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Ever since they were first detected in the interstellar medium, the radio wavelength (3.3 GHz) hyperfine-structure splitting transitions in the rotational ground state of CH have been observed to show anomalous excitation. Astonishingly, this behaviour has been uniformly observed towards a variety of different sources probing a wide range of physical conditions. While the observed level inversion can be explained globally by a pumping scheme involving collisions, a description of the extent of 'over-excitation' observed in individual sources requires the inclusion of radiative processes, involving transitions at higher rotational levels. Therefore, a complete description of the excitation mechanism in the CH ground state, observed towards individual sources entails observational constraints from the rotationally excited levels of CH and in particular that of its first rotationally excited state. Given the limited detections of these lines, the objective of this work is to characterise the physical and excitation properties of the rotationally excited lines of CH near 700 MHz, and investigate their influence on the pumping mechanisms of the ground-state lines of CH. This work presents the first interferometric search for the rotationally excited lines of CH near 700 MHz carried out using the uGMRT array and jointly models the physical and excitation conditions traced by lines from both the ground and first rotationally excited states of CH., Comment: Accepted for publication in A&A 18 Pages + Appendix, 22 Figures, 4 Tables

CF$^{+}$ has been established as a valuable diagnostic tool for investigating photo-dissociation regions (PDRs) and fluorine abundances in the Milky Way. However, its role in extragalactic environments remains largely uncharted. Our objective is to explore the significance of CF$^{+}$ in the Large Magellanic Cloud (LMC) and assess its utility as a valuable probe for examining C$^{+}$ and fluorine abundances in external galaxies. We performed pointed CF$^{+}$ observations toward an active star-forming region, N113 in the LMC, using the Atacama Pathfinder EXperiment 12~m sub-millimeter telescope. We report the first discovery of CF$^{+}$ in the LMC through the successful detection of the CF$^{+}$ (2$\to$1) and (3$\to$2) lines. The excitation models indicate that CF$^{+}$ emission originates from dense PDRs characterized by an H$_{2}$ number density of $(0.5-7.9)\times 10^{4}$~cm$^{-3}$ in N113. Our observations provide the first constraint on the fluorine abundance in molecular clouds in the LMC, disclosing a value of $\lesssim 1.7\times 10^{-9}$. This value is about an order of magnitude lower than those previously measured toward red giants in the LMC, indicative of fluorine deficiency in the molecular gas. The estimated column density ratio between C$^{+}$ and CF$^{+}$ appears to be lower than the anticipated equilibrium ratio derived from the fluorine abundance in red giants. Both phenomena can be explained by the deficiency of CF$^{+}$ caused by the freeze-out of its primary chemical precursor, HF, onto dust grains. The deficiency of CF$^{+}$ within molecular clouds suggests that the measurements presented in this work serve exclusively as conservative estimates, establishing lower bounds for both the fluorine abundance and C$^{+}$ column densities in external galaxies., Comment: 9 pages, 6 figures, 1 table, accepted for publication in A&A

While the abundance of elemental deuterium is relatively low (D/H ~ a few 1E-5), orders of magnitude higher D/H abundance ratios have been found for many interstellar molecules, enhanced by deuterium fractionation. In cold molecular clouds (T < 20K) deuterium fractionation is driven by the H2D+ ion, whereas at higher temperatures (T > 20-30K) gas-phase deuteration is controlled by reactions with CH2D+ and C2HD+. While the role of H2D+ in driving cold interstellar deuterium chemistry is well understood, thanks to observational constraints from direct measurements of H2D+, deuteration stemming from CH2D+ is far less understood, caused by the absence of direct observational constraints of its key ions. Therefore, making use of chemical surrogates is imperative for exploring deuterium chemistry at intermediate temperatures. Formed at an early stage of ion-molecule chemistry, directly from the dissociative recombination of CH3+ (CH2D+), CH (CD) is an ideal tracer for investigating deuterium substitution initiated by reactions with CH2D+. This paper reports the first detection of CD in the interstellar medium, carried out using the APEX 12m telescope toward the widely studied low-mass protostellar system IRAS 16293-2422. Gas-phase chemical models reproducing the observed CD/CH abundance ratio of 0.016 suggests that it reflects `warm deuterium chemistry' (which ensues in moderately warm conditions of the interstellar medium) and illustrates the potential use of the CD/CH ratio in constraining the gas temperatures of the envelope gas clouds it probes., Comment: Accepted for publication in Astronomy & Astrophysics (14 pages, 11 figures and 7 tables including Appendix)

