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Neutron-capture elements, those with Z > 35, are the least well-understood in terms of nucleosynthesis and formation environments. The rapid neutron-capture, or r-process, elements are formed in the environments and/or remnants of massive stars, while the slow neutron-capture, or s-process, elements are primarily formed in low-mass AGB stars. These elements can provide much information about Galactic star formation and enrichment, but observational data is limited. We have assembled a sample of 68 stars in 23 open clusters that we use to probe abundance trends for six neutron-capture elements (Eu, Gd, Dy, Mo, Pr, and Nd) with cluster age and location in the disk of the Galaxy. In order to keep our analysis as homogenous as possible, we use an automated synthesis fitting program, which also enables us to measure multiple (3-10) lines for each element. We find that the pure r-process elements (Eu, Gd, and Dy) have positive trends with increasing cluster age, while the mixed r- and s- process elements (Mo, Pr, and Nd) have insignificant trends consistent with zero. Pr, Nd, Eu, Gd, and Dy have similar, slight (though mostly statistically significant) gradients of ~0.04 dex/kpc. The mixed elements also appear to have nonlinear relationships with Galactocentric radius., Comment: 28 pages, 12 figures, 11 tables including two MRT. Accepted for publication in the Astrophysical Journal

We report the discovery of one extremely metal-poor (EMP; [Fe/H]<-3) and one ultra metal-poor (UMP; [Fe/H]<-4) star selected from the SDSS/SEGUE survey. These stars were identified as EMP candidates based on their medium-resolution (R~2,000) spectra, and were followed-up with high-resolution (R~35,000) spectroscopy with the Magellan-Clay Telescope. Their derived chemical abundances exhibit good agreement with those of stars with similar metallicities. We also provide new insights on the formation of the UMP stars, based on comparison with a new set of theoretical models of supernovae nucleosynthesis. The models were matched with 20 UMP stars found in the literature, together with one of the program stars (SDSS J1204+1201), with [Fe/H]=-4.34. From fitting their abundances, we find that the supernovae progenitors, for stars where carbon and nitrogen are measured, had masses ranging from 20.5 M_sun to 28 M_sun and explosion energies from 0.3 to 0.9x10^51 erg. These results are highly sensitive to the carbon and nitrogen abundance determinations, which is one of the main drivers for future high-resolution follow-up of UMP candidates. In addition, we are able to reproduce the different CNO abundance patterns found in UMP stars with a single progenitor type, by varying its mass and explosion energy., Comment: 15 pages, 12 figures; accepted for publication in ApJ

With [Fe/H] ~ -3.3, CD -24_17504 is a canonical metal-poor main sequence turn-off star. Though it has appeared in numerous literature studies, the most comprehensive abundance analysis for the star based on high resolution, high signal-to-noise spectra is nearly 15 years old. We present a new detailed abundance analysis for 21 elements based on combined archival Keck-HIRES and VLT-UVES spectra of the star that is higher in both spectral resolution and signal-to-noise than previous data. Our results for many elements are very similar to those of an earlier comprehensive study of the star, but we present for the first time a carbon abundance from the CH G-band feature as well as improved upper limits for neutron-capture species such as Y, Ba and Eu. In particular, we find that CD -24_17504 has [Fe/H] = -3.41, [C/Fe] = +1.10, [Sr/H] = -4.68 and [Ba/H] <= -4.46, making it a carbon enhanced metal-poor star with neutron-capture element abundances among the lowest measured in Milky Way halo stars., Comment: Accepted to ApJ. 24 pages, 13 figures, 7 tables

We present a Magellan/MIKE high-resolution (R ~ 35,000) spectrum of the ancient star SD 1313-0019 which has an iron abundance of [Fe/H] = -5.0, paired with a carbon enhancement of [C/Fe] ~ 3.0. The star was initially identified by Allende Prieto et al. in the BOSS survey. Its medium-resolution spectrum suggested a higher metallicity of [Fe/H] = -4.3 due to the CaII K line blending with a CH feature which is a common issue related to the search for the most iron-poor stars. This star joins several other, similar stars with [Fe/H] < -5.0 that all display a combination of low iron and high carbon abundances. Other elemental abundances of SD 1313-0019 follow that of more metal-rich halo stars. From fitting the abundance pattern with yields of Population III supernova, we conclude that SD 1313-0019 had only one massive progenitor star with 20 - 30 M_sun that must have undergone a mixing and fallback episode. Overall, there are now five stars known with [Fe/H] < -5.0 (1D LTE abundances). This population of second-generation stars strongly suggests massive first stars that almost exclusively produced large amounts of carbon through stellar winds and/or their mixing and fallback supernova explosions. As a consequence, their natal clouds -- presumably some early minihalo structures -- contained ample amounts of carbon and oxygen that likely facilitated the formation of these first low-mass stars., Comment: 7 pages and 3 figures, accepted by ApJL

