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Pore pressure (PP) information is essential for gas hydrate exploration, field development, and other geological modelling studies. The prediction of PP from borehole data is difficult due to the complex (non-linear) relationship between the input (e.g., well log; over-burden stress) and target variables (PP). An ensemble learning-based interpretable method (ELBIM) is proposed to model PP using multivariate borehole data of the IODP expedition 372 drill site U1517A of the Northern Hikurangi Margin, New Zealand. The predictive model is configured by taking input of seven petrophysical parameters (e.g., NMR porosity, caliper, gamma-ray, density, neutron porosity, temperature, and sonic transit time) with lags based on auto-correlation function (ACF) and partial autocorrelation function (PACF) analyses of well log and target PP using empirical techniques (Eaton’s and Porosity method). Comparative analysis showed that the ELBIM with extreme gradient boosting (XGB) regression outperformed gradient boosting machine (GB), random forest regression (RFR), and decision tree regression (DTR) based on root-mean-square errors (RMSEs) RMSEXGB ~0.0087, RMSEGB ~0.0090, RMSERFR~0.0123 and RMSE DTR ~0.0165, and coefficients of determination (R2) of R2XGB ~ 0.9954, R2GB ~ 0.9950, R2RFR ~ 0.9908 and R2DTR ~ 0.9834 between the observation and the prediction of PP with 95% confidence interval (CI). The present analysis suggests that the ELBIM with XGB yields more precise forecasts of PP and exhibits improved detection of the bottom-simulating reflector (BSR) at the drill site. The proposed ELBIM with XGB has the potential to predict the PP from multivariate well logs and could be applied to other complex areas.Highlights: Pore pressure data is vital for field planning, drilling, and geological studies. An ensemble learning-based interpretable method (ELBIM) is proposed for the prediction of PP from well-log data. Autocorrelation and partial auto-correlation analyses were performed. XGB regression outperformed GB, RRF, and DTR regression. The proposed method can be applied to other complex ocean areas. Ensemble-based machine learning approaches can be a handy tool to achieve reasonable accuracy with limited data exposure. [ABSTRACT FROM AUTHOR]

The microfossil record contains abundant, diverse, and well‐preserved fossils spanning multiple trophic levels from primary producers to apex predators. In addition, microfossils often constitute and are preserved in high abundances alongside continuous high‐resolution geochemical proxy records. These characteristics mean that microfossils can provide valuable context for understanding the modern climate and biodiversity crises by allowing for the interrogation of spatiotemporal scales well beyond what is available in neo‐ecological research. Here, we formalize a research framework of "micropaleoecology," which builds on a holistic understanding of global change from the environment to ecosystem level. Location: Global. Time period: Neoproterozoic‐Phanerozoic. Taxa studied: Fossilizing organisms/molecules. Our framework seeks to integrate geochemical proxy records with microfossil records and metrics, and draws on mechanistic models and systems‐level statistical analyses to integrate disparate records. Using multiple proxies and mechanistic mathematical frameworks extends analysis beyond traditional correlation‐based studies of paleoecological associations and builds a greater understanding of past ecosystem dynamics. The goal of micropaleoecology is to investigate how environmental changes impact the component and emergent properties of ecosystems through the integration of multi‐trophic level body fossil records (primarily using microfossils, and incorporating additional macrofossil data where possible) with contemporaneous environmental (biogeochemical, geochemical, and sedimentological) records. Micropaleoecology, with its focus on integrating ecological metrics within the context of paleontological records, facilitates a deeper understanding of the response of ecosystems across time and space to better prepare for a future Earth under threat from anthropogenic climate change. [ABSTRACT FROM AUTHOR]

The alteration of ocean crust through hydrothermal seawater circulation facilitates chemical exchange between Earth's surface and interior. Hydrothermal alteration leads to uranium (U) removal from seawater and net U uptake by the ocean crust, particularly during low temperature alteration that occurs on the vast ocean ridge flanks away from the spreading axes. Determining the timescales of U uptake and its associated 238U/235U signature has important implications for understanding U exchange processes during subduction and recycling into the mantle. Here we study the U systematics of ∼15 million year-old ocean crust drilled at Site 1256 on the eastern flank of the East Pacific Rise. Analysis of cores from the upper ∼1300 m of intact ocean crust at this site, reveal large variability in U concentrations and 238U/235U ratios. Many of the samples from the upper ∼600 m of extrusive lavas have elevated U concentrations and 238U/235U ratios lower than seawater, consistent with mechanisms of U uptake under relatively oxidised conditions. Samples from the underlying sheeted dikes and gabbros show evidence for hydrothermal U mobilisation, but negligible net U uptake. In contrast, in the transition zone between the extrusive lavas and the sheeted dikes, samples revealed large U enrichments and high 238U/235U ratios above seawater. This is consistent with uptake of the reduced U+4 species under relatively reducing conditions from seawater-derived hydrothermal fluids. In addition, large secular disequilibrium in 234U/238U ratios from samples in the lava-dike transition and upper sheeted dikes give evidence for U mobility within the last ∼1.5 million years, likely driven by deep channelled flow of seawater-derived hydrothermal fluids combined with preferential leaching of 234U from the rock matrix. Both the total estimated U uptake and mean 238U/235U at Site 1256 is lower than similar estimates from significantly older (>100 million years) altered ocean crusts at drill Sites 801 and 417/418. This shows the variable total U uptake and 238U/235U ratio in altered ocean crust over time, which needs to be taken into consideration when estimating global U budgets. [ABSTRACT FROM AUTHOR]

