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By the end of 2018, 42 years after the landing of the two Viking seismometers on Mars, InSight will deploy onto Mars’ surface the SEIS (Seismic Experiment for Internal Structure) instrument; a six-axes seismometer equipped with both a long-period three-axes Very Broad Band (VBB) instrument and a three-axes short-period (SP) instrument. These six sensors will cover a broad range of the seismic bandwidth, from 0.01 Hz to 50 Hz, with possible extension to longer periods. Data will be transmitted in the form of three continuous VBB components at 2 sample per second (sps), an estimation of the short period energy content from the SP at 1 sps and a continuous compound VBB/SP vertical axis at 10 sps. The continuous streams will be augmented by requested event data with sample rates from 20 to 100 sps. SEIS will improve upon the existing resolution of Viking’s Mars seismic monitoring by a factor of ∼2500 at 1 Hz and ∼200000 at 0.1 Hz. An additional major improvement is that, contrary to Viking, the seismometers will be deployed via a robotic arm directly onto Mars’ surface and will be protected against temperature and wind by highly efficient thermal and wind shielding. Based on existing knowledge of Mars, it is reasonable to infer a moment magnitude detection threshold of Mw∼3 at 40∘ epicentral distance and a potential to detect several tens of quakes and about five impacts per year. In this paper, we first describe the science goals of the experiment and the rationale used to define its requirements. We then provide a detailed description of the hardware, from the sensors to the deployment system and associated performance, including transfer functions of the seismic sensors and temperature sensors. We conclude by describing the experiment ground segment, including data processing services, outreach and education networks and provide a description of the format to be used for future data distribution., Space Science Reviews, 215 (1), ISSN:1572-9672, ISSN:0038-6308

International audience; The InSight mission is due to launch in May 2018, carrying a payload of novel instruments designed and tested to probe the interior of Mars whilst deployed directly on the Martian regolith and partially isolated from the Martian environment by the Wind and Thermal Shield. Central to this payload is the seismometry package SEIS consisting of two seismometers, which is supported by a suite of environmental/meteorological sensors (Temperature and Wind Sensor for InSight TWINS; and Auxiliary Payload Sensor Suite APSS). In this work, an optimal estimations inversion scheme which aims to decorrelate the short-period seismometer (SEIS-SP) signal due to seismic activity alone from the environmental signal and random noise is detailed, and tested on both simulated and Viking data. This scheme also applies a module to identify measurements contaminated by Single Event Phenomena (SEP). This scheme will be deployed as the pre-processing pipeline for all SEIS-SP data prior to release to the scientific community for analysis.

Saturn's polar stratosphere exhibits the seasonal growth and dissipation of broad, warm, vortices poleward of $\sim75^\circ$ latitude, which are strongest in the summer and absent in winter. The longevity of the exploration of the Saturn system by Cassini allows the use of infrared spectroscopy to trace the formation of the North Polar Stratospheric Vortex (NPSV), a region of enhanced temperatures and elevated hydrocarbon abundances at millibar pressures. We constrain the timescales of stratospheric vortex formation and dissipation in both hemispheres. Although the NPSV formed during late northern spring, by the end of Cassini's reconnaissance (shortly after northern summer solstice), it still did not display the contrasts in temperature and composition that were evident at the south pole during southern summer. The newly-formed NPSV was bounded by a strengthening stratospheric thermal gradient near $78^\circ$N. The emergent boundary was hexagonal, suggesting that the Rossby wave responsible for Saturn's long-lived polar hexagon - which was previously expected to be trapped in the troposphere - can influence the stratospheric temperatures some 300 km above Saturn's clouds., 51 pages, 12 figures, published in Nature Communications

The results for the design study of the Long Wave Infrared Module (LWIR), a goal spectroscopic channel for the EChO ESA medium class candidate mission, are presented. The requirements for the LWIR module were to provide coverage of the 11–16 μm spectral range at a moderate resolving power of at least R = 30, whilst minimising noise contributions above photon due to the thermal background of the EChO instrument and telescope, and astrophysical sources such as the zodiacal light. The study output module design is a KRS-6 prism spectrograph with aluminium mirror beam expander and coated germanium lenses for the final focusing elements. Thermal background considerations led to enclosing the beam in a baffle cooled to approximately 25–29 K. To minimise diffuse astrophysical background contributions due to the zodiacal light, anamorphic designs were considered in addition to the elliptical input beam provided by the EChO telescope. Given the requirement that measurements in this waveband place on the performance of the infrared detector array, an additional study on the likely scientific return with lower resolving power (R

The SEIS (Seismic Experiment for Interior Structures) instrument on board the InSight mission to Mars is the critical instrument for determining the interior structure of Mars, the current level of tectonic activity and the meteorite flux. Meeting the performance requirements of the SEIS instrument is vital to successfully achieve these mission objectives. The InSight noise model is a key tool for the InSight mission and SEIS instrument requirement setup. It will also be used for future operation planning. This paper presents the analyses made to build a model of the Martian seismic noise as measured by the SEIS seismometer, around the seismic bandwidth of the instrument (from 0.01 Hz to 1 Hz). It includes the instrument self-noise, but also the environment parameters that impact the measurements. We present the general approach for the model determination, the environment assumptions, and we analyze the major and minor contributors to the noise model.