The SkyMapper Southern Sky Survey is carrying out a search for the most metal-poor stars in the Galaxy. It identifies candidates by way of its unique filter set that allows for estimation of stellar atmospheric parameters. The set includes a narrow filter centered on the Ca II K 3933A line, enabling a robust estimate of stellar metallicity. Promising candidates are then confirmed with spectroscopy. We present the analysis of Magellan-MIKE high-resolution spectroscopy of 122 metal-poor stars found by SkyMapper in the first two years of commissioning observations. 41 stars have [Fe/H] <= -3.0. Nine have [Fe/H] <= -3.5, with three at [Fe/H] ~ -4. A 1D LTE abundance analysis of the elements Li, C, Na, Mg, Al, Si, Ca, Sc, Ti, Cr, Mn, Co, Ni, Zn, Sr, Ba and Eu shows these stars have [X/Fe] ratios typical of other halo stars. One star with low [X/Fe] values appears to be "Fe-enhanced," while another star has an extremely large [Sr/Ba] ratio: >2. Only one other star is known to have a comparable value. Seven stars are "CEMP-no" stars ([C/Fe] > 0.7, [Ba/Fe] < 0). 21 stars exhibit mild r-process element enhancements (0.3 <=[Eu/Fe] < 1.0), while four stars have [Eu/Fe] >= 1.0. These results demonstrate the ability to identify extremely metal-poor stars from SkyMapper photometry, pointing to increased sample sizes and a better characterization of the metal-poor tail of the halo metallicity distribution function in the future., Comment: Minor corrections to text, missing data added to Tables 3 and 4; updated to match published version. Complete tables included in source

We have obtained high-resolution spectra of 32 giants in the open cluster NGC 7789 using the Wisconsin-Indiana-Yale-NOAO Hydra spectrograph. We explore differences in atmospheric parameters and elemental abundances caused by the use of the linelist developed for the Gaia-ESO Survey (GES) compared to one based on Arcturus used in our previous work. [Fe/H] values decrease when using the GES linelist instead of the Arcturus-based linelist; these differences are probably driven by systematically lower (~ -0.1 dex) GES surface gravities. Using the GES linelist we determine abundances for 10 elements - Fe, Mg, Si, Ca, Ti, Na, Ni, Zr, Ba, and La. We find the cluster's average metallicity [Fe/H] = 0.03 +/- 0.07 dex, in good agreement with literature values, and a lower [Mg/Fe] abundance than has been reported before for this cluster (0.11 +/- 0.05 dex). We also find the neutron-capture element barium to be highly enhanced - [Ba/Fe] = +0.48 +/- 0.08 - and disparate from cluster measurements of neutron-capture elements La and Zr (-0.08 +/- 0.05 and 0.08 +/- 0.08, respectively). This is in accordance with recent discoveries of supersolar Ba enhancement in young clusters along with more modest enhancement of other neutron-capture elements formed in similar environments., Comment: 15 pages, 9 figures, Table 1 typo fixed

We present a homogeneous chemical abundance analysis of five of the most metal-poor stars in the Sculptor dwarf spheroidal galaxy. We analyze new and archival high resolution spectroscopy from Magellan/MIKE and VLT/UVES and determine stellar parameters and abundances in a consistent way for each star. Two of the stars in our sample, at [Fe/H] = -3.5 and [Fe/H] = -3.8, are new discoveries from our Ca K survey of Sculptor, while the other three were known in the literature. We confirm that Scl 07-50 is the lowest metallicity star identified in an external galaxy, at [Fe/H] = -4.1. The two most metal-poor stars both have very unusual abundance patterns, with striking deficiencies of the alpha elements, while the other three stars resemble typical extremely metal-poor Milky Way halo stars. We show that the star-to-star scatter for several elements in Sculptor is larger than that for halo stars in the same metallicity range. This scatter and the uncommon abundance patterns of the lowest metallicity stars indicate that the oldest surviving Sculptor stars were enriched by a small number of earlier supernovae, perhaps weighted toward high-mass progenitors from the first generation of stars the galaxy formed., Comment: 11 pages, 2 figures, 4 tables (2 landscape tables are at the end; for full tables, contact first author or wait for published version). Accepted for publication in ApJ

