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Understanding the near-ground vertical and temporal photochemical O3 formation mechanism is important to mitigate O3 pollution. Here, we measured the vertical profiles of O3 and its precursors at six different heights, ranging from 5 to 335 m, using a newly built vertical observation system in the Pearl River Delta (PRD) region of China. The net photochemical ozone production rate (P(O3)net) and O3 formation sensitivities at various heights were diagnosed using an observation-based model coupled with the Master Chemical Mechanism (MCM v3.3.1). Moreover, to assess model performance and identify the causative factors behind O3 pollution episodes, the P(O3)net was measured at 5 m above ground level with a custom-built detection system. In total, three O3 pollution episodes and two non-episodes were captured. The identified O3 pollution episodes were found to be jointly influenced by both photochemical production and physical transport, with local photochemical reactions playing a major role. The high index of agreement (IOA) calculated by comparing the modelled and measured P(O3)net values indicated the rationality of investigating the vertical and temporal variability in O3 formation mechanisms using model results. However, the measured P(O3)net values were generally higher than the modelled P(O3)net values, particularly under high-NOx conditions, which may indicate a potential underestimation of total RO2 by the model. Throughout the measurement period, the contribution of different reaction pathways to O3 production remained consistent across various heights, with HO2 + NO as the major O3 production pathway, followed by RO2 + NO. We observed that P(O3)net decreased with an increase in measurement height, which was primarily attributed to the reduction in O3 precursors, such as oxygenated volatile organic compounds (OVOCs) and non-methane hydrocarbons (NMHCs). The O3 formation regimes were similar at different heights during both episodes and non-episodes, either being located in the VOC-sensitive regime or in the transition regime that is more sensitive to VOCs. Diurnally, photochemical O3 formation typically remained in the VOC-sensitive regime during the morning and noon, but it transitioned to the transition regime and was more sensitive to VOCs in the afternoon at around 16:00 LT (local time). Vertical and temporal photochemical O3 formation is most sensitive to OVOCs, suggesting that targeting specific VOCs for control measures is more practical and feasible at the observation site. The vertical temporal analysis of O3 formation mechanisms near the ground surface in this study provides critical foundational knowledge that can be used to formulate effective short-term emergency and long-term control strategies to combat O3 pollution in the PRD region of China.

With the development of refined numerical forecasts, problems such as score distortion due to the division of precipitation thresholds in both traditional and improved scoring methods for precipitation forecasts and the increasing subjective risk arising from the scale setting of the neighborhood spatial verification method have become increasingly prominent. To address these issues, a general comprehensive evaluation method (GCEM) is developed for cross-scale precipitation forecasts by directly analyzing the proximity of precipitation forecasts and observations in this study. In addition to the core indicator of the precipitation accuracy score (PAS), the GCEM system also includes score indices for insufficient precipitation forecasts, excessive precipitation forecasts, precipitation forecast biases, and clear/rainy forecasts. The PAS does not distinguish the magnitude of precipitation and does not delimit the area of influence; it constitutes a fair scoring formula with objective performance and can be suitable for evaluating rainfall events such as general and extreme precipitation. The PAS can be used to calculate the accuracy of numerical models or quantitative precipitation forecasts, enabling the quantitative evaluation of the comprehensive capability of various refined precipitation forecasting products. Based on the GCEM, comparative experiments between the PAS and threat score (TS) are conducted for two typical precipitation weather processes. The results show that relative to the TS, the PAS better aligns with subjective expectations, indicating that the PAS is more reasonable than the TS. In the case of an extreme-precipitation event in Henan, China, two high-resolution models were evaluated using the PAS, TS, and fraction skill score (FSS), verifying the evaluation ability of PAS scoring for predicting extreme-precipitation events. In addition, other indices of the GCEM are utilized to analyze the range and extent of both insufficient and excessive forecasts of precipitation, as well as the precipitation forecasting ability for different weather processes. These indices not only provide overall scores similar to those of the TS for individual cases but also support two-dimensional score distribution plots which can comprehensively reflect the performance and characteristics of precipitation forecasts. Both theoretical and practical applications demonstrate that the GCEM exhibits distinct advantages and potential promotion and application value compared to the various mainstream precipitation forecast verification methods.

We report the first measurements of cumulants, up to 4th order, of deuteron number distributions and proton-deuteron correlations in Au+Au collisions recorded by the STAR experiment in phase-I of Beam Energy Scan (BES) program at the Relativistic Heavy Ion Collider. Deuteron cumulants, their ratios, and proton-deuteron mixed cumulants are presented for different collision centralities covering a range of center-of-mass energy per nucleon pair sNN=7.7 to 200 GeV. It is found that the cumulant ratios at lower collision energies favor a canonical ensemble over a grand canonical ensemble in thermal models. An anti-correlation between proton and deuteron multiplicity is observed across all collision energies and centralities, consistent with the expectation from global baryon number conservation. The UrQMD model coupled with a phase-space coalescence mechanism qualitatively reproduces the collision-energy dependence of cumulant ratios and proton-deuteron correlations.

The chiral magnetic effect (CME) is a phenomenon that arises from the QCD anomaly in the presence of an external magnetic field. The experimental search for its evidence has been one of the key goals of the physics program of the Relativistic Heavy-Ion Collider. The STAR Collaboration has previously presented the results of a blind analysis of isobar collisions (_{44}^{96}Ru+_{44}^{96}Ru, _{40}^{96}Zr+_{40}^{96}Zr) in the search for the CME. The isobar ratio (Y) of CME-sensitive observable, charge separation scaled by elliptic anisotropy, is close to but systematically larger than the inverse multiplicity ratio, the naive background baseline. This indicates the potential existence of a CME signal and the presence of remaining nonflow background due to two- and three-particle correlations, which are different between the isobars. In this postblind analysis, we estimate the contributions from those nonflow correlations as a background baseline to Y, utilizing the isobar data as well as Heavy Ion Jet Interaction Generator simulations. This baseline is found consistent with the isobar ratio measurement, and an upper limit of 10% at 95% confidence level is extracted for the CME fraction in the charge separation measurement in isobar collisions at sqrt[s_{NN}]=200 GeV.

This paper presents numerical modelling of the ballistic impact response of hybrid laminated structures, which are developed through combinations of ceramics, Ultra-High-Molecular-Weight Polyethylene (UHMWPE), Kevlar and compressed wood. It is, for the first time, to embed the compressed wood in the ballistic panel and numerically investigate the impact response of the hybrid structures made of the multiple constituent materials. Different constitutive models and the related failure criteria were employed in the modelling to capture the ballistic responses of the constituent materials and hybrid structures. The numerical simulations were compared with the corresponding experimental results with acceptable correlation. The essential features of the hybrid composite structures subjected to high velocity impact were simulated by the finite element (FE) models, such as deformation and failure modes, back-face signature and the residual velocities. The FE models developed are ready to be used to assist design lightweight composite armour with optimized ballistic resistance and self-weight.

The differential cross section for Z0 production, measured as a function of the boson's transverse momentum (pT), provides important constraints on the evolution of the transverse momentum dependent parton distribution functions (TMDs). The transverse single spin asymmetry (TSSA) of the Z0 is sensitive to one of the polarized TMDs, the Sivers function, which is predicted to have the opposite sign in p+p →W/Z+X from that which enters in semi-inclusive deep inelastic scattering. In this Letter, the STAR Collaboration reports the first measurement of the Z0/γ⁎ differential cross section as a function of its pT in p+p collisions at a center-of-mass energy of 510 GeV, together with the Z0/γ⁎ total cross section. We also report the measurement of Z0/γ⁎ TSSA in transversely polarized p+p collisions at 510 GeV.

