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Spectroscopic Imaging Scanning Tunneling Microscopy (SI-STM) measurements have previously been applied to the study of the heavy-fermion system CeCoIn5 to examine the superconducting gap structure and band dispersions via quasiparticle intereference. Here we directly measure the dispersing electron bands with angle-resolved photoelectron spectroscopy (ARPES) and compare with first-principles electronic structure calculations. By autocorrelating the ARPES-resolved bands with themselves we can measure the potential q vectors and discern exactly which bands the STM is measuring. We find that the STM results are dominated by scattering associated with a cloverleaf shaped band centered at the zone corners. This same band is also a viable candidate to host the superconducting gap. The electronic structure calculations indicate that this region of the Fermi surface involves significant contributions from the Co d electrons, an indication that the superconductivity in these materials is more three dimensional than that found in the related unconventional superconductors, the cuprates and the pnictides. publishedVersion

A compressive sensing hyperspectral imaging (CS-HSI) platform has been developed for low-cost, standoff, wide area Early Warning of chemical vapor plumes. The sensor, operating in the longwave infrared (LWIR) spectral range with a single-pixel architecture, simultaneously addresses two practical shortcomings of LWIR chemical plume imaging platforms: (1) the single pixel architecture enables an order of magnitude cost reduction relative to HSI sensors employing a cooled focal plane array or high-speed gimbaled scanner, and (2) the inherent imaging modality achieves a favorable pixel fill factor and associated probability of detection for relevant chemical threats relative to single pixel scanned sensors. The CS-HSI employs a low-cost digital micromirror device modified for use in the LWIR spectral range to spatially encode an image of the scene. An LWIR spectrometer employing a tunable Fabry-Perot filter and a mercury cadmium telluride single element photo-detector spectrally resolves the spatially integrated image while mitigating instrument radiance. A CS processing module reconstructs the spatially compressed hyperspectral image where the measurement and sparsity basis functions are specifically tailored to the CS-HSI hardware and chemical plume imaging. An automated target recognition algorithm is applied to the reconstructed hyperspectral data employing a variant of the Adaptive Cosine Estimator for the detection of the chemical plumes in cluttered and dynamic backgrounds. The development, characterization, and a series of capability demonstrations of a prototype CS-HSI sensor are presented. Capability demonstrations include chemical plume imaging of R-134 at mission-relevant concentration pathlength product levels in a laboratory setting.

A high-speed visible/near infrared, shortwave infrared (VNIR/SWIR) hyperspectral imaging (HSI) sensor for airborne, dynamic, spatially-resolved vegetation trait measurements in support of advanced terrestrial modeling is presented. The VNIR/SWIR-HSI sensor employs a digital micromirror device as an agile, programmable entrance slit into VNIR (0.5–1μm) and SWIR (1.2–2.4μm) grating spectrometer channels, each with a two-dimensional focal plane array. The sensor architecture, realized in a 13 lb package, is specifically tailored for deployment on a small rotary wing (hovering) unmanned aircraft system (UAS). The architecture breaks the interdependency between aircraft speed, frame rate, and spatial resolution characteristic of push-broom HSI systems. The approach enables imaging while hovering as well as flexible revisit and/or foveation over a region of interest without requiring cooperation by the UAS. Hyperspectral data cubes are acquired on the second timescale which alleviates the position accuracy requirements on the UAS’s GPS-IMU. The sensor employs a simultaneous and boresighted visible context imager for pan sharpening and orthorectification. The data product is a 384×290 (spatial) ×340 (spectral) format calibrated, orthorectified spectral reflectivity data cube with a 26×20° field of view. The development, characterization, and a series of capability demonstrations of an advanced prototype VNIR/SWIR HSI sensor are presented. Capability demonstrations include ground-based testing as well as flight testing from a commercial rotary wing UAS with remote operation of the HSI sensor via a dedicated ground station.

The high-${T}_{c}$ superconductor, $\mathrm{FeT}{\mathrm{e}}_{0.55}\mathrm{S}{\mathrm{e}}_{0.45}$, has recently been shown to support a surface state with topological character. Here we use low-energy laser-based angle-resolved photoemission spectroscopy with variable light polarization, including both linear and circular polarizations, to reexamine the same material and the related $\mathrm{FeT}{\mathrm{e}}_{0.7}\mathrm{S}{\mathrm{e}}_{0.3}$, with a larger Te concentration. In both cases, we observe the presence of a surface state displaying linear dispersion in a cone-like configuration. The use of circular polarization confirms the presence of a helical spin structure. These experimental studies are compared with theoretical studies that account for the local magnetic effects related to the paramagnetism observed in this system in the normal state. In contrast to previous studies, we find that including the magnetic contributions is necessary to bring the chemical potential of the calculated electronic band structure naturally into alignment with the experimental observations.

