provide important context for interpreting paleoclimate records from sediments and provide temporal and spatial constraints on the biogeography of aquatic species.

The southern Bouse Formation (late Miocene–early Pliocene) in Blythe basin, CA-AZ, contains a controversial record of the events that preceded the integration of the developing Colorado River with the Gulf of California. High resolution microfaunal and stable isotope (δ18O, δ13C; VPDB) data from a key outcrop of marl and claystone record an abrupt change in water chemistry that we interpret to be the result of a catastrophic sill breach. Basal marl contains a mix of brackish-water ostracodes and marine foraminifers. Ostracode δ18O values are slightly negative and 6‰ higher than the host sediment carbonate precipitated in the upper water column, indicating isotopically stratified hydrologic conditions during deposition. Freshwater ostracodes abruptly appear in the overlying sediments in association with marine foraminifers, in conjunction with an abrupt change in the isotopic composition of ostracode and host sediment carbonate. The δ18O values from brackish and freshwater ostracodes and the host ...

We applied multiple geochemical tracers ( 87 Sr/ 86 Sr, [Sr], δ 13 C, and δ 18 O) to waters and carbonates of the lower Colorado River system to evaluate its paleohydrology over the past 12 Ma. Modern springs in Grand Canyon reflect mixing of deeply derived (endogenic) fluids with meteoric (epigenic) recharge. Travertine ( 87 Sr/ 86 Sr and δ 13 C and δ 18 O values that overlap with associated water values, providing justification for use of carbonates as a proxy for the waters from which they were deposited. The Hualapai Limestone (12–6 Ma) and Bouse Formation (5.6–4.8 Ma) record paleohydrology immediately prior to and during integration of the Colorado River. The Hualapai Limestone was deposited from 12 Ma (new ash age) to 6 Ma; carbonates thicken eastward to ∼210 m toward the Grand Wash fault, suggesting that deposition was synchronous with fault slip. A fanning-dip geometry is suggested by correlation of ashes between subbasins using tephrochronology. New detrital-zircon ages are consistent with the “Muddy Creek constraint, ” which posits that Grand Wash Trough was internally drained prior to 6 Ma, with limited or no Colorado Plateau detritus, and that Grand Wash basin was sedimentologically distinct from Gregg and Temple basins until after 6 Ma. New isotopic data from Hualapai Limestone of Grand Wash basin show values and ranges of 87 Sr/ 86 Sr, δ 13 C, and δ 18 O that are similar to Grand Canyon springs and travertines, suggesting a long-lived springfed lake/marsh system sourced from western Colorado Plateau groundwater. Progressive up-section decrease in 87 Sr/ 86 Sr and δ 13 C and increase in δ 18 O in the uppermost 50 m of the Hualapai Limestone indicate an increase in meteoric water relative to endogenic inputs, which we interpret to record progressively increased input of high-elevation Colorado Plateau groundwater from ca. 8 to 6 Ma. Grand Wash, Hualapai, Gregg, and Temple basins, although potentially connected by groundwater, were hydrochemically distinct basins before ca. 6 Ma. The 87 Sr/ 86 Sr, δ 13 C, and δ 18 O chemostratigraphic trends are compatible with a model for downward integration of Hualapai basins by groundwater sapping and lake spillover. The Bouse Limestone (5.6–4.8 Ma) was also deposited in several hydrochemically distinct basins separated by bedrock divides. Northern Bouse basins (Cottonwood, Mojave, Havasu) have carbonate chemistry that is nonmarine. The 87 Sr/ 86 Sr data suggest that water in these basins was derived from mixing of high- 87 Sr/ 86 Sr Lake Hualapai waters with lower- 87 Sr/ 86 Sr, first-arriving “Colorado River” waters. Covariation trends of δ 13 C and δ 18 O suggest that newly integrated Grand Wash, Gregg, and Temple basin waters were integrated downward to the Cottonwood and Mojave basins at ca. 5–6 Ma. Southern, potentially younger Bouse basins are distinct hydrochemically from each other, which suggests incomplete mixing during continued downward integration of internally drained basins. Bouse carbonates display a southward trend toward less radiogenic 87 Sr/ 86 Sr values, higher [Sr], and heavier δ 18 O that we attribute to an increased proportion of Colorado River water through time plus increased evaporation from north to south. The δ 13 C and δ 18 O trends suggest alternating closed and open systems in progressively lower (southern) basins. We interpret existing data to permit the interpretation that the southernmost Blythe basin may have had intermittent mixing with marine water based on δ 13 C and δ 18 O covariation trends, sedimentology, and paleontology. [Sr] versus 87 Sr/ 86 Sr modeling suggests that southern Blythe basin 87 Sr/ 86 Sr values of ∼0.710–0.711 could be produced by 25%–75% seawater mixed with river water (depending on [Sr] assumptions) in a delta– marine estuary system. We suggest several refinements to the “lake fill-and-spill” downward integration model for the Colorado River: (1) Lake Hualapai was fed by western Colorado Plateau groundwater from 12 to 8 Ma; (2) high-elevation Colorado Plateau groundwater was progressively introduced to Lake Hualapai from ca. 8 to 6 Ma; (3) Colorado River water arrived at ca. 5–6 Ma; and (4) the combined inputs led to downward integration by a combination of groundwater sapping and sequential lake spillover that first delivered Colorado Plateau water and detritus to the Salton Trough at ca. 5.3 Ma. We propose that the groundwater sapping mechanism strongly influenced lake evolution of the Hualapai and Bouse Limestones and that groundwater flow from the Colorado Plateau to Grand Wash Trough led to Colorado River integration.