This is the second of a two-part New Zealand Journal of Geology and Geophysics Special Issue on understanding sedimentary systems in Aotearoa-New Zealand's Hikurangi Subduction Margin (HSM). This volume includes six research papers that explore sediment-tectonic interactions operating over a range of spatio-temporal scales. We take a distinctive perspective moving from the subduction deformation front in the Hikurangi Trough, upslope to the subduction wedge, and onshore to the Coastal Ranges. Temporally, papers span the onset of subduction in the Miocene, to disentangling provenance of turbidity currents triggered by the 2016 CE Kaikōura Earthquake. Collectively, the studies in the special issue reveal a complicated and continually evolving margin, where active tectonics and volcanism, coupled with vigorous climatic and oceanographic drivers, modulate erosion, transport, and depositional cycles of vast volumes of terrigenous sediment into ocean basins. Despite decades of significant research advances in our knowledge of the HSM, considerable scope remains for future work. A deeper understanding of fundamental tectonic-sediment interactions operating on active margins, along with the significant geohazards they pose remain outstanding research needs. Collectively, Volumes 1 and 2 highlight enduring interest in the HSM as a globally important natural laboratory for the study of subduction zone geoscience. [ABSTRACT FROM AUTHOR]

Glacio-eustatic cycles lead to changes in sedimentation on all types of continental margins. There is, however, a paucity of sedimentation rate data over eustatic sea-level cycles in active subduction zones. During International Ocean Discovery Program Expedition 375, coring of the upper ∼110 m of the northern Hikurangi Trough Site U1520 recovered a turbidite-dominated succession deposited during the last ∼45 kyrs (Marine Isotope Stages (MIS) 1–3). We present an age model integrating radiocarbon dates, tephrochronology, and δ18O stratigraphy, to evaluate the bed recurrence interval (RI) and sediment accumulation rate (SAR). Our analyses indicate mean bed RI varies from ∼322 yrs in MIS1, ∼49 yrs in MIS2, and ∼231 yrs in MIS3. Large (6-fold) and abrupt variations in SAR are recorded across MIS transitions, with rates of up to ∼10 m/kyr occurring during the Last Glacial Maximum (LGM), and <1 m/kyr during MIS1 and 3. The pronounced variability in SAR, with extremely high rates during the LGM, even for a subduction zone, are the result of changes in regional sediment supply associated with climate-driven changes in terrestrial catchment erosion, and critical thresholds of eustatic sea-level change altering the degree of sediment bypassing the continental shelf and slope via submarine canyon systems. [ABSTRACT FROM AUTHOR]

Sedimentological and rock magnetic analysis was performed on 67 turbidite samples recovered from Lithostratigraphic units I–III at IODP Site U1520 with the aim to characterise the sedimentary processes and post-depositional diagenesis within a Quaternary sequence in the Hikurangi Trough, New Zealand. Lithostratigraphic Unit I was rapidly emplaced with frequent turbidite deposition with high sedimentation rate (∼1.9 m/kyr). In contrast, in units II–III, the turbidites were finer grained and more thinly bedded, and were deposited at less than half the deposition rate of Unit I. The turbidites were classified into three clusters based on the magnetic properties. Clusters 1 and 2 are characterised by a high coercivity and SIRM/χ, but low to moderate Bcr/Bc. The recognition of gyroremanent magnetisation acquisition in their clusters indicates the diagenetic sulfidization. Cluster 3 was represented by low coercivity and SIRM/χ, but high Bcr/Bc, indicating lack of sulfidization. Restricted occurrence of Cluster 3 in Unit I may be ascribed to the high sedimentation rate, which prevents sulfidization at the sulfate–methane transition zone. Degree of sulfidization might be related with sedimentary features of turbidites in the trough, such as grain size, bed thickness and depositional rate. [ABSTRACT FROM AUTHOR]

