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There is a vital need and constraint for providing water of good quality all around the world. Thus, with the aim of groundwater treatment, different methods of water treatment have been reviewed. Considering modern methods of membrane filtration, in this study efficiency of nanofiltration for removing heavy metals (copper and chromium) has been examined. The investigation has been accomplished in two separate phases for removing copper and chromium. To prepare the samples of groundwater, urban waters have been utilized and for preparation of chromium‐contaminated and copper‐contaminated waters, powder of chromium‐oxide and powder of copper sulfate pentahydrate have been added into samples, respectively. In this research, system‐operating pressure has been changed, while concentration and pH were kept constant. The effect of pressure on the efficiency of heavy metals removal has been checked and optimum pressure of the process has been achieved. Then, with optimal pressure as system operating pressure, the removal of heavy metals in different pH have been checked and accordingly, the optimal pH for the process was obtained. The Optimum Pressure and pH for chromium and copper are 7.5 bars and 6.3, and 7.5 bars and 6.7, respectively. Taking into account the result of this study, Nano filtration is a suitable method with high efficiency (90% and higher in optimum pressure and pH) for the removal of heavy metals from groundwater. [ABSTRACT FROM AUTHOR]