Search

Wire Arc Additive Manufacturing (WAAM) is a metal 3D printing technology that deposits molten metal wire on a substrate to form desired geometries. Articulated robot arms are commonly used in WAAM to produce complex geometric shapes. However, they mostly rely on proprietary robot and weld control software that limits process tuning and customization, incorporation of third-party sensors, implementation on robots and weld controllers from multiple vendors, and customizable user programming. This paper presents a general open-source software architecture for WAAM that addresses these limitations. The foundation of this architecture is Robot Raconteur, an open-source control and communication framework that serves as the middleware for integrating robots and sensors from different vendors. Based on this architecture, we developed an end-to-end robotic WAAM implementation that takes a CAD file to a printed WAAM part and evaluates the accuracy of the result. The major components in the architecture include part slicing, robot motion planning, part metrology, in-process sensing, and process tuning. The current implementation is based on Motoman robots and Fronius weld controller, but the approach is applicable to other industrial robots and weld controllers. The capability of the WAAM tested is demonstrated through the printing of parts of various geometries and acquisition of in-process sensor data for motion adjustment.

Many biological objects possess bilateral symmetry about a midline or midplane, up to a ``noise'' term. This paper uses landmark-based methods to measure departures from bilateral symmetry, especially for the two-group problem where one group is more asymmetric than the other. In this paper, we formulate our work in the framework of size-and-shape analysis including registration via rigid body motion. Our starting point is a vector of elementary asymmetry features defined at the individual landmark coordinates for each object. We introduce two approaches for testing. In the first, the elementary features are combined into a scalar composite asymmetry measure for each object. Then standard univariate tests can be used to compare the two groups. In the second approach, a univariate test statistic is constructed for each elementary feature. The maximum of these statistics lead to an overall test statistic to compare the two groups and we then provide a technique to extract the important features from the landmark data. Our methodology is illustrated on a pre-registered smile dataset collected to assess the success of cleft lip surgery on human subjects. The asymmetry in a group of cleft lip subjects is compared to a group of normal subjects, and statistically significant differences have been found by univariate tests in the first approach. Further, our feature extraction method leads to an anatomically plausible set of landmarks for medical applications., Comment: 20 pages

Wildfire smoke is a health hazard as it contains a mixture of carcinogenic volatile compounds and fine particulate matter. In particular, exposure to polycyclic aromatic hydrocarbons (PAHs) is a major concern, since these compounds have been recognized as important contributors to the overall carcinogenic risk of smoke exposure. In this work, gas and particle-phase PAH emissions from the combustion of Eastern White Pine (pinus strobus) were quantified using time-of-flight mass spectrometry over a range of burn conditions representative of wildfires and prescribed fires. These experiments allow for controlling conditions of fuel moisture, heat flux, and oxygen concentration to understand their impact on PAH emissions. We find that optimal conditions for fuel moisture content of 20 - 30%, heat load onto the sample of 60 - 70 kW/m$^2$, and oxygen concentrations of the burn environment of 5 - 15% can reduce the emissions of the heavy molar weight PAHs by up to 77%. Our analysis shows that the relative carcinogenic risk can be reduced by more than 50% under optimal conditions, offering a way for reducing emission exposure from forest treatment activities., Comment: Submitted to Atmospheric Pollution Research

While shape optimization using isogeometric shells exhibits appealing features by integrating design geometries and analysis models, challenges arise when addressing computer-aided design (CAD) geometries comprised of multiple non-uniform rational B-splines (NURBS) patches, which are common in practice. The intractability stems from surface intersections within these CAD models. In this paper, we develop an approach for shape optimization of non-matching isogeometric shells incorporating intersection movement. Separately parametrized NURBS surfaces are modeled using Kirchhoff--Love shell theory and coupled using a penalty-based formulation. The optimization scheme allows shell patches to move without preserving relative location with other members during the shape optimization. This flexibility is achieved through an implicit state function, and analytical sensitivities are derived for the relative movement of shell patches. The introduction of differentiable intersections expands the design space and overcomes challenges associated with large mesh distortion, particularly when optimal shapes involve significant movement of patch intersections in physical space. Throughout optimization iterations, all members within the shell structures maintain the NURBS geometry representation, enabling efficient integration of analysis and design models. The optimization approach leverages the multilevel design concept by selecting a refined model for accurate analysis from a coarse design model while maintaining the same geometry. We adopt several example problems to verify the effectiveness of the proposed scheme and demonstrate its applicability to the optimization of the internal stiffeners of an aircraft wing., Comment: 41 pages, 18 figures