We document an apparent downward displacement of the Matuyama‐Brunhes magnetic reversal by ∼20 m at Scotia Sea International Ocean Discovery Program Site U1538 (Pirie Basin) by comparison with the well‐defined paleomagnetic record at nearby Site U1537 (Dove Basin). Detailed stratigraphic correlation between the two sites is possible due to similar lithologic variations. However, the two sites have distinctly different porewater geochemistry. Notably, Site U1538 indicates a greater demand for electron acceptors to oxidize organic carbon and Fe2+ enrichment below the depth of SO42− depletion. Magnetic parameters indicate enrichment of an authigenic magnetic mineral with strong remanence properties around the depth of SO42− depletion (∼46 m at Site U1538) relative to magnetic parameters at correlative depths at Site U1537. Fe2+ enrichment below the depth of SO42− depletion is not predicted based on the energetically favorable order of electron acceptors for microbial respiration but is documented here and in other depositional settings. This indicates Fe2+ production exceeds the production of H2S by SO42− reduction, providing a geochemical environment that favors the production and preservation of ferrimagnetic remanence‐bearing iron sulfides over paramagnetic pyrite and, thus, a mechanism for deep chemical remanent magnetization acquisition at depths of tens of meters. The influence of authigenic ferrimagnetic iron sulfides on paleomagnetic signals can be difficult to demonstrate with magnetic properties alone; therefore, this finding has implications for evaluating the fidelity of magnetostratigraphic records with complementary geochemical data. Such situations should be considered in other depositional environments with similar porewater Fe2+ accumulation below the SO42− reduction depth. Plain Language Summary: Sediment on the seafloor is an archive of Earth history, including past climate variations, ice sheet dynamics, and geomagnetic field variations. The lattermost include a history of when the Earth's magnetic field flipped upside down in the past so that compass needles would have pointed to the South Pole instead of the North Pole. Scientists have a good understanding of when these flips happened and, once identified in sedimentary layers, the flips can be used to identify time horizons—which are useful for dating other events recorded by the sediment. In this study, we present two magnetic reconstructions from nearby locations that initially recorded the same geomagnetic signals. After deposition, one of the magnetic records changed as a result of chemical reactions that modified the magnetic minerals in the sediment, making it difficult to correlate to the geomagnetic time scale. We have a nearby record with minimal chemical modifications so we could identify the chemical reactions were likely responsible for the changes. This observation will provide additional insights into what signals to look for when studying similar complications from other locations in the world. Key Points: The last magnetic reversal at Scotia Sea Site U1538 is offset downward by ∼20 m compared to the more reliable Site U1537 recordFerrous iron enrichment below the sulfate reduction depth is observed at Site U1538Anomalous magnetic minerals and porewater differences reveal a geochemical setting conducive to chemical remanent magnetization acquisition [ABSTRACT FROM AUTHOR]

The accurate extraction of useful signals from the measurement data is one of the important parts and challenges of the understanding of subsurface information. The desired signal is usually hidden in the background noise, and the amplitude is weak due to the particular geological environment of the subsurface or the consistency of the measuring instrument. By extending the theory of seismic interferometry to include the effects of adjacent virtual channels and by combining super- and reverse-virtual interferometry, we obtain a hybrid virtual interferometry technique based on stacking neighboring virtual traces for wave reconstruction. We have verified the effectiveness of the processing method in suppressing noise interference and extracting useful signals using synthetic data tests. The method is applied to the processing and interpretation of acoustic measurements acquired in a cased borehole of a coal formation and an open hole of an igneous formation, where the processed waveforms are finely reconstructed, and the estimated slowness results are in good agreement with other measurements, thus providing an effective tool for data analysis. [ABSTRACT FROM AUTHOR]

The marine subsurface is a long-term sink of atmospheric carbon dioxide with significant implications for climate on geologic timescales. Subsurface microbial cells can either enhance or reduce carbon sequestration in the subsurface, depending on their metabolic lifestyle. However, the activity of subsurface microbes is rarely measured. Here, we used nanoscale secondary ion mass spectrometry (nanoSIMS) to quantify anabolic activity in 3,203 individual cells from the thermally altered deep subsurface in the Guaymas Basin, Mexico (3-75 m below the seafloor, 0-14°C). We observed that a large majority of cells were active (83%-100%), although the rates of biomass generation were low, suggesting cellular maintenance rather than doubling. Mean single-cell activity decreased with increasing sediment depth and temperature and was most strongly correlated with porewater sulfate concentrations. Intracommunity heterogeneity in microbial activity decreased with increasing sediment depth and age. Using a dual-isotope labeling approach, we determined that all active cells analyzed were heterotrophic, deriving the majority of their cellular carbon from organic sources. However, we also detected inorganic carbon assimilation in these heterotrophic cells, likely via processes such as anaplerosis, and determined that inorganic carbon contributes at least 5% of the total biomass carbon in heterotrophs in this community. Our results demonstrate that the deep marine biosphere at Guaymas Basin is largely active and contributes to subsurface carbon cycling primarily by not only assimilating organic carbon but also fixing inorganic carbon. Heterotrophic assimilation of inorganic carbon may be a small yet significant and widespread underappreciated source of labile carbon in the global subsurface. [ABSTRACT FROM AUTHOR]

