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Nacre-inspired metal matrix composites have received much attention due to their excellent deformation coordination ability, which can achieve the synergy of strength and ductility. The preparation of nacre-like Al matrix composites by freeze casting has been a promising application, but the continuous ceramic-rich layer affects the corrosion resistance of the composites, facing complex corrosion problems during service. In this work, the microstructure and corrosion behavior of the nacre-inspired (TiBw-TiB2)/Al composites fabricated by freeze casting and squeeze casting were systematically studied. The results indicated that the Al layers and ceramic-rich layers had little change, about 35 μm and 31 μm, respectively, with an increasing ratio of the Ti/TiB2. Meanwhile, a high Ti/TiB2 ratio resulted in an increase in the Fe-Ti intermetallic phases, which was detrimental to the corrosion performance of the composites and was prone to pitting. The electrochemical test results showed that the 3Ti7TiB2 composite had the lowest corrosion current density (15.9 μA) and intergranular corrosion depth (231 μm), indicating that it had the best corrosion resistance, which can be attributable to its stable and dense passivation film. Two different corrosion phenomena during the intergranular corrosion test existed in the present nacre-inspired (TiBw-TiB2)/Al composites: intergranular corrosion in the Al matrix layer and pitting corrosion in the ceramic-rich layer. Among all the composites, the corrosion depth of the 3Ti7TiB2 composite was the smallest and significantly less than that of the 2024Al alloy. In addition, the continuous ceramic-rich layer acted as a corrosion channel during corrosion, significantly degrading the corrosion resistance of the nacre-like Al composites. [ABSTRACT FROM AUTHOR]

The distribution of reinforcements and interfacial bonding state with the metal matrix are crucial factors in achieving excellent comprehensive mechanical properties for aluminum (Al) matrix composites. Normally, after heat treatment, graphene nanosheets (GNSs)/Al composites experience a significant loss of strength. Here, better performance of GNS/Al was explored with a hybrid strategy by introducing 0.9 vol.% silicon carbide nanoparticles (SiCnp) into the composite. Pre-ball milling of Al powders and 0.9 vol.% SiCnp gained Al flakes that provided a large dispersion area for 3.0 vol.% GNS during the shift speed ball milling process, leading to uniformly dispersed GNS for both as-sintered and as-extruded (0.9 vol.% SiCnp + 3.0 vol.% GNS)/Al. High-temperature heat treatment at 600 °C for 60 min was performed on the as-extruded composite, giving rise to intragranular distribution of SiCnp due to recrystallization and grain growth of the Al matrix. Meanwhile, nanoscale Al4C3, which can act as an additional reinforcing nanoparticle, was generated because of an appropriate interfacial reaction between GNS and Al. The intragranular distribution of both nanoparticles improves the Al matrix continuity of composites and plays a key role in ensuring the plasticity of composites. As a result, the work hardening ability of the heat-treated hybrid (0.9 vol.% SiCnp + 3.0 vol.% GNS)/Al composite was well improved, and the tensile elongation increased by 42.7% with little loss of the strength. The present work provides a new strategy in achieving coordination on strength–plasticity of Al matrix composites. [ABSTRACT FROM AUTHOR]

The poor mechanical and tribological properties limit the higher requirements of aluminum alloys in engineering and industrial applications, which leads to the rapid development of aluminum matrix composites (AMCs). Particulate reinforced AMCs have attracted extensive attention in automobile, electronics and military industries due to their low density, high strength, and excellent wear resistance. However, the interfacial reaction between reinforcements and the Al matrix tends to occur in conventional preparation processes owing to the higher reaction temperatures. The spark plasma sintering (SPS) technique is considered to be an efficient method for the fabrication of metal matrix composites, which can achieve rapid sintering, lower sintering temperatures, and higher densities than conventional fabrication processes. In addition, SPS can produce AMCs with excellent non-porous microstructure, fine grain size, and a strong bonding interface between reinforcement and Al matrix. Therefore, the interfacial reaction is effectively controlled and the structural integrity is maintained, resulting in enhanced strength and ductility. Based on the advantages of particulate reinforced AMCs and the SPS technique, the particulate reinforced AMCs fabricated by SPS have been extensively studied in recent decades, but have not been systematically evaluated. Therefore, this paper reviews the state-of-the-art particulate reinforced AMCs fabricated by SPS, focusing on the microstructure characterization, strengthening mechanisms, and mechanical and physical properties. Furthermore, the future research priorities and challenges of the high-performance particulate reinforced AMCs fabricated by SPS are also prospected. [ABSTRACT FROM AUTHOR]

