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We report a detailed analysis of the XMM-Newton spectra of six Narrow-Line Seyfert 1 (NLS1) galaxies at redshift z = 0.35--0.92. Compared with the NLS1s at lower redshift in the previously most-studied sample, these NLS1s have larger black hole (BH) masses ($\log\,M_\text{BH}>7.5$) with similar or even lower Eddington ratios. Our extended XMM-Newton sample of NLS1s shows strong soft X-ray excess emission below 2 keV. The quantified soft excess strength does not show an obvious discrepancy from previous studies of the lower-redshift NLS1s. The systematic effect in the measurement of the Eddington ratio mainly lies in the bolometric correction factor. We also tentatively fit the spectra assuming two more physical models for the soft excess: warm Comptonization and relativistic reflection from the inner accretion disk. In the first scenario, we confirm the ubiquity of a warm and optically thick corona. The behavior of a single source can be better explained by relativistic reflection, although we cannot distinguish which model is a more favorable explanation for the soft excess based on the best-fit statistics., 13 pages, 10 figures

We present a spectral analysis of two XMM-Newton observations of the narrow-line Seyfert 1 galaxy UGC 11763. UGC 11763 shows very different soft X-ray spectral shapes in the two observations separated by 12 years. Three spectral models are considered to explain the multi-epoch X-ray variability of UGC 11763, one based on the relativistic disc reflection model, one based on multiple partially-covering absorbers combined with the warm corona model, and a hybrid model. In the first model, the X-ray variability of UGC 11763 is caused by the emission from a compact coronal region with a variable size. The resulting disc reflection component changes accordingly. A warm absorption model with a modest column density is required in this model too. In the partially-covering absorption scenario, the X-ray variability of UGC 11763 is caused by the variable covering factors of two absorbers located within a region of $r, 13 pages, 10 figures, accepted by MNRAS

Previously, we modelled the X-ray spectra of the narrow-line Seyfert 1 galaxy IRAS 13224$-$3809 using a disc reflection model with a fixed electron density of $10^{15}$ cm$^{-3}$. An additional blackbody component was required to fit the soft X-ray excess below 2 keV. In this work, we analyse simultaneously five flux-resolved XMM-Newton spectra of this source comprising data collected over 2 Ms. A disc reflection model with an electron density of $n_{\rm e}\approx10^{20}$ cm$^{-3}$ and an iron abundance of $Z_{\rm Fe}=3.2\pm0.5Z_{\odot}$ is used to fit the broad-band spectra of this source. No additional component is required to fit the soft excess. Our best-fit model provides consistent measurements of black hole spin and disc inclination angle as in previous models where a low disc density was assumed. In the end, we calculate the average illumination distance between the corona and the reflection region in the disc of IRAS 13224$-$3809 based on best-fit density and ionisation parameters, which changes from 0.43$\sqrt{f_{\rm AD}/f_{\rm INF}}$ $r_{\rm g}$ in the lowest flux state to 1.71$\sqrt{f_{\rm AD}/f_{\rm INF}}$ $r_{\rm g}$ in the highest flux state assuming a black hole mass of $2\times10^{6}M_{\odot}$. $f_{\rm AD}/f_{\rm INF}$ is the ratio between the flux of the coronal emission that reaches the accretion disc and infinity. This ratio depends on the geometry of the coronal region in IRAS 13224$-$3809. So we only discuss its value based on the simple `lamp-post' model, although detailed modelling of the disc emissivity profile of IRAS 13224$-$3809 is required in future to reveal the exact geometry of the corona., Comment: 17 pages, 15 figures including appendices; accepted for publication in MNRAS

Neural network (NN) computing contains a large number of multiply-and-accumulate (MAC) operations. The performance of NN accelerator is limited with the traditional von Neumann architecture due to the tremendous off-chip memory accesses. Resistive random-access memory (ReRAM)-based crossbars can naturally perform matrix–vector multiplication (MVM) operations and are well suitable for NN accelerators. In the existing ReRAM-based NN accelerators, the synaptic weights represented by the conductances of ReRAMs are mainly based on the binary coding. However, the imperfect fabrication process combined with stochastic filament-based switching leads to resistance variations of ReRAMs, which can significantly alter the weights in binary synapses and degrade the NN accuracy. Moreover, the NN accuracy further deteriorates with multilevel cells (MLCs) used for reducing hardware overhead. In this article, a novel unary coding of synaptic weights is proposed to overcome the resistance variations of MLCs and achieve reliable ReRAM-based neuromorphic computing. A variation-aware optimal mapping scheme is also proposed in compliance with the unary coding to guarantee high accuracy by leveraging a unique feature of unary coding—the existence of multiple ways to represent the same value. The optimal mapping obtains very small errors for weights with resistance variations of MLCs. Our simulation results show that under resistance variations, the proposed method achieves less than 0.08% and 3.43% accuracy loss on CIFAR10 and ImageNet, respectively, compared to the ideal accuracy. With each synaptic weight represented by four 2-b MLCs, the proposed method improves the accuracy over the traditional binary coding scheme by 83.39% and 87.6% for CIFAR10 and ImageNet, respectively.