An outcrop-based lake-level curve, constrained by ~ 70 calibrated 14C ages on Anodonta shells, indicates at least 8 highstands between 45 and 25 cal ka BP within 10 m of the 543-m upper threshold of Lake Manix in the Mojave Desert of southern California. Correlations of Manix highstands with ice, marine, and speleothem records suggest that at least the youngest three highstands coincide with Dansgaard–Oeschger (D–O) stadials and Heinrich events 3 and 4. The lake-level record is consistent with results from speleothem studies in the Southwest that indicate cool wet conditions during D–O stadials. Notably, highstands between 43 and 25 ka apparently occurred at times of generally low levels of pluvial lakes farther north as interpreted from core-based proxies. Mojave lakes may have been supported by tropical moisture sources during oxygen-isotope stage 3, perhaps controlled by southerly deflection of Pacific storm tracks due to weakening of the sea-surface temperature gradient in response to North Atlantic climate perturbations.

In North America, terrestrial records of biodiversity and climate change that span Marine Oxygen Isotope Stage (MIS) 5 are rare. Where found, they provide insight into how the coupling of the ocean–atmosphere system is manifested in biotic and environmental records and how the biosphere responds to climate change. In 2010–2011, construction at Ziegler Reservoir near Snowmass Village, Colorado (USA) revealed a nearly continuous, lacustrine/wetland sedimentary sequence that preserved evidence of past plant communities between ~140 and 55 ka, including all of MIS 5. At an elevation of 2705 m, the Ziegler Reservoir fossil site also contained thousands of well-preserved bones of late Pleistocene megafauna, including mastodons, mammoths, ground sloths, horses, camels, deer, bison, black bear, coyotes, and bighorn sheep. In addition, the site contained more than 26,000 bones from at least 30 species of small animals including salamanders, otters, muskrats, minks, rabbits, beavers, frogs, lizards, snakes, fish, and birds. The combination of macro- and micro-vertebrates, invertebrates, terrestrial and aquatic plant macrofossils, a detailed pollen record, and a robust, directly dated stratigraphic framework shows that high-elevation ecosystems in the Rocky Mountains of Colorado are climatically sensitive and varied dramatically throughout MIS 5.