Acetylene (C 2 H 2 ) and ethane (C 2 H 6 ) are by-products of complex photochemistry in the stratosphere of Saturn. Both hydrocarbons are important to the thermal balance of Saturn’s stratosphere and serve as tracers of vertical motion in the lower stratosphere. Earlier studies of Saturn’s hydrocarbons using Cassini-CIRS observations have provided only a snapshot of their behaviour. Following the vernal equinox in August 2009, Saturn’s northern and southern hemispheres have entered spring and autumn, respectively, however the response of Saturn’s hydrocarbons to this seasonal shift remains to be determined. In this paper, we investigate how the thermal structure and concentrations of acetylene and ethane have evolved with the changing season on Saturn. We retrieve the vertical temperature profiles and acetylene and ethane volume mixing ratios from Δ ν = 15.5 cm - 1 Cassini-CIRS observations. In comparing 2005 (solar longitude, L s ∼ 308°), 2009 ( L s ∼ 3°) and 2010 ( L s ∼ 15°) results, we observe the disappearance of Saturn’s warm southern polar hood with cooling of up to 17.1 K ± 0.8 K at 1.1 mbar at high-southern latitudes. Comparison of the derived temperature trend in this region with a radiative climate model (Section 4 of Fletcher et al., 2010 and Greathouse et al. (2013, in preparation)) indicates that this cooling is radiative although dynamical changes in this region cannot be ruled out. We observe a 21 ± 12% enrichment of acetylene and a 29 ± 11% enrichment of ethane at 25°N from 2005 to 2009, suggesting downwelling at this latitude. At 15°S, both acetylene and ethane exhibit a decrease in concentration of 6 ± 11% and 17 ± 9% from 2005 to 2010, respectively, which suggests upwelling at this latitude (though a statistically significant change is only exhibited by ethane). These implied vertical motions at 15°S and 25°N are consistent with a recently-developed global circulation model of Saturn’s tropopause and stratosphere( Friedson and Moses, 2012 ), which predicts this pattern of upwelling and downwelling as a result of a seasonally-reversing Hadley circulation. Ethane exhibits a general enrichment at mid-northern latitudes from 2005 to 2009. As the northern hemisphere approaches summer solstice in 2017, this feature might indicate an onset of a meridional enrichment of ethane, as has been observed in the southern hemisphere during/after southern summer solstice.

NASA’s InSight lander will deploy a tripod-mounted seismometer package onto the surface of Mars in late 2018. Mars is expected to have lower seismic activity than the Earth, so minimisation of environmental seismic noise will be critical for maximising observations of seismicity and scientific return from the mission. Therefore, the seismometers will be protected by a Wind and Thermal Shield (WTS), also mounted on a tripod. Nevertheless, wind impinging on the WTS will cause vibration noise, which will be transmitted to the seismometers through the regolith (soil). Here we use a 1:1-scale model of the seismometer and WTS, combined with field testing at two analogue sites in Iceland, to determine the transfer coefficient between the two tripods and quantify the proportion of WTS vibration noise transmitted through the regolith to the seismometers. The analogue sites had median grain sizes in the range 0.3–1.0 mm, surface densities of $1.3\mbox{--}1.8~\mbox{g}\,\mbox{cm}^{-3}$ , and an effective regolith Young’s modulus of $2.5^{+1.9}_{-1.4}~\mbox{MPa}$ . At a seismic frequency of 5 Hz the measured transfer coefficients had values of 0.02–0.04 for the vertical component and 0.01–0.02 for the horizontal component. These values are 3–6 times lower than predicted by elastic theory and imply that at short periods the regolith displays significant anelastic behaviour. This will result in reduced short-period wind noise and increased signal-to-noise. We predict the noise induced by turbulent aerodynamic lift on the WTS at 5 Hz to be $\sim2\times10^{-10}~\mbox{ms}^{-2}\,\mbox{Hz}^{-1/2}$ with a factor of 10 uncertainty. This is at least an order of magnitude lower than the InSight short-period seismometer noise floor of $10^{-8}~\mbox{ms}^{-2}\,\mbox{Hz}^{-1/2}$ .

Rosetta, the Solar System cornerstone mission of ESA's Horizon 2000 programme, consists of an orbiter and a lander, and is due to arrive at the comet 67P/Churyumov-Gerasimenko in May 2014. Following its 2004 launch, Rosetta carried out a series of planetary fly-bys and gravitational assists. On these close fly-bys of the Earth, measurements were taken by the Visible Infrared Thermal Imaging Spectrometer (VIRTIS). Analysis of these spectra and comparison with spectra acquired by Earth-observing satellites can support the verification of the inflight calibration of Rosetta/VIRTIS. In this paper, measurements taken by VIRTIS in November 2009 are compared with suitable coincident data from Earth-observing instruments (ESA-ENVISAT/AATSR and SCIAMACHY, and EOS-TERRA/MODIS). Radiative transfer simulations using NEMESIS (Irwin et al., 2008) are fit to the fly-by data taken by VIRTIS, using representative atmospheric and surface parameters. VIRTIS measurements correlate 90% with AATSR's, 85-94% with MODIS, and 82-88% with SCIAMACHYs. The VIRTIS spectra are reproducible in the 1-5 μm region, except in the 1.4 μm deep water vapour spectral absorption band in the near-infrared in cases in which the radiance is very low (cloud-free topographies), where VIRTIS consistently registers more radiance than do MODIS and SCIAMACHY. Over these cloud-free regions, VIRTIS registers radiances a factor of 3-10 larger than SCIAMACHY and of 3-8 greater than MODIS. It is speculated that this discrepancy could be due to a spectral light leak originating from reflections from the order-sorting filters above the detector around 1.4 μm. © 2013 Elsevier Ltd. All rights reserved.

The Uranian atmosphere was observed in August 2009 from 0.8 to 1.8 μm using the near-infrared spectrometer, SpeX, at NASA’s Infrared Telescope Facility. The observations had a spectral resolution of R = 1200 and an average seeing of between 0.5″ in the H-Band (1.4–1.8 μm) and 0.6″ in the I-Band (0.8–0.9 μm). The reduced data were analyzed with a multiple-scattering retrieval code. We were able to reproduce observations when using a vertically-compact cloud in the upper troposphere and a vertically-extended, optically-thin haze above the 1-bar level. The existence of these two clouds is consistent with previous studies. The sub-micron portion of the data are most sensitive to very small scattering particles, allowing more insight into particle size than other portions of the infrared spectrum. This portion of the spectrum was therefore of particular interest and was not available in most previous studies of the planet. We assumed the particles in both clouds to be relatively strong forward scatterers (with a Henyey-Greenstein asymmetry factor of g = 0.7). Given this assumption, we found single-scattering albedos in the tropospheric cloud particles to be ω ¯ = 0.7 at wavelengths above 1.4 μm and to gradually increase to ω ¯ = 1.0 at wavelengths shortward of 1.0 μm. In the upper haze, we found single-scattering albedos to be ω ¯ = 1.0 with the exception of a narrow drop at 1.0 μm to ω ¯ = 0.6 . We found a preference for upper haze particle radii at r = 0.10 μm. Retrievals of base pressure, fractional scale height, and optical depth in both cloud layers showed the best agreement with data when the base pressure of the upper haze was fixed just above the tropospheric clouds, rather than at or above the tropopausal cold trap. We found that these same retrievals strongly preferred tropospheric cloud particles of 1.35-μm radii, and observed cloud top height to increase away from the equator in the case of latitudinally invariant methane abundance. Latitudinal methane variability was also considered, both through a reflectivity study at the 825-nm collision-induced hydrogen absorption feature, as well as through radiative transfer analysis, using forward modeling and retrievals of cloud properties and methane abundance. The data suggested that methane abundance above the tropospheric clouds increased when moving from the midlatitudes towards the equator by at least 9%. The peak of this equatorial methane enrichment was determined to be at 4 ± 2° S latitude, having moved nearly 15° northward since a reflectance study of 2002 data ( Karkoschka and Tomasko, 2009 ).