Estuaries are a conduit of mercury (Hg) from watersheds to the coastal ocean, and salt marshes play an important role in coastal Hg cycling. Hg cycling in upland terrestrial ecosystems has been well studied, but processes in densely vegetated salt marsh ecosystems are poorly characterized. We investigated Hg dynamics in vegetation and soils in the Plum Island Sound estuary in Massachusetts, USA, and specifically assessed the role of marsh vegetation for Hg deposition and turnover. Monthly quantitative harvesting of aboveground biomass showed strong linear seasonal increases in Hg associated with plants, with a 4-fold increase in Hg concentration and an 8-fold increase in standing Hg mass from June (3.9 ± 0.2 µg kg−1 and 0.7 ± 0.4 µg m−2, respectively) to November (16.2 ± 2.0 µg kg−1 and 5.7 ± 2.1 µg m−2, respectively). Hg did not increase further in aboveground biomass after plant senescence, indicating physiological controls of vegetation Hg uptake in salt marsh plants. Hg concentrations in live roots and live rhizomes were 11 and 2 times higher than concentrations in live aboveground biomass, respectively. Furthermore, live belowground biomass Hg pools (Hg in roots and rhizomes, 108.1 ± 83.4 µg m−2) were more than 10 times larger than peak standing aboveground Hg pools (9.0 ± 3.3 µg m−2). A ternary mixing model of measured stable Hg isotopes suggests that Hg sources in marsh aboveground tissues originate from about equal contributions of root uptake (∼ 35 %), precipitation uptake (∼ 33 %), and atmospheric gaseous elemental mercury (GEM) uptake (∼ 32 %). These results suggest a more important role of Hg transport from belowground (i.e., roots) to aboveground tissues in salt marsh vegetation than upland vegetation, where GEM uptake is generally the dominant Hg source. Roots and soils showed similar isotopic signatures, suggesting that belowground tissue Hg mostly derived from soil uptake. Annual root turnover results in large internal Hg recycling between soils and plants, estimated at 58.6 µg m−2 yr−1. An initial mass balance of Hg indicates that the salt marsh presently serves as a small net Hg sink for environmental Hg of 5.2 µg m−2 yr−1.

Inter-basin water transfer projects are the main measure to address the water deficit crisis caused by uneven distribution of water resources. The current water transfer operation mainly tends to be present in areas with small water transfer costs and is prone to encounter the problem of spatial and temporal imbalances in water allocation. To address these issues, this paper defines a water deficit evenness index (WDEI), aimed at minimizing regional differences in water scarcity and sharing the pressure of water scarcity as a social demand objective. This index is incorporated into a joint optimization model for the Jiangsu section of the South-to-North Water Diversion Project (J-SNWDP), which comprises both the ecological objective of the total water deficit (TWD) and the economic objective of the pumping water (PW). Further, the Nondominated Sorting Genetic Algorithm III (NSGA-III) and multi-attribute decision-making were applied to solve the model and obtain an optimal operation strategy. The results showed the following: (1) the WDEI defined in this paper can mitigate the synchronized water scarcity in certain water users. In typical normal years (wet year and dry year), the WDEI shows a reduction of 94.2 % (81.8 %, 76.7 %) compared to the historical operation strategy. (2) The optimized operation strategy can significantly reduce TWD and PW by 82.06% (37.69 %, 52.36 %) and 45.13 % (3.25 %, 21.51 %) compared with the historical values, respectively, which can improve the water supply satisfaction and reduce the project cost. At the same time, the lake storage capacity of the optimal operation strategy performs well, and the water transfer efficiency of the river is significantly improved. (3) In this paper, targeted optimal operation strategies and potential ways to secure the project tasks are proposed for different natural flow. Overall, it is of great significance to study the water supply equity in the J-SNWDP to alleviate the concentrated water deficit in Jiangsu Province and other similar regions.

Nucleophilic high molecular-weight organic compounds (HMWOCs) are sensitive to protons (H+) in Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) analysis. A comprehensive evaluation of the diurnal evolution of nucleophilic HMWOCs was performed. HMWOCs aged significantly in daily cycles, accompanied by functionality shifts, particularly oxygenated and reduced nitrogen (CHON and CHN) as well as oxygenated organics. The intensities of high molecular-weight (HMW) oxygenated compounds increased during both daytime and nighttime. The daytime evolution produced more nitrogen-containing compounds with carboxylic group (–COOH) homologues with molecular weights greater than 300, while the nighttime evolution produced mostly small CHON compounds (molecular weights < 300). During evolution, nighttime CHON removals were observed; meanwhile, carboxylation was also identified in CHON groups. The daytime evolution produced significantly more reduced-nitrogen-containing compounds; a day- and nighttime increase in CHN compounds with five members was also observed. This study can provide insights into the aging of less polar organic aerosols.

Land surface temperature (LST) is a key variable within Earth's climate system and a necessary input parameter required by numerous land–atmosphere models. It can be directly retrieved from satellite thermal infrared (TIR) observations, which contain many invalid pixels mainly caused by cloud contamination. To investigate the spatial and temporal variations in LST in China, long-term, high-quality, and spatiotemporally continuous LST datasets (i.e., all-weather LST) are urgently needed. Fusing satellite TIR LST and reanalysis datasets is a viable route to obtain long time-series all-weather LSTs. Among satellite TIR LSTs, the MODIS LST is the most commonly used, and a few corresponding all-weather LST products have been reported recently. However, the publicly reported all-weather LSTs were not available during the temporal gaps of MODIS between 2000 and 2002. In this study, we generated a daily (four observations per day) 1 km all-weather LST dataset for China's landmass and surrounding areas, the Thermal and Reanalysis Integrating Moderate-resolution Spatial-seamless (TRIMS) LST, which begins on the first day of the new millennium (1 January 2000). We used the enhanced reanalysis and thermal infrared remote sensing merging (E-RTM) method to generate the TRIMS LST dataset with the temporal gaps being filled, which had not been achieved by the original RTM method. Specifically, we developed two novel approaches, i.e., the random-forest-based spatiotemporal merging (RFSTM) approach and the time-sequential LST-based reconstruction (TSETR) approach, respectively, to produce Terra/MODIS-based and Aqua/MODIS-based TRIMS LSTs during the temporal gaps. We also conducted a thorough evaluation of the TRIMS LST. A comparison with the Global Land Data Assimilation System (GLDAS) and ERA5-Land LST demonstrates that the TRIMS LST has similar spatial patterns but a higher image quality, more spatial details, and no evident spatial discontinuities. The results outside the temporal gap show consistent comparisons of the TRIMS LST with the MODIS LST and the Advanced Along-Track Scanning Radiometer (AATSR) LST, with a mean bias deviation (MBD) of 0.09/0.37 K and a standard deviation of bias (SD) of 1.45/1.55 K. Validation based on the in situ LST at 19 ground sites indicates that the TRIMS LST has a mean bias error (MBE) ranging from −2.26 to 1.73 K and a root mean square error (RMSE) ranging from 0.80 to 3.68 K. There is no significant difference between the clear-sky and cloudy conditions. For the temporal gap, it is observed that RFSTM and TSETR perform similarly to the original RTM method. Additionally, the differences between Aqua and Terra remain stable throughout the temporal gap. The TRIMS LST has already been used by scientific communities in various applications such as soil moisture downscaling, evapotranspiration estimation, and urban heat island modeling. The TRIMS LST is freely and conveniently available at https://doi.org/10.11888/Meteoro.tpdc.271252 (Zhou et al., 2021).

