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7. Thin films deposition versus nanoparticles formation: How can the desired polymer coating be obtained?

Author

Jebali, Syrine, Carneiro de Oliveira, Jamerson, Airoudj, Aissam, Josien, Ludovic, Fioux, Philippe, Ferreira, Isabelle, Roucoules, Vincent, and Bally‐Le Gall, Florence

Subjects
*THIN film deposition, *THIN films, *POLYMER films, *MALEIC anhydride, *GLOW discharges, *PLASMA polymerization, *POLYMERIZATION, *SURFACE coatings
Abstract

The properties of the final product resulting from plasma polymerization strongly depend on the operating conditions and they impact the final application of the plasma polymer coating. Low‐pressure pulsed plasma polymerization of maleic anhydride was investigated at two different positions in relation to the glow discharge in a 1‐m‐long tubular reactor. Interestingly, competition was observed in the deposition of maleic anhydride plasma polymer in the form of a smooth thin film versus that in the form of nanoparticles. The possibility of a spatiotemporal control of plasma polymerization enabled the deposition of a plasma coating with tunable morphological properties depending on the sample position from the glow discharge and on the plasma pulse parameters (on‐time and off‐time). [ABSTRACT FROM AUTHOR]

Published
2022
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