Since the 1970s, it has been predicted that both CO2 and H2O clouds can form in the Martian atmosphere, and many remote-sounding instruments have directly observed layers of extinction asserted to be clouds composed of either CO2 or H2O ice on Mars. The Mars Climate Sounder, onboard the Mars Reconnaissance Orbiter (MRO/MCS), entered orbit around Mars in 2006, and has been providing near-continuous coverage of the full planet since, at wavelengths from visible through to the mid-infrared, primarily in limb-viewing geometry, making it a suitable candidate to study the parameters of these clouds. In this work, the multiple scattering radiative-transfer tool NemesisMCS has been used to create a large dataset of simulations of CO2 and H2O clouds on Mars as would be measured by MRO/MCS, using a range of atmospheric conditions as well as cloud parameters derived from literature suitable for upper atmospheric clouds, and building specifically on the work of Sefton-Nash et al. (2013). This ensemble of simulations has been used to characterise the spectral signature of plausible CO2 and H2O clouds, as well as to assess the suitability of MRO/MCS to observe, to differentiate between, and to derive properties of such clouds. It has been found, given the noise levels expected for MRO/MCS and the range of atmospheric and cloud parameters sampled in this study, that radiance signals introduced by upper atmospheric clouds having nadir optical depths greater than about 10−5 should be distinguishable, with S/N≥1. This corresponds to specific concentrations greater than about 105 particles/g, particle radii greater than around View the MathML source, and cloud depths greater than about 2 km. MRO/MCS measurements should be able to be used with confidence to differentiate between upper atmospheric cloud and dust in the lower atmosphere, and clear conditions, with high success (≈100%). Lower reliability classification is accomplished for CO2 clouds, with only 60% being correctly identified as CO2, and the remainder classified instead as H2O cloud, in the case of optical depths in the expected range for upper atmospheric cloudswhich are detectable by MRO/MCS, although this result is highly dependent upon the sampled selection of optically thin and thick clouds and the atmospheric model employed. Although almost all the H2O clouds are correctly identified, the fact that such a large proportion of CO2 clouds are misclassified as H2O clouds shows that the spectral information alone from MRO/MCS is insufficient to differentiate between CO2 and H2O clouds when optically thin—but detectable—clouds are included in the analysis. Using a simple look-up table (LUT) scheme and simulated data, retrieval of properties of upper atmospheric clouds of sufficient opacity is possible, with preliminary estimates indicating that H2O cloud and dust parameters can be correctly reproduced between 48% and 100% of the time, and between 18% and 92% of the time for CO2 cloud test cases, although it must be noted that these values must be taken as a qualitative measure which does not capture the full range of atmospheric and cloud conditions on Mars which would be present in real MRO/MCS data. Furthermore, because of the optical properties of H2O and CO2, on a like-with-like selection, the H2O clouds always produce greater perturbations in radiance, thus biasing results to a higher success rate for H2O cloud retrievals. Application of the method to MRO/MCS data with a full-optimal estimation retrieval tool such as NemesisMCS will be the topic of a future study.

The design of a versatile dual-telescope thermal-infrared radiometer spanning the spectral wavelength range 8–200 µm, in five spectral pass bands, for outer planet fly-by missions is described. The dual-telescope design switches between a narrow-field-of-view and a wide-field-of-view to provide optimal spatial resolution images within a range of spacecraft encounters to the target. The switchable dual-field-of-view system uses an optical configuration based on the axial rotation of a source-select mirror along the optical axis. The optical design, spectral performance, radiometric accuracy, and retrieval estimates of the instrument are discussed. This is followed by an assessment of the surface coverage performance at various spatial resolutions by using the planned NASA Europa Mission 13-F7 fly-by trajectories as a case study.

The planet-encircling springtime storm in Saturn's troposphere (December 2010-July 2011, Fletcher, L.N. et al. [2011]. Science 332, 1413-1414; Sánchez-Lavega, A. et al. [2011]. Nature 475, 71-74; Fischer, G. et al. [2011]. Nature 475, 75-77) produced dramatic perturbations to stratospheric temperatures, winds and composition at mbar pressures that persisted long after the tropospheric disturbance had abated. Thermal infrared (IR) spectroscopy from the Cassini Composite Infrared Spectrometer (CIRS), supported by ground-based IR imaging from the VISIR instrument on the Very Large Telescope and the MIRSI instrument on NASA's IRTF, is used to track the evolution of a large, hot stratospheric anticyclone between January 2011 and March 2012. The evolutionary sequence can be divided into three phases: (I) the formation and intensification of two distinct warm airmasses near 0.5. mbar between 25 and 35°N (B1 and B2) between January-April 2011, moving westward with different zonal velocities, B1 residing directly above the convective tropospheric storm head; (II) the merging of the warm airmasses to form the large single 'stratospheric beacon' near 40°N (B0) between April and June 2011, disassociated from the storm head and at a higher pressure (2 mbar) than the original beacons, a downward shift of 1.4 scale heights (approximately 85. km) post-merger; and (III) the mature phase characterised by slow cooling (0.11. ±. 0.01. K/day) and longitudinal shrinkage of the anticyclone since July 2011. Peak temperatures of 221.6. ±. 1.4. K at 2. mbar were measured on May 5th 2011 immediately after the merger, some 80. K warmer than the quiescent surroundings. From July 2011 to the time of writing, B0 remained as a long-lived stable stratospheric phenomenon at 2. mbar, moving west with a near-constant velocity of 2.70. ±. 0.04. deg/day (-24.5. ±. 0.4. m/s at 40°N relative to System III longitudes). No perturbations to visible clouds and hazes were detected during this period.With no direct tracers of motion in the stratosphere, we use thermal windshear calculations to estimate clockwise peripheral velocities of 200-400m/s at 2mbar around B0. The peripheral velocities of the two original airmasses were smaller (70-140m/s). In August 2011, the size of the vortex as defined by the peripheral collar was 65° longitude (50,000km in diameter) and 25° latitude. Stratospheric acetylene (C 2H 2) was uniformly enhanced by a factor of three within the vortex, whereas ethane (C 2H 6) remained unaffected. The passage of B0 generated a new band of warm stratospheric emission at 0.5mbar at its northern edge, and there are hints of warm stratospheric structures associated with the beacons at higher altitudes (p