High entropy oxides (HEO)s have garnered much interest due to their available high degree of tunability. Here, we study the local structure of (MgNiCuCoZn)0.167(MnCr)0.083O, a composition based on the parent HEO (MgNiCuCoZn)0.2O.We synthesized a series of thin films via pulsed laser deposition at incremental oxygen partial pressures. X-ray diffraction shows lattice parameter to decrease with increased pO2 pressures until the onset of phase separation. X-ray absorption fine structure shows that specific atomic species in the composition dictate the global structure of the material as Cr, Co, and Mn shift to energetically favorable coordination with increasing pressure. Transmission electron microscopy analysis on a lower-pressure sample exhibits a rock salt structure, but the higher-pressure sample reveals reflections reminiscent of the spinel structure. In all, these findings give a more complete picture on how (MgNiCuCoZn)0.167(MnCr)0.083O forms with varying initial conditions and advances fundamental knowledge of cation behavior in high entropy oxides.

Many record-breaking climate extremes arise from both greenhouse gas-induced warming and natural climate variability. Marine cloud brightening, a solar geoengineering strategy originally proposed to reduce long-term warming, could potentially mitigate extreme events by instead targeting seasonal phenomena, such as El Ni\~no-Southern Oscillation (ENSO). By exploiting the 2019-2020 Australian wildfire experiment-of-opportunity, we show that simulated marine cloud brightening in the southeast Pacific reproduces observed cloud changes and induces La Ni\~na-like responses. We then explore how cloud brightening timing and duration modifies the 1997-1998 and 2015-2016 El Ni\~no events. We find the earliest and longest interventions effectively restore neutral ENSO conditions and dampen El Ni\~no's impacts. Solar geoengineering that targets climate variability could complement tools such as ENSO forecasting and provide a pathway for climate risk mitigation.

Mamba state-space models (SSMs) have recently outperformed state-of-the-art (SOTA) Transformer large language models (LLMs) in various tasks and been widely adapted. However, Mamba's downstream learning capabilities remain either unexplored$\unicode{x2013}$e.g., mixed-precision (MPFT) and parameter-efficient fine-tuning (PEFT)--or under-evaluated$\unicode{x2013}$e.g., in-context learning (ICL). For the latter, recent works reported Mamba's ICL rivals SOTA Transformer LLMs using non-standard benchmarks. In contrast, we show that on standard benchmarks, pretrained Mamba models achieve only 38% of the ICL performance improvements (over zero-shot) of comparable Transformers. Enabling MPFT and PEFT in Mamba architectures is challenging due to recurrent dynamics and highly customized CUDA kernels, respectively. However, we prove that Mamba's recurrent dynamics are robust to small input changes using dynamical systems theory. Empirically, we show that performance changes in Mamba's inference and fine-tuning due to mixed-precision align with Transformer LLMs. Furthermore, we show that targeting key memory buffers in Mamba's customized CUDA kernels for low-rank adaptation regularizes SSM parameters, thus achieving parameter efficiency while retaining speedups. We show that combining MPFT and PEFT enables up to 2.15 times more tokens-per-second and 65.5% reduced per-token-memory compared to full Mamba fine-tuning, while achieving up to 81.5% of the ICL performance improvements (over zero-shot) of comparably fine-tuned Transformers., Comment: 16 pages, 4 figures, 3 tables