The high-${T}_{c}$ superconducting cuprates are recognized as doped Mott insulators. Several studies indicate that as a function of doping and temperature, there is a crossover from this regime into a phase characterized as a marginal Fermi liquid. Several calculations of the doped Mott insulating phase indicate that the Fermi surface defines small pockets which at the higher doping levels switch to a full closed Fermi surface, characteristic of a more metallic system. Here we use femtosecond laser-based pump-probe techniques to investigate the structure of the Fermi surface in the underdoped region of $\mathrm{B}{\mathrm{i}}_{2}\mathrm{S}{\mathrm{r}}_{2}\mathrm{CaC}{\mathrm{u}}_{2}{\mathrm{O}}_{8+\ensuremath{\delta}}$ and compare it with that associated with the optimally doped material. We confirm the concept of a small pocket in the underdoped system consistent with theoretical predictions in this strongly correlated state.

The interplay between the electronic and lattice degrees of freedom in nonequilibrium states of strongly correlated systems has been debated for decades. Although progress has been made in establishing a hierarchy of electronic interactions with the use of time-resolved techniques, the role of the phonons often remains in dispute, a situation highlighting the need for tools that directly probe the lattice. We present the first combined megaelectron volt ultrafast electron diffraction and time- and angle-resolved photoemission spectroscopy study of optimally doped Bi2Sr2CaCu2O8+δ. Quantitative analysis of the lattice and electron subsystems’ dynamics provides a unified picture of nonequilibrium electron-phonon interactions in the cuprates beyond the N-temperature model. The work provides new insights on the specific phonon branches involved in the nonequilibrium heat dissipation from the high-energy Cu–O bond stretching “hot” phonons to the lowest-energy acoustic phonons with correlated atomic motion along the crystal directions and their characteristic time scales. It reveals a highly nonthermal phonon population during the first several picoseconds after the photoexcitation. The approach, taking advantage of the distinct nature of electrons and photons as probes, is applicable for studying energy relaxation in other strongly correlated electron systems. OA gold - CA extern

In complex materials various interactions have important roles in determining electronic properties. Angle-resolved photoelectron spectroscopy (ARPES) is used to study these processes by resolving the complex single-particle self-energy and quantifying how quantum interactions modify bare electronic states. However, ambiguities in the measurement of the real part of the self-energy and an intrinsic inability to disentangle various contributions to the imaginary part of the self-energy can leave the implications of such measurements open to debate. Here we employ a combined theoretical and experimental treatment of femtosecond time-resolved ARPES (tr-ARPES) show how population dynamics measured using tr-ARPES can be used to separate electron–boson interactions from electron–electron interactions. We demonstrate a quantitative analysis of a well-defined electron–boson interaction in the unoccupied spectrum of the cuprate Bi2Sr2CaCu2O8+x characterized by an excited population decay time that maps directly to a discrete component of the equilibrium self-energy not readily isolated by static ARPES experiments., Differentiation of quantum interactions in correlated materials is ambiguous in measurements of the single particle self-energy. Here, Rameau et al. employ a combined theoretical and experimental time domain treatment to separate electron-boson interactions from electron-electron interactions in Bi2Sr2CaCu2O8+x .

In-situ electron microscopy has gained considerable attention in recent years. It provides a “live” view of a material or device under study at various length scales. For example, by heating or cooling a sample one can study structural change at the atomic scale to understand the driving forces and mechanisms of phase transitions. By applying electric and magnetic fields on a ferroelectric or magnetic architecture in operation, one can directly observe how electric and magnetic domains switch, how anions and cations shift their positions, and how spins change their configuration across a domain wall, aiding the development of better electromagnetic devices. In the study of photovoltaic devices and junctions, a major challenge is to directly correlate light-induced electric currents with local structural inhomogeneities and dynamics. Such a capability would allow us to evaluate the performance of individual p-n junctions and to improve optoelectronic efficiency.

Angle-resolved photoemission has developed into one of the leading probes of the electronic structure and associated dynamics of condensed matter systems. As with any experimental technique the ability to resolve features in the spectra is ultimately limited by the resolution of the instrumentation used in the measurement. Previously developed for sharpening astronomical images, the Lucy–Richardson deconvolution technique proves to be a useful tool for improving the photoemission spectra obtained in modern hemispherical electron spectrometers where the photoelectron spectrum is displayed as a 2D image in energy and momentum space.

In the pseudogap phase of the copper oxide superconductors, a significant portion of the Fermi surface is still gapped at temperatures above the superconducting transition temperature T C. Instead of a closed Fermi surface, the low-energy electronic excitations appear to form unconnected Fermi arcs separated by gapped regions. It is generally believed that the spectral function is particle–hole symmetric (at low energies) in both regions—with a peak at the Fermi level on the Fermi arcs and a local minimum at the Fermi level in the gapped regions. Here, using high resolution angle-resolved photoemission and new techniques of analysis, we show that on a sizable portion of the Fermi surface, the electronic structure in the immediate vicinity of the Fermi level is not particle–hole symmetric in the pseudogap phase. This is clear evidence that an alternative ground state competes with the superconductivity. The observations are also consistent with the possibility that the Fermi arcs are, in fact, the inner surface of the predicted Fermi pockets.