LiNi0.8Co0.1Mn0.1O2 (LNCMO) cathode materials for lithium-ion batteries (LIBs) were prepared by the hydrothermal synthesis of precursors and high-temperature calcination. The effect of precursor hydrothermal synthesis temperature on the microstructures and electrochemical cycling performances of the Ni-rich LNCMO cathode materials were investigated by SEM, XRD, XPS and electrochemical tests. The results showed that the cathode material prepared using the precursor synthesized at a hydrothermal temperature of 220 °C exhibited the best charge/discharge cycle stability, whose specific capacity retention rate reached 81.94% after 50 cycles. Such enhanced cyclic stability of LNCMO was directly related to the small grain size, high crystallinity and structural stability inherited from the precursor obtained at 220 °C. [ABSTRACT FROM AUTHOR]

As an alternative anode to graphene, molybdenum disulfide (MoS2) has attracted much attention due to its layered structure and high specific capacity. Moreover, MoS2 can be synthesized by hydrothermal method with low cost and the size of its layer spacing can be controlled. In this work, the results of experiment and calculation proved that the presence of intercalated Mo atoms, leading to the expansion of MoS2 layer spacing and weakening of Mo–S bonding. For the electrochemical properties, the presence of intercalated Mo atoms causes the lower reduction potentials for the Li+ intercalation and Li2S formation. In addition, the effective reduction of diffusion resistance and charge transfer resistance in Mo1+ x S2 leads to the acquisition of high specific capacity for battery applications. [ABSTRACT FROM AUTHOR]

Three kinds of quartzites from different regions were crushed, ground, shaped, dried and fired at different temperatures (1 350,1 450 and 1 550 °C) for 2 h. The quartzites powders were investigated in terms of the infrared spectrum, the particle size distribution, and the microstructure. The fired specimens were tested in terms of the phase composition, the true density and the linear change rate. The results show that: (1) the grain size distribution of quartzite from different regions is different; there both exist fine grains of more than ten microns and coarse grains of hundreds of microns; (2) under the same crushing and grinding conditions, the quartzite with smaller average size has small particle size and presents a bimodal distribution, while the quartzite with larger average size has large particle size and presents a multi-modal distribution; (3) the phase transformation rate of the quartzites is affected by both the impurity content and the crystal grain size; and the transformation rate of crystalline quartzite is relatively fast. [ABSTRACT FROM AUTHOR]

Nacre-inspired metal matrix composites have received much attention due to their excellent deformation coordination ability, which can achieve the synergy of strength and ductility. The preparation of nacre-like Al matrix composites by freeze casting has been a promising application, but the continuous ceramic-rich layer affects the corrosion resistance of the composites, facing complex corrosion problems during service. In this work, the microstructure and corrosion behavior of the nacre-inspired (TiBw-TiB 2 )/Al composites fabricated by freeze casting and squeeze casting were systematically studied. The results indicated that the Al layers and ceramic-rich layers had little change, about 35 μm and 31 μm, respectively, with an increasing ratio of the Ti/TiB 2 . Meanwhile, a high Ti/TiB 2 ratio resulted in an increase in the Fe-Ti intermetallic phases, which was detrimental to the corrosion performance of the composites and was prone to pitting. The electrochemical test results showed that the 3Ti7TiB 2 composite had the lowest corrosion current density (15.9 μA) and intergranular corrosion depth (231 μm), indicating that it had the best corrosion resistance, which can be attributable to its stable and dense passivation film. Two different corrosion phenomena during the intergranular corrosion test existed in the present nacre-inspired (TiBw-TiB 2 )/Al composites: intergranular corrosion in the Al matrix layer and pitting corrosion in the ceramic-rich layer. Among all the composites, the corrosion depth of the 3Ti7TiB 2 composite was the smallest and significantly less than that of the 2024Al alloy. In addition, the continuous ceramic-rich layer acted as a corrosion channel during corrosion, significantly degrading the corrosion resistance of the nacre-like Al composites.

As an alternative anode to graphene, molybdenum disulfide (MoS 2 ) has attracted much attention due to its layered structure and high specific capacity. Moreover, MoS 2 can be synthesized by hydrothermal method with low cost and the size of its layer spacing can be controlled. In this work, the results of experiment and calculation proved that the presence of intercalated Mo atoms, leading to the expansion of MoS 2 layer spacing and weakening of Mo-S bonding. For the electrochemical properties, the presence of intercalated Mo atoms causes the lower reduction potentials for the Li + intercalation and Li 2 S formation. In addition, the effective reduction of diffusion resistance and charge transfer resistance in Mo 1+ x S 2 leads to the acquisition of high specific capacity for battery applications., (© 2023 IOP Publishing Ltd.)