We report results on an elastic cross section measurement in proton–proton collisions at a center-of-mass energy s=510 GeV, obtained with the Roman Pot setup of the STAR experiment at the Relativistic Heavy Ion Collider (RHIC). The elastic differential cross section is measured in the four-momentum transfer squared range 0.23≤−t≤0.67 GeV2. This is the only measurement of the proton-proton elastic cross section in this t range for collision energies above the Intersecting Storage Rings (ISR) and below the Large Hadron Collider (LHC) colliders. We find that a constant slope B does not fit the data in the aforementioned t range, and we obtain a much better fit using a second-order polynomial for B(t). This is the first measurement below the LHC energies for which the non-constant behavior B(t) is observed. The t dependence of B is also determined using six subintervals of t in the STAR measured t range, and is in good agreement with the phenomenological models. The measured elastic differential cross section dσ/dt agrees well with the results obtained at s=540 GeV for proton–antiproton collisions by the UA4 experiment. We also determine that the integrated elastic cross section within the STAR t-range is σelfid=462.1±0.9(stat.)±1.1(syst.)±11.6(scale) μb.

Detection of low viral load samples has long been a challenge for African swine fever (ASF) prevention and control. This study aimed to compare the detection efficacy of droplet digital PCR(ddPCR) and quantitative PCR(qPCR) for African swine fever virus (ASFV) at different viral loads, with a focus on assessing the accuracy of ddPCR in detecting low viral load samples. The results revealed that ddPCR had a detection limit of 1.97 (95% CI 1.48 – 4.12) copies/reaction and was 18.99 times more sensitive than qPCR (detection limit: 37.42, 95% CI 29.56 – 69.87 copies/reaction). In the quantification of high, medium, and low viral load samples, ddPCR showed superior stability with lower intra- (2.06% – 7.58%) and inter-assay (3.83% – 7.50%) coefficients of variation than those of qPCR (intra-assay: 8.08%–29.86%; inter-assay: 9.27%–34.58%). Bland-Altman analysis indicated acceptable consistency between ddPCR and qPCR for high and medium viral load samples; however, discrepancies were observed for low viral load samples, where two samples (2/24, 8.33%) exhibited deviations beyond the acceptable range (−46.18 copies/reaction). Moreover, ddPCR demonstrated better performance in detecting ASFV in clinical samples from asymptomatic pigs and environmental samples, with qPCR showing false negative rates of 7.69% (2/26) and 27.27% (12/44), respectively. McNemar analysis revealed significant differences between the two methods (P = 0.000) for samples with a viral load

This paper proposes a real-time 3D image point clouds mapping algorithm for UAVs that is capable of mapping effectively in weak GNSS environments. And a UAV mapping system is integrated with a RGB camera, an inertial measurement unit (IMU), a GNSS receiver, data transmission devices, and a DJI M300 flight platform. To achieve real-time and robust mapping, the system utilizes a visual-inertial odometry (VIO) that tightly couples GNSS, RGB image, and IMU, which provides stable state estimation information for mapping. Subsequently, a dense matching algorithm based on key frames is adopted to recover 3D mapping information with low-computational cost. Extensive experiments are conducted on our test site, demonstrating the system's ability to build maps stably, even under the effect of wind. The results compared with the trajectory reconstructed by Pix4D show that the system achieves competitive accuracy of pose estimation and is capable of real-time mapping.

Oases and deserts generally act as a landscape matrix and mosaic in arid and semiarid regions. The significant difference in thermal and dynamic characteristics between an oasis and desert surface will result in oasis–desert interaction. Specifically, this refers to the interaction between an oasis and desert system via the exchange of momentum, energy, water, and carbon, which can lead to a series of microclimate effects that affect the structure of the atmospheric boundary layer, changes in carbon sources and sinks in an oasis, and the local ecological environment. Therefore, studying water, heat, and carbon exchange is significant to achieve the goals of carbon peaking and carbon neutrality in oasis–desert areas and support the ecological security and sustainable development of oases. To monitor energy, water vapor, and carbon exchange between the land surface and atmosphere, a land surface process integrated observatory network was established in the oasis–desert area in the middle and lower reaches of the Heihe River basin, the second largest endorheic basin in China. In this study, we present a suite of observational datasets from artificial and natural oasis–desert systems that consist of long-term energy, water vapor, carbon and methane fluxes as well as auxiliary data involving hydrometeorology, vegetation, and soil parameters from 2012 to 2021. Half-hourly turbulent flux data were acquired by an eddy covariance system and scintillometer. The hydrometeorological data (including radiation, soil heat flux, and soil temperature profiles; gradients of air temperature and humidity and of wind speed and direction; and air pressure, precipitation, and soil moisture profiles) were observed from automatic weather stations with a 10 min average period as well as the groundwater table data. Moreover, vegetation and soil parameters were also supplemented in the datasets. Careful data processing and quality control were implemented during data production, including data collection, processing, archiving, and sharing. The current datasets can be used to explore the water–heat–carbon process and its mechanism of influence; to calibrate and validate related remote-sensing products; to simulate energy, water vapor, and carbon exchange in oasis and desert areas; and to provide references and representatives for other similar artificial and natural oases along the “Silk Road”. The data are available from the National Tibetan Plateau Third Pole Environment: https://doi.org/10.11888/Terre.tpdc.300441 (Liu et al., 2023).

Hypoxia and adverse health outcomes might be affected by O3 pollution in the highland city of Lhasa. NOx emissions can amplify the role of volatile organic compounds (VOCs) in the secondary production of O3 under the conditions of high ultraviolet (UV) radiation levels and unfavourable dispersion patterns in the Lhasa River valley. Here, online C2–C11 VOC measurements, accompanied by other parameters concerning the O3 chemical budget, were first obtained and employed to identify the key VOC species and key sources of VOCs in terms of the loss rate against OH radicals (LOH), ozone formation potential (OFP), secondary organic aerosol potential (SOAP), and toxicity. Oxygenated VOCs (OVOCs) not only were the most abundant VOCs but also dominated LOH, OFP, and toxicity. Isoprene and anthropogenic VOCs were further identified as precursors of these OVOCs. Aromatics accounted for 5 % of the total VOCs (TVOCs) but contributed 88 % to the SOAP and 10 % to the toxicity. As the primary oxidative intermediates of aromatics were not well characterized by our measurements, the environmental impact of aromatics could be underestimated by our data. Source appointment and ternary analysis of benzene, toluene, and ethylbenzene confirmed the combined contribution of traffic emissions, solvent usage, and biomass burning. This suggests that O3 precursors are mainly from sources associated with residents' lives, except for solvent usage emissions which contribute to aromatics. Preliminary comparisons between source spectrums of transport sector emissions with positive matrix factorization (PMF)-decomposed ones and our measured ones suggest that vehicle emission patterns of VOCs at high altitude generally follow the ground-level impression. More quantitative data are required to further confirm this point though. Emission reduction strategy analysis for O3 pollution control highlighted multiple benefits of the simultaneous reduction in NOx originating from diesel vehicle emissions, biomass burning, and background sources (possibly dominated by incense burning). The notable biogenic emission contribution to the OFP was also first confirmed in our study, and this highlights the side effects of the government's pursuit of a greener city.