We unravel the distinct roles each cation plays in phase evolution, stability, and properties within Mg1/5Co1/5Ni1/5Cu1/5Zn1/5O high-entropy oxide (HEO) by integrating experimental findings, thermodynamic analyses, and first-principles predictions. Our approach is through sequentially removing one cation at a time from the five-component high-entropy oxide to create five four-component derivatives. Bulk synthesis experiments indicate that Mg, Ni, and Co act as rock salt phase stabilizers whereas only Mg and Ni enthalpically enhance single-phase rock salt stability in thin film growth; synthesis conditions dictate whether Co is a rock salt phase stabilizer or destabilizer. By examining the competing phases and oxidation state preferences using pseudo-binary phase diagrams and first-principles calculations, we resolve the stability differences between bulk and thin film for all compositions. We systematically explore HEO macroscopic property sensitivity to cation selection employing both predicted and measured optical spectra. This study establishes a framework for understanding high-entropy oxide synthesizability and properties on a per-cation basis that is broadly applicable to tailoring functional property design in other high-entropy materials., Comment: Saeed S. I. Almishal and Jacob T. Sivak contributed equally to this work

The recently introduced graph-accelerated non-intrusive polynomial chaos (NIPC) method has shown effectiveness in solving a broad range of uncertainty quantification (UQ) problems with multidisciplinary systems. It uses integration-based NIPC to solve the UQ problem and generates the quadrature rule in a desired tensor structure, so that the model evaluations can be efficiently accelerated through the computational graph transformation method, Accelerated Model evaluations on Tensor grids using Computational graph transformations (AMTC). This method is efficient when the model's computational graph possesses a certain type of sparsity which is commonly the case in multidisciplinary problems. However, it faces limitations in high-dimensional cases due to the curse of dimensionality. To broaden its applicability in high-dimensional UQ problems, we propose AS-AMTC, which integrates the AMTC approach with the active subspace (AS) method, a widely-used dimension reduction technique. In developing this new method, we have also developed AS-NIPC, linking integration-based NIPC with the AS method for solving high-dimensional UQ problems. AS-AMTC incorporates rigorous approaches to generate orthogonal polynomial basis functions for lower-dimensional active variables and efficient quadrature rules to estimate their coefficients. The AS-AMTC method extends AS-NIPC by generating a quadrature rule with a desired tensor structure. This allows the AMTC method to exploit the computational graph sparsity, leading to efficient model evaluations. In an 81-dimensional UQ problem derived from an air-taxi trajectory optimization scenario, AS-NIPC demonstrates a 30% decrease in relative error compared to the existing methods, while AS-AMTC achieves an 80% reduction.

This paper presents the development of a deep-atmosphere, nonhydrostatic dynamical core (DyCore) targeted towards ground-thermosphere atmospheric prediction. This DyCore is based on a novel formulation of the specific internal energy equation (SIEE), which, unlike standard potential temperature formulations, is valid for variable composition atmospheres. Two versions of a SIEE are derived from basic principles. The first version, which uses a product-rule (PR) continuity equation, contains an additional compressible term and does not conserve mass. The second version, which does not use the product-rule (No-PR) in the continuity equation, contains two compressible terms and conserves mass to machine precision regardless of time truncation error. The pressure gradient and gravitational forces in the momentum balance equation are formulated in a manner appropriate for HA applications and the spectral element method (SEM) is used with Implicit-Explicit (IMEX) and Horizontally Explicit Vertically Implicit (HEVI) time-integration. These new equation sets were implemented in two U. S. Navy atmospheric models: the Nonhydrostatic Unified Model of the Atmosphere (NUMA) and the Navy Environmental Prediction sysTem Using a Nonhydrostatic Core (NEPTUNE). Numerical results using a nonhydrostatic and hydrostatic baroclinic instability, a balanced zonal flow, and HA mountain wave experiments are shown. These results are compared to existing deep-atmosphere dynamical cores, indicating that the proposed discretized IEE equation sets are viable next-generation ground-to-thermosphere DyCores.

