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Large sample datasets are transforming the catchment sciences, but there are few off-the-shelf stream water chemistry datasets with complementary atmospheric deposition, streamflow, meteorology, and catchment physiographic attributes. The existing CAMELS (Catchment Attributes and Meteorology for Large-sample Studies) dataset includes data on topography, climate, streamflow, land cover, soil, and geology across the continental US. With CAMELS-Chem, we pair these existing attribute data for 516 catchments with atmospheric deposition data from the National Atmospheric Deposition Program and water chemistry and instantaneous discharge data from the US Geological Survey over the period from 1980 through 2018 in a relational database and corresponding dataset. The data include 18 common stream water chemistry constituents: Al, Ca, Cl, dissolved organic carbon, total organic carbon, HCO3, K, Mg, Na, total dissolved N, total organic N, NO3, dissolved oxygen, pH (field and lab), Si, SO4, and water temperature. Annual deposition loads and concentrations include hydrogen, NH4, NO3, total inorganic N, Cl, SO4, Ca, K, Mg, and Na. We demonstrate that CAMELS-Chem water chemistry data are sampled effectively across climates, seasons, and discharges for trend analysis and highlight the coincident sampling of stream constituents for process-based understanding. To motivate their use by the larger scientific community across a variety of disciplines, we show examples of how these publicly available datasets can be applied to trend detection and attribution, biogeochemical process understanding, and new hypothesis generation via data-driven techniques.

Lateral carbon flux through river networks is an important and poorly understood component of the global carbon budget. This work investigates how temperature and hydrology control the production and export of dissolved organic carbon (DOC) in the Susquehanna Shale Hills Critical Zone Observatory in Pennsylvania, USA. Using field measurements of daily stream discharge, evapotranspiration, and stream DOC concentration, we calibrated the catchment-scale biogeochemical reactive transport model BioRT-Flux-PIHM (Biogeochemical Reactive Transport–Flux–Penn State Integrated Hydrologic Model, BFP), which met the satisfactory standard of a Nash–Sutcliffe efficiency (NSE) value greater than 0.5. We used the calibrated model to estimate and compare the daily DOC production rates (Rp; the sum of the local DOC production rates in individual grid cells) and export rate (Re; the product of the concentration and discharge at the stream outlet, or load). Results showed that daily Rp varied by less than an order of magnitude, primarily depending on seasonal temperature. In contrast, daily Re varied by more than 3 orders of magnitude and was strongly associated with variation in discharge and hydrological connectivity. In summer, high temperature and evapotranspiration dried and disconnected hillslopes from the stream, driving Rp to its maximum but Re to its minimum. During this period, the stream only exported DOC from the organic-poor groundwater and from organic-rich soil water in the swales bordering the stream. The DOC produced accumulated in hillslopes and was later flushed out during the wet and cold period (winter and spring) when Re peaked as the stream reconnected with uphill and Rp reached its minimum. The model reproduced the observed concentration–discharge (C–Q) relationship characterized by an unusual flushing–dilution pattern with maximum concentrations at intermediate discharge, indicating three end-members of source waters. A sensitivity analysis indicated that this nonlinearity was caused by shifts in the relative contribution of different source waters to the stream under different flow conditions. At low discharge, stream water reflected the chemistry of organic-poor groundwater; at intermediate discharge, stream water was dominated by the organic-rich soil water from swales; at high discharge, the stream reflected uphill soil water with an intermediate DOC concentration. This pattern persisted regardless of the DOC production rate as long as the contribution of deeper groundwater flow remained low ( % of the streamflow). When groundwater flow increased above 18 %, comparable amounts of groundwater and swale soil water mixed in the stream and masked the high DOC concentration from swales. In that case, the C–Q patterns switched to a flushing-only pattern with increasing DOC concentration at high discharge. These results depict a conceptual model that the catchment serves as a producer and storage reservoir for DOC under hot and dry conditions and transitions into a DOC exporter under wet and cold conditions. This study also illustrates how different controls on DOC production and export – temperature and hydrological flow paths, respectively – can create temporal asynchrony at the catchment scale. Future warming and increasing hydrological extremes could accentuate this asynchrony, with DOC production occurring primarily during dry periods and lateral export of DOC dominating in major storm events.

Crowdsourcing of citizens was used to determine the effectiveness of corrosion control in a water distribution system. This study examines the frequency and severity of "Red Water" complaints over a period of 4 years, and two different corrosion control chemicals, polyphosphate and zinc orthophosphate. The data revealed that the frequency of Red Water complaints was higher when using zinc orthophosphate while the severity (higher iron) was higher when using polyphosphates. Varying the dose of zinc orthophosphate to account for cold months induced a greater number of customer complaints. Moreover, corrosion coupons studies suggest similar performance of both corrosion inhibitor products. The corrosion and complaints might be driven by microbial-induced processes in which diatoms might play a significant role.