Pore pressure (PP) information plays an important role in analysing the geomechanical properties of the reservoir and hydrocarbon field development. PP prediction is an essential requirement to ensure safe drilling operations and it is a fundamental input for well design, and mud weight estimation for wellbore stability. However, the pore pressure trend prediction in complex geological provinces is challenging particularly at oceanic slope setting, where sedimentation rate is relatively high and PP can be driven by various complex geo-processes. To overcome these difficulties, an advanced machine learning (ML) tool is implemented in combination with empirical methods. The empirical method for PP prediction is comprised of data pre-processing and model establishment stage. Eaton's method and Porosity method have been used for PP calculation of the well U1517A located at Tuaheni Landslide Complex of Hikurangi Subduction zone of IODP expedition 372. Gamma-ray, sonic travel time, bulk density and sonic derived porosity are extracted from well log data for the theoretical framework construction. The normal compaction trend (NCT) curve analysis is used to check the optimum fitting of the low permeable zone data. The statistical analysis is done using the histogram analysis and Pearson correlation coefficient matrix with PP data series to identify potential input combinations for ML-based predictive model development. The dataset is prepared and divided into two parts: Training and Testing. The PP data and well log of borehole U1517A is pre-processed to scale in between [-1, þ1] to fit into the input range of the non-linear activation/transfer function of the decision tree regression model. The Decision Tree Regression (DTR) algorithm is built and compared to the model performance to predict the PP and identify the overpressure zone in Hikurangi Tuaheni Zone of IODP Expedition 372. [ABSTRACT FROM AUTHOR]

Abstract We document an apparent downward displacement of the Matuyama‐Brunhes magnetic reversal by ∼20 m at Scotia Sea International Ocean Discovery Program Site U1538 (Pirie Basin) by comparison with the well‐defined paleomagnetic record at nearby Site U1537 (Dove Basin). Detailed stratigraphic correlation between the two sites is possible due to similar lithologic variations. However, the two sites have distinctly different porewater geochemistry. Notably, Site U1538 indicates a greater demand for electron acceptors to oxidize organic carbon and Fe2+ enrichment below the depth of SO42− depletion. Magnetic parameters indicate enrichment of an authigenic magnetic mineral with strong remanence properties around the depth of SO42− depletion (∼46 m at Site U1538) relative to magnetic parameters at correlative depths at Site U1537. Fe2+ enrichment below the depth of SO42− depletion is not predicted based on the energetically favorable order of electron acceptors for microbial respiration but is documented here and in other depositional settings. This indicates Fe2+ production exceeds the production of H2S by SO42− reduction, providing a geochemical environment that favors the production and preservation of ferrimagnetic remanence‐bearing iron sulfides over paramagnetic pyrite and, thus, a mechanism for deep chemical remanent magnetization acquisition at depths of tens of meters. The influence of authigenic ferrimagnetic iron sulfides on paleomagnetic signals can be difficult to demonstrate with magnetic properties alone; therefore, this finding has implications for evaluating the fidelity of magnetostratigraphic records with complementary geochemical data. Such situations should be considered in other depositional environments with similar porewater Fe2+ accumulation below the SO42− reduction depth.

Ice loss in the Southern Hemisphere has been greatest over the past 30 years in West Antarctica. The high sensitivity of this region to climate change has motivated geologists to examine marine sedimentary records for evidence of past episodes of West Antarctic Ice Sheet (WAIS) instability. Sediments accumulating in the Scotia Sea are useful to examine for this purpose because they receive iceberg-rafted debris (IBRD) sourced from the Pacific- and Atlantic-facing sectors of West Antarctica. Here we report on the sedimentology and provenance of the oldest of three cm-scale coarse-grained layers recovered from this sea at International Ocean Discovery Program Site U1538. These layers are preserved in opal-rich sediments deposited ∼1.2 Ma during a relatively warm regional climate. Our microCT-based analysis of the layer's in-situ fabric confirms its ice-rafted origin. We further infer that it is the product of an intense but short-lived episode of IBRD deposition. Based on the petrography of its sand fraction and the Phanerozoic 40Ar/39Ar ages of hornblende and mica it contains, we conclude that the IBRD it contains was likely sourced from the Weddell Sea and/or Amundsen Sea embayment(s) of West Antarctica. We attribute the high concentrations of IBRD in these layers to "dirty" icebergs calved from the WAIS following its retreat inland from its modern grounding line. These layers also sit at the top of a ∼366-m thick Pliocene and early Pleistocene sequence that is much more dropstone-rich than its overlying sediments. We speculate this fact may reflect that WAIS mass-balance was highly dynamic during the ∼41-kyr (inter)glacial world.