Along several sight lines within the Milky Way ArH+ has been ubiquitously detected with only one detection in extragalactic environments, namely along two sight lines in the red shift z=0.89 absorber towards the lensed blazar PKS 1830-211. Being formed in predominantly atomic gas by reactions between Ar+, which were initially ionised by cosmic rays and molecular hydrogen, ArH+ has been shown to be an excellent tracer of atomic gas as well as the impinging cosmic-ray ionisation rates. In this work, we attempt to extend the observations of ArH+in extragalactic sources to examine its use as a tracer of the atomic interstellar medium (ISM) in these galaxies. We report the detection of ArH+ towards two luminous nearby galaxies, NGC 253 and NGC 4945, and the non-detection towards Arp 220 observed using the SEPIA660 receiver on the APEX 12 m telescope. In addition, the two sidebands of this receiver allowed us to observe the NKaKc=1_1,0-1_0,1 transitions of another atomic gas tracer p-H2O+ at 607.227 GHz with the ArH+ line, simultaneously. We modelled the optically thin spectra of both species and compared their observed line profiles with that of other well-known atomic gas tracers such as OH+ and o-H2O+ and diffuse and dense molecular gas tracers HF and CO, respectively. By further assuming that the observed absorption from the ArH+, OH+, and H2O+ molecules are affected by the same flux of cosmic rays, we investigate the properties of the different cloud layers based on a steady-state analysis of the chemistry of these three species., Comment: Accepted for publication in Astronomy and Astrophysics 16 pages, 11 figures, 3 tables

The intensities of the three widely observed radio-wavelength hyperfine structure (HFS) lines between the {\Lambda}-doublet components of the rotational ground state of CH are inconsistent with LTE and indicate ubiquitous population inversion. While this can be qualitatively understood assuming a pumping cycle that involves collisional excitation processes, the relative intensities of the lines and in particular the dominance of the lowest frequency satellite line has not been well understood. This has limited the use of CH radio emission as a tracer of the molecular interstellar medium. We present the first interferometric observations, with the Karl G. Jansky Very Large Array, of the CH 9 cm ground state HFS transitions at 3.264 GHz, 3.335 GHz, and 3.349 GHz toward four high mass star-forming regions (SFRs) Sgr B2 (M), G34.26+0.15, W49 (N), and W51. We investigate the nature of the (generally) weak CH ground state masers by employing synergies between the ground state HFS transitions themselves and with the far-infrared lines, near 149 {\mu}m (2 THz), that connect these levels to an also HFS split rotationally excited level. Employing recently calculated collisional rate coefficients, we perform statistical equilibrium calculations with the non-LTE radiative transfer code MOLPOP-CEP in order to model the excitation conditions traced by the ground state HFS lines of CH and to infer the physical conditions in the emitting regions while also accounting for the effects of far-infrared line overlap., Comment: Accepted for publication in A&A 18 pages, 15 figures and 4 tables