We present an analysis of all the archival high resolution spectra of the Narrow-line Seyfert 1 galaxy Mrk~335 obtained with Reflection Grating Spectrometer (RGS) on board \textit{XMM-Newton}. The spectra show rich emission and absorption features in low and intermediate flux intervals. We model the emission lines with the \textsc{pion\_xs} grid and try to find any possible correlation between the properties of the emitting gas and the source flux. Current data does not allow detailed trace of the response of the line emitting gas to the X-ray flux of Mrk~335, but the flux of the X-ray lines is significantly less variable than the X-ray continuum. We also find that the warm absorber's properties are not correlated with the flux variability. From the latest \textit{XMM-Newton} observation in 2019 December, we find that the photoionized emission and distant reflection components have not responded to the flux drop of Mrk~335 from 2018 July. However, the possible existence of partial covering absorber in the 2018--2019 low state of Mrk~335 makes it difficult to constrain the scale of the emitting gas using this lack of response., 11 pages, 6 figures

We analyze three observations of GRS 1915+105 in 2017 by Insight–Hard X-ray Modulation Telescope when the source was in a spectrally soft state. We find strong absorption lines from highly ionized iron, which are due to absorption by disk wind outflowing at a velocity of ∼1000 km s−1 along our line of sight. Two of the three observations show large amplitude oscillation in their light curves and the variation pattern corresponds to state κ of GRS 1915+105. From time-averaged and flux-resolved analysis, we find that the variation in the ionization state of the disk wind follows the X-ray continuum on timescales from hundreds of seconds to months. The radial location of the disk wind is consistent with thermal driving. The mass-loss rate due to the outflowing wind is comparable to the mass accretion rate in the inner disk, which demonstrates the important role of the disk wind in the disk accretion system.

Selective carbon–carbon bond activation is important in chemical industry and fundamental organic synthesis, but remains challenging. In this study, non-polar unstrained Csp2–Csp3 and Csp2–Csp2 bond activation was achieved by B(OMe)3/B2pin2-mediated fragmentation borylation. Various indole derivatives underwent C2-regioselective C–C bond activation to afford two C–B bonds under transition-metal-free conditions. Preliminary mechanistic investigations suggested that C–B bond formation and C–C bond cleavage probably occurred in a concerted process. This new reaction mode will stimulate the development of reactions based on inert C–C bond activation.

Swift J1858.6-0814 is a recently discovered X-ray binary notable for extremely strong variability (by factors $>100$ in soft X-rays) in its discovery state. We present the detection of five thermonuclear (Type I) X-ray bursts from Swift J1858.6-0814, implying that the compact object in the system is a neutron star. Some of the bursts show photospheric radius expansion, so their peak flux can be used to estimate the distance to the system. The peak luminosity, and hence distance, can depend on several system parameters; for the most likely values, a high inclination and a helium atmosphere, $D=12.8_{-0.6}^{+0.8}$ kpc, although systematic effects allow a conservative range of $9-18$ kpc. Before one burst, we detect a QPO at $9.6\pm0.5$ mHz with a fractional rms amplitude of $2.2\pm0.2$% ($0.5-10$ keV), likely due to marginally stable burning of helium; similar oscillations may be present before the other bursts but the light curves are not long enough to allow their detection. We also search for burst oscillations but do not detect any, with an upper limit in the best case of 15% fractional amplitude (over $1-8$ keV). Finally, we discuss the implications of the neutron star accretor and this distance on other inferences which have been made about the system. In particular, we find that Swift J1858.6-0814 was observed at super-Eddington luminosities at least during bright flares during the variable stage of its outburst., 14 pages, 8 figures, 2 tables, MNRAS accepted