On glacial‐interglacial time scales, changes in the Earth's orbital configuration control climate seasonality and mean conditions. Tropical coral skeletons can be sampled at a sufficient resolution to reconstruct past seasonality. Here, last deglacial Porites skeletons from Integrated Ocean Drilling Program Expedition 310 to Tahiti are investigated and, supported by a modern calibration, monthly resolved time series in geochemical proxies (Sr/Ca, δ18O, δ13C) are constructed. For most of the deglaciation, Sr/Ca seasonality was similar to modern (0.139 ± 0.010 mmol mol−1; 2.8 ± 0.2°C) reflecting the small change in insolation seasonality. However, during the Younger Dryas, high values in Sr/Ca seasonality (0.171 ± 0.017 mmol mol−1; 3.4 ± 0.3°C) suggest a reduced mixed layer depth and enhanced influence of the South Pacific Subtropical Gyre due to South Pacific Convergence Zone (SPCZ) inactivity. Furthermore, high amplitudes in Younger Dryas skeletal δ18O (0.40 ± 0.22 ‰) and δ13C (0.86 ± 0.22 ‰) seasonality compared to modern (δ18O = 0.29 ± 0.08 ‰; δ13C = 0.27 ± 0.08 ‰) point to elevated winter‐summer discrepancies in rainfall and runoff. Mean coral Sr/Ca variability suggests an influence of Northern Hemisphere climate events, such as the Younger Dryas cooling (+0.134 ± 0.012 mmol mol−1;−2.6 ± 0.2°C), or the Bølling–Allerød warming (+0.032 ± 0.040 mmol mol−1; −0.6 ± 0.4°C). Deglacial mean coral Δδ18O (δ18Oseawater contribution to skeletal δ18O), corrected for the ice volume effect, was elevated pointing to more saline, thus dryer conditions, likely due to a northward migration of the SPCZ. Seasonal cycles in coral δ13C were likely caused by variations in linear extension rates that were reduced during the last deglaciation (1.00 ± 0.6 cm year−1) compared to today (1.6 ± 0.3 cm year−1). Plain Language Summary: Changes in the Earth's movement around the sun are the primary cause of changes in the annual cycle and annual mean of environmental conditions during the last glacial‐interglacial periods. Distinct from most climate archives, the annual bands of coral skeletons can be sampled at a monthly resolution that allows for reconstructions of past seasonal cycles. In this study, the chemical composition of coral skeletons from the genus Porites that grew during the last deglaciation at Tahiti (∼15,000–9,000 years ago) was analyzed to infer seasonal variations and mean conditions in past sea surface temperature and salinity. Prior to application, the methods were successfully calibrated using modern coral skeletons from Tahiti. Results showed that sea surface temperature seasonality was similar to today during most of the deglaciation. However, for the Younger Dryas, a particular cold interval, a marked increase in sea surface temperature seasonality suggests that Tahiti was at that time located outside the South Pacific Convergence Zone, a rain band extending across the tropical Southwest Pacific. Furthermore, coral reconstructions revealed that, although distant, North Atlantic last deglacial climate events influenced mean climate conditions at Tahiti. In addition, we show that last‐deglacial coral growth rates were reduced compared to today. Key Points: Last deglacial changes in Tahiti coral Sr/Ca suggest an influence of Northern‐Hemisphere climate events on the tropical South PacificVariations in last deglacial Tahitian climate were modulated by meridional migrations of the South Pacific Convergence ZoneLast deglacial Porites corals revealed reduced linear extension rates (1.0 ± 0.6 cm year−1) compared to today (1.6 ± 0.3 cm year−1) [ABSTRACT FROM AUTHOR]

This study characterizes the microstructure and mineralogy of 132 (ODP sample), 1000 and 1880 million‐year‐old chert samples. By using ultra‐small‐angle X‐ray scattering (USAXS), wide‐angle X‐ray scattering and other techniques, the preservation of organic matter (OM) in these samples is studied. The scarce microstructural data reported on chert contrast with many studies addressing porosity evolution in other sedimentary rocks. The aim of this work is to solve the distribution of OM and silica in chert by characterizing samples before and after combustion to pinpoint the OM distribution inside the porous silica matrix. The samples are predominantly composed of alpha quartz and show increasing crystallite sizes up to 33 ± 5 nm (1σ standard deviation or SD). In older samples, low water abundances (∼0.03%) suggest progressive dehydration. (U)SAXS data reveal a porous matrix that evolves over geological time, including, from younger to older samples, (1) a decreasing pore volume down to 1%, (2) greater pore sizes hosting OM, (3) decreasing specific surface area values from younger (9.3 ± 0.1 m2 g−1) to older samples (0.63 ± 0.07 m2 g−1, 1σ SD) and (4) a lower background intensity correlated to decreasing hydrogen abundances. The pore‐volume distributions (PVDs) show that pores ranging from 4 to 100 nm accumulate the greater volume fraction of OM. Raman data show aromatic organic clusters up to 20 nm in older samples. Raman and PVD data suggest that OM is located mostly in mesopores. Observed structural changes, silica–OM interactions and the hydrophobicity of the OM could explain the OM preservation in chert. [ABSTRACT FROM AUTHOR]