Sediments containing terrestrial and aquatic mollusks and ostracodes from the Ziegler Reservoir fossil site (2705 m elevation) near Snowmass Village, Colorado, span ~130–87 ka (MIS 5e through 5b). The southeastern area of the site where taxa were recovered was a relatively fresh, shallow, well-vegetated wetland during MIS 5e through 5c time, approximately 2 m deep, with a total dissolved solids value of ~200–1000 mg L− 1. The wetland was seasonally or annually variable and groundwater discharged along the margins of the bounding moraine. Groundwater likely contributed solutes to the system and may have contributed 18O-enriched water. Based on stable isotopes from ostracode calcite (δ18OOST and δ13COST), seasonal evaporation occurred and the dissolved inorganic carbon pool was unexpectedly enriched in 13C. The mollusk and ostracode faunas changed little across the MIS 5e/5d/5c boundaries, whereas a distinct change in the ostracode fauna occurred between the deposition of Unit 11 and Unit 13, which corresponds in time to the MIS 5c/5b boundary, indicating some combination of increased surface and/or groundwater flow, a decrease in water temperature, and a freshening and a possible deepening of the wetland.

Limestone beds underlain and overlain by alluvial fan conglomerate near Amboy, California, are very similar in many respects to parts of the Bouse Formation, suggesting that an arm of the Pliocene Bouse water body extended across a wide part of the southern Mojave Desert. The deposits are north of the town of Amboy at and below an elevation of 290 m, along the northern piedmont of the Bristol “dry” Lake basin. The Amboy outcrops contain the Lawlor Tuff (4.83 Ma), which is also found in an outcrop of the Bouse Formation in the Blythe basin near Buzzards Peak in the Chocolate Mountains, 180 km southeast of Amboy. Bouse exposures near Amboy are ∼3.4 m thick, white, distinctly bedded, with limestone and calcareous sandstone as well as stromatolite mounds; we interpret these as nearshore deposits. The Bouse at Amboy contains ostracodes, diatoms, and mollusks that indicate saline lake or estuarine environments with an admixture of fresh-water forms. Along with wading bird tracks and a spine from a marine fish, these fossils suggest that the deposits formed in saline waters near a fresh-water source such as a perennial stream. Beds of the outcrop dip southward and are 113 m above the surface of Bristol Playa, where similar age sediments are buried 270+ m deep, indicating significant faulting and vertical tectonics in this part of the Eastern California Shear Zone during the past 5 m.y. Confirmation of the Bouse Formation at Amboy strengthens previous assignments to the Bouse Formation for mudstones in driller logs at Danby “dry” Lake, California, and suggests that areally extensive arms of the Bouse water body were west of the Blythe basin. The Bristol basin arm of the lower Bouse basin probably was restricted from the main water body by narrow passages, but Bouse sediment there is similar to that in the Blythe basin, suggesting generally similar water chemistry and environmental conditions. Examining the degree to which Bouse deposits in the western arms differed from Bouse deposits in the Blythe basin offers an approach to test whether the southernmost Bouse water body was deposited in an estuarine or lacustrine setting.

Desert wetlands support flora and fauna in a variety of hydrologic settings, including seeps, springs, marshes, wet meadows, ponds, and spring pools. Over time, eolian, alluvial, and fluvial sediments become trapped in these settings by a combination of wet ground conditions and dense plant cover. The result is a unique combination of clastic sediments, chemical precipitates, and organic matter that is preserved in the geologic record as ground-water discharge (GWD) deposits. GWD deposits contain information on the timing and magnitude of past changes in water-table levels and, therefore, are a potential source of paleohydrologic and paleoclimatic information. In addition, they can be important archeological and paleontological archives because desert wetlands provide reliable sources of fresh water, and thus act as focal points for human and faunal activities, in some of the world's harshest and driest lands. Here, we review some of the physical, sedimentological, and geochemical characteristics common to GWD deposits, and provide a contextual framework that researchers can use to identify and interpret geologic deposits associated with desert wetlands. We discuss several lines of evidence used to differentiate GWD deposits from lake deposits (they are commonly confused), and examine how various types of microbiota and depositional facies aid in reconstructing past environmental and hydrologic conditions. We also review how late Quaternary GWD deposits are dated, as well as methods used to investigate desert wetlands deeper in geologic time. We end by evaluating the strengths and limitations of hydrologic and climatic records derived from GWD deposits, and suggest several avenues of potential future research to further develop and utilize these unique and complex systems.