Measuring interstellar magnetic fields is extremely important for understanding their role in different evolutionary stages of interstellar clouds and of star formation. However, detecting the weak field is observationally challenging. We present measurements of the Zeeman effect in the 1665 and 1667~MHz (18~cm) lines of the hydroxyl radical (OH) lines toward the dense photodissociation region (PDR) associated with the compact H{\sc ii} region DR~21~(Main). From the OH 18~cm absorption, observed with the Karl G. Jansky Very Large Array, we find that the line of sight magnetic field in this region is $\sim 0.13$~mG. The same transitions in maser emission toward the neighboring DR~21(OH) and W~75S-FR1 regions also exhibit the Zeeman splitting. Along with the OH data, we use [C{\sc ii}] 158 $\mu$m line and hydrogen radio recombination line data to constrain the physical conditions and the kinematics of the region. We find the OH column density to be $\sim 3.6\times10^{16}(T_{\rm ex}/25~{\rm K})~{\rm cm}^{-2}$, and that the 1665 and 1667 MHz absorption lines are originating from the gas where OH and C$^+$ are co-existing in the PDR. Under reasonable assumptions, we find the measured magnetic field strength for the PDR to be lower than the value expected from the commonly discussed density--magnetic field relation while the field strength values estimated from the maser emission are roughly consistent with the same. Finally, we compare the magnetic field energy density with the overall energetics of DR~21's PDR and find that, in its current evolutionary stage, the magnetic field is not dynamically important., Comment: 13 pages with 14 figures and 3 tables; version accepted for publication in MNRAS

One of the surprises of the Herschel mission was the detection of ArH+ towards the Crab Nebula in emission and in absorption towards strong Galactic background sources. Although these detections were limited to the first quadrant of the Galaxy, the existing data suggest that ArH+ ubiquitously and exclusively probes the diffuse atomic regions of the ISM. In this study, we extend the coverage of ArH+ to other parts of the Galaxy with new observations of its J = 1-0 transition along seven Galactic sight lines towards bright sub-mm continuum sources. We aim to benchmark its efficiency as a tracer of purely atomic gas by evaluating its correlation (or lack there of) with other well-known atomic and molecular gas tracers. The observations of ArH+ near 617.5 GHz were made feasible with the new, sensitive SEPIA660 receiver on the APEX 12 m telescope. The two sidebands of this receiver allowed us to observe p-H2O+ transitions of at 607.227 GHz simultaneously with the ArH+ line. By analysing the steady state chemistry of OH+ and o-H2O+, we derive on average a cosmic-ray ionisation rate (CRIR), of 2.3e-16 s^-1 towards the sight lines studied in this work. Using the derived values of the CRIR and the observed ArH+ abundances we constrain the molecular fraction of the gas traced by ArH+ to lie below 2e-2 with a median value of 8.8e-4. Combined, our observations of ArH+, OH+, H2O+, and CH probe different regimes of the ISM, from diffuse atomic to diffuse and translucent molecular clouds. Over Galactic scales, we see that the distribution of N(ArH+) is associated with that of N(H), particularly in the inner Galaxy with potentially even contributions from the warm neutral medium phase of atomic gas at larger galactocentric distances. We derive an average o/p-ratio for H2O+ of 2.1, which corresponds to a nuclear spin temperature of 41 K, consistent with the typical gas temperatures of diffuse clouds., Comment: Accepted for publication in Astronomy & Astrophysics (24 pages, 30 figures)

In recent years, a plethora of high spectral resolution observations of sub-mm and FIR transitions of methylidene (CH), have demonstrated this radical to be a valuable proxy for H2, that can be used for characterising molecular gas within the interstellar medium (ISM) on a Galactic scale, including the CO-dark component. Here we report the discovery of the 13CH isotopologue in the ISM using the upGREAT receiver on board SOFIA. We have detected the three hyperfine structure components of the 2THz frequency transition from its ground-state toward four high-mass star-forming regions and determine 13CH column densities. The ubiquity of molecules containing carbon in the ISM has turned the determination of the ratio between the abundances of carbon's two stable isotopes, 12C/13C, into a cornerstone for Galactic chemical evolution studies. Whilst displaying a rising gradient with Galactocentric distance, this ratio, when measured using observations of different molecules (CO, H2CO, and others) shows systematic variations depending on the tracer used. These observed inconsistencies may arise from optical depth effects, chemical fractionation or isotope-selective photo-dissociation. Formed from C+ either via UV-driven or turbulence-driven chemistry, CH reflects the fractionation of C+, and does not show any significant fractionation effects unlike other molecules previously used to determine the 12C/13C isotopic ratio which make it an ideal tracer for the 12C/13C ratio throughout the Galaxy. Therefore, by comparing the derived column densities of 13CH with previously obtained SOFIA data of the corresponding transitions of the main isotopologue 12CH, we derive 12C/13C isotopic ratios toward Sgr B2(M), G34.26+0.15, W49(N) and W51E. Adding our values derived from 12/13CH to previous calculations of the Galactic isotopic gradient we derive a revised value of 12C/13C = 5.85(0.50)R_GC + 15.03(3.40).

