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Chirality ubiquitously appears in nature, however, its quantification remains obscure owing to the lack of microscopic description at the quantum-mechanical level. We propose a way of evaluating chirality in terms of electric toroidal monopole, a practical entity of time-reversal even pseudoscalar (parity-odd) object reflecting relevant electronic wave functions. For this purpose, we analyze a twisted methane at the quantum-mechanical level, showing that the electric toroidal monopoles become a quantitative indicator for chirality. In the twisted methane, we clarify that the handedness of chirality corresponds to the sign of the expectation value of the electric toroidal monopole, and that the most important ingredient is the modulation of the spin-dependent imaginary hopping between the hydrogen atoms, while the relativistic spin-orbit coupling within the carbon atom is irrelevant for chirality., Comment: 11 pages, 8 figures, 5 tables

Magnetic anisotropy is one of the important factors in determining magnetic structures. A type of magnetic anisotropy is closely related to the symmetry of crystals. We theoretically investigate magnetic anisotropy and its related magnetic instability arising from an electric axial moment, which appears under the breaking of the mirror symmetry parallel to the moment but does not require the breakings of both spatial inversion and time-reversal symmetries. By performing perturbation and mean-field calculations in a complementary way, we show the appearance of the in-plane magnetic anisotropy when the electric axial moment occurs, which tends to tilt in-plane spin moments from the crystal axes in collaboration with relativistic spin--orbit coupling. We demonstrate such a tendency for single-site and four-site cluster models, the latter of which leads to the instability toward a spin vortex phase accompanying magnetic monopole and magnetic toroidal dipole., Comment: 9 pages, 8 figures

An electric toroidal dipole (ETD) moment is one of the fundamental dipole moments as well as electric and magnetic ones. Although it directly couples to neither an electric nor magnetic field due to its spatial inversion and time-reversal parities, its ordered state leads to unconventional transverse responses of the conjugate physical quantities. We here theoretically investigate nonlinear transverse magnetic susceptibility under the ETD ordering. By performing a self-consistent mean-field calculation for a five $d$-orbital model under a tetragonal crystalline electric field and using the nonlinear Kubo formula, we show that a third-order transverse magnetic susceptibility corresponding to a uniform magnetization perpendicular to the external magnetic field becomes nonzero once the ETD moment is ordered under tetragonal crystalline electric field. Moreover, we find that spin-orbital entanglement and a low-lying first excited crystal-field level are important for realizing large transverse responses., Comment: 5 pages with 4 figures