Accurate reconstruction of the paleo-Mojave River and pluvial lake (Harper, Manix, Cronese, and Mojave) system of southern California is critical to understanding paleoclimate and the North American polar jet stream position over the last 500 ka. Previous studies inferred a polar jet stream south of 35°N at 18 ka and at ~ 40°N at 17–14 ka. Highstand sediments of Harper Lake, the upstream-most pluvial lake along the Mojave River, have yielded uncalibrated radiocarbon ages ranging from 24,000 to > 30,000 14C yr BP. Based on geologic mapping, radiocarbon and optically stimulated luminescence dating, we infer a ~ 45–40 ka age for the Harper Lake highstand sediments. Combining the Harper Lake highstand with other Great Basin pluvial lake/spring and marine climate records, we infer that the North American polar jet stream was south of 35°N about 45–40 ka, but shifted to 40°N by ~ 35 ka. Ostracodes (Limnocythere ceriotuberosa) from Harper Lake highstand sediments are consistent with an alkaline lake environment that received seasonal inflow from the Mojave River, thus confirming the lake was fed by the Mojave River. The ~ 45–40 ka highstand at Harper Lake coincides with a shallowing interval at downstream Lake Manix.

The deep-sea environment is among the most stable on Earth, making it well suited for amino acid geochronology. Foraminifera with calcareous tests are distributed across the World Ocean and are oft ...

Pluvial lakes in the southwestern U.S. responded sensitively to past climate through effects on rainfall, runoff, and evaporation. Although most studies agree that pluvial lakes in the southwestern U.S. reached their highest levels coeval with glacial stages, the specific timing of increased effective moisture and lake-level rise is debated, particularly for the southwesternmost lakes. We obtained a 45-m core of lacustrine sediment from Lake Manix, the former terminus of the Mojave River prior to about 25 ka, and supplemented data from the core with outcrop studies. These sediments provide a robust record of Mojave River discharge over the last half-million years. Lake Manix persisted from OIS 12 through early OIS 2, including during interstadial OIS 3 and interglacials OIS 5, 7, and 9. The ostracode faunal record displays a shift from an unexpectedly warm, summer-dominated lake hydrology during OIS 12 to predominantly colder, winter-dominated conditions afterwards. The ostracode-based stable isotope record displays a large degree of intra-sample variability and does not mimic other well-known isotopic records of climate change. Evaporation likely buffered the Manix δ18O record from most of the expected isotopic differences between interglacial and glacial-interval discharge. Isotopically depleted and stable lakes occurred only four to six times, most notably during OIS 7 and OIS 9. Internal drainage-basin changes also affected the isotopic record. Persistence of lakes in the Manix basin during interglacials requires atmospheric or oceanic circulation controls on the mean position of the Pacific storm track other than large ice sheets. We propose that the relative strength and sign of the Northern Annular Mode (NAM) and its influence on atmospheric river-derived precipitation is a potential explanation.