We distinguish the axiomatic study of proofs in geometry from study about geometry from general axioms for mathematics. We briefly report on an abuse of that distinction and its unfortunate effect on US high school education. We review a number of 20th century approaches to synthetic geometry. In doing so, we disambiguate (in the Wikipedia sense) the terms: metric, orthogonal, isotropic and hyperbolic. With some of these systems we are able to axiomatize `affine geometry' over the complex field (The argument is trivial from [Wu94] or [Szm78], but not remarked by either of them.). We examine the general question of the connections between axioms for Affine geometries and the stability classification of associated complete first order theories of fields. We conclude with reminiscences of a half-century friendship with Jan\'{o}s., Comment: preprint for collection

Many air-taxi concepts are capable of vertical takeoff and landing, enabling them to fly to and from urban locations. An important capability for these air taxis is the transition between hover and forward flight. We propose a robust methodology for computing optimal takeoff and transition trajectories using surrogate models trained on data from physics-based models. The use of surrogate models reduces the computational complexity and improves the robustness of the trajectory optimization algorithm. We demonstrate the versatility and robustness of the proposed methodology by applying it to 12 trajectory optimization problems that involve air-taxi takeoff and outbound transition. These trajectories are representative of real air-taxi operations, with a variety of constraints derived, in part, from proposed mission requirements.

Molecular-scale diodes made from self-assembled monolayers (SAMs) could complement silicon-based technologies with smaller, cheaper, and more versatile devices. However, advancement of this emerging technology is limited by insufficient electronic performance exhibited by the molecular current rectifiers. We overcome this barrier by exploiting the charge-transfer state that results from co-assembling SAMs of molecules with strong electron donor and acceptor termini. We obtain a substantial enhancement in current rectification, which correlates with the degree of charge transfer, as confirmed by several complementary techniques. These findings provide a previously unexplored method for manipulating the properties of molecular electronic devices by exploiting donor/acceptor interactions. They also serve as a model test platform for the study of doping mechanisms in organic systems. Our devices have the potential for fast widespread adoption due to their low-cost processing and self-assembly onto silicon substrates, which could allow seamless integration with current technologies.

Quantum state comparison, utilizing metrics like fidelity and trace distance, underpins the assessment of quantum networks within quantum information theory. While recent research has expanded theoretical understanding, incorporating error analysis and scalability considerations remains crucial for practical applications. The primary contribution of this letter is to address these gaps by deriving the novel operational trace distance for multi-node networks, establishing a trace distance vs. fidelity benchmark incorporating error bounds, and bridging quantum operations with tensor network analysis. We further explore the application of tensor network tools to quantum networks, offering new analytical avenues. This comprehensive approach provides a robust framework for evaluating quantum network performance under realistic error conditions, facilitating the development of reliable quantum technologies.

Industrial robotic applications such as spraying, welding, and additive manufacturing frequently require fast, accurate, and uniform motion along a 3D spatial curve. To increase process throughput, some manufacturers propose a dual-robot setup to overcome the speed limitation of a single robot. Industrial robot motion is programmed through waypoints connected by motion primitives (Cartesian linear and circular paths and linear joint paths at constant Cartesian speed). The actual robot motion is affected by the blending between these motion primitives and the pose of the robot (an outstretched/near-singularity pose tends to have larger path tracking errors). Choosing the waypoints and the speed along each motion segment to achieve the performance requirement is challenging. At present, there is no automated solution, and laborious manual tuning by robot experts is needed to approach the desired performance. In this paper, we present a systematic three-step approach to designing and programming a dual robot system to optimize system performance. The first step is to select the relative placement between the two robots based on the specified relative motion path. The second step is to select the relative waypoints and the motion primitives. The final step is to update the waypoints iteratively based on the actual measured relative motion. Waypoint iteration is first executed in simulation and then completed using the actual robots. For performance assessment, we use the mean path speed subject to the relative position and orientation constraints and the path speed uniformity constraint. We have demonstrated the effectiveness of this method on two systems, a physical testbed of two ABB robots and a simulation testbed of two FANUC robots, for two challenging test curves.