The dressing of quasiparticles in solids is investigated by changes in the electronic structure $E$($k$) driven by femtosecond laser pulses. Employing time- and angle-resolved photoemission on an optimally doped cuprate above ${T}_{\mathrm{c}}$, we observe two effects with different characteristic temporal evolutions and, therefore, different microscopic origins. First, a marked change in the effective mass due to the 70-meV kink in $E$($k$) is found to occur during the experiment's 100-fs temporal resolution and is assigned to laser-driven perturbation of an electronic interaction dressing the bare band. Second, a change in ${k}_{\mathrm{F}}$ is explained by effective photodoping due to particle-hole asymmetry and offers opportunities for ultrafast optoelectronic switches based on an optically driven insulator-superconductor transition.

Perfect fluids are characterized as having the smallest ratio of shear viscosity to entropy density, {\eta}/s, consistent with quantum uncertainty and causality. So far, nearly perfect fluids have only been observed in the Quark-Gluon Plasma (QGP) and in unitary atomic Fermi gases (UFG), exotic systems that are amongst the hottest and coldest objects in the known universe, respectively. We use Angle Resolve Photoemission Spectroscopy (ARPES) to measure the temperature dependence of an electronic analogue of {\eta}/s in an optimally doped cuprate high temperature superconductor, finding it too is a nearly perfect fluid around, and above, its superconducting transition temperature Tc., Comment: Article in press with Phys. Rev. B 22 pages, 9 Figures, 41 References

A microscopic scaling relation linking the normal and superconducting states of the cuprates in the presence of a pseudogap is presented using angle-resolved photoemission spectroscopy. This scaling relation, complementary to the bulk universal scaling relation embodied by Homes' law, explicitly connects the momentum-dependent amplitude of the $d$-wave superconducting order parameter at $T\ensuremath{\sim}0$ to quasiparticle scattering mechanisms operative at $T\ensuremath{\gtrsim}{T}_{c}$. The form of the scaling is proposed to be a consequence of the marginal Fermi-liquid phenomenology and the inherently strong dissipation of the normal pseudogap state of the cuprates.

The Fermi surface topologies of underdoped samples of the high-T(c) superconductor Bi2Sr2CaCu2O(8+δ) have been measured with angle resolved photoemission. By examining thermally excited states above the Fermi level, we show that the observed Fermi surfaces in the pseudogap phase are actually components of fully enclosed hole pockets. The spectral weight of these pockets is vanishingly small at the magnetic zone boundary, creating the illusion of Fermi "arcs." The area of the pockets as measured in this study is consistent with the doping level, and hence carrier density, of the samples measured. Furthermore, the shape and area of the pockets is well reproduced by phenomenological models of the pseudogap phase as a spin liquid.

Electron emission from the negative electron affinity (NEA) surface of hydrogen terminated, boron doped diamond in the [100] orientation is investigated using angle resolved photoemission spectroscopy (ARPES). ARPES measurements using 16 eV synchrotron and 6 eV laser light are compared and found to show a catastrophic failure of the sudden approximation. While the high energy photoemission is found to yield little information regarding the NEA, low energy laser ARPES reveals for the first time that the NEA results from a novel Franck-Condon mechanism coupling electrons in the conduction band to the vacuum. The result opens the door to the development of a new class of NEA electron emitter based on this effect.

The Fermi surface topologies of underdoped samples of the high-T(c) superconductor Bi2Sr2CaCu2O(8+δ) have been measured with angle resolved photoemission. By examining thermally excited states above the Fermi level, we show that the observed Fermi surfaces in the pseudogap phase are actually components of fully enclosed hole pockets. The spectral weight of these pockets is vanishingly small at the magnetic zone boundary, creating the illusion of Fermi "arcs." The area of the pockets as measured in this study is consistent with the doping level, and hence carrier density, of the samples measured. Furthermore, the shape and area of the pockets is well reproduced by phenomenological models of the pseudogap phase as a spin liquid.

Laser-based photoemission with photons of energy 6 eV is used to examine the fine details of the very low-energy electron dispersion and associated dynamics in the nodal region of optimally doped Bi2212. A ``kink'' in the dispersion in the immediate vicinity of the Fermi energy is associated with scattering from an optical phonon previously identified in Raman studies. The identification of this phonon as the appropriate mode is confirmed by comparing the scattering rates observed experimentally with the results of calculated scattering rates based on the properties of the phonon mode.

Very high energy resolution photoemission experiments on high quality samples of optimally doped Bi2Sr2CaCu2O8+delta show new features in the low-energy electronic excitations. A marked change in the binding energy and temperature dependence of the near-n

The electronic structure of $p$-type doped \BiTe is studied by angle resolved photoemission spectroscopy (ARPES) to experimentally confirm the mechanism responsible for the high thermoelectric figure of merit. Our ARPES study shows that the band edges are located off the $\Gamma$-Z line in the Brillouin zone, which provides direct observation that the spin-orbit interaction is a key factor to understand the electronic structure and the corresponding thermoelectric properties of \BiTe. Successive time dependent ARPES measurement also reveals that the electron-like bands crossing E$_F$ near the $\underline{\Gamma}$ point are formed in an hour after cleaving the crystals. We interpret these as surface states induced by surface band bending, possibly due to quintuple inter-layer distance change of \BiTe.