We present a detailed analysis of the spectral properties of the black hole transient GRS 1716-249, based on the archival Swift and NuSTAR observations taken during the outburst of this source in 2016-2017. The first six NuSTAR observations show that the source is in a canonical hard state, where the spectrum is dominated by a power-law continuum. The seventh NuSTAR observation is taken during the intermediate state where both a disc thermal component and a power-law continuum are shown. All of our observations show a broad emission line feature in the iron band and a Compton hump above 10 keV. We model the broad band spectra using a high density disc reflection model, where the soft X-ray emission in the hard state is interpreted as part of the disc reflection component. This model enables us to constrain the disc density parameter of GRS 1716-249 in the range of $10^{19}$-$10^{20}$ cm$^{-3}$. We only obtain an upper limit of the inner disc radius using high density disc reflection spectroscopy and the results indicate either a non-truncated disc or a slightly truncated disc with $R_{\rm in}, 10 pages, 7 figures, accepted by MNRAS

The low mass X-ray binary GX 339-4 went into a new outburst in 2021. At the end of the hard to soft transition of this outburst, Insight-HXMT found that the source rapidly alternated between low flux and high flux states on a timescale of hours. Two high flux states lasted only for a period comparable to the orbital period of the observatory. Time-resolved spectral analysis shows that the sudden changes of flux are confined in the hard X-ray band (>4 keV). The variable non-thermal emission, including the power-law continuum from the corona and the reflected emission from the inner accretion disk, is responsible for the observed variability. The strength of disk thermal emission and the inner radius of the accretion disk are consistent between the two flux states. Assuming the lamppost geometry, our best-fit disk reflection models suggest a very low corona height (within 3 $R_{\rm g}$) and there is no evidence of significant variation in the corona geometry either. The observed rapidly alternating flux states suggest that the intrinsic power of the corona must change during the state transition. We discuss possible mechanisms for the observed sudden changes in the coronal power of GX 339-4., 10 pages, 7 figures. v2: refereed version

We present an analysis of the NuSTAR and Swift spectra of the black hole candidate MAXI J1813-095 in a failed-transition outburst in 2018. The NuSTAR observations show evidence of reflected emission from the inner region of the accretion disc. By modelling the reflection component in the spectra, we find a disc inner radius of $R_{\rm in}, 9 pages, 12 figures, accepted for publication in MNRAS

We present a re-analysis of the XMM-Newton and NuSTAR observing campaign for the well-studied, X-ray-bright AGN MCG-06-30-15. In particular, we consider a disc model with finite thickness. By fitting the disc reflection spectra in the data, we obtain a black hole spin of 0.87--0.99 (90\% confidence range) after taking the thickness of the disc into consideration. Spectral models with a grid of mass accretion rate from 0 to $30\%\dot{M}_{\rm Edd}$ are calculated for MCG-06-30-15. This result is obtained by considering a free disc reflection fraction parameter $f_{\rm refl}$ and is consistent with previous measurements based on razor-thin disc models. Besides, an isotropic, point-like geometry, i.e. the `lamppost' geometry, is assumed for the corona in our model. We find that such a geometry overestimates $f_{\rm refl}$ in the data. Therefore, thin disc models with consistent `lamppost' values of $f_{\rm refl}$ provide a worse fit than ones with a free $f_{\rm refl}$ parameter. We discuss possible reasons for the discrepancy between the observed and theoretical values of $f_{\rm refl}$ at the end of the paper. Modifications for the over-simplified lamppost model might be needed when the thickness of the thin disc is considered in future work., Comment: 15 pages, 14 figures, accepted for publication in MNRAS

The optical and UV variability of the majority of AGN may be related to the reprocessing of rapidly-changing X-ray emission from a more compact region near the central black hole. Such a reprocessing model would be characterised by lags between X-ray and optical/UV emission due to differences in light travel time. Observationally however, such lag features have been difficult to detect due to gaps in the lightcurves introduced through factors such as source visibility or limited telescope time. In this work, Gaussian process regression is employed to interpolate the gaps in the Swift X-ray and UV lightcurves of the narrow-line Seyfert 1 galaxy Mrk 335. In a simulation study of five commonly-employed analytic Gaussian process kernels, we conclude that the Matern 1/2 and rational quadratic kernels yield the most well-specified models for the X-ray and UVW2 bands of Mrk 335. In analysing the structure functions of the Gaussian process lightcurves, we obtain a broken power law with a break point at 125 days in the UVW2 band. In the X-ray band, the structure function of the Gaussian process lightcurve is consistent with a power law in the case of the rational quadratic kernel whilst a broken power law with a breakpoint at 66 days is obtained from the Matern 1/2 kernel. The subsequent cross-correlation analysis is consistent with previous studies and furthermore, shows tentative evidence for a broad X-ray-UV lag feature of up to 30 days in the lag-frequency spectrum where the significance of the lag depends on the choice of Gaussian process kernel., Comment: 24 pages, 9 figures, 2 tables. Accepted for publication in ApJ. Code available at https://github.com/Ryan-Rhys/Mrk_335

