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Chemistry plays an important role in the structure and evolution of protoplanetary disks, with implications for the composition of comets and planets. This is the first of a series of papers based on data from DISCS, a Submillimeter Array survey of the chemical composition of protoplanetary disks. The six Taurus sources in the program (DM Tau, AA Tau, LkCa 15, GM Aur, CQ Tau and MWC 480) range in stellar spectral type from M1 to A4 and offer an opportunity to test the effects of stellar luminosity on the disk chemistry. The disks were observed in 10 different lines at ~3" resolution and an rms of ~100 mJy beam-1 at ~0.5 km s-1. The four brightest lines are CO 2-1, HCO+ 3-2, CN 2_3-1_2 and HCN 3-2 and these are detected toward all sources (except for HCN toward CQ Tau). The weaker lines of CN 2_2-1_1, DCO+ 3-2, N2H+ 3-2, H2CO 3_03-2_02 and 4_14-3_13 are detected toward two to three disks each, and DCN 3-2 only toward LkCa 15. CH3OH 4_21-3_12 and c-C3H2 are not detected. There is no obvious difference between the T Tauri and Herbig Ae sources with regard to CN and HCN intensities. In contrast, DCO+, DCN, N2H+ and H2CO are detected only toward the T Tauri stars, suggesting that the disks around Herbig Ae stars lack cold regions for long enough timescales to allow for efficient deuterium chemistry, CO freeze-out, and grain chemistry.

We present new observations leading to an improved black hole mass estimate for the Seyfert 1 galaxy NGC 4593 as part of a reverberation-mapping campaign conducted at the MDM Observatory. Cross-correlation analysis of the H_beta emission-line light curve with the optical continuum light curve reveals an emission-line time delay of 3.73 (+-0.75) days. By combining this time delay with the H_beta line width, we derive a central black hole mass of M_BH = 9.8(+-2.1)x10^6 M_sun, an improvement in precision of a factor of several over past results., 22 pages, 3 tables, 5 figures, accepted for publication in ApJ

We explore the chemical structure of a disk that contains a large central gap of R ~ 45 AU, as is commonly seen in transitional disk systems. In our chemical model of a disk with a cleared inner void, the midplane becomes revealed to the central star so that it is directly irradiated. The midplane material at the truncation radius is permissive to reprocessed optical heating radiation, but opaque to the photo-dissociating ultraviolet, creating an environment abundant in gas-phase molecules. Thus the disk midplane, which would otherwise for a full disk be dominated by near complete heavy element freeze-out, should become observable in molecular emission. If this prediction is correct this has exciting prospects for observations with the Atacama Large Millimeter/Submillimeter Array (ALMA), as the inner transition region should thus be readily detected and resolved, especially using high-J rotational transitions excited in the high density midplane gas. Therefore such observations will potentially provide us with a direct probe of the physics and chemistry at this actively evolving interface., 6 pages, 4 figures. Accepted to ApJ Letters

This is the second in a series of papers based on data from DISCS, a Submillimeter Array observing program aimed at spatially and spectrally resolving the chemical composition of 12 protoplanetary disks. We present data on six Southern sky sources - IM Lup, SAO 206462 (HD 135344b), HD 142527, AS 209, AS 205 and V4046 Sgr - which complement the six sources in the Taurus star forming region reported previously. CO 2-1 and HCO+ 3-2 emission are detected and resolved in all disks and show velocity patterns consistent with Keplerian rotation. Where detected, the emission from DCO+ 3-2, N2H+ 3-2, H2CO 3-2 and 4-3,HCN 3-2 and CN 2-1 are also generally spatially resolved. The detection rates are highest toward the M and K stars, while the F star SAO 206462 has only weak CN and HCN emission, and H2CO alone is detected toward HD 142527. These findings together with the statistics from the previous Taurus disks, support the hypothesis that high detection rates of many small molecules depend on the presence of a cold and protected disk midplane, which is less common around F and A stars compared to M and K stars. Disk-averaged variations in the proposed radiation tracer CN/HCN are found to be small, despite two orders of magnitude range of spectral types and accretion rates. In contrast, the resolved images suggest that the CN/HCN emission ratio varies with disk radius in at least two of the systems. There are no clear observational differences in the disk chemistry between the classical/full T Tauri disks and transitional disks. Furthermore, the observed line emission does not depend on measured accretion luminosities or the number of infrared lines detected, which suggests that the chemistry outside of 100 AU is not coupled to the physical processes that drive the chemistry in the innermost few AU., Comment: accepted for publication in ApJ, 41 pages including 7 figures

Icy bodies may have delivered the oceans to the early Earth, yet little is known about water in the ice-dominated regions of extra-solar planet-forming disks. The Heterodyne Instrument for the Far-Infrared on-board the Herschel Space Observatory has detected emission from both spin isomers of cold water vapor from the disk around the young star TW Hydrae. This water vapor likely originates from ice-coated solids near the disk surface hinting at a water ice reservoir equivalent to several thousand Earth Oceans in mass. The water's ortho-to-para ratio falls well below that of Solar System comets, suggesting that comets contain heterogeneous ice mixtures collected across the entire solar nebula during the early stages of planetary birth., Comment: 18 pages, 2 figures. Corrected typo in reported mass (in g) of detected water vapor reservoir. All conclusions are unchanged

