1. Preparation and Electrochemical Characterization of Si@C Nanoparticles as an Anode Material for Lithium-Ion Batteries via Solvent-Assisted Wet Coating Process
- Author
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Jongha Hwang, Mincheol Jung, Jin-Ju Park, Eun-Kyung Kim, Gunoh Lee, Kyung Jin Lee, Jae-Hak Choi, and Woo-Jin Song
- Subjects
silicon anode ,carbon coating ,lithium-ion batteries ,phenolic resin ,Chemistry ,QD1-999 - Abstract
Silicon-based electrodes are widely recognized as promising anodes for high-energy-density lithium-ion batteries (LIBs). Silicon is a representative anode material for next-generation LIBs due to its advantages of being an abundant resource and having a high theoretical capacity and a low electrochemical reduction potential. However, its huge volume change during the charge–discharge process and low electrical conductivity can be critical problems in its utilization as a practical anode material. In this study, we solved the problem of the large volume expansion of silicon anodes by using the carbon coating method with a low-cost phenolic resin that can be used to obtain high-performance LIBs. The surrounding carbon layers on the silicon surface were well made from a phenolic resin via a solvent-assisted wet coating process followed by carbonization. Consequently, the electrochemical performance of the carbon-coated silicon anode achieved a high specific capacity (3092 mA h g−1) and excellent capacity retention (~100% capacity retention after 50 cycles and even 64% capacity retention after 100 cycles at 0.05 C). This work provides a simple but effective strategy for the improvement of silicon-based anodes for high-performance LIBs.
- Published
- 2022
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