Amino acids in ostracode valves are abundant and well preserved in Quaternary sediments. Ostracode valves are increasingly useful targets for amino acid geochronologic investigations yet little is known about the influence of taxonomy or environmental variables on ostracode protein diagenesis. This paper documents the effects of taxonomy and elevated environmental pH on the amino acid composition of ostracode valves. In one experiment, modern ostracode valves from the genus Candona (Cypridoidea) and Limnocythere (Cytheroidea) were submerged in pH 7 and pH 10 buffers and heated at 120 °C for up to 32 d. The buffer solutions and a subset of the ostracode valves were analyzed for their total hydrolysable amino acid (THAA) d / l values and concentrations. The remaining valves were analyzed for their free amino acid (FAA) d / l values and concentrations. In a second experiment, modern valves from four species of ostracodes within the Cypridoidea were heated at 110 °C for up to 160 d. THAA aspartic acid (Asp) and glutamic acid (Glu) d / l values were monitored. Finally, the amino acid compositions in a suite of fossil Candona valves from outcrops in the western United States, including the problematic Ana River section, are compared across a broader spectrum of amino acid data. A total of 586 samples were analyzed. The results show that both THAA and FAA d / l values and concentrations were higher in ostracode valves heated in pH 10 buffer than in valves heated in pH 7 buffer. THAA d / l values in the buffers were consistently higher than in the associated ostracode valves. Amino acids were readily leached from modern Limnocythere valves but minimal leaching was observed from young fossil Candona valves. The extent of leaching was not pH dependent. The rates and extent of racemization for Asp and Glu were similar in Candona spp. and Limnocythere valves heated in either pH 7 or 10 buffers. The rates and extent of amino acid racemization for alanine, valine, and epimerization of isoleucine were consistently lower in Limnocythere valves, regardless of pH environment. Asp racemized significantly faster in Heterocypris valves than in Candona or Ilyocypris valves. There were no substantial differences in the rate of Glu racemization in Heterocypris , Candona , or Ilyocypris valves, nor in the rate of racemization of Asp or Glu in valves from three species of Candona . The heating experiments demonstrate that environmental pH can have significant impact on the amino acid composition of ostracode valves. Differences in the rates of amino acid racemization were detected at both the family and superfamily level. The Ana River Candona valves are strongly enriched in Asp, Glu, and glycine when compared with other fossil Candona valves. These results are not explained by taxonomic differences or by diagenesis under basic (alkaline) environmental conditions. Instead, they suggest that other environmental variables during valve calcification may be responsible for the unique amino acid signature of the Ana River material.

During the late Pleistocene, emergent groundwater supported persistent and long-lived desert wetlands in many broad valleys and basins in the American Southwest. When active, these systems provided important food and water sources for local fauna, supported hydrophilic and phreatophytic vegetation, and acted as catchments for eolian and alluvial sediments. Desert wetlands are represented in the geologic record by groundwater discharge deposits, which are also called spring or wetland deposits. Groundwater discharge deposits contain information on the timing and magnitude of past changes in water-table levels and, thus, are a source of paleohydrologic and paleoclimatic information. Here, we present the results of an investigation of extensive groundwater discharge deposits in the central Mojave Desert at Valley Wells, California. We used geologic mapping and stratigraphic relations to identify two distinct wetland sequences at Valley Wells, which we dated using radiocarbon, luminescence, and uranium-series techniques. We also analyzed the sediments and microfauna (ostracodes and gastropods) to reconstruct the specifi c environments in which they formed. Our results suggest that the earliest episode of high water-table conditions at Valley Wells began ca. 60 ka (thousands of calendar yr B.P.), and culminated in peak discharge between ca. 40 and 35 ka. During this time, cold (4‐12 °C) emergent groundwater supported extensive wetlands that likely were composed of a wet, sedge-rush-tussock meadow mixed with mesic riparian forest. After ca. 35 ka, the water table dropped below the ground surface but was still shallow enough to support dense stands of phreatophytes through the Last Glacial Maximum (LGM). The water table dropped further after the LGM, and xeric conditions prevailed until modest wetlands returned briefl y during the Younger Dryas cold event (13.0‐11.6 ka). We did not observe any evidence of wet conditions during the Holocene at Valley Wells. The timing of these fl uctuations is consistent with changes in other paleowetland systems in the Mojave Desert, the nearby Great Basin Desert, and in southeastern Arizona, near the border of the Sonoran and Chihuahuan Deserts. The similarities in hydrologic conditions between these disparate locations suggest that changes in groundwater levels during the late Pleistocene in desert wetlands scattered throughout the American Southwest were likely driven by synopticscale climate processes.

