1. Assessing the nature of nanoscale ferroelectric domain walls in lead titanate multilayers
- Author
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Zatterin, Edoardo, Ondrejkovic, Petr, Bastogne, Louis, Lichtensteiger, Céline, Tovaglieri, Ludovica, Chaney, Daniel A., Sasani, Alireza, Schülli, Tobias, Bosak, Alexei, Leake, Steven, Zubko, Pavlo, Ghosez, Philippe, Hlinka, Jirka, Triscone, Jean-Marc, and Hadjimichael, Marios
- Subjects
Condensed Matter - Materials Science ,Condensed Matter - Mesoscale and Nanoscale Physics - Abstract
The observation of unexpected polarisation textures such as vortices, skyrmions and merons in various oxide heterostructures has challenged the widely accepted picture of ferroelectric domain walls as being Ising-like. Bloch components in the 180{\deg} domain walls of PbTiO3 have recently been reported in PbTiO3/SrTiO3 superlattices and linked to domain wall chirality. While this opens exciting perspectives, the ubiquitous nature of this Bloch component remains to be further explored. In this work, we present a comprehensive investigation of domain walls in PbTiO3/SrTiO3 superlattices, involving a combination of first- and second-principles calculations, phase-field simulations, diffuse scattering calculations, and synchrotron based diffuse x-ray scattering. Our theoretical calculations highlight that the previously predicted Bloch polarisation in the 180{\deg} domain walls in PbTiO3/SrTiO3 superlattices might be more sensitive to the boundary conditions than initially thought and is not always expected to appear. Employing diffuse scattering calculations for larger systems we develop a method to probe the complex structure of domain walls in these superlattices via diffuse x-ray scattering measurements. Through this approach, we investigate depolarization-driven ferroelectric polarization rotation at the domain walls. Our experimental findings, consistent with our theoretical predictions for realistic domain periods, do not reveal any signatures of a Bloch component in the centres of the 180{\deg} domain walls of PbTiO3/SrTiO3 superlattices, suggesting that the precise nature of domain walls in the ultrathin PbTiO3 layers is more intricate than previously thought and deserves further attention.
- Published
- 2024
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