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for these rocks to about 5008C and 15^16 kbar. These P–T constraints, together with the tectonic fabric of the marbles, suggest that deformation and recrystallization occurred at or near the thermal maximum of metamorphism.

Monazite crystallization ages have been measured in situ using SIMS and EMP analysis of samples from the Bronson Hill anticlinorium in central New England. In west-central New Hampshire, each major tectonic unit (nappe) displays a distinctive P-T path and metamorphic history that requires significant post-metamorphic faulting to place them in their current juxtaposition, and monazite ages were determined to constrain the timing of metamorphism and nappe assembly. Monazite ages from the low- pressure, high-temperature Fall Mountain nappe range from c. 455 to 355 Ma, and Y zoning indicates that these ages comprise three to four distinct age domains, similar to that found in the overlying Chesham Pond nappe. The underlying Skitchewaug nappe contains monazite ages that range from c. 417 to 307 Ma. 40 Ar/ 39 Ar ages indicate rapid cooling of the Chesham Pond and Fall Mountain nappes after 350 Ma, which is believed to represent the time of emplacement of the high-level Chesham Pond and Fall Mountain nappes onto rocks of the underlying Skitchewaug nappe. Garnet zone rocks from western New Hampshire contain monazite that display a range of ages (c. 430-340 Ma). Both the metamorphic style and monazite ages suggest that the low-grade belt in western New Hampshire is continuous with the Vermont sequence to the west. Rocks of the Big Staurolite nappe in western New Hampshire contain monazite that crystallized between c. 370 and 290 Ma and the same unit along strike in northern New Hampshire and central Connecticut records ages of c. 257-300 Ma. Conspicuously absent from this nappe are the older age populations that are found in both the overlying nappes and underlying garnet zone rocks. These monazite ages confirm that the metamorphism observed in the Big Staurolite nappe occurred significantly later than that in the units structurally above and below. These data support the hypothesis that the Big Staurolite nappe represents a major tectonic boundary, along which rocks of the New Hampshire metamorphic series were juxtaposed against rocks of the Vermont series during the Alleghanian.

An exposure near Gassetts, Vermont, contains lithologies varying from staurolite-kyanite grade aluminous schists with paragonitic muscovite to potassic gneiss with phengitic muscovite. Single-crystal laser fusion 40 Ar/ 39 Ar ages for paragonitic and phengitic muscovite yield similar distributions with ranges between 366 ± 4 and 326 ± 4 Ma. Intracrystalline ages vary from ca. 394 ± 4 to 330 ± 4 Ma. Thus, we find that the intracrystalline (core-rim) age distribution of relatively large, single crystals essentially encompasses the range of ages obtained through total fusion of smaller crystals, consistent with models for development of diffusion profiles and 40 Ar-closure during cooling with a diffusion dimension controlled by the physical grain size. However, some of the larger crystals studied, particularly those with prominent microscopic defects (features readily evident such as internal grain boundaries and twin planes), yield relatively young ages and lack significant core-rim age discordance. Furthermore, the overall distribution of single-crystal ages in the two samples is bimodal, and we suggest that this age distribution reflects metamorphic deformation and recrystallization event(s) superimposed on early generation muscovite. Thus, the mean age of muscovite in these samples (typical of K/Ar and 40 Ar/ 39 Ar incremental heating analysis of bulk mineral separates) has little relationship to any single, hypothetical closure temperature. In view of the similar results we obtain for muscovite of contrasting composition, the net effects of variations in grain size, deformational character, and growth history are interpreted to be more important in forming the observed variations in age than are the chemical substitutions in these samples.

Zr-in-rutile thermometry on samples of blueschist from Sifnos, Greece, yields temperatures that reflect progressive crystallization of rutile from ca. 445 to 505°C with an analytical precision of + 18/−27 and ± 10°C using the electron microprobe and ± 1.5–3.5°C using the ion microprobe. Individual grains are generally homogeneous within analytical uncertainty. Different grains within a single sample record temperature differences as large 55°, although in most samples the range of temperatures is on the order of 25°. In several samples, Zr-in-rutile temperatures from grains within garnet are lower than temperatures from matrix grains, reflecting growth of rutile with increasing temperature of metamorphism. Although the specific rutile-producing reactions have not been identified, it is inferred that rutile grows from either continuous reaction involving the breakdown of lower grade phases (possibly ilmenite), or from pseudomorph reactions involving the breakdown of relic igneous precursors at blueschist-facies conditions. No systematic variation in rutile temperatures was observed across the blueschist belt of northern Sifnos, consistent with the belt having behaved as a coherent block during subduction.