Bleaching biominerals reduces the concentration of amino acids to a residual fraction which is thought to be preserved within intra-crystalline proteins. Intra-crystalline amino acids represent a relatively closed-system and may be superior for amino acid geochronological and paleothermometry investigations. Here we quantify the effects of extended bleaching (to 144 h) on amino acid concentrations and d / l values in the valves of seven modern ostracode species. Then we compare the effects of increasingly aggressive pre-treatments (sonication, exposure to 3% hydrogen peroxide for 2 h, and exposure to 10% bleach for 48 h) on amino acid concentrations and d / l values in fossil ostracode ( Candona ) valves from numerous locations throughout the western United States and northern Mexico. Bleaching modern ostracode valves results in a rapid order-of-magnitude reduction in amino acid concentrations and a slight increase in d / l values. Amino acid concentrations in five of the seven modern species increased slightly after prolonged exposure to bleach, suggesting that bleaching weakens a resistant protein source within the ostracode valves. Increasingly aggressive pre-treatments had virtually no effect on amino acid concentrations, d / l values, or inter-sample variability in fossil Candona valves older than about 1 ka. Candona valves younger than about 1 ka showed a progressive decrease in amino acid concentrations with more aggressive oxidizing pre-treatments. Valves older than 1 ka generally had amino acid concentrations −1 . A delayed increase in amino acid concentrations (15–30 nM mg −1 ), followed by a gradual decrease to residual concentrations consistently −1 , was observed in both outcrop and core samples. We propose that a large amount of weakly bound proteins is leached geologically instantaneously from Candona valves. Long-term (10’s of ka) diagenesis gradually weakens and then destroys a secondary pool of tightly bound proteins contained within the valves. Residual amino acid concentrations are likely derived from intra-crystalline proteins and resistant inter-crystalline proteins that are essentially immune to leaching. Candona valves deposited in pluvial Lake Chewaucan and exposed in sediments that crop out along the Ana River, Oregon, have unexpectedly well-preserved proteins and lower d / l values compared to fossil Candona valves of similar age from other locations. The Ana River results argue for developing site-specific calibrations for amino acid geochronology or paleothermometry studies that utilize ostracodes.

A recently discovered Bison-bearing fossil locality at Terapa, Sonora, Mexico, had previously been dated to 440 ± 130 ka using whole rock 40Ar/39Ar on a basalt flow that impounds the deposit. This age is considerably older than the accepted age of about 240–160 ka for the migration of Bison into greater North America. The Terapa deposit also contains a mixture of fossils from extralimital or extinct tropical animals and temperate animals. Constraining the age of the deposit is critical to interpret the paleontologic and paleoclimatologic implications of this unique Sonoran fossil locality. Three additional geochronological methods have been applied to this deposit (infrared stimulated luminescence (IRSL), amino acid racemization (AAR), and radiocarbon) and the data from the original 40Ar/39Ar age were revisited. The IRSL data suggest that the impounding basalt flow and the sediments that abut it were emplaced 43 ka ago and that the oldest sediments were deposited shortly after. Two radiocarbon ages suggest the fossiliferous sediments were emplaced by 42 ka. Effective diagenetic temperatures inferred from the AAR results, combined with AAR data from a similar-age deposit in southern Arizona, are in accordance with the 40–43 ka age estimates. For the AAR results to corroborate the 40Ar/39Ar age, the effective diagenetic temperature for the area would need to be approximately 3 °C, which is unrealistically low for northern Mexico. The new geochronological results suggest the Terapa deposit and fossils are 40–43 ka old. The anomalously old 40Ar/39Ar age for the impounding basalt is probably the result of low 40Ar* concentrations and inherited 40Ar.