The univariate dimension reduction (UDR) method stands as a way to estimate the statistical moments of the output that is effective in a large class of uncertainty quantification (UQ) problems. UDR's fundamental strategy is to approximate the original function using univariate functions so that the UQ cost only scales linearly with the dimension of the problem. Nonetheless, UDR's effectiveness can diminish when uncertain inputs have high variance, particularly when assessing the output's second and higher-order statistical moments. This paper proposes a new method, gradient-enhanced univariate dimension reduction (GUDR), that enhances the accuracy of UDR by incorporating univariate gradient function terms into the UDR approximation function. Theoretical results indicate that the GUDR approximation is expected to be one order more accurate than UDR in approximating the original function, and it is expected to generate more accurate results in computing the output's second and higher-order statistical moments. Our proposed method uses a computational graph transformation strategy to efficiently evaluate the GUDR approximation function on tensor-grid quadrature inputs, and use the tensor-grid input-output data to compute the statistical moments of the output. With an efficient automatic differentiation method to compute the gradients, our method preserves UDR's linear scaling of computation time with problem dimension. Numerical results show that the GUDR is more accurate than UDR in estimating the standard deviation of the output and has a performance comparable to the method of moments using a third-order Taylor series expansion.

Recently, the graph-accelerated non-intrusive polynomial chaos (NIPC) method has been proposed for solving uncertainty quantification (UQ) problems. This method leverages the full-grid integration-based NIPC method to address UQ problems while employing the computational graph transformation approach, AMTC, to accelerate the tensor-grid evaluations. This method exhibits remarkable efficacy on a broad range of low-dimensional (three dimensions or less) UQ problems featuring multidisciplinary models. However, it often does not scale well with problem dimensions due to the exponential increase in the number of quadrature points when using the full-grid quadrature rule. To expand the applicability of this method to a broader range of UQ problems, this paper introduces a new framework for generating a tailored, partially tensor-structured quadrature rule to use with the graph-accelerated NIPC method. This quadrature rule, generated through the designed quadrature approach, possesses a tensor structure that is tailored for the computational model. The selection of the tensor structure is guided by an analysis of the computational graph, ensuring that the quadrature rule effectively capitalizes on the sparsity within the computational graph when paired with the AMTC method. This method has been tested on one 4D and one 6D UQ problem, both originating from aircraft design scenarios and featuring multidisciplinary models. Numerical results show that, when using with graph-accelerated NIPC method, our approach generates a partially tensor-structured quadrature rule that outperforms the full-grid Gauss quadrature and the designed quadrature methods (more than 40% reduction in computational costs) in both of the test problems.

Modern language models, while sophisticated, exhibit some inherent shortcomings, particularly in conversational settings. We claim that many of the observed shortcomings can be attributed to violation of one or more conversational principles. By drawing upon extensive research from both the social science and AI communities, we propose a set of maxims -- quantity, quality, relevance, manner, benevolence, and transparency -- for describing effective human-AI conversation. We first justify the applicability of the first four maxims (from Grice) in the context of human-AI interactions. We then argue that two new maxims, benevolence (concerning the generation of, and engagement with, harmful content) and transparency (concerning recognition of one's knowledge boundaries, operational constraints, and intents), are necessary for addressing behavior unique to modern human-AI interactions. We evaluate the degree to which various language models are able to understand these maxims and find that models possess an internal prioritization of principles that can significantly impact their ability to interpret the maxims accurately.

We study gravitational wave production during kinetic preheating after inflation with a focus on scenarios that arise in $\alpha$-attractor models where a scalar dilaton-like inflaton is kinetically coupled to a second scalar field. We present high-resolution lattice simulations of three $\alpha$-attractor models for a range of parameters to probe regions where preheating is efficient. We find that preheating in these models can be extremely violent, resulting in gravitational wave energy densities that can be constrained by cosmic microwave background measurements of the effective number of relativistic species, $N_{\rm eff}$, Comment: 13 pages, 10 figures

The multifaceted applications of polymers are often limited by their thermal conductivity. Therefore, understanding the mechanisms of thermal transport in polymers is of vital interest. Here, we leverage molecular layer deposition to grow three types of hybrid metalcone (i.e., alucone, zincone, and tincone) films and study their thermal and acoustic properties. The thermal conductivity of the hybrid polymer films ranges from 0.43 to 1.14 W/mK. Using kinetic theory, we trace the origin of thermal conductivity difference to sound speed change, which is dictated by the structural disorder within the films. Changing the disorder has negligible impacts on volumetric heat capacity and vibrational lifetimes. Our findings provide means to improve the thermal conductivity of organic, hybrid, and inorganic polymer films.