Four distinct generations of monazite growth have been identified in samples from the Chesham Pond Nappe, and three (monazite compositional domains 2, 3, and 4) have been correlated with both temperature and mineral assemblage. Domain 1 cores were interpreted previously to be detrital relics or vestiges of an earlier Acadian metamorphism. The four monazite domains have been dated by in situ isotope and chemical methods; the following are chemical ages of each domain (weighted average ±2 standard errors of the mean): 400 ± 10 Ma (domain 1); 381 ± 8 Ma (domain 2); 372 ± 6 Ma (domain 3); 352 ± 14 Ma (domain 4). Heating and cooling rates derived from combining monazite ages, monazite thermometry, and 40Ar/39Ar closure temperatures are approximately 10–15 °C/m.y. for heating from 470 to 740 °C, approximately 8 °C/m.y. for cooling from 740 to 375 °C, and approximately 1–2 °C/m.y for cooling from 375 to 150 °C. Temperature-time paths calculated with monazite ages and monazite thermometry indicate that (1) plutonism at ca. 400 Ma was the likely heat source for the formation of monazite domain 1 and (2) monazite domains 2–4 were produced during a regional low-pressure, high-temperature metamorphism active between 380–350 Ma. The regional metamorphism is ascribed to lithospheric mantle delamination, followed by asthenospheric mantle upwelling, which heated a wide area of the Merrimack basin (southwestern New Hampshire, central Massachusetts, central Connecticut) to temperatures in excess of 725 °C. Monazite ages in the Chesham Pond Nappe and adjacent structural units to the west constrain the commencement of nappe overthrusting to roughly 355 Ma.

U‐Pb ages measured on zircons from the Tobacco Root Mountains and monazite from the Highland Mountains indicate that the northwestern Wyoming province experienced an episode of high‐grade metamorphism at ∼1.77 Ga. Leucosome emplaced in Archean gneisses from the Tobacco Root Mountains contains a distinctive population of zircons with an age of 1.77 Ga but also contains zircons to ∼3.5 Ga; it is interpreted to have been derived primarily by anatexis of nearby Archean schist. A granulite facies mafic dike that cuts across Archean gneissic banding in the Tobacco Root Mountains contains two distinct populations of zircons. A group of small (

Numerous rod-shaped calcite crystals occur in the blueschist to eclogite facies marbles of Syros, Greece. The rods show a shape-preferred orientation, and the long axes of the rods are oriented at a large angle to foliation. The crystals also have a crystallographic-preferred orientation: calcite c-axes are oriented parallel to the long axes of the rods. Based on their chemical composition, shape, and occurrence in high-pressure marbles, these calcite crystals are interpreted as topotactic pseudomorphs after aragonite that developed a crystallographic-preferred orientation during peak metamorphism. This interpretation is consistent with deformation of aragonite by dislocation creep, which has been observed in laboratory experiments but has not been previously reported on the basis of field evidence. Subsequent to the high-pressure deformation of the aragonite marbles, the aragonite recrystallized statically into coarse rod-shaped crystals, maintaining the crystallographic orientation developed during deformation. During later exhumation, aragonite reverted to calcite, and the marbles experienced little further deformation, at least in the pseudomorph-rich layers. Some shearing of pseudomorph-bearing marble layers did occur and is indicated by twinning of calcite and by a variable inclination of the pseudomorphs relative to foliation.