We describe the first recorded occurrence of oolite in the main Hawaiian Islands. Well-cemented oolite was recovered at several locations at − 140 to − 150 m depth south of Lana'i. The ooids contain foraminiferal, skeletal, and peloidal nuclei, coated by thin to moderately thick (20–50% of ooid radius) tangential cortices, and are cemented by fibrous aragonite needles. The extent of amino acid racemization (AAR) analysed on 127 ooid grains and 55 pristine foraminifera in the same deposits confirm that the particles formed during a brief interval estimated at 1900 yr duration. A single, large benthic foraminiferan (Amphisorus sp.) intermixed with the ooid grains yielded a calibrated 14C age of 12.2 ± 0.3 ka. In contrast, a series of progressive leaches on two splits of ooid grains yielded a sequence of 14C ages ranging from ∼ 27 ka for the nuclei to

A Late Quaternary spit-shoreline complex on the northern shore of Pleistocene Lake Mojave of southeastern California, USA was studied with the goal of comparing accelerator mass spectrometry (AMS) radiocarbon, luminescence, electron spin resonance (ESR), terrestrial cosmogenic radionuclide (TCN) surface exposure, amino acid racemization (AAR) and U-series dating methods. The pattern of ages obtained by the different methods illustrates the complexity of processes acting in the lakeshore environment and highlights the utility of a multi-method approach. TCN surface exposure ages (mostly ∼20–30 ka) record the initial erosion of shoreline benches, whereas radiocarbon ages on shells (determined in this and previous studies) within the spit, supported by AAR data, record its construction at fluctuating lake levels from ∼16 to 10 ka. Luminescence ages on spit sediment (∼6–7 ka) and ESR ages on spit shells (∼4 ka) are anomalously young relative to radiocarbon ages of shells within the same deposits. The significance of the surprisingly young luminescence ages is not clear. The younger ESR ages could be a consequence of post-mortem enrichment of U in the shells. High concentrations of detrital thorium in tufa coating spit gravels inhibited the use of single-sample U-series dating. Detailed comparisons such as this provide one of the few means of assessing the accuracy of Quaternary dating techniques. More such comparisons are needed

Bear River, the largest river in the Great Basin, had some of its flow diverted into Bear Lake through a series of canals constructed between 1911 and 1918, turning Bear Lake into a reservoir. The prediversion lake had an unusually high Mg2+ :C a2+ ratio (38 by weight), which resulted in precipitation of CaCO3 as aragonite. The amount and mineralogy of the carbonate did not change immediately after the diversion, but during the middle of the 20th century, high-Mg calcite began to precipitate. In contrast, at the time of diversion there were very distinct changes in the isotopic composition of the carbonate that clearly define the time of diversion within the sediments. Sedimenttrap studies show that the CaCO3 polymorph that precipitates in the epilimnion of the lake today is high-Mg calcite. Samples in sediment traps placed 2 m above the bottom of the lake in 45 m of water (bottom traps) contain predominantly aragonite and quartz, with lesser amounts of high-Mg and low-Mg calcite and dolomite. Isotopic evidence from the sediments shows that the aragonite that accumulated in the bottom sediment traps and that constitutes the bulk of postdiversion sediments is reworked and redistributed from shallow sites to deep sites.

The Quaternary sediments sampled by continuous 120-m-long drill cores from Bear Lake (Utah-Idaho) comprise one of the longest lacustrine sequences recovered from an extant lake. The cores serve as a good case study for the construction of an age model for sequences that extend beyond the range of radiocarbon dating. From a variety of potential age indicators, we selected a combination of radiocarbon ages, one magnetic excursion (correlated to a standard sequence), and a single Uranium-series age to develop an initial data set. The reliability of the excursion and U-series data require consideration of their position with respect to sediments of inferred interglacial character, but not direct correlation with other paleoclimate records. Data omitted from the age model include amino acid age estimates, which have a large amount of scatter, and tephrochronology correlations, which have relatively large uncertainties. Because the initial data set was restricted to the upper half of the BL00-1 core, we inferred additional ages by direct correlation to the independently dated paleoclimate record from Devils Hole. We developed an age model for the entire core using statistical methods that consider both the uncertainties of the original data and that of the curve-fitting process, with a combination of our initial data set and the climate correlations as control points. This age model represents our best estimate of the chronology of deposition in Bear Lake. Because the age model contains assumptions about the correlation of Bear Lake to other climate records, the model cannot be used to address some paleoclimate questions, such as phase relationships with other areas.