Current process-based research mainly uses box models to evaluate photochemical ozone production and destruction rates, and it is unclear to what extent the photochemical reaction mechanisms are elucidated. Here, we modified and improved a net photochemical ozone production rate (NPOPR, P(O3)net) detection system based on the current dual-channel reaction chamber technique, which makes the instrument applicable to different ambient environments, and its various operating indicators were characterized, i.e., “airtightness”, light transmittance, wall losses of the reaction and reference chambers, conversion rate of O3 to NO2, air residence time, and performance of the reaction and reference chambers. The limits of detection of the NPOPR detection system were determined to be 0.07, 1.4, and 2.3 ppbv h−1 at sampling flow rates of 1.3, 3, and 5 L min−1, respectively. We further applied the NPOPR detection system to field observations at an urban site in the Pearl River Delta (China). During the observation period, the maximum value of P(O3)net was 34.1 ppbv h−1, which was ∼ 0 ppbv h−1 at night within the system detection error and peaked at approximately noon local time. The daytime (from 06:00–18:00 LT) average value of P(O3)net was 12.8 (± 5.5) ppbv h−1. We investigated the detailed photochemical O3 formation mechanism in the reaction and reference chambers of the NPOPR detection system using a zero-dimensional box model. We found that the photochemical reactions in the reaction chamber were very close to those in ambient air, but there was not zero chemistry in the reference chamber because the reaction related to the production and destruction of RO2 (= HO2 + RO2) continued in the reference chamber, which led to a small amount of P(O3)net. Therefore, the P(O3)net measured here can be regarded as the lower limit of the real P(O3)net in the atmosphere; however, the measured P(O3)net was still ∼ 7.5 to 9.3 ppbv h−1 higher than the modeled P(O3)net value depending on different modeling methods, which may be due to the inaccurate estimation of HO2 / RO2 radicals in the modeling study. Short-lived intermediate measurements coupled with direct P(O3)net measurements are needed in the future to better understand O3 photochemistry. Our results show that the NPOPR detection system can achieve high temporal resolution and continuous field observations, which helps us to better understand photochemical O3 formation and provides a key scientific basis for continuous improvement of air quality in China.

Abstract We report a new measurement of the production of electrons from open heavy-flavor hadron decays (HFEs) at mid-rapidity (|y| < 0.7) in Au+Au collisions at s NN $$ \sqrt{s_{\textrm{NN}}} $$ = 200 GeV. Invariant yields of HFEs are measured for the transverse momentum range of 3.5 < p T < 9 GeV/c in various configurations of the collision geometry. The HFE yields in head-on Au+Au collisions are suppressed by approximately a factor of 2 compared to that in p + p collisions scaled by the average number of binary collisions, indicating strong interactions between heavy quarks and the hot and dense medium created in heavy-ion collisions. Comparison of these results with models provides additional tests of theoretical calculations of heavy quark energy loss in the quark-gluon plasma.

New particle formation (NPF) is an important source of cloud condensation nuclei (CCN), which affects Earth's radiative balance and global climate. The mechanism and CCN contribution of NPF at the high-altitude mountains, especially in the Tibetan Plateau (TP), was unclear due to lack of measurements. In this study, intensive measurements were conducted at the Nam Co station (4730 m a.s.l.) in the central TP during both the pre-monsoon and summer monsoon seasons. The frequencies of NPF events exhibited evident seasonal differences with 15 % in the pre-monsoon season and 80 % in the monsoon season. The comprehensive analysis of the measured condensation sink (CS), gaseous precursors and meteorological conditions, supplemented by the model simulations of SO2 and volatile organic compound (VOC), points to the organic involved nucleation as the dominant mechanism. Condensation sink and gaseous sulfuric acid could have no significant effect on the occurrence of NPF events. The frequent NPF events in the summer monsoon season may result from the higher frequency of southerly and southwesterly air masses, which brought the organic precursors to participate in the NPF process. It had increased the aerosol number concentrations and CCN at supersaturation of 1.2 % by more than 2 and 0.6 times compared with those in the pre-monsoon season, respectively. Considering that the smaller particles formed by NPF may further grow and reach CCN size during the following days due to the low-level coagulation sink, the amount of potential CCN in the monsoon season could be much larger than our local measurement results. Our results emphasized the importance of considering the seasonal effect of NPF when simulating the amounts of aerosols and CCN in the high-altitude atmosphere. Long-term investigations with a full set of instrumentation are required for deeper scientific understanding of NPF process and its role in the global budget in the TP.

Density fluctuations near the QCD critical point can be probed via an intermittency analysis in relativistic heavy-ion collisions. We report the first measurement of intermittency in Au+Au collisions at sNN = 7.7-200 GeV measured by the STAR experiment at the Relativistic Heavy Ion Collider (RHIC). The scaled factorial moments of identified charged hadrons are analyzed at mid-rapidity and within the transverse momentum phase space. We observe a power-law behavior of scaled factorial moments in Au+Au collisions and a decrease in the extracted scaling exponent (ν) from peripheral to central collisions. The ν is consistent with a constant for different collisions energies in the mid-central (10-40%) collisions. Moreover, the ν in the 0-5% most central Au+Au collisions exhibits a non-monotonic energy dependence that reaches a minimum around sNN = 27 GeV. The physics implications on the QCD phase structure are discussed.

Reliable precipitation data are highly necessary for geoscience research in the Third Pole (TP) region but still lacking, due to the complex terrain and high spatial variability of precipitation here. Accordingly, this study produces a long-term (1979–2020) high-resolution (1/30∘, daily) precipitation dataset (TPHiPr) for the TP by merging the atmospheric simulation-based ERA5_CNN with gauge observations from more than 9000 rain gauges, using the climatologically aided interpolation and random forest methods. Validation shows that TPHiPr is generally unbiased and has a root mean square error of 5.0 mm d−1, a correlation of 0.76 and a critical success index of 0.61 with respect to 197 independent rain gauges in the TP, demonstrating that this dataset is remarkably better than the widely used datasets, including the latest generation of reanalysis (ERA5-Land), the state-of-the-art satellite-based dataset (IMERG) and the multi-source merging datasets (MSWEP v2 and AERA5-Asia). Moreover, TPHiPr can better detect precipitation extremes compared with these widely used datasets. Overall, this study provides a new precipitation dataset with high accuracy for the TP, which may have broad applications in meteorological, hydrological and ecological studies. The produced dataset can be accessed via https://doi.org/10.11888/Atmos.tpdc.272763 (Yang and Jiang, 2022).

Haze pollution is a severe environmental problem, caused by elevation of fine particles (aerodynamic diameter µm, PM2.5), which is related to secondary aerosol formation, unfavourable synoptic conditions and regional transport, etc. The regional haze formation in basin areas, along with intensive emission of precursors, high relative humidity and poor dispersion conditions, is still limitedly understood. In this study, a field campaign was conducted to investigate the factors resulting in haze formation in the Sichuan Basin (SCB) during winter in 2021. The fine aerosol chemical composition was characterised using a time-of-flight aerosol chemical speciation monitor (ToF-ACSM), which also provided detailed information on the sources for organic aerosols (OAs). The average concentration of non-refractory fine particles (NR-PM2.5) was 98.5±38.7 µg m−3, and organics aerosols, nitrate, sulfate, ammonium and chloride took up 40.3 %, 28.8 %, 10.6 %, 15.3 % and 5.1 % of PM2.5. Three factors, including a hydrocarbon-like OA (HOA), a biomass burning OA (BBOA) and an oxygenated OA (OOA), were identified by applying the positive matrix factorisation (PMF) analysis, and they constituted 24.2 %, 24.2 % and 51.6 % of OA on average, respectively. Nitrate formation was promoted by gas-phase and aqueous-phase oxidation, while sulfate was mainly formed through aqueous-phase process. OOA showed strong dependence on Ox, demonstrating the contribution of photooxidation to OOA formation. OOA concentration increased as aerosol liquid water content (ALWC) increased within 200 µg m−3 and kept relatively constant when ALWC >200 µg m−3, suggesting the insignificant effect of aqueous-phase reactions on OOA formation. Among the three haze episodes identified during the whole campaign, the driving factors were different: the first haze episode (H1) was driven by nitrate formation through photochemical and aqueous-phase reactions, and the second haze episode (H2) was mainly driven by the intense emission of primary organic aerosols from biomass burning and vehicle exhaust, while the third haze episode (H3) was mainly driven by reactions involving nitrate formation and biomass burning emission. HOA and BBOA were scavenged, while OOA, nitrate and sulfate formation was enhanced by aqueous-phase reactions during fog periods, which resulted in the increase of O:C from pre-fog to post-fog periods. This study revealed the factors driving severe haze formation in the SCB and implied the benefit of controlling nitrate as well as intense biomass burning and vehicle exhaust emission for the mitigation of heavy aerosol pollution in this region.