Thunderstorm activity has been observed on Saturn via radio emissions from lightning discharges and optical detections of the lightning flashes on the planets nightside. Thunderstorms provide extreme environments in which specific atmospheric chemistry can be induced - namely through energy release via lightning discharges, and fast vertical transport resulting in rapid advection of tropospheric species. It is thus theorised that certain atmospheric trace species such as C 2H 2, HCN, and CO can be generated in the troposphere by large bursts of energy in the form of lightning, and transported upward towards the upper troposphere by the extreme dynamics of thunderstorms, where they should be observable by satellite instruments. In this work, high-spectral-resolution Cassini/CIRS observations from October 2005 through April 2009 are used to study whether there is an observable increase in upper tropospheric acetylene in regions of known normal thunderstorm activity. Using both individual measurements in which there is known thunderstorm activity, as well as large coadditions of data to study latitudinal-dependencies over the full disc, no systematic enhancement in upper tropospheric (100 mbar) C 2H 2 was detected around regions in which there are known occurrences of normally sized (2000 km) thunderstorms, or in normally sized thunderstorm-prone regions such as 40°S. It is likely that the magnitude of the enhancement theorised is too generous or that enhancements are not advected into the upper troposphere as vertical mixing rates in models would suggest, since Cassini/CIRS can only detect C 2H 2 above the 200 mbar level - although the massive northern hemisphere thunderstorm of 2010/2011 seems able to decrease stratospheric concentrations of C 2H 2. From this, it can be asserted that lightning from normal thunderstorm activity cannot be the key source for upper tropospheric C 2H 2 on Saturn, since the upper-tropospheric concentrations retrieved agree with the concentrations stemming from the photolysis of CH 4 (23 ppbv) from solar radiation penetrating through the Saturnian atmosphere, with an upper limit for lightning-induced C 2H 2 volume mixing ratio of 10 -9. © 2012 Elsevier Ltd. All rights reserved.

Observations of Neptune were made in September 2009 with the Gemini-North Telescope in Hawaii, using the NIFS instrument in the H-band covering the wavelength range 1.477-1.803 μm. Observations were acquired in adaptive optics mode and have a spatial resolution of approximately 0.15-0.25″. The observations were analysed with a multiple-scattering retrieval algorithm to determine the opacity of clouds at different levels in Neptune's atmosphere. We find that the observed spectra at all locations are very well fit with a model that has two thin cloud layers, one at a pressure level of ∼2. bar all over the planet and an upper cloud whose pressure level varies from 0.02 to 0.08. bar in the bright mid-latitude region at 20-40°S to as deep as 0.2. bar near the equator. The opacity of the upper cloud is found to vary greatly with position, but the opacity of the lower cloud deck appears remarkably uniform, except for localised bright spots near 60°S and a possible slight clearing near the equator. A limb-darkening analysis of the observations suggests that the single-scattering albedo of the upper cloud particles varies from ∼0.4 in regions of low overall albedo to close to 1.0 in bright regions, while the lower cloud is consistent with particles that have a single-scattering albedo of ∼0.75 at this wavelength, similar to the value determined for the main cloud deck in Uranus' atmosphere. The Henyey-Greenstein scattering particle asymmetry of particles in the upper cloud deck are found to be in the range g∼ 0.6-0.7 (i.e. reasonably strongly forward scattering).Numerous bright clouds are seen near Neptune's south pole at a range of pressure levels and at latitudes between 60 and 70°S. Discrete clouds were seen at the pressure level of the main cloud deck (∼2. bar) at 60°S on three of the six nights observed. Assuming they are the same feature we estimate the rotation rate at this latitude and pressure to be 13.2 ± 0.1. h. However, the observations are not entirely consistent with a single non-evolving cloud feature, which suggests that the cloud opacity or albedo may vary very rapidly at this level at a rate not seen in any other giant-planet atmosphere. © 2011 Elsevier Inc.

The sub-millimetre/microwave range of the spectrum has been exploited in the field of Earth observation by many instruments over the years and has provided a plethora of information on atmospheric chemistry and dynamicshowever, this spectral range has not been fully explored in planetary science, having been exclusively employed to carry out ground-based measurements. To this end, a sub-millimetre instrument, the Orbiter Terahertz Infrared Spectrometer (ORTIS), is studied by the University of Oxford and the Rutherford Appleton Laboratory, to meet the requirements of the European Space Agency's Cosmic Visions 2015-2025 programme-in particular, the Europa Jupiter System Mission (EJSM), which has the European Space Agency and the National Aeronautics and Space Administration as partners. ORTIS is designed to measure atmospheric temperature, the abundance of stratospheric water vapour and other jovian gases, and is intended to be capable of retrieving vertical profiles of horizontal windspeed in the stratosphere for the first time, from Doppler-shifted emission lines measured at high spectral resolution. In this work, a preliminary study and implementation of the estimation of windspeed profiles on simulated spectra representative of Jupiter is presented, detailing the development of the retrieval algorithm, showing that a sub-millimetre instrument such as ORTIS should be able to retrieve windspeed profiles to an accuracy of about 15 m/s between 70 and 200 km/0.1-10 mb using a single near-limb measurement, for expected noise amplitudes. © 2010 Elsevier B.V.. All rights reserved.

Numerical and laboratory results of the drag characteristics are presented for different configurations of an underwater buoyancy package. It is shown that the drag and oscillation of an underwater sphere can be reduced substantially with the addition of a shaped cowling. The influence of several different cowling shapes on the drag and lift are determined. The results from a numerical fluid dynamical calculation are compared and laboratory measurements are scaled. Both the dynamic and static components of drag and lift are presented. The drag force for an underwater sphere can be reduced by more than 80% for a full teardrop-shaped cowling. A truncated teardrop, more practical for real applications, will still reduce the drag by 60%–70%. In addition to the drag, the amplitude of oscillations driven by eddy shedding is similarly reduced.