Hemipelagic calcareous ooze is a mixture of biogenic carbonate ooze and detrital terrigenous materials from continental weathering. Understanding its early diagenetic features is critical for geophysical measurement and geo-hazard assessment. However, the early diagenesis of hemipelagic calcareous ooze has rarely been studied due to a lack of samples and in-situ measurement in shallow strata. During IODP Expedition 368, hemipelagic calcareous oozes, up to hundreds of meters thick, were encountered in the shallow subsurface (< 400 m) at two sites (U1501 and U1505) close to the continent-ocean transition zone in the northern South China Sea margin. Here, we use coring and well logging data to perform rock physics diagnostics to characterize early diagenetic processes in hemipelagic calcareous ooze. The calcareous ooze in the study area is primarily chalky marl with the ratio of carbonate to carbonate plus siliciclastic minerals ranging 30% ~ 70%, according to a mineralogy-based lithofaices classification scheme. In the chalky marl interval, pyrite accounts for around 15% of the total mineral composition and this existence may be related to significant post-rift magmatic activity that produced significant amouts of volcanic material. The porosity reduction with depth in the chalky marl interval has three phases and carbonate content is suggested to be the controlling factor affecting porosity reduction. The varying carbonate content in the oozes can result in contrasting mechanical properties and porosities, potentially serving as weak layers for submarine landslides. Additionally, the interface between calcareous ooze and siliciclastic sediment is also a potential failure plane. Therefore, we propose that the development of hemipelagic calcareous ooze has significant implications for seafloor instability on continental margins. [ABSTRACT FROM AUTHOR]

Sedimentary beds of alternating red and green colour are commonly interpreted to reflect orbitally‐forced cyclic climatic, syn‐depositional conditions, although colour changes caused by post‐depositional fluids are also documented. Results from IODP Hole U1502A marine sediments in the South China Sea exemplify post‐depositional reducing fluid–rock interactions that locally changed the sediment colour from red to green. Petrographic, rock magnetic and paleomagnetic data on cores show that the red colouration originates from an early, basin‐wide, pervasive diagenetic oxidation event (forming haematite), whereas the green colouration results from subsequent fluid‐driven reduction (forming pyrrhotite‐magnetite). The dense sulfidic stockwork in the basaltic basement underlying these sediments was the likely source of reducing fluids. Drilling deep holes into marine basin basements can thus provide useful information on fluid transfer from the basement to the overlying sedimentary layers. [ABSTRACT FROM AUTHOR]

Abstract Background Marine deep subsurface sediments were once thought to be devoid of eukaryotic life, but advances in molecular technology have unlocked the presence and activity of well-known closely related terrestrial and marine fungi. Commonly detected fungi in deep marine sediment environments includes Penicillium, Aspergillus, Cladosporium, Fusarium, and Schizophyllum, which could have important implications in carbon and nitrogen cycling in this isolated environment. In order to determine the diversity and unknown metabolic capabilities of fungi in deep-sea sediments, their genomes need to be fully analyzed. In this study, two Penicillium species were isolated from South Pacific Gyre sediment enrichments during Integrated Ocean Drilling Program Expedition 329. The inner gyre has very limited productivity, organic carbon, and nutrients. Results Here, we present high-quality genomes of two proposed novel Penicillium species using Illumina HiSeq and PacBio sequencing technologies. Single-copy homologues within the genomes were compared to other closely related genomes using OrthoMCL and maximum-likelihood estimation, which showed that these genomes were novel species within the genus Penicillium. We propose to name isolate SPG-F1 as Penicillium pacificasedimenti sp. nov. and SPG-F15 as Penicillium pacificagyrus sp. nov. The resulting genome sizes were 32.6 Mbp and 36.4 Mbp, respectively, and both genomes were greater than 98% complete as determined by the presence of complete single-copy orthologs. The transposable elements for each genome were 4.87% for P. pacificasedimenti and 10.68% for P. pacificagyrus. A total of 12,271 genes were predicted in the P. pacificasedimenti genome and 12,568 genes in P. pacificagyrus. Both isolates contained genes known to be involved in the degradation of recalcitrant carbon, amino acids, and lignin-derived carbon. Conclusions Our results provide the first constructed genomes of novel Penicillium isolates from deep marine sediments, which will be useful for future studies of marine subsurface fungal diversity and function. Furthermore, these genomes shed light on the potential impact fungi in marine sediments and the subseafloor could have on global carbon and nitrogen biogeochemical cycles and how they may be persisting in the most energy-limited sedimentary biosphere.