The deconfined quark-gluon plasma (QGP) created in relativistic heavy-ion collisions enables the exploration of the fundamental properties of matter under extreme conditions. Noncentral collisions can produce strong magnetic fields on the order of 10^{18} G, which offers a probe into the electrical conductivity of the QGP. In particular, quarks and antiquarks carry opposite charges and receive contrary electromagnetic forces that alter their momenta. This phenomenon can be manifested in the collective motion of final-state particles, specifically in the rapidity-odd directed flow, denoted as v_{1}(y). Here, we present the charge-dependent measurements of dv_{1}/dy near midrapidities for π^{±}, K^{±}, and p(p[over ¯]) in Au+Au and isobar (_{44}^{96}Ru+_{44}^{96}Ru and _{40}^{96}Zr+_{40}^{96}Zr) collisions at sqrt[s_{NN}]=200 GeV, and in Au+Au collisions at 27 GeV, recorded by the STAR detector at the Relativistic Heavy Ion Collider. The combined dependence of the v_{1} signal on collision system, particle species, and collision centrality can be qualitatively and semiquantitatively understood as several effects on constituent quarks. While the results in central events can be explained by the u and d quarks transported from initial-state nuclei, those in peripheral events reveal the impacts of the electromagnetic field on the QGP. Our data put valuable constraints on the electrical conductivity of the QGP in theoretical calculations.

Current CMOS single-photon detectors operating in Geiger mode use passive quenching, yielding slow recovery due to the RC delay. Active quenching of CMOS photon detectors operating in the Geiger mode requires external quenching circuitry that occupies a large area, reducing the fill factor and spatial resolution. Here, we demonstrate a self-quenched active recovery (SQUARE) single-photon detector having its recovery accelerated by a secondary carrier multiplication process. The device consists of two gain regions, one giving rise to the photon response and the other quenching the device and amplifying the residual current for a speedy self-recovery. The first gain region is a crystalline silicon p/n junction fabricated through a commercial CMOS process, and the second gain region is a carbon-doped amorphous silicon layer deposited on the top metal layer of a completed CMOS wafer. The SQUARE single-photon detector shows a Geiger-mode gain greater than 100 000 and achieved

We report on new measurements of elliptic flow (v2) of electrons from heavy-flavor hadron decays at mid-rapidity (|y|

Intro: Pulmonary fibrosis has been reported as a common complication of severe COVID-19, especially in patients who have undergone ARDS or mechanical ventilation treatment. As innate lymphocytes, NK cells play important roles in antiviral immunity and inhibit the progression of organ fibrosis.The exploration of key NK populations will clarify their role in the progression of COVID-19 and provide crucial cues for the treatment of post-COVID pulmonary fibrosis. Methods: Single-cell transcriptome data from bronchoalveolar lavage fluid (BALF) of COVID-19 patients and healthy donors were analyzed on normalized expression matrices of all cells screened. After annotation according to the marker genes, NK cells were extracted for further clustering and subsequent analyses of gene expression profiling, gene set enrichment, and molecular interaction. Findings: Reduced-dimensional clustering showed that NK cells in BALF were divided into 10 subpopulations. Compared with healthy persons, NK cells in the lungs of COVID-19 patients showed higher activated features and up-regulation of IFN-related genes. However, the GZMs+PRF1+ subpopulation was only 30% of the total NK cells and highly expressed apoptotic genes of Bax and BCL2L11 in severe patients, which may lead to insufficiency and poor cytotoxicity. In severe patients, AREG+ subpopulation was enriched in the lungs and decreased the expression of TNFSF10, FasL, and CCR2, which indicated under-recruitment and impaired antifibrosis function. Conclusion: Our data showed that NK cells decreased in BALF of severe COVID-19 patients, especially the effector/cytotoxic NK subset very significantly decreased. The impaired activity of antifibrotic NK cells may be associated with collagen deposition and senescent cell accumulation in the lungs with severe SARS-COV-2 infection. Improving the antiviral function and antifibrosis ability may be valid measures to prevent severe COVID-19 and reduce fibrosis complications.

Abstract Partons traversing the strongly interacting medium produced in heavy-ion collisions are expected to lose energy depending on their color charge and mass. We measure the nuclear modification factors for charm- and bottom-decay electrons, defined as the ratio of yields, divided by the number of binary nucleon–nucleon collisions, in $$\sqrt{s_{\textrm{NN}}}=200$$ s NN = 200 GeV Au+Au collisions to p+p collisions ( $$R_{\textrm{AA}}$$ R AA ), or in central to peripheral Au+Au collisions ( $$R_{\textrm{CP}}$$ R CP ). We find the bottom-decay electron $$R_{\textrm{AA}}$$ R AA and $$R_{\textrm{CP}}$$ R CP to be significantly higher than those of charm-decay electrons. Model calculations including mass-dependent parton energy loss in a strongly coupled medium are consistent with the measured data. These observations provide evidence of mass ordering of charm and bottom quark energy loss when traversing through the strongly coupled medium created in heavy-ion collisions.

Landslides present a significant hazard for humans, but continuous landslide monitoring is not yet possible due to their unpredictability. In recent years, numerical simulation and seismic inversion methods have been used to provide valuable data for understanding the entire process of landslide movement. However, each method has shortcomings. Dynamic inversion based on long-period seismic signals gives the force–time history of a landslide using an empirical Green's function but lacks detailed flowing characteristics for the hazards. Numerical simulation can simulate the entire movement process, but results are strongly influenced by the choice of modeling parameters. Therefore, developing a method for combining those two techniques has become a focus for research in recent years. In this study, we develop such a protocol based on analysis of the 2018 Baige landslide in China. Seismic signal inversion results are used to constrain and optimize the numerical simulation. We apply the procedure to the Baige event and, combined with a field geological survey, show it provides a comprehensive and accurate method for dynamic process reconstruction. We found that the Baige landslide was triggered by detachment of the weathered layer, with severe top fault segmentation. The landslide process comprised four stages: initiation, main slip, blocking, and deposition. Multi-method mutual verification effectively reduces the inherent drawbacks of each method, and multi-method joint analysis improves the rationality and reliability of the results. The approach outlined in this study could help us to better understand the landslide dynamic process.

