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Glass is a familiar material that requires abundant mineral sources, with devastating consequences for the environment. Rice husk ash (RHA) presents a very high silica content (&gt, 95%) and it can be a very promising alternative source for silica in silica-based glass. However, impurities like manganese and iron, which depend on the rice harvest, might limit RHA use, particularly in the production of optical transparent glasses. In this work, we discussed how Mn and Fe can affect the coloring of the produced glass, and how the effect of these impurities can be removed. First, the RHA was treated with acid solutions, leading to the production of a soda-lime glass with similar transparency to commercial glass (&gt, 70%). Secondly, another simpler approach was studied: a small amount of antimony oxide was added in the composition of the glass, obtaining a transparent glass (&gt, 80%, same thickness) with RHA.

Single-drop microextraction (SDME) was coupled with surface-enhanced Raman scattering (SERS) to provide sample extraction and pre-concentration for detection of analyte at low concentrations. A gold nanohole array substrate (AuNHAS), fabricated by interference lithography, was used as SERS substrate and para-mercaptobenzoic acid (p-MBA) was tested as a probe molecule, in the concentration range 10−8−10−4 mol L−1. With this approach, a limit of 10−7 mol L−1 was clearly detected. To improve the detection to lower p-MBA concentration, as 10−8 mol L−1, the SDME technique was applied. The p-MBA Raman signature was detected in two performed extractions and its new concentration was determined to be ~4.6 × 10−5 mol L−1. This work showed that coupling SDME with SERS allowed a rapid (5 min) and efficient pre-concentration (from 10−8 mol L−1 to 10−5 mol L−1), detection, and quantification of the analyte of interest, proving to be an interesting analytical tool for SERS applications.