Objectives: Personal emergency response systems (PERSs) are reported to reduce anxiety and health care use and may assist in planning the disposition of older patients discharged from the emergency department (ED) to home. This study measured the impact of a PERS on anxiety, fear of falling, and subsequent health care use among older ED patients. Methods: This study was a randomized controlled trial comparing PERS use with standard ED discharge planning in subjects 70 years of age or older discharged home after a fall. Outcome assessors were blinded to the study objectives. Anxiety and fear of falling were measured at baseline and 30 days using the Hospital Anxiety and Depression Scale anxiety subscale (HADS-A) and modified Falls Efficacy Scale (mFES). Return to the ED, hospitalization, and length of stay were recorded after 30 and 60 days. Results: Eighty-six subjects were randomized and completed follow up (43 per group). There was no important difference in mean reduction in anxiety (mean change treatment − control, +0.35; 95% confidence interval [CI] =−1.5 to 0.76; p = 0.55) or fear of falling (mean change, +4.5; 95% CI =−6.7 to 15.7; p = 0.70). Return visits to the ED occurred in eight of 43 patients in both the control and treatment groups (risk difference, 0.0%; 95% CI =−16% to 16%). Hospitalization occurred in six of 43 in the control group versus three of 43 in the treatment group (risk difference treatment − control =−7.0%; 95% CI =−19.8% to 5.9%). Conclusions: In contrast to previous studies, there was no evidence that a PERS reduced anxiety, fear of falling, or return to the ED among older persons discharged from the ED.

The seasonal evolution of Saturn's polar atmospheric temperatures and hydrocarbon composition is derived from a decade of Cassini Composite Infrared Spectrometer (CIRS) 7-16 $\mu$m thermal infrared spectroscopy. We construct a near-continuous record of atmospheric variability poleward of 60$^\circ$ from northern winter/southern summer (2004, $L_s=293^\circ$) through the equinox (2009, $L_s=0^\circ$) to northern spring/southern autumn (2014, $L_s=56^\circ$). The hot tropospheric polar cyclones and the hexagonal shape of the north polar belt are both persistent features throughout the decade of observations. The hexagon vertices rotated westward by $\approx30^\circ$ longitude between March 2007 and April 2013, confirming that they are not stationary in the Voyager-defined System III longitude system as previously thought. The extended region of south polar stratospheric emission has cooled dramatically poleward of the sharp temperature gradient near 75$^\circ$S, coinciding with a depletion in the abundances of acetylene and ethane, and suggestive of stratospheric upwelling with vertical wind speeds of $w\approx+0.1$ mm/s. This is mirrored by a general warming of the northern polar stratosphere and an enhancement in acetylene and ethane abundances that appears to be most intense poleward of 75$^\circ$N, suggesting subsidence at $w\approx-0.15$ mm/s. However, the sharp gradient in stratospheric emission expected to form near 75$^\circ$N by northern summer solstice (2017, $L_s=90^\circ$) has not yet been observed, so we continue to await the development of a northern summer stratospheric vortex. North polar minima in tropospheric and stratospheric temperatures were detected in 2008-2010 (lagging one season, or 6-8 years, behind winter solstice); south polar maxima appear to have occurred before the start of the Cassini observations (1-2 years after summer solstice). [Abridged], Comment: Preprint of article accepted for publication in Icarus

We present an intercomparison of Saturn’s stratosphere between Voyager 1-IRIS observations in 1980 and Cassini-CIRS observations in 2009 and 2010. Over a saturnian year (∼29.5 years) has now passed since the Voyager flybys of Saturn in 1980/1981. Cassini observations in 2009/2010 capture Saturn in the same season as Voyager observations (just after the vernal equinox) but one year later. Any differences in Saturn’s atmospheric properties implied by a comparison of these two datasets could therefore reveal the extent of interannual variability. We retrieve temperature and stratospheric acetylene and ethane concentrations from Voyager 1-IRIS ( Δ ν = 4.3 cm - 1 ) observations in 1980 and Cassini-CIRS ( Δ ν = 15.5 cm - 1 ) ‘FIRMAP’ observations in 2009 and 2010. We observe a difference in temperature at the equator of 7.1 ± 1.2 K at the 2.1-mbar level that implies that the two datasets have captured Saturn’s semiannual oscillation (SSAO) in a slightly different phase suggesting that its period is more quasi-semiannual. Elevated concentrations of acetylene at 25°S in 1980 with respect to 2010 imply stronger downwelling at the former date which may also be explained by a difference in the phase of the SSAO and its dynamical forcing at low latitudes. At high-southern and high-northern latitudes, stratospheric temperatures and hydrocarbon concentrations appear elevated in 1980 with respect to 2009/2010. This could be an artefact of the low signal-to-noise ratio of the corresponding observations but might also be explained by increased auroral activity during solar maximum in 1980.

New line data describing the absorption of CH4 and CH3D from 1.26 to 1.71 μm (WKMC-80K, Campargue, A., Wang, L., Mondelain, D., Kassi, S., Bezard, B., Lellouch, E., Coustenis, A., de Bergh, C., Hirtzig, M., Drossart, P. [2012]. Icarus 219, 110–128) have been applied to the analysis of Gemini-N/NIFS observations of Neptune made in 2009 and VLT/CRIRES observations made in 2010. The new line data are found to greatly improve the fit to the observed spectra and present a considerable advance over previous methane datasets. The improved fits lead to an empirically derived wavelength-dependent correction to the scattering properties of the main observable cloud deck at 2–3 bars that is very similar to the correction determined for Uranus’ lower cloud using the same line dataset by Irwin et al. (Irwin, P.G.J., de Bergh, C., Courtin, R., Bezard, B., Teanby, N.A., Davis, G.R., Fletcher, L.N., Orton, G.S., Calcutt, S.B., Tice, D., Hurley, J. [2012]. Icarus 220, 369–382). By varying the abundance of CH3D in our simulations, analysis of the Gemini/NIFS observations leads to a new determination of the CH3D/CH4 ratio for Neptune of 3.0 - 0.9 + 1.0 × 10 - 4 , which is smaller than previous determinations, but is identical (to within error) with the CH3D/CH4 ratio of 2.9 - 0.5 + 0.9 × 10 - 4 derived by a similar analysis of Gemini/NIFS observations of Uranus made in the same year. Thus it appears that the atmospheres of Uranus and Neptune have an almost identical D/H ratio, which suggests that the icy planetisimals forming these planets came from the same source reservoir, or a reservoir that was well-mixed at the locations of ice giant formation, assuming complete mixing between the atmosphere and interior of both these planets. VLT/CRIRES observations of Neptune have also been analysed with the WKMC-80K methane line database, yielding very good fits, with little evidence for missing absorption features. The CRIRES spectra indicate that the mole fraction of CO at the 2–3 bar level must be substantially less than its estimated stratospheric value of 1 × 10−6, which suggests that the predominant source of CO in Neptune’s atmosphere is external, through the influx of micrometeorites and comets, although these data cannot rule out an additional internal source.