Phosphorus is one of the few remaining light elements for which little is known about its nucleosynthetic origin and chemical evolution, given the lack of optical absorption lines in the spectra of long-lived FGK-type stars. We have identified a P I doublet in the near-ultraviolet (2135/2136 A) that is measurable in stars of low metallicity. Using archival Hubble Space Telescope-STIS spectra, we have measured P abundances in 13 stars spanning -3.3 <= [Fe/H] <= -0.2, and obtained an upper limit for a star with [Fe/H] ~ -3.8. Combined with the only other sample of P abundances in solar-type stars in the literature, which spans a range of -1 <= [Fe/H] <= +0.2, we compare the stellar data to chemical evolution models. Our results support previous indications that massive-star P yields may need to be increased by a factor of a few to match stellar data at all metallicities. Our results also show that hypernovae were important contributors to the P production in the early universe. As P is one of the key building blocks of life, we also discuss the chemical evolution of the important elements to life, C-N-O-P-S, together., Comment: Accepted for publication in Astrophysical Journal Letters. 6 pages, 4 figures; reference added to earlier version

We report the detection of several absorption lines of neutral phosphorus (P, Z=15) in archival near ultraviolet spectra obtained with the Space Telescope Imaging Spectrograph on board the Hubble Space Telescope. We derive phosphorus abundances or interesting upper limits in 14 late-type stars with metallicities spanning -3.8<[Fe/H]<-0.1. Previously, phosphorus had only been studied in Galactic stars with -1.0<[Fe/H]<+0.3. Iron lines reveal abundance offsets between the optical and ultraviolet regions, and we discuss and apply a correction factor to account for this offset. In stars with [Fe/H]>-1.0, the [P/Fe] ratio decreases toward the solar value with increasing metallicity, in agreement with previous observational studies. In stars with [Fe/H]<-1.0, <[P/Fe]>=+0.04+/-0.10, which overlaps with the [P/Fe] ratios found in several high-redshift damped Lyman-alpha systems. This behavior hints at a primary origin in massive stars., Comment: Accepted for publication in the Astrophysical Journal. 13 pages, 4 figures

Large spectroscopic surveys such as the Gaia-ESO Survey produce huge quantities of data. Automatic tools are necessary to efficiently handle this material. The measurement of equivalent widths in stellar spectra is traditionally done by hand or with semi-automatic procedures that are time-consuming and not very robust with respect to the repeatability of the results. The program DAOSPEC is a tool that provides consistent measurements of equivalent widths in stellar spectra while requiring a minimum of user intervention. However, it is not optimised to deal with large batches of spectra, as some parameters still need to be modified and checked by the user. Exploiting the versatility and portability of BASH, we have built a pipeline called DAOSPEC Option Optimiser (DOOp) automating the procedure of equivalent widths measurement with DAOSPEC. DOOp is organised in different modules that run one after the other to perform specific tasks, taking care of the optimisation of the parameters needed to provide the final equivalent widths, and providing log files to ensure better control over the procedure. In this paper, making use of synthetic and observed spectra, we compare the performance of DOOp with other methods, including DAOSPEC used manually. The measurements made by DOOp are identical to the ones produced by DAOSPEC when used manually, while requiring less user intervention, which is convenient when dealing with a large quantity of spectra. DOOp shows its best performance on high-resolution spectra (R>20 000) and high signal-to-noise ratio (S/N>30), with uncertainties ranging from 6 m{\AA} to 2 m{\AA}. The only subjective parameter that remains is the normalisation, as the user still has to make a choice on the order of the polynomial used for the continuum fitting. As a test, we use the equivalent widths measured by DOOp to re-derive the stellar parameters of four well-studied stars.