We present analysis of two type-I X-ray bursts observed by NuSTAR originating from the very faint transient neutron star low-mass X-ray binary GRS 1741.9-2853 during a period of outburst in May 2020. We show that the persistent emission can be modeled as an absorbed, Comptonized blackbody in addition to Fe K$\alpha$ emission which can be attributed to relativistic disk reflection. We measure a persistent bolometric, unabsorbed luminosity of $L_{\mathrm{bol}}=7.03^{+0.04}_{-0.05}\times10^{36}\,\mathrm{erg\,s^{-1}}$, assuming a distance of 7 kpc, corresponding to an Eddington ratio of $4.5\%$. This persistent luminosity combined with light curve analysis leads us to infer that the bursts were the result of pure He burning rather than mixed H/He burning. Time-resolved spectroscopy reveals that the bolometric flux of the first burst exhibits a double-peaked structure, placing the source within a small population of accreting neutron stars which exhibit multiple-peaked type-I X-ray bursts. We find that the second, brighter burst shows evidence for photospheric radius expansion (PRE) and that at its peak, this PRE event had an unabsorbed bolometric flux of $F_{\mathrm{peak}}=2.94^{+0.28}_{-0.26}\times10^{-8}\,\mathrm{erg\,cm^{-2}\,s^{-1}}$. This yields a new distance estimate of $d=9.0\pm0.5$ kpc, assuming that this corresponds to the Eddington limit for pure He burning on the surface of a canonical neutron star. Additionally, we performed a detailed timing analysis which failed to find evidence for quasiperiodic oscillations or burst oscillations, and we place an upper limit of $16\%$ on the rms variability around 589 Hz, the frequency at which oscillations have previously been reported., Comment: 15 pages, 4 figures, 4 tables, accepted for publication in ApJ

Selective carbon–carbon bond activation is important in chemical industry and fundamental organic synthesis, but remains challenging. In this study, non-polar unstrained Csp2–Csp3 and Csp2–Csp2 bond activation was achieved by B(OMe)3/B2pin2-mediated fragmentation borylation. Various indole derivatives underwent C2-regioselective C–C bond activation to afford two C–B bonds under transition-metal-free conditions. Preliminary mechanistic investigations suggested that C–B bond formation and C–C bond cleavage probably occurred in a concerted process. This new reaction mode will stimulate the development of reactions based on inert C–C bond activation., Non-polar unstrained Csp2–Csp3 and Csp2–Csp2 bond activation was achieved via B(OMe)3/B2pin2-mediated fragmentation borylation, in which C–C bond activation occurred regioselectively at the C2-position in various substituted indoles.

Relativistic reflection features are commonly observed in the X-ray spectra of accreting black holes. In the presence of high quality data and with the correct astrophysical model, X-ray reflection spectroscopy can be quite a powerful tool to probe the strong gravity region, study the morphology of the accreting matter, measure black hole spins, and possibly test Einstein's theory of general relativity in the strong field regime. In the last decade, there has been significant progress in the development of the analysis of these features, thanks to more sophisticated astrophysical models and new observational facilities. Here we review the state-of-the-art in relativistic reflection modeling, listing assumptions and simplifications that may affect, at some level, the final measurements and may be investigated better in the future. We review black hole spin measurements and the most recent efforts to use X-ray reflection spectroscopy for testing fundamental physics., 64 pages, 23 figures. Prepared within the ISSI International Team project "Can We Use X-Ray Reflection Spectroscopy For Precision Measurements Of Accreting Black Holes?". v3: refereed version

Einstein's theory of General Relativity predicts that the spacetime metric around astrophysical black holes is described by the Kerr solution. In this work, we employ state-of-the-art in relativistic reflection modeling to analyze a selected set of NuSTAR spectra of Galactic black holes to obtain the most robust and precise constraints on the Kerr black hole hypothesis possible today. Our constraints are much more stringent than those from other electromagnetic techniques, and with some sources we get stronger constraints than those currently available from gravitational waves., 15 pages, 11 figures. v2: refereed version