To create early warning capabilities for upcoming Space Weather disturbances, we have selected a dataset of 61 emerging active regions, which allows us to identify characteristic features in the evolution of acoustic power density to predict continuum intensity emergence. For our study, we have utilized Doppler shift and continuum intensity observations from the Helioseismic and Magnetic Imager (HMI) onboard the Solar Dynamics Observatory (SDO). The local tracking of 30.66 x 30.66-degree patches in the vicinity of active regions allowed us to trace the evolution of active regions starting from the pre-emergence state. We have developed a machine learning model to capture the acoustic power flux density variations associated with upcoming magnetic flux emergence. The trained Long Short-Term Memory (LSTM) model is able to predict 5 hours ahead whether, in a given area of the solar surface, continuum intensity values will decrease. The performed study allows us to investigate the potential of the machine learning approach to predict the emergence of active regions using acoustic power maps as input., Comment: 9 pages, 4 figures, IAU Symposium 365 Proceedings

The class of Galileon scalar fields theories encapsulate the Vainshtein screening mechanism which is characteristic of a large range of infrared modified theories of gravity. Such theories can lead to testable departures from General Relativity through fifth forces and new scalar modes of gravitational radiation. However, the inherent non-linearity of the Vainshtein mechanism has limited analytic attempts to describe Galileon theories with both cubic and quartic interactions. To improve on this, we perform direct numerical simulations of the quartic Galileon model for a rotating binary source and infer the power spectrum of given multipoles. To tame numerical instabilities we utilize a low-pass filter, extending previous work on the cubic Galileon. Our findings show that the multipole expansion is well-defined and under control. Moreover, our results confirm that despite being a non-linear scalar, the dominant Galileon radiation is quadrupole, and we find a new scaling behaviour deep inside the Vainshtein region., Comment: 12 pages, 6 figures

The Galileon theory is a prototypical effective field theory that incorporates the Vainshtein screening mechanism--a feature that arises in some extensions of General Relativity, such as massive gravity. The Vainshtein effect requires that the theory contain higher order derivative interactions, which results in Galileons, and theories like them, failing to be technically well-posed. While this is not a fundamental issue when the theory is correctly treated as an effective field theory, it nevertheless poses significant practical problems when numerically simulating this model. These problems can be tamed using a number of different approaches: introducing an active low-pass filter and/or constructing a UV completion at the level of the equations of motion, which controls the high momentum modes. These methods have been tested on cubic Galileon interactions, and have been shown to reproduce the correct low-energy behavior. Here we show how the numerical UV-completion method can be applied to quartic Galileon interactions, and present the first simulations of the quartic Galileon model using this technique. We demonstrate that our approach can probe physics in the regime of the effective field theory in which the quartic term dominates, while successfully reproducing the known results for cubic interactions., Comment: 12 pages, 5 figures

YBa$_2$Cu$_3$O$_{7-\delta}$ (YBCO) has favorable macroscopic superconducting properties of $T_\mathrm{c}$ up to 93 K and $H_{c2}$ up to 150 T. However, its nanoscale electronic structure remains mysterious because bulk-like electronic properties are not preserved near the surface of cleaved samples for easy access by local or surface-sensitive probes. It has been hypothesized that Ca-doping at the Y site could induce an alternate cleavage plane that mitigates this issue. We use scanning tunneling microscopy (STM) to study both Ca-free and 10% Ca-doped YBCO, and find that the Ca-doped samples do indeed cleave on an alternate plane, yielding a spatially-disordered partial (Y,Ca) layer. Our density functional theory calculations support the increased likelihood of this new cleavage plane in Ca-doped YBCO. On this surface, we image a superconducting gap with average value 24 $\pm$ 3 meV and characteristic length scale 1-2 nm, similar to Bi-based high-$T_\mathrm{c}$ cuprates, but the first map of gap inhomogeneity in the YBCO family., Comment: corrected typo in metadata author name

