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The current work deals with the mechanical buckling behavior of saturated porous toroidal shell segments sandwiched by piezoelectric actuator layers. Material properties of the porous shells with nonuniform distributed porosities are assumed to vary as a specific function of the thickness and porosity parameters. The nonlinear equations of the sandwich toroidal shell having either positive or negative Gaussian curvature are obtained on the basis of Biot's poroelasticity theory. The energy method as the minimum potential energy principle is applied to derive the governing equations of the sandwich shells. The buckling equations of the piezo-porous sandwich shells under various types of mechanical loading are established by employing the adjacent equilibrium criterion. The governing equations as a set of the coupled partial differential equations are solved using an analytical method including the Airy stress function. Closed-form solutions are derived for shallow segments of the sandwich toroidal shell with positive/negative Gaussian curvature under lateral pressure, axial compression, and hydrostatic pressure loadings. Novel numerical results are presented in this work to show the effects of important factors such as the piezoelectric layer thickness, applied voltage, shell geometrical ratio, and variation of the porosity coefficient on the buckling behavior of these structures. [ABSTRACT FROM AUTHOR]