We present a detailed analysis of high-resolution, high S/N spectra for 5 Aquarius stream stars observed with the MIKE spectrograph on the Magellan Clay telescope. Our sample represents one third of the 15 known members in the stream. We find the stream is not mono-metallic: the metallicity ranges from [Fe/H] = -0.63 to -1.58. No anti-correlation in Na-O abundances is present, and we find a strong positive Mg-Al relationship, similar to that observed in the thick disk. We find no evidence that the stream is a result of a disrupted classical globular cluster, contrary to a previously published claim. High [(Na, Ni, alpha)/Fe] and low [Ba/Y] abundance ratios in the stream suggests it is not a tidal tail from a disrupted dwarf galaxy, either. The stream is chemically indistinguishable from Milky Way field stars with the exception of one candidate, C222531-145437. From its position, velocity, and detailed chemical abundances, C222531-145437 is likely a star that was tidally disrupted from omega-Centauri. We propose the Aquarius stream is Galactic in origin, and could be the result from a disk-satellite perturbation in the Milky Way thick disk on the order of a few Gyr ago: derived orbits, UVW velocities, and angular momenta of the Aquarius members offer qualitative support for our hypothesis. Assuming C222531-145437 is a tidally disrupted member of omega-Centauri, this system is the most likely disk perturber. In the absence of compelling chemical and/or dynamical evidence that the Aquarius stream is the tidal tail of a disrupted satellite, we advocate the "Aquarius group" as a more appropriate description. Like the Canis Major over-density, as well as the Hercules and Monoceros groups, the Aquarius group joins the list of kinematically-identified substructures that are not actually accreted material: they are simply part of the rich complexity of the Milky Way structure., Comment: Accepted to MNRAS. Updated to journal version

The chemical abundances of metal-poor stars provide a great deal of information regarding the individual nucleosynthetic processes that created the observed elements and the overall process of chemical enrichment of the galaxy since the formation of the first stars. Here we review the abundance patterns of the neutron-capture elements (Z > 38) in those metal-poor stars and our current understanding of the conditions and sites of their production at early times. We also review the relative contributions of these different processes to the build-up of these elements within the galaxy over time, and outline outstanding questions and uncertainties that complicate the interpretation of the abundance patterns observed in metal-poor stars. It is anticipated that future observations of large samples of metal-poor stars will help discriminate between different proposed neutron-capture element production sites and better trace the chemical evolution of the galaxy., Comment: 21 pages, 7 figures, accepted to Journal of Physics G (to appear in Focus issue "Nucleosynthesis and the role of neutrinos", ed. Baha Balantekin and Cristina Volpe)

It is well established that stellar effective temperatures determined from photometry and spectroscopy yield systematically different results. We describe a new, simple method to correct spectroscopically derived temperatures ("excitation temperatures") of metal-poor stars based on a literature sample with -3.3<[Fe/H]<-2.5. Excitation temperatures were determined from FeI line abundances in high-resolution optical spectra in the wavelength range of ~3700 to ~7000A, although shorter wavelength ranges, up to 4750 to 6800A, can also be employed, and compared with photometric literature temperatures. Our adjustment scheme increases the temperatures up to several hundred degrees for cool red giants, while leaving the near-main-sequence stars mostly unchanged. Hence, it brings the excitation temperatures in good agreement with photometrically derived values. The modified temperature also influences other stellar parameters, as the FeI-FeII ionization balance is simultaneously used to determine the surface gravity, while also forcing no abundance trend on the absorption line strengths to obtain the microturbulent velocity. As a result of increasing the temperature, the often too low gravities and too high microturbulent velocities in red giants become higher and lower, respectively. Our adjustment scheme thus continues to build on the advantage of deriving temperatures from spectroscopy alone, independent of reddening, while at the same time producing stellar chemical abundances that are more straightforwardly comparable to studies based on photometrically derived temperatures. Hence, our method may prove beneficial for comparing different studies in the literature as well as the many high-resolution stellar spectroscopic surveys that are or will be carried out in the next few years., Comment: 12 pages, emulateapj, accepted for publication in ApJ