Mountain, Skitchewaug and Big Staurolite nappes. Reactivation of A new, detailed tectonic model is presented for the Acadian orogenic this fabric during thrusting is recorded in some rocks of the Big belt of central New England (Vermont and New Hampshire) that Staurolite nappe by rotated garnets that grew during near-isothermal accounts for a wide range of petrological and structural observations. loading. Only the sillimanite isograd crosses the Fall Mountain– Three belts are considered: the Eastern Vermont, Merrimack, and Skitchewaug nappe boundary. Metamorphic breaks across the Skitintervening Bronson Hill belts. Specific observations in eastern chewaug–Big Staurolite nappe boundary, at the base of the Big Vermont that are accounted for in the model include the following. Staurolite nappe, and at the margin of the Keene and Alstead domes P–T paths are clockwise with maximum pressures near the Athens, require post-metamorphic thrusting when P–T conditions were in Chester, and Strafford domes of 8–11 kbar, but with maximum the greenschist facies. These observations can be explained by a pressures decreasing to 3–5 kbar at the boundary with the Bronson relatively simple model involving in-sequence thrusting from east to Hill belt. Differential exhumation of the Vermont domes relative to west commencing in central New Hampshire at 400–410 Ma. the rocks in easternmost Vermont is required by the recorded differences Preservation of the low-grade belt along the Vermont–New Hampin maximum pressure (5–6 kbar; 15–20 km) and the present-day shire border requires that crustal thickening in Vermont was not geographical separation (7–10 km). Specific observations in New caused by emplacement of New Hampshire nappes onto eastern Hampshire that are explained include the following. P–T paths in Vermont and that the nappes of western New Hampshire had time the Merrimack belt are counter-clockwise with maximum pressures to cool before final juxtaposition against the low-grade belt. Cooling of 4–5 kbar and are related to high regional heat flow and heat ages constrain this final juxtaposition to have occurred in the transfer by early Acadian plutons. P–T paths in the Bronson Hill Carboniferous, suggesting that the Acadian was a prolonged event belt are intimately associated with structural position. An early spanning as much as 100 Myr. contact metamorphism is evidenced in the Skitchewaug and Fall Mountain nappes near contacts with the early Acadian Bethlehem gneiss (>400–410 Ma). Peak metamorphic temperature rises upwards in the nappe sequence (an inverted metamorphic sequence)

The reaction muscovite+cordieritebiotite+Al2SiO5 +quartz+H2O is of considerable importance in the low pressure metamorphism of pelitic rocks: (1) its operation is implied in the widespread assemblage Ms + Crd +And± Sil + Bt + Qtz, a common mineral assemblage in contact aureoles and low pressure regional terranes; (2) it is potentially an important equilibrium for pressure estimation in low pressure assemblages lacking garnet; and (3) it has been used to distinguish between clockwise and anticlockwise P–T paths in low pressure metamorphic settings. Experiments and thermodynamic databases provide conflicting constraints on the slope and position of the reaction, with most thermodynamic databases predicting a positive slope for the reaction. Evidence from mineral assemblages and microtextures from a large number of natural prograde sequences, in particular contact aureoles, is most consistent with a negative slope (andalusite and/or sillimanite occurs upgrade of, and may show evidence for replacement of, cordierite). Mineral compositional trends as a function of grade are variable but taken as a whole are more consistent with a negative slope than a positive slope. Thermodynamic modelling of reaction 1 and associated equilibria results in a low pressure metapelitic petrogenetic grid in the system K2O–FeO–MgO–Al2O3–SiO2–H2O (KFMASH) which satisfies most of the natural and experimental constraints. Contouring of the Fe–Mg divariant interval represented by reaction 1 allows for pressure estimation in garnet-absent andalusite+cordierite-bearing schists and hornfelses. The revised topology of reaction 1 allows for improved analysis of P–T paths from mineral assemblage sequences and microtextures in the same rocks.

A relatively simple petrogenetic grid for partial melting of pelitic rocks in the NCKFMASH system is presented based on the assumption that the only H2O available for melting is through dehydration reactions. The grid includes both discontinuous and continuous Fe-Mg reactions; contours of Fe/(Fe+Mg) for continuous reactions define P-T vectors along which continuous melting will occur. For biotite-bearing assemblages (garnet+biotite + sillimanite + K-feldspar + liquid and garnet + biotite + cordierite + K-feldspar + liquid), Fe/(Fe+Mg) contours have negative slopes and melting will occur with increasing temperature or pressure. For biotite-absent assemblages (garnet + cordierite + sillimanite + K-feldspar + liquid or garnet + cordierite + orthopyroxene + K-feldspar + liquid) Fe/(Fe + Mg) contours have flat slopes and melting will occur only with increasing pressure. The grid predicts that abundant matrix K-feldspar should only be observed if rocks are heated at P 3.8 kbar, and that generation of late biotite + sillimanite replacing garnet, cordierite, or as selvages around leu- cosomes should be common in rocks in which melt is not removed. There is also a predicted field for dehydration melting of staurolite between 5 and 12 kbar. Textures in migmatites from New Hampshire, USA, suggest that prograde dehydration melting reactions are very nearly completely reversible during cooling and crystallization in rocks in which melt is not removed. Therefore, many reaction textures in “low grade” migmatites may represent retrograde rather than prograde reactions.