Three volcanic arcs have been the source of New Zealand's volcanic activity since the Neogene: Northland arc, Coromandel Volcanic Zone (CVZ) and Taupō Volcanic Zone (TVZ). The eruption chronology for the Quaternary, sourced by the TVZ, is well studied and established, whereas the volcanic evolution of the precursor arc systems, like the CVZ (central activity c. 18 to 2 Ma), is poorly known due to limited accessibility to, or identification of, onshore volcanic deposits and their sources. Here, we investigate the marine tephra record of the Neogene, mostly sourced by the CVZ, of cores from IODP Exp. 375 (Sites U1520 and U1526), ODP Leg 181 (Sites 1123, 1124 and 1125), IODP Leg 329 (Site U1371) and DSDP Leg 90 (Site 594) offshore of New Zealand. In total, we identify 306 primary tephra layers in the marine sediments. Multi‐approach age models (e.g. biostratigraphy, zircon ages) are used in combination with geochemical fingerprinting (major and trace element compositions) and the stratigraphic context of each marine tephra layer to establish 168 tie‐lines between marine tephra layers from different holes and sites. Following this approach, we identify 208 explosive volcanic events in the Neogene between c. 17.5 and 2.6 Ma. This is the first comprehensive study of New Zealand's Neogene explosive volcanism established from tephrochronostratigraphic studies, which reveals continuous volcanic activity between c. 12 and 2.6 Ma with an abrupt compositional change at c. 4.5 Ma, potentially associated with the transition from CVZ to TVZ. Plain Language Summary: Since 18 Ma, volcanic activity in New Zealand is dominantly sourced by the Coromandel Volcanic Zone (CVZ). Most caldera systems of the CVZ identified so far are located on Coromandel Peninsula in the NW of North Island, New Zealand, but studies of the CVZ are rare mainly due to the limited accessibility of its volcanic deposits, as well as missing stratigraphic continuity between different outcrops and the volcanic source. Here, our ocean drilling tephra record—mainly volcanic ash from explosive eruptions, distributed and falling out over the ocean—has a great potential to reveal the eruption history of the CVZ because it is preserved in marine sediments in a nearly undisturbed stratigraphic context. We analyzed ∼400 marine tephra layers from multiple ocean sediment cores off the coast of New Zealand for their geochemical glass compositions and identified 306 as largely undisturbed ash deposits. These primary ash deposits correspond to a total number of 208 Neogene volcanic events. Different dating methods result in a continuous marine tephra record for the last 12 Ma, equivalent to a unique and most complete eruptive history for the CVZ. This enables us to further unravel changes in the composition of the associated magmas with time. Key Points: New Zealand's Neogene explosive volcanism based on the marine tephra recordGeochemical fingerprinting of marine tephra layers across the study area to establish volcanic eventsInsights into geochemical variations with time, repose times and spatiotemporal distribution [ABSTRACT FROM AUTHOR]

Modern grasslands on the Indian subcontinent, North and South America, and East Africa expanded widely during the late Miocene – earliest Pleistocene, likely in response to increasing aridity. Grasses utilizing the C4 photosynthetic pathway are more tolerant of high temperatures and dry conditions, and because they induce less C isotope fractionation than plants using the C3 pathway, the expansion of C4 grasslands can be traced through the δ13C of organic matter in soils and terrigenous marine sediments. We present a high-resolution record of the elemental and isotopic composition of bulk organic matter in the Nicobar Fan sediments from IODP Site U1480, off western Sumatra, to elucidate the timing and pace of the C3–C4 plant transition within the ∼1.5 × 106 km2 catchments of the Ganges/Brahmaputra river system, which continue to supply voluminous Himalaya-derived sediments to the Bay of Bengal. Using a multi-proxy approach to correct for the effects of marine organic matter and account for major sources of uncertainty, we recognize two phases of C4 expansion starting at ∼7.1 Ma, and at ∼3.5 Ma, with a stepwise transition at ∼2.5 Ma. These intervals appear to coincide with periods of Indian Ocean and East Asian monsoon intensification, as well as the expansion of Northern Hemisphere glaciation starting at ∼2.7 Ma. Our data from the deep sea for a multi-phased C4 expansion on the Indian subcontinent are in agreement with terrestrial data from the Indian Siwaliks. [ABSTRACT FROM AUTHOR]