Soybean (Glycine max (L.) Merrill) is an important component of the human diet and animal feed, but soybean production is limited by abiotic stresses especially salinity. We recently found that rhizobia inoculation enhances soybean tolerance to salt stress, but the underlying mechanisms are unaddressed. Here, we used quantitative phosphoproteomic and metabonomic approaches to identify changes in phosphoproteins and metabolites in soybean roots treated with rhizobia inoculation and salt. Results revealed differential regulation of 800 phosphopeptides, at least 32 of these phosphoproteins or their homologous were reported be involved in flavonoid synthesis or trafficking, and 27 out of 32 are transcription factors. We surveyed the functional impacts of all these 27 transcription factors by expressing their phospho-mimetic/ablative mutants in the roots of composite soybean plants and found that phosphorylation of GmMYB183 could affect the salt tolerance of the transgenic roots. Using data mining, ChIP and EMSA, we found that GmMYB183 binds to the promoter of the soybean GmCYP81E11 gene encoding for a Cytochrome P450 monooxygenase which contributes to the accumulation of ononin, a monohydroxy B-ring flavonoid that negatively regulates soybean tolerance to salinity. Phosphorylation of GmMYB183 was inhibited by rhizobia inoculation; overexpression of GmMYB183 enhanced the expression of GmCYP81E11 and rendered salt sensitivity to the transgenic roots; plants deficient in GmMYB183 function are more tolerant to salt stress as compared with wild-type soybean plants, these results correlate with the transcriptional induction of GmCYP81E11 by GmMYB183 and the subsequent accumulation of ononin. Our findings provide molecular insights into how rhizobia enhance salt tolerance of soybean plants.

We present a detailed X-ray timing analysis of the highly variable NLS1 galaxy, IRAS 13224-3809. The source was recently monitored for 1.5 Ms with XMM-Newton which, combined with 500 ks archival data, makes this the best studied NLS1 galaxy in X-rays to date. We apply standard time- and Fourier-domain in order to understand the underlying variability process. The source flux is not distributed lognormally, as would be expected for accreting sources. The first non-linear rms-flux relation for any accreting source in any waveband is found, with $\mathrm{rms} \propto \mathrm{flux}^{2/3}$. The light curves exhibit significant strong non-stationarity, in addition to that caused by the rms-flux relation, and are fractionally more variable at lower source flux. The power spectrum is estimated down to $\sim 10^{-7}$ Hz and consists of multiple peaked components: a low-frequency break at $\sim 10^{-5}$ Hz, with slope $\alpha < 1$ down to low frequencies; an additional component breaking at $\sim 10^{-3}$ Hz. Using the high-frequency break we estimate the black hole mass $M_\mathrm{BH} = [0.5-2] \times 10^{6} M_{\odot}$, and mass accretion rate in Eddington units, $\dot m_{\rm Edd} \gtrsim 1$. The non-stationarity is manifest in the PSD with the normalisation of the peaked components increasing with decreasing source flux, as well as the low-frequency peak moving to higher frequencies. We also detect a narrow coherent feature in the soft band PSD at $0.7$ mHz, modelled with a Lorentzian the feature has $Q \sim 8$ and an $\mathrm{rms} \sim 3$ %. We discuss the implication of these results for accretion of matter onto black holes., Comment: Accepted to MNRAS. 19 pages, 17 figures

KUG 1141+371 is a Seyfert 1 galaxy that shows a simultaneous flux increase in the optical and UV bands in the past decade. For instance, the latest Swift observation in 2019 shows that the UVW2 flux of the AGN in KUG 1141+371 has increased by over one order of magnitude since 2009. Meanwhile, the soft X-ray flux of KUG 1141+371 also shows a steady increase by one order of magnitude since 2007. The significant multi-wavelength luminosity change is likely due to a boost of mass accretion rate from approximately 0.6% of the Eddington limit to 3.2%, assuming a black hole mass of $10^{8}M_{\odot}$. In this work, we conduct detailed multi-epoch X-ray spectral analysis focusing on the variability of the X-ray continuum emission and the puzzling soft excess emission. In addition, our SED models also suggest a simultaneous increase of disc temperature and a decreasing inner disc radius along with the increasing accretion rate. Finally, we discuss possible connection between KUG 1141+371 and black hole transients in outburst., 18 pages, 14 figures, accepted by MNRAS

With the development of remote collaboration platforms, the word ‘workplace’ is no longer limited to offices. With the impact of COVID-19, more and more people bring their workplaces out of the corporate office. With that said, moving workplaces to different places has offered researchers opportunities to study the impact on productivity and ergonomics on traditional office workers in various environments. This study is a systematic literature review of the topic of workplace ergonomics and productivity. The review was conducted using platforms such as Scopus, VOSviewer, MAXQDA, Vicinitas, and Web of Science. Bibliometric and co-citation analyses were performed using these tools to show the relationship between diseases caused by bad posture and habits, such as Musculoskeletal Disorders and Computer Vision Syndrome, and productivity. Additionally, environmental and cognitive ergonomics, such as room humidity, room temperature, brightness, also play important roles in worker productivity. It is crucial to understand these issues so that employers can offer better support for their employees in all sorts of working environments without sacrificing much productivity.