Recent laser studies have documented 40Ar concentration gradients in micas that correspond to age variations of tens to hundreds of millions of years. A fundamental problem to interpretation of such variations is to evaluate whether they represent loss via lattice diffusion or, alternatively, loss during chemical reactions and deformation. New data of this study and comparisons with previous work suggest that muscovite is far less prone to lose accumulated 40Ar via lattice diffusion during overprinting events than has been inferred previously. Kyanite-muscovite assemblages in Proterozoic schist along the eastern flank of the Green Mountain massif, central Vermont Appalachians, formed during Proterozoic metamorphism at ca. 1.1 Ga and were remetamorphosed in the greenschist facies during both Taconian (ca. 465 Ma) and Acadian (ca. 390 Ma) events. The overprinting events resulted in deformation of earlier kyanite and muscovite, growth of chemically and isotopically distinct rims on earlier muscovite, and growth of neoblastic muscovite and chloritoid, with each event at inferred minimum temperatures of ca. 425°C. Laser spot analyses of the Grenville muscovite range from 988 ± 11 Ma in the centers of porphyroclasts to 397 ± 7 Ma along rims. Ages younger than 750 Ma occur only on the deformed edges of porphyroclasts and in highly deformed areas within crystals. Parts of early-formed muscovite that escaped late deformation and chemical reaction seem remarkably retentive of accumulated 40Ar; laser spot analyses along the outer 100 μm of an undeformed growth face yield ages close to the timing of Proterozoic metamorphism and cooling. The present study suggests episodic heating events are ineffective for producing measurable, diffusive argon loss along the edges of large muscovite crystals (ca. 1 mm in diameter), particularly in comparison with deformation and reaction mechanisms, and are unlikely to result in complete 40 Ar 39 Ar age resetting of such crystals. The results of this study further emphasize that the argon diffusivity in muscovite is lower than commonly considered in previous work.

Integrated studies by Keck Geology Consortium participants have generated many new insights into the Precambrian geology of the Tobacco Root Mountains. We have clarifi ed the tectonic setting and origin of two suites of metamorphic rocks: (1) a quartzofeldspathic gneiss complex with associated metasupracrustal rocks (the combined Indian Creek and Pony–Middle Mountain Metamorphic Suites) that originated in a continental arc setting between 3.35 and 3.2 Ga with subsequent sedimentation and (2) mafi c metavolcanic rocks with intercalated metasedimentary rocks (the Spuhler Peak Metamorphic Suite) from a suprasubduction zone ophiolite or backarc basin possibly of Proterozoic age. A poorly preserved metamorphic event at 2.45 Ga affected the former but not the latter, as did the intrusion of rift-related mafi c dikes and sills at 2.06 Ga. Both suites were amalgamated, metamorphosed to at least upper amphibolite facies, subjected to simple shear strain and folded into mapand outcrop-scale sheath folds, and tectonically unroofed during the period 1.78 to 1.71 Ga. We name this event the Big Sky orogeny. The Proterozoic geology of the Tobacco Root Mountains can be integrated with coeval features of the geology of the northern Wyoming province to outline a northeast-trending, southeast-vergent belt as the Big Sky orogen. The Big Sky orogen consists of a metamorphic hinterland fl anked to the southeast by a foreland of discrete ductile shear zones cutting older basement, and to the northwest by arc-related metaplutonic bodies and the trace of a fossil subduction zone in the upper mantle. Archean blocks to the north of the Big Sky orogen may have been accreted as allochthonous terranes during collision and convergence. The remarkable synchroneity of collision along the Big Sky orogen with tectonism in the Trans-Hudson orogen along the eastern margin of the Wyoming province and in the Cheyenne belt to the south of the province raise profound but unanswered questions about the process by which the Wyoming province was added to the rest of the ancestral North American craton.