On a labour ward, providing an objective means of assessing midwifery staffing is essential to match workload with available resources thereby ensuring effective utilization of staff, and to maintain quality intrapartum care. This report describes the application of a workforce planning tool, based upon GRASP® systems workload methodology, to identify staffing needs based on patient dependency levels on a labour ward, some findings relating to trends in unit activity and projected work time equivalents are provided.

The assumption that midwifery practice should be based on research evidence is universally accepted, yet practices based on tradition or ineffective or unproven assumptions continue. This article reviews the development of research-based practice and considers the factors influencing the extent to which midwives value and implement research-based care.

International audience; Mesospheric clouds have been previously observed on Mars in a variety of datasets. However, because the clouds are optically thin and most missions have performed surface-focussed nadir sounding, geographic and seasonal coverage is sparse. We present new detections of mesospheric clouds using a limb spectra dataset with global coverage acquired by NASA's Mars Climate Sounder (MCS) aboard Mars Reconnaissance Orbiter. Mesospheric aerosol layers, which can be CO2 ice, water ice or dust clouds, cause high radiances in limb spectra, either by thermal emission or scattering of sunlight. We employ an object recognition and classification algorithm to identify and map aerosol layers in limb spectra acquired between December 2006 and April 2011, covering more than two Mars years. We use data from MCS band A4, to show thermal signatures of day and nightside features, and A6, which is sensitive to short wave IR and visible daytime features only. This large dataset provides several thousand detections of mesospheric clouds, more than an order of magnitude more than in previous studies.Our results show that aerosol layers tend to occur in two distinct regimes. They form in equatorial regions (30°S-30°N) during the aphelion season/northern hemisphere summer (Ls150°) a greater number of features are observed and are distributed in two mid-latitude bands, with a southern hemisphere bias. We observe temporal and longitudinal clustering of cloud occurrence, which we suggest is consistent with a formation mechanism dictated by interaction of broad temperature regimes imposed by global circulation and the propagation to the mesosphere of small-scale dynamics such as gravity waves and thermal tides.Using calculated frost point temperatures and a parameterization based on synthetic spectra we find that aphelion clouds are present in generally cooler conditions and are spectrally more consistent with H2O or CO2 ice. A significant fraction has nearby temperature retrievals that are within a few degrees of the CO2 frost point, indicating a CO2 composition for those clouds. Perihelion season clouds are spectrally most similar to H2O ice and dust aerosols, consistent with temperature retrievals near to the clouds that are 30-80K above the CO2 frost point. © 2012 Elsevier Inc.

Ammonia (NH 3 ) has been detected both on Saturn and Jupiter, and although its concentration and distribution has been well-studied on Jupiter, it has proven more difficult to do so on Saturn due to higher sensitivity requirements resulting from Saturn's lower atmospheric temperatures and the dominance of Saturn's phosphine which masks the ammonia signal. Using far-infrared measurements of Saturn taken by Cassini/CIRS between February 2005 and December 2010, the latitudinal variations of upper tropospheric ammonia on Saturn are studied. Sensitivity to NH 3 in the far-infrared is explored to provide estimates of temperature, para-H 2 and PH 3 , from 2.5 cm −1 spectral resolution measurements alone, 0.5 cm −1 spectral-resolution measurements alone, and 0.5 cm −1 measurements degraded to 2.5 cm −1 spectral resolution. The estimates of NH 3 from these three different datasets largely agree, although there are notable differences using the high emission angle 0.5 cm −1 data, which are asserted to result from a reduction in sensitivity at higher emission angles. For low emission angles, the 0.5 cm −1 -retrieved values of NH 3 can be used to reproduce the 2.5 cm −1 spectra with similar efficacy as those derived directly from the 2.5 cm −1 resolution data itself, and vice versa. Using low emission angle data, NH 3 is observed to have broad peak abundances at ±25° latitude, attributed to result from condensation and/or photolytic processes. Lack of data coverage at equatorial latitudes precludes analysis of NH 3 abundance at less than about 10° latitude. Noise levels are not sufficient to distinguish fine zonal features, although it seems that NH 3 cannot trace the zonal belt/zone structure in the upper troposphere of Saturn.

Near-infrared observations of Uranus were made in October/November 2010 with the Gemini-North telescope in Hawaii, using NIFS, an integral field spectrograph, and the NIRI instrument in imaging mode. Observations were acquired using adaptive optics and have a spatial resolution of approximately 0.1-0.2'.The observed spectra along Uranus' central meridian were analysed using a multiple-scattering retrieval algorithm to infer the vertical/latitudinal variation in cloud optical depth, which we compare with previous observations made by Gemini-North/NIFS in 2009 and UKIRT/UIST observations made between 2006 and 2008. Assuming a continuous distribution of small particles (r~ 1μm, and refractive index of 1.4. +. 0. i) with the single scattering albedo set to 0.75 and using a Henyey-Greenstein phase function with asymmetry parameter set to 0.7 at all wavelengths and latitudes, the retrieved cloud density profiles show that the north polar zone at 45°N has continued to steadily brighten while the south polar zone at 45°S has continued to fade. As with our previous analyses we find that, assuming that the methane vertical profile is the same at all latitudes, the clouds forming these polar zones at 45°N and 45°S lie at slightly lower pressures than the clouds at more equatorial latitudes. However, we also find that the Gemini data can be reproduced by assuming that the main cloud remains fixed at ~2. bar at all latitudes and adjusting the relative humidity of methane instead. In this case we find that the deep cloud is still more opaque at the equator and at the zones at 45°N and 45°S and shows the same seasonal trends as when the methane humidity remain fixed. However, with this approach the relative humidity of methane is seen to rise sharply from approximately 20% at polar latitudes to values closer to 80% for latitudes equatorward of 45°S and 45°N, consistent with the analysis of 2002 HST observations by Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2009]. Icarus 202, 287-302), with a possible indication of seasonal variability. Overall, Uranus appeared to be less convectively active in 2010 than in the previous 4. years, supporting the conclusion that now the northern spring equinox (which occurred in 2007) has passed, the atmosphere is settling back into the more quiescent state seen by Voyager 2 in 1986. © 2011 Elsevier Inc.

