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Nitrogen dioxide (NO2) is a short-lived atmospheric pollutant that serves as an air quality indicator and is itself a health concern. The Airborne Compact Atmospheric Mapper (ACAM) was flown on board the NASA UC-12 aircraft during the Deriving Information on Surface Conditions from Column and Vertically Resolved Observations Relevant to Air Quality Maryland field campaign in July 2011. The instrument collected hyperspectral remote sensing measurements in the 304-910 nm range, allowing daytime observations of several tropospheric pollutants, including nitrogen dioxide (NO2), at an unprecedented spatial resolution of 1.5 × 1.1 sq. km. Retrievals of slant column abundance are based on the differential optical absorption spectroscopy method. For the air mass factor computations needed to convert these retrievals to vertical column abundance, we include high-resolution information for the surface reflectivity by using bidirectional reflectance distribution function data from the Moderate Resolution Imaging Spectroradiometer. We use high-resolution simulated vertical distributions of NO2 from the Community Multiscale Air Quality and Global Modeling Initiative models to account for the temporal variation in atmospheric NO2 to retrieve middle and lower tropospheric NO2 columns (NO2 below the aircraft). We compare NO2 derived from ACAM measurements with in situ observations from NASA's P-3B research aircraft, total column observations from the ground-based Pandora spectrometers, and tropospheric column observations from the space-based Ozone Monitoring Instrument. The high-resolution ACAM measurements not only give new insights into our understanding of atmospheric composition and chemistry through observation of subsampling variability in typical satellite and model resolutions, but they also provide opportunities for testing algorithm improvements for forthcoming geostationary air quality missions.

The calibration and characterization of two new instruments designed to retrieve ozone profiles into the lower stratosphere will be presented. These instruments will fly as a single payload on the Space Shuttle Columbia currently scheduled to lift off July 11, 2002. The purpose of SOLSE (Shuttle Ozone Limb Sounding Experiment) and LORE (Limb Ozone Retrieval Experiment) is to provide a thorough test of the limb ozone retrieval technique, which is being employed on several satellite instruments currently deployed or planned for deployment in the near future. OSIRIS (Optical Spectrograph and Infrared Imager System) and SCIAMACHY (Scanning Imaging Absorption Spectrometer for Atmospheric Chartography) are already in orbit, while OMPS (the Ozone Mapping and Profiler Suite) is planned as the primary US ozone monitoring instrument in the next decade.. SOLSE is a Czerny-Turner spectrograph utilizing a 1k x 1k cooled CCD at the focal plane and covering the spectral range of 310-380 nm in the ultraviolet and 535-865 nm in the visible to near infrared. LORE is a 5 channel filter radiometer with center band wavelengths of 322, 350, 603, 675, and 1000 nm. The focus of this paper will be on measurements of the SOLSE spectrograph performance in the limb-viewing configuration including stray light rejection, spatial and spectral resolution and absolute radiometric response.

The use of limb scattered radiance profiles to retrieve ozone profiles is currently being investigated. The goal is to produce ozone profiles with better vertical resolution than is available with the Backscattered Ultraviolet (BUV) technique and with much greater spatial and temporal coverage than with the solar occultation method (i.e. SAGE II). This method, which uses UV and visible light scattered from the earth's limb, has recently been proven to work for clear sky cases with data from the STS-87 flight of the Shuttle Ozone Sounding Limb Experiment/Limb Ozone Retrieval Experiment (SOLSE/LORE). As to be expected, clouds have a substantial impact upon the limb radiance (increasing the radiance as much as 80-100% is some cases). Here we use a variety of radiative transfer models and limited SOLSE/LORE data to investigate the effect of clouds upon the limb radiance at wavelengths used in the ozone retrieval (approximately 600 nm). Though the presence of clouds can greatly increase the limb radiance, they have a minimal effect upon the retrieved ozone profile, since the retrieval uses a differential absorption technique.

The SSBUV experiment flew eight Space Shuttle missions from October 1989 to January 1996 in conducted eight missions between October 1989 and support of the US long-term ozone monitoring program. Contributions of the SSBUV experiment are reviewed in this paper. SSBUV data are being used to provide and validate the absolute and long-term calibrations of multiple satellite-based ozone monitoring instruments. SSBUV observed a significant decrease in Northern hemisphere total ozone from the winter of 1992 to the following winter, and SSBUV data were combined with Nimbus-7 data to assess long-term ozone changes during the 1980's. SSBUV solar irradiance measurements are being used to determine the absolute solar spectral irradiance in the middle UV, validate solar data from two UARS instruments, and independently measure long-term solar change at wavelengths important for ozone photochemistry. SSBUV data where also used to study the effects of surface reflectivity and rotational Raman scattering on the ozone retrievals, determine the NO column amount and its altitude distribution, measure the UV lunar albedo, and assist in the optimization of wavelengths for new instruments.