Measurements of 60 single-grain, UV laser microprobe 40 Ar/ 39 Ar total gas ages for hornblende from metamorphic rocks of the Tobacco Root Mountains in southwest Montana yield a mean age of 1.71 ± 0.02 Ga. Measurements of 40 Ar/ 39 Ar step-heating plateau ages of three bulk hornblende samples from the Tobacco Root Mountains metamorphic rocks average 1.70 ± 0.02 Ga. We believe that these and the K/Ar or 40 Ar/ 39 Ar ages reported by previous workers are cooling ages from a 1.78 to 1.72 Ga, upper-amphibolite to granulite facies, regional metamorphism (Big Sky orogeny) that affected the northwestern portion of the Wyoming province, including the Tobacco Root Mountains and adjacent ranges. Based on the 40 Ar/ 39 Ar data, this 1.78–1.72 Ga metamorphism must have achieved temperatures greater than ~500 °C to reset the hornblende 40 Ar/ 39 Ar ages of samples from the Indian Creek Metamorphic Suite, which was previously metamorphosed at 2.45 Ga, and of the crosscutting metamorphosed mafi c dikes and sills (MMDS), which were intruded at 2.06 Ga. Biotite and hornblende from the Tobacco Root Mountains appear to give the same 40 Ar/ 39 Ar or K/Ar age (within uncertainty), indicating that the rocks cooled rapidly through the interval from 500 to 300 °C. This is consistent with a model of the Big Sky orogeny that includes late-stage tectonic denudation that leads to decompression and rapid cooling. A similar cooling history is suggested by our data for the Ruby Range. Three biotite samples from the Ruby Range yield 40 Ar/ 39 Ar step-heating plateau ages with a mean of 1.73 ± 0.02 Ga, identical to the best-estimate (near-plateau) age for a hornblende from the same rocks. Two samples of the orthoamphibole, gedrite, from the Tobacco Root Mountains were studied, but did not have enough K to yield a reliable 40 Ar/ 39 Ar age. Several biotite and three hornblende samples from the region yield 40 Ar/ 39 Ar dates signifi cantly younger than 1.7 Ga. We believe these samples were partially reset during contact metamorphism by Cretaceous (75 Ma) intrusive rocks. Hydrothermal alteration associated with ca. 1.4 Ga rifting led to growth of muscovite with that age in the Ruby Range, but this alteration was apparently not hot enough to reset biotite and hornblende ages there.

The island of Syros, Greece is part of the Attic-Cycladic blueschist belt, formed during Mesozoic Eurasia-Africa subduction. The rocks of Syros can be broadly divided into three tectono-stratigraphic units: (I) metamorphosed sedimentary and volcanic rocks (marble-schist sequence), (II) remnants of oceanic crust with fault-bounded packages of blueschist/eclogite-facies mafic rocks and serpentinite (mafic-ultramafic rocks) and (III) the Vari gneiss, which is a tectonic klippe. Low-temperature, high-pressure assemblages are found on several islands in the Cyclades. The best preserved of these rocks are on Syros and Sifnos islands. Mineral compositions and peak metamorphic assemblages are similar on both islands. Both islands are considered to share similar P-T histories with highest-pressure mineral assemblages reflecting conditions of at least 15 kbar and about 500°C.

A quantitative petrogenetic grid for pelitic schists in the system KFMASH that includes the phases garnet, chlorite, biotite, chloritoid, cordierite, staurolite, talc, kyanite, andalusite, sillimanite, and pyrophyllite (with quartz, H2O and muscovite or K-feldspar in excess) is presented. The grid is based on thermodynamic data of Berman et al. (1985) and Berman (1988) for endmember KFASH and KMASH equilibria and natural Fe-Mg partitioning for the KFMASH system. Calculation of P-T slopes and the change in Fe/(Fe+Mg) along reactions in the KFMASH system were made using the Gibbs method. In addition, the effect on the grid of MnO and CaO is evaluated quantitatively. The resulting grid is consistent with typical Buchan and Barrovian parageneses at medium to high grades. At low grades, the grid predicts an extensive stability field for the paragenesis chloritoid+biotite which arises because of the unusual facing of the reaction chloritoid+biotite + quartz+H2O = garnet+chlorite+muscovite, which proceeds to the right with increasing T in the KFMASH system. However, the reaction proceeds to the left with increasing T in the MnKFASH system so the assemblage chloritoid + biotite is restricted to bulk compositions with high Fe/(Fe+Mg+Mn). Typical metapelites will therefore contain garnet+chlorite at low grades rather than chloritoid + biotite.

New chemical data on coexisting cordierite + chlorite + biotite from Maine shows that on an AFM diagram, the biotite-cordierite join passes on the Mg-side of chlorite. This information has important implications for ascertaining the reactions that terminate the stability field of chlorite in pelitic schist. Addition of the several cordierite-bearing assemblages to the AFM plots for the staurolite zone and lower sillimanite zone of northwestern Maine enables an almost complete topologic representation for each zone.