In this paper, we investigate the influence of hyperfine splitting on complex spectral lines, with the aim of evaluating canonical abundances by decomposing their dependence on hyperfine structures. This is achieved from first principles through deconvolution. We present high spectral resolution observations of the rotational ground state transitions of CH near 2 THz seen in absorption toward the strong FIR-continuum sources AGAL010.62$-$00.384, AGAL034.258+00.154, AGAL327.293$-$00.579, AGAL330.954$-$00.182, AGAL332.826$-$00.549, AGAL351.581$-$00.352 and SgrB2(M). These were observed with the GREAT instrument on board SOFIA. The observed line profiles of CH were deconvolved from the imprint left by the lines' hyperfine structures using the Wiener filter deconvolution, an optimised kernel acting on direct deconvolution. The quantitative analysis of the deconvolved spectra first entails the computation of CH column densities. Reliable N(CH) values are of importance owing to the status of CH as a powerful tracer for H$_2$ in the diffuse regions of the interstellar medium. The N(OH)/N(CH) column density ratio is found to vary within an order of magnitude with values ranging from one to 10, for the individual sources that are located outside the Galactic centre. Using CH as a surrogate for H$_2$, we determined the abundance of the OH molecule to be X(OH)=1.09$\times$10$^{-7}$ with respect to H$_2$. The radial distribution of CH column densities along the sightlines probed in this study, excluding SgrB2(M), showcase a dual peaked distribution peaking between 5 and 7 kpc. The similarity between the correspondingly derived column density profile of H$_2$ with that of the CO-dark H$_2$ gas traced by the cold neutral medium component of [CII] 158$~\mu$m emission across the Galactic plane, further emphasises the use of CH as a tracer for H$_2$.

The methylidyne radical CH is commonly used as a proxy for H$_2$ in the cold, neutral phase of the interstellar medium. The optical spectroscopy of CH is limited by interstellar extinction, whereas far-infrared observations provide an integral view through the Galaxy. While the HF ground state absorption, another H$_2$ proxy in diffuse gas, frequently suffers from saturation, CH remains transparent both in spiral-arm crossings and high-mass star forming regions, turning this light hydride into a universal surrogate for H$_2$. However, in slow shocks and in regions dissipating turbulence its abundance is expected to be enhanced by an endothermic production path, and the idea of a "canonical" CH abundance needs to be addressed. The $N=2\leftarrow 1$ ground state transition of CH at $\lambda 149\,\mu$m has become accessible to high-resolution spectroscopy thanks to GREAT aboard SOFIA. Its unsaturated absorption and the absence of emission makes it an ideal candidate for the determination of column densities with a minimum of assumptions. Here we present an analysis of four sightlines towards distant, far-infrared bright Galactic star forming regions. If combined with the sub-millimeter line of CH at $\lambda 560\,\mu$m, environments forming massive stars can be analyzed. For this we present a case study on the "proto-Trapezium" cluster W3 IRS5, and demonstrate that the sub-millimeter/far-infrared lines of CH reliably trace not only diffuse but also dense, molecular gas. While we confirm the global correlation between the column densities of HF and those of CH, clear signposts of an over-abundance of CH are observed towards lower densities. A quiescent ion-neutral chemistry alone cannot account for this over-abundance. Vortices forming in turbulent, diffuse gas may be the setting for an enhanced production path., Comment: 15 pages, 11 figures