1. Investigations of LiNb1−xTaxO3 Nanopowders Obtained with Mechanochemical Method
- Author
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Leonid Vasylechko, Volodymyr Sydorchuk, Andrey Lakhnik, Yuriy Suhak, Damian Wlodarczyk, Stepan Hurskyy, Uliana Yakhnevych, Yaroslav Zhydachevskyy, Dmytro Sugak, Ihor I. Syvorotka, Ivan Solskii, Oleh Buryy, Andrzej Suchocki, and Holger Fritze
- Subjects
nanoparticles ,nanopowders ,lithium niobate-tantalate ,X-ray diffraction ,Raman spectroscopy ,temperature dependence of electroconductivity ,Crystallography ,QD901-999 - Abstract
Nanocrystalline compounds LiNb1−xTaxO3 of various compositions (x = 0, 0.25, 0.5, 0.75, 1) were synthesized by high-energy ball milling of the initial materials (Li2CO3, Nb2O5, Ta2O5) and subsequent high-temperature annealing of the resulting powders. Data on the phase composition of the nanopowders were obtained by X-ray diffraction methods, and the dependence of the structural parameters of LiNb1−xTaxO3 compounds on the value of x was established. As a result of the experiments, the optimal parameters of the milling and annealing runs were determined, which made it possible to obtain single-phase compounds. The Raman scattering spectra of LiNb1−xTaxO3 compounds (x = 0, 0.25, 0.5, 0.75, 1) have been investigated. Preliminary experiments have been carried out to study the temperature dependences of their electrical conductivity.
- Published
- 2021
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