Understanding the hydrological processes related to snow in global mountainous regions under climate change is necessary for achieving regional water and food security (e.g., the United Nation's Sustainable Development Goals 2 and 6). However, the impacts of future snow changes on the hydrological processes in the high mountains of the “Third Pole” are still largely unclear. In this study, we aimed to project future snow changes and their impacts on hydrology in the upstream region of the Salween River (USR) under two shared socioeconomic pathway (SSP) scenarios (SSP126 and SSP585) using a physically based cryosphere–hydrology model. We found that the climate would become warmer (0.2 ∘C per decade under SSP126 and 0.7 ∘C per decade under SSP585) and wetter (5 mm per decade under SPP126 and 27.8 mm per decade under SSP585) in the USR in the future under these two SSPs. In this context, the snowfall, snow cover, snow water equivalent, and snowmelt runoff are projected to exhibit significant decreasing trends during 1995–2100, and the decreases are projected to be most prominent in summer and autumn. The future (2021–2100) snowmelt runoff is projected to significantly increase in spring compared with the reference period (1995–2014), which would benefit the availability of water resources in the growing season. The annual total runoff would significantly increase in all of the future periods due to increased rainfall, which would increase the availability of water resources within the basin, but the high peak flow that occurs in summer may cause rain flooding with short duration and high intensity. Compared with the reference period (the contribution of snowmelt runoff to the total runoff was determined to be 17.5 %), the rain- and snow-dominated pattern of runoff would shift to a rain-dominated pattern after the near term (2021–2040) under SSP585, whereas it would remain largely unchanged under SSP126. Climate change would mainly change the pattern of the snowmelt runoff, but it would not change the annual hydrograph pattern (dominated by increased rainfall). These findings improve our understanding of the responses of cryosphere–hydrological processes under climate change, providing valuable information for integrated water resource management, natural disaster prevention, and ecological environmental protection at the Third Pole.

Porous biodegradable Mg and its alloys are considered to have a great potential to serve as ideal bone substitutes. The recent progress in additive manufacturing (AM) has prompted its application to fabricate Mg scaffolds with geometrically ordered porous structures. Extrusion-based AM, followed by debinding and sintering, has been recently demonstrated as a powerful approach to fabricating such Mg scaffolds, which can avoid some crucial problems encountered when applying powder bed fusion AM techniques. However, such pure Mg scaffolds exhibit a too high rate of in vitro biodegradation. In the present research, alloying through a pre-alloyed Mg-Zn powder was ultilized to enhance the corrosion resistance and mechanical properties of AM geometrically ordered Mg-Zn scaffolds simultaneously. The in vitro biodegradation behavior, mechanical properties, and electrochemical response of the fabricated Mg-Zn scaffolds were evaluated. Moreover, the response of preosteoblasts to these scaffolds was systematically evaluated and compared with their response to pure Mg scaffolds. The Mg-Zn scaffolds with a porosity of 50.3% and strut density of 93.1% were composed of the Mg matrix and MgZn2 second phase particles. The in vitro biodegradation rate of the Mg-Zn scaffolds decreased by 81% at day 1, as compared to pure Mg scaffolds. Over 28 days of static immersion in modified simulated body fluid, the corrosion rate of the Mg-Zn scaffolds decreased from 2.3 ± 0.9 mm/y to 0.7 ± 0.1 mm/y. The yield strength and Young's modulus of the Mg-Zn scaffolds were about 3 times as high as those of pure Mg scaffolds and remained within the range of those of trabecular bone throughout the biodegradation tests. Indirect culture of MC3T3-E1 preosteoblasts in Mg-Zn extracts indicated favorable cytocompatibility. In direct cell culture, some cells could spread and form filopodia on the surface of the Mg-Zn scaffolds. Overall, this study demonstrates the great potential of the extrusion-based AM Mg-Zn scaffolds to be further developed as biodegradable bone-substituting biomaterials.

Ecosystems in arid areas are fragile and are easily disturbed by various natural and human factors. As natural tracers widely exist in nature, stable isotopes can be valuable for studying environmental change and the water cycle. From 2015 to 2020, we took the Shiyang River basin, which has the highest utilization rate of water resources and the most prominent contradiction of water use, as a typical demonstration basin to establish and improve the isotope hydrology observation system. The data in the observation system are classified by water type (precipitation, river water, lake water, groundwater, soil water, and plant water). Six observation systems with stable isotopes as the main observation elements have been built. These include river source region, oasis region, reservoir channel system region, oasis farmland region, ecological engineering construction region, and salinization process region; meteorological and hydrological data have also been collected. We will gradually improve the various observation systems, increase the data of observation sites, and update the data set yearly. We can use these data to research the continental river basin ecological hydrology, such as surface water evaporation loss, landscape river water cycle impact of the dam, dam water retention time, oasis farmland irrigation methods, and the atmosphere, such as the contribution of inland water circulation to inland river precipitation, climate transformation, below-cloud evaporation effect, and extreme climate events, which provides a scientific basis for water resources utilization and ecological environment restoration in the arid area. The data sets are available at https://doi.org/10.17632/vhm44t74sy.1 (Zhu, 2022).

A decisive experimental test of the Chiral Magnetic Effect (CME) is considered one of the major scientific goals at the Relativistic Heavy-Ion Collider (RHIC) towards understanding the nontrivial topological fluctuations of the Quantum Chromodynamics vacuum. In heavy-ion collisions, the CME is expected to result in a charge separation phenomenon across the reaction plane, whose strength could be strongly energy dependent. The previous CME searches have been focused on top RHIC energy collisions. In this Letter, we present a low energy search for the CME in Au+Au collisions at sNN=27 GeV. We measure elliptic flow scaled charge-dependent correlators relative to the event planes that are defined at both mid-rapidity |η|

The linear and mode-coupled contributions to higher-order anisotropic flow are presented for Au+Au collisions at sNN = 27, 39, 54.4, and 200 GeV and compared to similar measurements for Pb+Pb collisions at the Large Hadron Collider (LHC). The coefficients and the flow harmonics' correlations, which characterize the linear and mode-coupled response to the lower-order anisotropies, indicate a beam energy dependence consistent with an influence from the specific shear viscosity (η/s). In contrast, the dimensionless coefficients, mode-coupled response coefficients, and normalized symmetric cumulants are approximately beam-energy independent, consistent with a significant role from initial-state effects. These measurements could provide unique supplemental constraints to (i) distinguish between different initial-state models and (ii) delineate the temperature (T) and baryon chemical potential (μB) dependence of the specific shear viscosity ηs(T,μB).

Combined with the acceptance of the surface coverage data results of the national geographic situation monitoring project, as well as the consistency requirements between the surface coverage data results and the background data, the "three tone" data results, the digital orthophoto data and the field investigation and verification data, this paper puts forward the quality control method of the surface coverage classification data results by analyzing the quality problems found in the inspection. This method provides a technical reference for the quality control of the national geographic situation monitoring project and a method basis for quality inspection.

In recent years, the quality control of surveying, mapping and geographic information engineering has attracted much attention because of its importance. On the basis of the quality control of the first phase of the 927 project and the western surveying and mapping project, in response to the supervision needs of major national surveying, mapping and geographic information projects, this paper is based on the needs of surveying and mapping supervision, characteristics, development status, this paper analyzes the limitations of traditional surveying and mapping supervision in national major surveying and mapping geographic information projects, and proposes an improved surveying and mapping supervision method, namely the concept of surveying and mapping technical supervision. The research determines that the content of technical supervision is divided into two parts: quality management control and stage achievement quality control, and analyzes its application characteristics. Through the application and effect analysis of technical supervision in actual projects, the advantages and feasibility of technical supervision are verified, which can effectively overcome the limitations of traditional surveying and mapping supervision. The research content of this paper can guide the development of the corresponding quality control work, and provide a reference for the quality control of major national projects.