Humans understand sentences word-by-word, in the order that they hear them. This incrementality entails resolving temporary ambiguities about syntactic relationships. We investigate how humans process these syntactic ambiguities by correlating predictions from incremental generative dependency parsers with timecourse data from people undergoing functional neuroimaging while listening to an audiobook. In particular, we compare competing hypotheses regarding the number of developing syntactic analyses in play during word-by-word comprehension: one vs more than one. This comparison involves evaluating syntactic surprisal from a state-of-the-art dependency parser with LLM-adapted encodings against an existing fMRI dataset. In both English and Chinese data, we find evidence for multipath parsing. Brain regions associated with this multipath effect include bilateral superior temporal gyrus., Comment: Accepted at ACL2024, main conference. 15 pages

Decades of exponential scaling in high performance computing (HPC) efficiency is coming to an end. Transistor based logic in complementary metal-oxide semiconductor (CMOS) technology is approaching physical limits beyond which further miniaturization will be impossible. Future HPC efficiency gains will necessarily rely on new technologies and paradigms of compute. The Ising model shows particular promise as a future framework for highly energy efficient computation. Ising systems are able to operate at energies approaching thermodynamic limits for energy consumption of computation. Ising systems can function as both logic and memory. Thus, they have the potential to significantly reduce energy costs inherent to CMOS computing by eliminating costly data movement. The challenge in creating Ising-based hardware is in optimizing useful circuits that produce correct results on fundamentally nondeterministic hardware. The contribution of this paper is a novel machine learning approach, a combination of deep neural networks and random forests, for efficiently solving optimization problems that minimize sources of error in the Ising model. In addition, we provide a process to express a Boltzmann probability optimization problem as a supervised machine learning problem.

We discuss the implications of generative AI on education across four critical sections: the historical development of AI in education, its contemporary applications in learning, societal repercussions, and strategic recommendations for researchers. We propose ways in which generative AI can transform the educational landscape, primarily via its ability to conduct assessment of complex cognitive performances and create personalized content. We also address the challenges of effective educational tool deployment, data bias, design transparency, and accurate output verification. Acknowledging the societal impact, we emphasize the need for updating curricula, redefining communicative trust, and adjusting to transformed social norms. We end by outlining the ways in which educational stakeholders can actively engage with generative AI, develop fluency with its capacities and limitations, and apply these insights to steer educational practices in a rapidly advancing digital landscape., Comment: This is a preprint version of an edited book chapter to appear in Kourkoulou, D., O. Tzirides, B. Cope, M. Kalantzis, (eds) (2024). Trust and Inclusion in AI-Mediated Education: Where Human Learning Meets Learning Machines, Springer

Insulating materials featuring ultralow thermal conductivity for diverse applications also require robust mechanical properties. Conventional thinking, however, which correlates strong bonding with high atomic-vibration-mediated heat conduction, led to diverse weakly bonded materials that feature ultralow thermal conductivity and low elastic moduli. One must, therefore, search for strongly-bonded materials in which heat transport is impeded by other means. Here, we report intrinsic, glass-like, ultralow thermal conductivity and ultrahigh elastic-modulus/thermal-conductivity ratio in single-crystalline, BaZrS3-derived, Ruddlesden-Popper phases Ban+1ZrnS3n+1, n = 2, 3. Their key features are strong anharmonicity and intra-unit-cell rock-salt blocks. The latter produce strongly bonded intrinsic superlattices, impeding heat conduction by broadband reduction of phonon velocities and mean free paths and concomitant strong phonon localization. The present study initiates a paradigm of "mechanically stiff phonon glasses".