The infrared limb spectra of the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) on board the Envisat satellite include detailed information on tropospheric clouds and polar stratospheric clouds (PSC). However, no consolidated cloud product is available for the scientific community. Here we describe a fast prototype processor for cloud parameter retrieval from MIPAS (MIPclouds). Retrieval of parameters such as cloud top height, temperature, and extinction are implemented, as well as retrieval of microphysical parameters, e.g. effective radius and the integrated quantities over the limb path (surface area density and volume density). MIPclouds classifies clouds as either liquid or ice cloud in the upper troposphere and polar stratospheric clouds types in the stratosphere based on statistical combinations of colour ratios and brightness temperature differences. Comparison of limb measurements of clouds with model results or cloud parameters from nadir looking instruments is often difficult due to different observation geometries. We therefore introduce a new concept, the limb-integrated surface area density path (ADP). By means of validation and radiative transfer calculations of realistic 2-D cloud fields as input for a blind test retrieval (BTR), we demonstrate that ADP is an extremely valuable parameter for future comparison with model data of ice water content, when applying limb integration (ray tracing) through the model fields. In addition, ADP is used for a more objective definition of detection thresholds of the applied detection methods. Based on BTR, a detection threshold of ADP = 107 μm2 cm−2 and an ice water content of 10−5 g m−3 is estimated, depending on the horizontal and vertical extent of the cloud. Intensive validation of the cloud detection methods shows that the limb-sounding MIPAS instrument has a sensitivity in detecting stratospheric and tropospheric clouds similar to that of space- and ground-based lidars, with a tendency for higher cloud top heights and consequently higher sensitivity for some of the MIPAS detection methods. For the high cloud amount (HCA, pressure levels below 440 hPa) on global scales the sensitivity of MIPAS is significantly greater than that of passive nadir viewers. This means that the high cloud fraction will be underestimated in the ISCCP dataset compared to the amount of high clouds deduced by MIPAS. Good correspondence in seasonal variability and geographical distribution of cloud occurrence and zonal means of cloud top height is found in a detailed comparison with a climatology for subvisible cirrus clouds from the Stratospheric Aerosol and Gas Experiment II (SAGE II) limb sounder. Overall, validation with various sensors shows the need to consider differences in sensitivity, and especially the viewing geometries and field-of-view size, to make the datasets comparable (e.g. applying integration along the limb path through nadir cloud fields). The simulation of the limb path integration will be an important issue for comparisons with cloud-resolving global circulation or chemical transport models.

International audience; New line data describing the absorption of CH4 and CH3D from 1.26 to 1.71 mum (Campargue, A., Wang, L., Mondelain, D., Kassi, S., Bézard, B., Lellouch, E., Coustenis, A., de Bergh, C., Hirtzig, M., Drossart, P. [2012]. Icarus 219, 110-128), building upon previous papers by Campargue et al. (Campargue, A., Wang, L., Kassi, S., Masat, M., Votava, O. [2010]. J. Quant. Spectrosc. Radiat. Transfer 111, 1141-1151; Wang, L., Kassi, S., Campargue, A. [2010]. J. Quant. Spectrosc. Radiat. Transfer 111, 1130-1140; Wang, L., Kassi, S., Liu, A.W., Hu, S.M., Campargue, A. [2011]. J. Quant. Spectrosc. Radiat. Transfer 112, 937-951)) have been applied to the analysis of Gemini-N/NIFS observations of Uranus made in 2010 and compared with earlier disc-averaged observations made by KPNO/FTS in 1982. The new line data are found to improve greatly the fit to the observed spectra and present a huge advance over previous methane absorption tables by allowing us to determine the CH3D/CH4 ratio and also start to break the degeneracy between methane abundance and cloud top height. The best fits are obtained if the cloud particles in the main cloud deck at the 2-3 bar level become less scattering with wavelength across the 1.4-1.6 mum region and we have modelled this variation here by varying the extinction cross-section and single-scattering albedo of the particles. Applying the new line data to the NIFS spectra of Uranus, we determine a new estimate of the CH3D/CH4 ratio of 2.9-0.5+0.9×10-4, which is consistent with the estimate of de Bergh et al. (de Bergh, C., Lutz, B.L., Owen, T., Brault, J., Chauville, J. [1986]. Astrophys. J. 311, 501-510) of 3.6-2.8+3.6×10-4, made by fitting a disc-averaged KPNO/FTS spectrum measured in 1982, but much better constrained. The NIFS observations made in 2010 have been disc-averaged and compared with the 1982 KPNO/FTS spectrum and found to be in excellent agreement. Using k-tables fitted to the new line data, the central meridian observations of Uranus' H-band spectrum (1.49-1.64 mum) made by Gemini-N/NIFS in 2010 have been reanalyzed. The use of the new methane absorption coefficients and the modified scattering properties of the cloud particles in the main cloud deck appears to break the degeneracy between cloud height and methane abundance immediately above it in this spectral region and we find that both vary with latitude across Uranus' disc. Overall, we find that the main cloud deck becomes higher, but thinner from equator to poles, with a local maximum in cloud top height in the circumpolar zones at 45°N and 45°S. At the same time, using the 'D' temperature pressure profile of Lindal et al. (Lindal, G.F., Lyons, J.R., Sweetnam, D.N., Eshleman, V.R., Hinson, D.P. [1987]. J. Geophys. Res. 92, 14987-15001) and a deep methane abundance of 1.6% (Baines, K.H., Mickelson, M.E., Larson, L.E., Ferguson, D.W. [1995]. Icarus 144, 328-340) we find that the relative humidity of methane is high near the equator (˜60%) and decreases sharply towards the poles, except near the circumpolar zone at 45°N, which has brightened steadily since 2007, and where there is a local maximum in methane relative humidity. In tests conducted with the warmer 'F1' profile of Sromovsky et al. (2011) we find a similar variation of methane abundance above the main cloud, although for this warmer temperature profile this abundance is dependent mostly on the fitted deep methane mole fraction.