Accurate particle classification plays a vital role in aerosol studies. Differential mobility analyzers (DMAs), centrifugal particle mass analyzers (CPMAs) and aerodynamic aerosol classifiers (AACs) are commonly used to select particles with a specific mobility diameter, aerodynamic diameter or mass, respectively. However, multiple charging effects cannot be entirely avoided when using either individual techniques or tandem systems such as DMA–CPMA, especially when selecting soot particles with fractal structures. In this study, we calculate the transfer functions of the DMA–CPMA and DMA–AAC in static configurations for flame-generated soot particles. We propose an equation that constrains the resolutions of the DMA and CPMA to eliminate the multiple charging effect when selecting particles with a certain mass–mobility relationship using the DMA–CPMA system. The equation for the DMA–AAC system is also derived. For DMA–CPMA in a static configuration, our results show that the ability to remove multiply charged particles mainly depends on the particle morphology and resolution settings of the DMA and CPMA. Using measurements from soot experiments and literature data, a general trend in the appearance of the multiple charging effect with decreasing size when selecting aspherical particles is observed. As for DMA–AAC in a static configuration, the ability to eliminate particles with multiple charges is mainly related to the resolutions of the classifiers. In most cases, the DMA–AAC in a static configuration can eliminate the multiple charging effect regardless of the particle morphology, but multiply charged particles will be selected when decreasing the resolution of the DMA or AAC. We propose that the potential influence of the multiple charging effect should be considered when using the DMA–CPMA or DMA–AAC systems in estimating size- and mass-resolved optical properties in field and lab experiments.

The stereo matching algorithm is commonly used in dealing with disparity discontinuous areas. However, the algorithm may have higher computational complexity and lack of well-aligned input images. To improve that, this paper presents an improved energy segmentation based stereo matching algorithm. The proposed algorithm incorporates gradient information of each segmented region into the energy function according to the facts that gradients inside the same segmentation should be closer than those from different segmentation. The invalid matching pixels are interpolated with vertical-horizontal nearest neighboring pixels to keep the consistency of stereo image pairs in the initial disparity map. Thus, the proposed method can reduce the deviations and the number of executions of the Random Sample Consensus (RANSAC) which arises from misalignment of input image pairs. Experiments results demonstrate that the proposed algorithm has a better disparity result while the running time is decreased by about 20%.

In view of the problems that the permanent scatterer synthetic aperture radar interferometry (PS-InSAR) technology was limited by the difference of processing algorithms and the professional level of data processing personnel, and its monitoring results were still difficult to fully achieve the theoretical accuracy, a new technical process suitable for the detection of PS-InSAR surface deformation monitoring results was proposed in this paper. Based on the analysis of the characteristics of monitoring results, the inspection work was carried out by means of overall inspection. The test parameters, test objects and test items to be tested, as well as the test methods of different test parameters were determined; The key links of PS-InSAR surface deformation monitoring data processing were analyzed in detail, and the technical flow of mathematical accuracy detection was given. Finally, the quality detection of surface deformation monitoring results based on PS-InSAR technology of 3000 square kilometres were carried out, the results showed that the proposed technical route was feasible and quality evaluation result was objective.

A systematic solution to the one status map (core area) of Beijing - housing thematic data (hereinafter referred to as "the one status map (core area) of housing thematic data") aims to provide housing thematic data with full coverage, high precision, dynamic update and attribute integration, and has the characteristics of "accurate data, fast update, complete attributes and multiple classifications". This paper makes full use of relevant standards and specifications, combined with internal specifications related to data processing and quality evaluation. Based on the analysis of the characteristics and technical requirements of the data, this paper puts forward a quality evaluation system suitable for the data, including quality elements, quality measurement and quality evaluation, so as to provide technical guarantee for ensuring the quality of achievements.

Online camera calibration technology can estimate the pose of the camera onboard in real time, playing an important role in many fields such as HD map production and autonomous vehicles. Some researchers use one vanishing point (VP) to calculate the pitch and yaw angle of the onboard camera. However, this method assumes that the roll angle is zero, which is impractical because of the inevitable installation error. This paper proposes a novel online camera orientation determination method based on a longitudinal vanishing point without the zero-roll hypothesis. The orientation of the camera is determined in two steps: calculating the pitch and yaw angles according to vanishing point theory, and then obtaining the roll angle with lane widths constraint which is modeled as an optimization problem. To verify the effectiveness of our algorithm, we evaluated it on the nuScenes dataset. As a result, the rotation error of the roll and pitch angle can achieve 0.154° and 0.116° respectively. Also, we deployed our method in the “Tuyou”, an autonomous vehicle developed by Wuhan University, and then tested it in the urban structured road. Our proposed method can reconstruct the ground space accurately compared with previous methods with zero-roll hypothesis.

Ambient nitrate has been of increasing concern in PM2.5, while there are still large uncertainties in quantifying the formation of nitrate aerosol. The formation pathways of nitrate aerosol at an urban site and a suburban site in the Pearl River Delta (PRD) are investigated using an observation-constrained box model. Throughout the campaigns, aerosol pollution episodes were constantly accompanied with the increase in nitrate concentrations and fractions at both urban and suburban sites. The simulations demonstrate that chemical reactions in the daytime and at night both contributed significantly to formation of nitrate in the boundary layer at the two sites. However, nighttime reactions predominantly occurred aloft in the residual layer at the urban site, and downward transport from the residual layer in the morning is an important source (53 %) for surface nitrate at the urban site, whereas similar amounts of nitrate were produced in the nocturnal boundary layer and residual layer at the suburban site, which results in little downward transport of nitrate from the residual layer to the ground at the suburban site. We show that nitrate formation was in the volatile-organic-compound-limited (VOC-limited) regime at the urban site, and in the transition regime at the suburban site, identical to the response of ozone at both sites. The reduction of VOC emissions can be an efficient approach to mitigate nitrate in both urban and suburban areas through influencing hydroxyl radical (OH) and N2O5 production, which will also be beneficial for the synergistic control of regional ozone pollution. The results highlight that the relative importance of nitrate formation pathways and ozone can be site-specific, and the quantitative understanding of various pathways of nitrate formation will provide insights for developing nitrate and ozone mitigation strategies.

To absorb the vibration of the car body of the high-speed train in multiple degrees of freedom, a multi-degree of freedom dynamic vibration absorber (MDOF DVA) is proposed. Installed under the car body, the natural frequency of the MDOF DVA from each DOF can be designed as a DVA for every single degree of freedom of the car body. Hence, a 12-DOF model including the main vibration system and an MDOF DVA is established, and the principle of Multi-DOF dynamic vibration absorption is analyzed by combining the design method of a single DVA and genetic algorithm. Based on a high-speed train dynamics model including an under-car-body MDOF DVA, the vibration control effect on each DOF of the MDOF DVA is analyzed by the virtual excitation method. Moreover, a high static and low dynamic stiffness (HSLDS) mount is proposed based on a cam–roller–spring mechanism for the installation of the MDOF DVA due to the requirement of the low vertical dynamic stiffness. From the dynamic simulation of a non-linear model in the time domain, the vibration control performance of the MDOF DVA installed with a nonlinear HSLDS mount on the car body is analyzed. The results show that the MDOF DVA can absorb the vibration of the car body in multiple degrees of freedom effectively and improve the running ride quality of the vehicle.