The Cascadia subduction megathrust off the Pacific Northwest follows an "end member" seismogenic behavior, producing large (up to moment magnitude 9) but infrequent (every several hundred years) earthquakes and tsunamis. Crustal deformation associated with the ongoing plate convergence has been characterized by land‐based geodetic observations, but the state of locking across the full breadth of the seismogenic fault is poorly constrained. We report results of offshore monitoring of borehole fluid pressure, as a proxy for formation volumetric strain, at a site ∼20 km landward of the Cascadia subduction deformation front since 2010. The multi‐depth pressure records were plagued by hydrologic noise, but noise at the deepest monitoring level (303 m sub‐seafloor) abated in 2015. Subsequently, including at the times of regional large earthquakes that caused significant dynamic stressing, no persistent pressure transients are present above a threshold of 0.08 kPa imposed by unremovable oceanographic signals, corresponding to a strain detection limit of ∼16 nanostrain. Simple dislocation models using local megathrust geometry suggest a resolvable slip of <1 cm along a trench‐normal corridor beneath the borehole for a range of slip‐patch dimensions. A large slip patch can be well resolved even at considerable along‐strike distances from the borehole; for instance, ∼10 cm slip is detectable over a 200‐km strike range for a slip‐patch radius of ∼50 km. This high sensitivity for detecting slip, along with the lack of observed events, stands in stark contrast to observations at other subduction zones, and suggests that the Northern Cascadia megathrust is most likely fully locked. Plain Language Summary: Subduction thrust faults can produce Earth's largest earthquakes and tsunamis. Estimating the seismic and tsunami potential requires knowing how complete the fault locking is. The Cascadia subduction zone is known to have hosted very large earthquakes, but with the existing measurements of deformation being on land, the state of locking of the shallow sub‐marine portion of the fault remains unclear. Addressing this question requires offshore deformation measurements directly above the shallow fault. In this study, we report results of formation fluid pressure measurement—as a volumetric strain indicator—from a deep‐ocean borehole off Vancouver Island near the deformation front of Cascadia. While data from shallow monitoring depths suffer from noise likely caused by formation gas dynamics, the record from the deepest level (300 m beneath the seafloor) has been sufficiently quiet since mid‐2015 to allow detection of any slip‐triggered pressure variations. Lack of such variations, together with deformation modeling, limits local slip events to be <1 cm. This suggests that the slip deficit of the plate convergence is being accumulated at a substantial rate and it may be released in the next megathrust earthquake. This contrasts with other subduction margins where slip‐related pressure transients have been frequently detected. Key Points: 8‐year formation pressure records from northern Cascadia suggest a lack of tectonic transients despite occasional large dynamic stressingNoise level of the record defines a detection threshold of 0.08 kPa, equivalent to 16 nanostrain for shallow accretionary prism sedimentDeformation modeling shows that the data would resolve local slip down to <1 cm, and thus suggests a fully locked state of the megathrust [ABSTRACT FROM AUTHOR]

Abstract Three volcanic arcs have been the source of New Zealand's volcanic activity since the Neogene: Northland arc, Coromandel Volcanic Zone (CVZ) and Taupō Volcanic Zone (TVZ). The eruption chronology for the Quaternary, sourced by the TVZ, is well studied and established, whereas the volcanic evolution of the precursor arc systems, like the CVZ (central activity c. 18 to 2 Ma), is poorly known due to limited accessibility to, or identification of, onshore volcanic deposits and their sources. Here, we investigate the marine tephra record of the Neogene, mostly sourced by the CVZ, of cores from IODP Exp. 375 (Sites U1520 and U1526), ODP Leg 181 (Sites 1123, 1124 and 1125), IODP Leg 329 (Site U1371) and DSDP Leg 90 (Site 594) offshore of New Zealand. In total, we identify 306 primary tephra layers in the marine sediments. Multi‐approach age models (e.g. biostratigraphy, zircon ages) are used in combination with geochemical fingerprinting (major and trace element compositions) and the stratigraphic context of each marine tephra layer to establish 168 tie‐lines between marine tephra layers from different holes and sites. Following this approach, we identify 208 explosive volcanic events in the Neogene between c. 17.5 and 2.6 Ma. This is the first comprehensive study of New Zealand's Neogene explosive volcanism established from tephrochronostratigraphic studies, which reveals continuous volcanic activity between c. 12 and 2.6 Ma with an abrupt compositional change at c. 4.5 Ma, potentially associated with the transition from CVZ to TVZ.

Abstract The Cascadia subduction megathrust off the Pacific Northwest follows an “end member” seismogenic behavior, producing large (up to moment magnitude 9) but infrequent (every several hundred years) earthquakes and tsunamis. Crustal deformation associated with the ongoing plate convergence has been characterized by land‐based geodetic observations, but the state of locking across the full breadth of the seismogenic fault is poorly constrained. We report results of offshore monitoring of borehole fluid pressure, as a proxy for formation volumetric strain, at a site ∼20 km landward of the Cascadia subduction deformation front since 2010. The multi‐depth pressure records were plagued by hydrologic noise, but noise at the deepest monitoring level (303 m sub‐seafloor) abated in 2015. Subsequently, including at the times of regional large earthquakes that caused significant dynamic stressing, no persistent pressure transients are present above a threshold of 0.08 kPa imposed by unremovable oceanographic signals, corresponding to a strain detection limit of ∼16 nanostrain. Simple dislocation models using local megathrust geometry suggest a resolvable slip of