The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) onboard ENVISAT has the potential to be particularly useful for studying high, thin clouds, which have been difficult to observe in the past. This paper details the development, implementation and testing of an optimal-estimation-type retrieval for three macrophysical cloud parameters (cloud top height, cloud top temperature and cloud extinction coefficient) from infrared spectra measured by MIPAS. A preliminary estimation of a parameterisation of the optical and geometrical filling of the measurement field-of-view by cloud is employed as the first step of the retrieval process to improve the choice of a priori for the macrophysical parameters themselves. Preliminary application to single-scattering simulations indicates that the retrieval error stemming from uncertainties introduced by noise and by a priori variances in the retrieval process itself is small – although it should be noted that these retrieval errors do not include the significant errors stemming from the assumption of homogeneity and the non-scattering nature of the forward model. Such errors are preliminarily and qualitatively assessed here, and are likely to be the dominant error sources. The retrieval converges for 99% of input cases, although sometimes fails to converge for vetically-thin (

The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) onboard ENVISAT has the potential to be particularly useful for studying high, thin clouds, which have been difficult to observe in the past. This paper details the development, implementation and testing of an optimal-estimation-type retrieval for three macrophysical cloud parameters (cloud top height, cloud top temperature and cloud extinction coefficient) from infrared spectra measured by MIPAS, employing additional information derived to improve the choice of a priori. The retrieval is applied and initially validated on MIPAS data. From application to MIPAS data, the retrieved cloud top heights are assessed to be accurate to within 50 m, the cloud top temperatures to within 0.5 K and extinction coefficients to within a factor of 15%. This algorithm has been adopted by the European Space Agency's ''MIPclouds'' project, which itself recognises the potential of MIPAS beyond monitoring atmospheric chemistry and seeks to study clouds themselves rigorously using MIPAS.

Clouds are increasingly recognised for their influence on the radiative balance of the Earth and the implications that they have on possible climate change, as well as in air pollution and acid-rain production. However, clouds remain a major source of uncertainty in climate models. Satellite-borne high-resolution limb sounders, such as the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) onboard ENVISAT, provide information on clouds, especially optically thin clouds, which have been difficult to observe in the past. The aim of this work is to develop, implement and test a reliable cloud detection method for infrared spectra measured by MIPAS. Current MIPAS cloud detection methods used operationally have been developed to detect thick cloud filling more than 30% of the measurement field-of-view (FOV). In order to resolve thin clouds, a new detection method using Singular Vector Decomposition (SVD) is formulated and tested. A rigorous comparison of the current operational and newly-developed detection methods for MIPAS is carried out – and the new SVD detection method has been proven to be much more reliable than the current operational method, and very sensitive even to thin clouds only marginally filling the MIPAS FOV.

Background: The dental health of the British Army has been reported as being in decline for the past 10 years, and this is having a significant impact on operations. One of the major factors in the decline is the increasing number of recruits who enlist with outstanding dental treatment needs. The current policy for provision of routine dental care to recruits targets resources toward those with the worst dental health and provides only emergency dental care for the remainder. Aims: The goal was to review recruit dental care provision, to determine whether improvements in the overall dental health of the trained Army could be made during recruit training. Results: It was found that >85% of recruit dental treatment need could be met with the routine provision of 2 hours of dental treatment during training. Conclusion: A horizontally equitable model of recruit dental care, whereby all recruits access routine dental care during training, has been recommended to and accepted by the chain of command.

In this paper, we study systems of two conservation laws with homogeneous quadratic flux functions. We use the viscous profile criterion for shock admissibility. This criterion leads to the occurrence of non-classical transitional shock waves, which are sensitively dependent on the form of the viscosity matrix. The goal of this paper is to lay a foundation for investigating how the structure of solutions of the Riemann problem is affected by the choice of viscosity matrix. Working in the framework of the fundamental wave manifold, we derive a necessary and sufficient condition on the model parameters for the presence of transitional shock waves. Using this condition, we are able to identify the regions in the wave manifold that correspond to transitional shock waves. Also, we determine the boundaries in the space of model parameters that separate models with differing numbers of transitional regions.

Following 10 weeks of fat supplementation a group of aerobically trained thoroughbred horses exhibited a significant decrease in postprandial plasma triacylglycerol concentration. This decrease was associated with a mean 50% increase in plasma total lipase activity following pentosan polysulfate administration and an increase in postprandial plasma cholesterol concentration. A significant increase in the activity of muscle citrate synthase (EC4.1.3.7), expressed as a ratio to the total fractional area occupied by type I and type IIa muscle fibres, was also observed. No significant change in the concentration of resting muscle glycogen or triacylglycerol occurred as a result of fat supplementation. These results suggest that there was improved management of the fat load and that the triacylglycerol-clearing capacity of the horses was increased as a result of fat supplementation. It is suggested that the increase in plasma total lipase activity following pentosan polysulfate administration may have reflected an increase in muscle lipoprotein lipase (EC3.1.1.34) activity, which would increase the capacity of muscle for free fatty acid uptake from circulating triacylglycerol-rich plasma lipoproteins. Fat supplementation may also enhance the oxidative capacity of muscle, as suggested by the significant increase in muscle citrate synthase and the trend towards an increase in β-hydroxyacyl CoA dehydrogenase (EC1.1.1.35) following 10 weeks of fat supplementation.

Inorganic lead ion, in micromolar concentrations, reversibly inhibits the sodium-plus-potassium-activated adenosinetriphosphatase (ATPase) and potassium-activated p-nitrophenylphosphatase (NPPase) activities of microsomal fractions from electric organ, rat kidney, and rat brain. In the presence of 3 mM MgCl2 and 3 mM ATP, the concentrations of PbCl2 producing half-maximal inhibition of the ATPase from these tissues are 4 × 10-6 M, 20 × 10-6 M, and 55 × 10-6 M, respectively. The corresponding values for inhibition of the NPPase are 10-6 M, 53 × 10-6 M, and 22 × 10-6 M. PbCl2 also stimulates the phosphorylation by [γ-32P]ATP of a microsomal protein from all three tissues in the absence of added sodium ion. This reaction -was extensively studied with electroplax microsomes. In common -with the well-known Na+-dependent phosphorylation of CNa+ + K+)-ATPase, the Fb2 -dependent reaction is inhibited by ouabain, specific for ATP, dependent on Mg2+, and yields an acid-stable phosphoprotein with a molecular weight of 98,000 in sodium dodecylsulfate. The Pb2+-dependent phosphoprotein, however, is not sensitive to K+. These observations are pertinent to the biochemistry and toxicity of inorganic lead in tissues and to the molecular mechanism of the cation transport enzyme.