Oxygen and carbon isotopes from a continuous, 120-m-long, carbonate-rich core from Bear Lake, Utah-Idaho, document dramatic fluctuations in the hydrologic budget of the lake over the last 250,000 yr. Isotopic analyses of bulk sediment samples capture millennial-scale variability. Ostracode calcite was analyzed from 78 levels, mainly from the upper half of the core where valves are better preserved, to compare the isotopic value of purely endogenic carbonate with the bulk sediment, which comprises both endogenic and detrital components. The long core exhibits three relatively brief intervals with abundant endogenic aragonite (50±10%) and enriched δ 18 O and δ 13 C. These intervals are interpreted as warm/dry periods when the lake retracted into a topographically closed basin. We correlate these intervals with the interglacial periods of marine oxygen-isotope stages 1, 5e, and 7a, consistent with the presently available geochronological control. During most of the time represented by the core, the lake was fresher than the modern lake, as evidenced by depleted δ 18 O and δ 13 C in bulk-sediment carbonate.

One of the most intriguing episodes in the Quaternary evolution of the Grand Canyon of the Colorado River, Arizona, was the development of vast lakes that are thought to have backed up behind lava erupted into the gorge. Stratigraphic evidence for these deep lava-dammed lakes is expectedly sparse. Possible lacustrine deposits at six areas in the eastern canyon yielded no compelling evidence for sediment deposited in a deep lake. At two of the sites the sediment was associated with late Quaternary spring-fed pools and marshes. Water-lain silt and sand at lower Havasu Creek was deposited ∼3000 cal yr ago. The deposit contains an ostracode assemblage similar to that living in the modern travertine-dammed pools adjacent to the outcrop. The second deposit, at Lees Ferry, formed in a spring-fed marsh ∼43,000 cal yr ago, as determined by 14C and amino acid geochronology. It contains abundant ostracode and mollusk fossils, the richest assemblages reported from the Grand Canyon to date. Our interpretation of these sediments as spring-fed deposits, and their relative youth, provides an alternative to the conventional view that deposits like these were formed in deep lava-dammed lakes that filled the Grand Canyon.

Luminescence geochronology, especially infrared stimulated luminescence analyses on marsh mud, shows that a relatively deep lake reached its peak (∼1340 m above sea level) in the Bonneville basin 59,000±5000 yr ago. The age is consistent with nonfinite14C ages and with amino acid geochronology on ostracodes. The Cutler Dam Alloformation was deposited during this lake cycle, which, like the subsequent Bonneville lake cycle, appears to have reached its maximum highstand following the peak of a global glacial stage (marine oxygen-isotope stage 4) but at a time when other records from North America show evidence for cold climate and expanded glacier ice.

Initial interpretation of the sediments from the Burmester core (Eardley et al. (1973). Geological Society of America Bulletin 84, 211–216) indicated that 17 deep-lake cycles, separated by shallow-lake and soil-forming intervals, occurred in the Bonneville basin during the Brunhes Chron (the last 780 × 103 yr). Our re-examination of the core, along with new sedimentological, geochronological, and paleontological data, indicate that only four deep-lake cycles occurred during this period, apparently correlative with marine oxygen-isotope stages 2, 6, 12, and 16. This interpretation suggests that large lakes formed in the Bonneville basin only during the most extensive of the Northern Hemisphere glaciations.