The global marine biogeochemical cycle of aluminium (Al) is believed to be driven by marine diatoms, due to the uptake of dissolved Al (DAl) by living diatoms from surface seawater. The occurrence of Al in diatom biogenic silica (BSi) can inhibit the dissolution of BSi, thus benefiting the effects of the ballast role of diatoms in the biological pump and forming a coupled Si–Al biogeochemical cycle. However, the occurrence characteristic of Al in marine diatoms is still unclear. In particular, whether or not Al is incorporated into the structure of BSi of living diatoms is unrevealed, resulting in difficulties in understanding the biogeochemical behaviours of Al. In this study, Thalassiosira weissflogii, a widely distributed marine diatom in marginal seas, was selected as the model to evaluate the occurrence of structural Al in BSi based on culturing experiments with the addition of DAl. The structural Al in BSi was detected by combining focused ion beam (FIB) scanning electron microscopy and energy-dispersive X-ray spectroscopy (EDS) mapping analysis. Visible, direct evidence of structural Al in living BSi was obtained, and the distribution and content of this Al were revealed by the EDS-mapping analysis. The effects of structural Al on BSi dissolution–inhibition are discussed based on the content of this Al. The fundamental results indicate the significant contribution of marine diatoms to the biogeochemical migration of marine Al.

The amount of water vapor in the atmosphere is very small, but its content varies greatly in different humidity areas. The change in water vapor will affect the transmission of microwave link signals, and most of the water vapor is concentrated in the lower layer, so the water vapor density can be measured by the change in the near-ground microwave link transmission signal. This study collected 1-year data of the E-band millimeter wave link in Hebei, China, and used a model based on the International Telecommunication Union Radiocommunication Sector (ITU-R) to estimate the water vapor density. An improved method of extracting the water-vapor-induced attenuation value is also introduced. It has a higher time resolution, and the estimation error is lower than the previous method. In addition, this paper conducts the seasonal analysis of water vapor inversion for the first time. The monthly and seasonal evaluation index results show a high correlation between the retrieved water vapor density and the actual water vapor density value measured by the local weather station. The correlation value for the whole year is up to 0.95, the root mean square error is as low as 0.35 g m−3, and the average relative error is as low as 5.00 %. Compared with European Center for Medium-Range Weather Forecast (ECMWF) reanalysis, the correlation of the daily water vapor density estimation of the link has increased by 0.17, the root mean square error has been reduced by 3.14 g m−3, and the mean relative error has been reduced by 34.00 %. This research shows that millimeter wave backhaul link provides high-precision data for the measurement of water vapor density and has a positive effect on future weather forecast research.

The mechanical properties of a magnesium alloy strongly depend on its grain structure. It is desirable to minimize grain growth during the post-forming annealing treatment, thereby minimizing the loss in strength while regaining ductility. In the present research, the annealing of the hot-rolled AZ61 Mg alloy at different temperatures for different times was performed to reveal the kinetics of grain growth, as affected by the precipitation or dissolution of second-phase particles. Three approaches, i.e., experimental, analytical modeling and atomistic simulation were taken and the results were compared. The predictions made from the analytical model and Monte Carlo simulation were both in acceptable agreement with experimental results in terms of the resultant grain sizes. However, the Monte Carlo simulation showed advantages over the analytical model. It was found that with increasing annealing temperature and holding time, the fraction of second-phase particles reduced, which strongly affected the kinetics of grain growth, limiting grain size and grain size homogeneity. The average grain sizes and the largest grain sizes were both taken as the characteristic parameters of the as-annealed microstructure. The results pointed out the importance of choosing an appropriate combination of annealing temperature and time in order to retain second-phase particles during annealing not only for preventing unrestricted grain growth but also for avoiding grain size inhomogeneity.

Measurements of mass and Λ binding energy of Λ4H and Λ4He in Au+Au collisions at sNN=3 GeV are presented, with an aim to address the charge symmetry breaking (CSB) problem in hypernuclei systems with atomic number A = 4. The Λ binding energies are measured to be 2.22±0.06(stat.)±0.14(syst.) MeV and 2.38±0.13(stat.)±0.12(syst.) MeV for Λ4H and Λ4He, respectively. The measured Λ binding-energy difference is 0.16±0.14(stat.)±0.10(syst.) MeV for ground states. Combined with the γ-ray transition energies, the binding-energy difference for excited states is −0.16±0.14(stat.)±0.10(syst.) MeV, which is negative and comparable to the value of the ground states within uncertainties. These new measurements on the Λ binding-energy difference in A = 4 hypernuclei systems are consistent with the theoretical calculations that result in ΔBΛ4(1exc+)≈−ΔBΛ4(0g.s.+)

The linear and the non-linear behaviors of the ion temperature gradient (ITG) mode in a plasma with regularized κ-distributed electrons are investigated using the fluid model. The dispersion relation of the ITG mode obtained on the basis of the local approximation shows that the growth rate of the ITG mode decreases with the increase in the spectral index κ and the exponential cut-off parameter α. It indicates that the presence of the superthermal electron leads to destabilization of the ITG mode, especially in the low κ (κ < 1.5) region. In addition, the existence and the nature of the soliton structure driven by the ITG are studied using the pseudopotential technology. The soliton amplitude increases with the increase in the exponential cut-off parameter α and the spectral index κ, whereas the width of the soliton varies inversely. The present results will help to understand the low-frequency electrostatic wave and nonlinear structure in space and experimental plasmas with non-thermal electrons.

Temozolomide (TMZ) resistance is an important cause of clinical treatment failure and poor prognosis in gliomas. Increasing evidence indicates that cancer-derived exosomes contribute to chemoresistance; however, the specific contribution of glioma-derived exosomes remains unclear. The aim of this study was to explore the role and underlying mechanisms of exosomal macrophage migration inhibitory factor (MIF) on TMZ resistance in gliomas. We first demonstrated that MIF was upregulated in the exosomes of TMZ-resistant cells, engendering the transfer of TMZ resistance to sensitive cells. Our results indicated that exosomal MIF conferred TMZ resistance to sensitive cells through the enhancement of cell proliferation and the repression of cell apoptosis upon TMZ exposure. MIF knockdown enhanced TMZ sensitivity in resistant glioma cells by upregulating Metalloproteinase Inhibitor 3 (TIMP3) and subsequently suppressing the PI3K/AKT signaling pathway. Additionally, exosomal MIF promoted tumor growth and TMZ resistance of glioma cells in vivo, while IOS-1 (MIF inhibitor) promotes glioma TMZ sensitive in vivo. Taken together, our study demonstrated that exosome-mediated transfer of MIF enhanced TMZ resistance in glioma through downregulating TIMP3 and further activating the PI3K/AKT signaling pathway, highlighting a prognostic biomarker and promising therapeutic target for TMZ treatment in gliomas.

HO2 uptake kinetics onto ambient aerosols play pivotal roles in tropospheric chemistry but are not fully understood. Field measurements of aerosol chemical and physical properties should be linked to molecular-level kinetics; however, given that the HO2 reactivity of ambient aerosols is low, traditional analytical techniques are unable to achieve this goal. We developed an online approach to precisely investigate the lower-limit values of (i) the HO2 reactivities of ambient gases and aerosols and (ii) HO2 uptake coefficients onto ambient aerosols (γ) during the 2019 Air QUAlity Study (AQUAS) in Yokohama, Japan. We identified the effects of individual chemical components of ambient aerosols on γ. The results were verified in laboratory studies on individual chemical components: transition metals play a key role in HO2 uptake processes, and chemical components indirectly influence such processes (i.e., by altering aerosol surface properties or providing active sites), with smaller particles tending to yield higher γ values than larger particles owing to the limitation of gas-phase diffusion being smaller with micrometer particles and the distribution of depleting species such as transition metal ions being mostly distributed in accumulation mode of aerosol. The modeling of γ utilized transition metal chemistry derived by previous studies, further confirming our conclusion. However, owing to the high NO concentrations in Yokohama, peroxy radical loss onto submicron aerosols has a negligible impact on O3 production rate and sensitivity regime.