We performed a sensitive search for the ground-state emission lines of ortho- and para-water vapor in the DM Tau protoplanetary disk using the Herschel/HIFI instrument. No strong lines are detected down to 3sigma levels in 0.5 km/s channels of 4.2 mK for the 1_{10}--1_{01} line and 12.6 mK for the 1_{11}--0_{00} line. We report a very tentative detection, however, of the 1_{10}--1_{01} line in the Wide Band Spectrometer, with a strength of T_{mb}=2.7 mK, a width of 5.6 km/s and an integrated intensity of 16.0 mK km/s. The latter constitutes a 6sigma detection. Regardless of the reality of this tentative detection, model calculations indicate that our sensitive limits on the line strengths preclude efficient desorption of water in the UV illuminated regions of the disk. We hypothesize that more than 95-99% of the water ice is locked up in coagulated grains that have settled to the midplane., 5 pages, 3 figures. Accepted for publication in the Herschel HIFI special issue of A&A

We present results from a model of the chemical evolution of protoplanetary disks. In our models we directly calculate the changing propagation and penetration of a high energy radiation field with Lyman alpha radiation included. We also explore the effect on our models of including dust grain settling. We find that, in agreement with earlier studies, the evolution of dust grains plays a large role in determining how deep the UV radiation penetrates into the disk. Significant grain settling at the midplane leads to much smaller freeze-out regions and a correspondingly larger molecular layer, which leads to an increase in column density for molecular species such as CO, CN and SO. The inclusion of Lyman alpha radiation impacts the disk chemistry through specific species that have large photodissociation cross sections at 1216 A. These include HCN, NH3 and CH4, for which the column densities are decreased by an order of magnitude or more due to the presence of Lyman alpha radiation in the UV spectrum. A few species, such as CO2 and SO, are enhanced by the presence of Lyman alpha radiation, but rarely by more than a factor of a few., Comment: 17 pages, 15 Figures. Accepted to ApJ

We analyze the far-ultraviolet (FUV) spectra of 33 classical T Tauri stars (CTTS), including 20 new spectra obtained with the Advanced Camera for Surveys Solar Blind Channel (ACS/SBC) on the Hubble Space Telescope. Of the sources, 28 are in the ~1 Myr old Taurus-Auriga complex or Orion Molecular Cloud, 4 in the 8-10 Myr old Orion OB1a complex and one, TW Hya, in the 10 Myr old TW Hydrae Association. We also obtained FUV ACS/SBC spectra of 10 non-accreting sources surrounded by debris disks with ages between 10 and 125 Myr. We use a feature in the FUV spectra due mostly to electron impact excitation of \h2 to study the evolution of the gas in the inner disk. We find that the \h2 feature is absent in non-accreting sources, but is detected in the spectra of CTTS and correlates with accretion luminosity. Since all young stars have active chromospheres which produce strong X-ray and UV emission capable of exciting \h2 in the disk, the fact that the non-accreting sources show no \h2 emission implies that the \h2 gas in the inner disk has dissipated in the non-accreting sources, although dust (and possibly gas) remains at larger radii. Using the flux at 1600 {\AA}, we estimate that the column density of \h2 left in the inner regions of the debris disks in our sample is less than ~ 3x10^-6 g cm^-2, nine orders of magnitude below the surface density of the minimum mass solar nebula at 1 AU., Comment: 15 pages, 4 figures, accepted to ApJL

We have undertaken a new ground-based monitoring campaign to improve the estimates of the mass of the central black hole in NGC 4151. We measure the lag time of the broad H beta line response compared to the optical continuum at 5100 A and find a lag of 6.6 (+1.1/-0.8) days. We combine our data with the recent reanalysis of UV emission lines by Metzroth et al. to calculate a weighted mean of the black hole mass, M_BH = 4.57 (+0.57/-0.47) x 10^7 M_sun. The absolute calibration of the black hole mass is based on normalization of the AGN black hole mass - stellar velocity dispersion (M_BH - sigma_*) relationship to that of quiescent galaxies by Onken et al. The scatter in the M_BH - sigma_* relationship suggests that reverberation-mapping based mass measurements are typically uncertain by a factor of 3-4., Comment: 17 pages, 3 tables, 3 figures, accepted for publication in ApJ

We have carried out a narrow-band survey of the Local Group galaxy, M33, in the HeII4686 emission line, to identify HeII nebulae in this galaxy. With spectroscopic follow-up observations, we confirm three of seven candidate objects, including identification of two new HeII nebulae, BCLMP651, HBW673. We also obtain spectra of associated ionizing stars for all the HII regions, identifying two new WN stars. We demonstrate that the ionizing source for the known HeII nebula, MA 1, is consistent with being the early-type WN star MC8 (M33-WR14), by carrying out a combined stellar and nebular analysis of MC8 and MA1. We were unable to identify the helium ionizing sources for HBW 673 and BCLMP 651, which do not appear to be Wolf-Rayet stars. According to the [OIII]5007/Hbeta vs [NII]6584/Halpha diagnostic diagram, excitation mechanisms apart from hot stellar continuum are needed to account for the nebular emission in HBW 673, which appears to have no stellar source at all., Accepted for publication in Astronomy and Astrophysics. 22 pages, 10 figures