We present an online catalog of distance determinations for $\rm 6036$ K giants, most of which are members of the Milky Way's stellar halo. Their medium-resolution spectra from SDSS/SEGUE are used to derive metallicities and rough gravity estimates, along with radial velocities. Distance moduli are derived from a comparison of each star's apparent magnitude with the absolute magnitude of empirically calibrated color-luminosity fiducials, at the observed $(g-r)_0$ color and spectroscopic [Fe/H]. We employ a probabilistic approach that makes it straightforward to properly propagate the errors in metallicities, magnitudes, and colors into distance uncertainties. We also fold in ${\it prior}$ information about the giant-branch luminosity function and the different metallicity distributions of the SEGUE K-giant targeting sub-categories. We show that the metallicity prior plays a small role in the distance estimates, but that neglecting the luminosity prior could lead to a systematic distance modulus bias of up to 0.25 mag, compared to the case of using the luminosity prior. We find a median distance precision of $16\%$, with distance estimates most precise for the least metal-poor stars near the tip of the red-giant branch. The precision and accuracy of our distance estimates are validated with observations of globular and open clusters. The stars in our catalog are up to 125 kpc distant from the Galactic center, with 283 stars beyond 50 kpc, forming the largest available spectroscopic sample of distant tracers in the Galactic halo., Comment: accepted by APJ

The Sloan Digital Sky Survey III (SDSS-III) presents the first spectroscopic data from the Baryon Oscillation Spectroscopic Survey (BOSS). This ninth data release (DR9) of the SDSS project includes 535,995 new galaxy spectra (median z=0.52), 102,100 new quasar spectra (median z=2.32), and 90,897 new stellar spectra, along with the data presented in previous data releases. These spectra were obtained with the new BOSS spectrograph and were taken between 2009 December and 2011 July. In addition, the stellar parameters pipeline, which determines radial velocities, surface temperatures, surface gravities, and metallicities of stars, has been updated and refined with improvements in temperature estimates for stars with T_eff<5000 K and in metallicity estimates for stars with [Fe/H]>-0.5. DR9 includes new stellar parameters for all stars presented in DR8, including stars from SDSS-I and II, as well as those observed as part of the SDSS-III Sloan Extension for Galactic Understanding and Exploration-2 (SEGUE-2). The astrometry error introduced in the DR8 imaging catalogs has been corrected in the DR9 data products. The next data release for SDSS-III will be in Summer 2013, which will present the first data from the Apache Point Observatory Galactic Evolution Experiment (APOGEE) along with another year of data from BOSS, followed by the final SDSS-III data release in December 2014., Comment: 9 figures; 2 tables. Submitted to ApJS. DR9 is available at http://www.sdss3.org/dr9

Fifty-one dense cores associated with water masers were mapped at 350 micron. These cores are very luminous, 10^3 < Lbol/Lsun < 10^6, indicative of the formation of massive stars. Dust continuum contour maps and photometry are presented for these sources. The spectral energy distributions and normalized radial profiles of dust continuum emission were modeled for 31 sources using a one-dimensional dust radiative transfer code, assuming a power law density distribution in the envelope, n = n_f (r/r_f)^{-p}. The best fit density power law exponent, p, ranged from 0.75 to 2.5 with = 1.8 +/- 0.4. The mean value of p is comparable to that found in regions forming only low mass stars. The mean p is incompatible with a logatropic sphere (p = 1), but other star formation models cannot be ruled out. Different mass estimates are compared and mean masses of gas and dust are reported within a half-power radius determined from the dust emission and within a radius where the total density exceeds 10^4 cm^3. Evolutionary indicators commonly used for low mass star formation may have some utility for regions forming massive stars. For comparison with extragalactic star formation studies, the luminosity to dust mass ratio is calculated for these sources with a method most parallel to that used in studies of distant galaxies and is found to be similar to that seen in high redshift starburst galaxies., Comment: 45 pages, 20 figures, accepted to ApJ Supplement

We have observed 51 high mass star forming cores associated with water masers at 350 micron. The spectral energy distributions (SEDs) and dust continuum normalized radial intensity profiles were modeled for 28 sources using a one-dimensional dust radiative transfer code assuming a power law density distribution in the envelope n = n_0 (r/r_0)^{-p}. The best fit density power law exponent, p, ranged from 1.0 to 2.5 with a mean value of p = 1.72. We determined the dust masses for the modeled cores and found a mean mass of 209 M_{sun}., Comment: 2 pages to appear in Hot Star Workshop III: The Earliest Phases of Massive Star Birth, ASP Conference Series, 2002, ed. P.A. Crowther