An orthogonal involution σ on a central simple algebra A, after scalar extension to the function field F ( A ) of the Severi–Brauer variety of A, is adjoint to a quadratic form q σ over F ( A ) , which is uniquely defined up to a scalar factor. Some properties of the involution, such as hyperbolicity, and isotropy up to an odd-degree extension of the base field, are encoded in this quadratic form, meaning that they hold for the involution σ if and only if they hold for q σ . As opposed to this, we prove that there exists non-totally decomposable orthogonal involutions that become totally decomposable over F ( A ) , so that the associated form q σ is a Pfister form. We also provide examples of nonisomorphic involutions on an index 2 algebra that yield similar quadratic forms, thus proving that the form q σ does not determine the isomorphism class of σ, even when the underlying algebra has index 2. As a consequence, we show that the e 3 invariant for orthogonal involutions is not classifying in degree 12, and does not detect totally decomposable involutions in degree 16, as opposed to what happens for quadratic forms.