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Magnetic anisotropy is crucial in examining suitable materials for magnetic functionalities because it affects their magnetic characteristics. In this study, disordered-perovskite RCr0.5Fe0.5O3 (R = Gd, Er) single crystals were synthesized and the influence of magnetic anisotropy and additional ordering of rare-earth moments on cryogenic magnetocaloric properties was investigated. Both GdCr0.5Fe0.5O3 (GCFO) and ErCr0.5Fe0.5O3 (ECFO) crystallize in an orthorhombic Pbnm structure with randomly distributed Cr3+ and Fe3+ ions. In GCFO, the long-range order of Gd3+ moments emerges at a temperature of TGd (the ordering temperature of Gd3+ moments) = 12 K. The relatively isotropic nature of large Gd3+ moment originating from zero orbital angular momentum exhibits giant and virtually isotropic magnetocaloric effect (MCE), with a maximum magnetic entropy change of $$\Delta {S}_{M}$$ Δ S M ≈ 50.0 J/kg·K. In ECFO, the highly anisotropic magnetizations result in a large rotating MCE characterized by a rotating magnetic entropy change $$\Delta {S}_{\theta }$$ Δ S θ = 20.8 J/kg·K. These results indicate that a detailed understanding of magnetically anisotropic characteristics is the key for exploring improved functional properties in disordered perovskite oxides.

The influence of magnetocrystalline anisotropy in antiferromagnets is evident in a spin flip or flop transition. Contrary to spin flops, a spin-flip transition has been scarcely presented due to its specific condition of relatively strong magnetocrystalline anisotropy and the role of spin-flips on anisotropic phenomena has not been investigated in detail. In this study, we present antiferromagnet-based functional properties on an itinerant Ising antiferromagnet Ca0.9Sr0.1Co2As2. In the presence of a rotating magnetic field, anomalous Hall conductivity and anisotropic magnetoresistance are demonstrated, the effects of which are maximized above the spin-flip transition. Moreover, a joint experimental and theoretical study is conducted to provide an efficient tool to identify various spin states, which can be useful in spin-processing functionalities.

A helimagnet comprises a noncollinear spin structure formed by competing exchange interactions. Recent advances in antiferromagnet-based functionalities have broadened the scope of target materials to include noncollinear antiferromagnets. However, a microscopic understanding of the magnetic anisotropy associated with the intricate evolution of noncollinear spin states has not yet been accomplished. Here, we have explored the anisotropic magnetic aspects in a layered helimagnet of EuCo2As2 by measuring the magnetic field and angle dependence of the magnetic torque. By adopting an easy-plane anisotropic spin model, we can visualize the detailed spin configurations that evolve in the presence of rotating magnetic fields. This is directly related to the two distinctive magnetic phases characterized by the reversal of the magnetic torque variation across the helix-to-fan transition. Our advanced approach provides an in-depth understanding of the anisotropic properties of noncollinear-type antiferromagnets and a useful guidance for potential applications in spin-processing functionalities.

Spin-flip transition can occur in antiferromagnets with strong magnetocrystalline anisotropy, inducing a significant modification of the anisotropic magnetic properties through phase conversion. In contrast to ferromagnets, antiferromagnets have not been thoroughly examined in terms of their anisotropic characteristics. We investigated the magnetic-field and angle-dependent magnetic properties of Ising-type antiferromagnetic Ca0.9Sr0.1Co2As2 using magnetic torque measurements. An A-type antiferromagnetic order emerges below TN = 97 K aligned along the magnetically easy c-axis. The reversal of the angle-dependent torque across the spin-flip transition was observed, revealing the strong influence of the magnetocrystalline anisotropy on the magnetic properties. Based on the easy-axis anisotropic spin model, we theoretically generated torque data and identified specific spin configurations associated with the magnetic torque variation in the presence of a rotating magnetic field. Our results enrich fundamental and applied research on diverse antiferromagnetic compounds by shedding new light on the distinct magnetic features of the Ising-type antiferromagnet.

Magnetic properties can be manipulated to enhance certain functionalities by tuning different material processing parameters. Here, we present the controllable magnetization steps of hysteresis loops in double-perovskite single crystals of Eu2CoMnO6. Ferromagnetic order emerges below TC ≈ 122 K along the crystallographic c axis. The difficulty in altering Co2+ and Mn4+ ions naturally induces additional antiferromagnetic clusters in this system. Annealing the crystals in different gas environments modifies the mixed magnetic state, and results in the retardation (after O2-annealing) and bifurcation (after Ar-annealing) of the magnetization steps of isothermal magnetization. This remarkable variation offers an efficient approach for improving the magnetic properties of double-perovskite oxides.

Emerging from competing exchange interactions, the helimagnetic order describes a noncollinear spin texture of antiferromagnets. Although collinear antiferromagnets act as the elemental building blocks of antiferromagnetic (AFM) spintronics, until now, the potential of implementing spintronic functionality in noncollinear antiferromagnets has not been clarified. Here, we propose an AFM helimagnet of EuCo2As2 as a novel single-phase spintronic material that exhibits a remarkable sign reversal of anisotropic magnetoresistance (AMR). The contrast in the AMR arises from two electrically distinctive magnetic phases with spin reorientation that is driven by the magnetic field prevailing in the easy plane, which converts the AMR from positive to negative. Furthermore, based on an easy-plane anisotropic spin model, we theoretically identified various AFM memory states associated with the evolution of the spin structure under magnetic fields. The results revealed the potential of noncollinear antiferromagnets for application in the development of spintronic devices.

We investigated the magnetic and dielectric properties of perovskite HoCr0.5Fe0.5O3. The coexistence of various magnetic interactions resulting from disordered transition-metal ions leads to an intricate temperature dependence of the magnetic properties. From the examination of the temperature dependence of magnetic susceptibility and heat capacity, an antiferromagnetic order of Cr3+/Fe3+ moments arises below TN = 304 K and a spin reorientation transition occurs at TSR = 170 K. In addition, an antiferromagnetic order of Ho3+ spins emerges at THo = 18 K. Based on the sufficiently low dielectric loss below 150 K, excluding the influence of extrinsic effects, a highly nonlinear variation in the isothermal dielectric constant, with a similar hysteretic behavior of the magnetic-field derivative of magnetization, is observed. In comparison to the lack of a noticeable magnetodielectric effect in YCr0.5Fe0.5O3, the strong correlation between magnetic and dielectric order parameters in HoCr0.5Fe0.5O3 suggests the important role of magnetic rare-earth Ho3+ ions. Our results accompanied by intricate magnetic correlations in the disordered HoCr0.5Fe0.5O3 are expected to trigger fundamental and applied research on magnetic materials through the scope of specific magnetic characteristics in disordered perovskites.

Strongly correlated materials with multiple order parameters provide unique insights into the fundamental interactions in condensed matter systems and present opportunities for innovative technological applications. A class of antiferromagnetic honeycomb lattices compounds, A4B2O9 (A = Co, Fe, Mn; B = Nb, Ta), have been explored owing to the occurrence of linear magnetoelectricity. From our investigation of magnetoelectricity on single crystalline Co4Ta2O9, we discovered strongly nonlinear and antisymmetric magnetoelectric behavior above the spin-flop transition for magnetic fields applied along two orthogonal in-plane directions. This observation suggests that two types of inequivalent Co2+ sublattices generate magnetic-field-dependent ferroelectric polarization with opposite signs. The results motivate fundamental and applied research on the intriguing magnetoelectric characteristics of these buckled-honeycomb lattice materials.

We have conducted a terahertz spectroscopic study of antiferromagnetic resonances in bulk orthoferrite YFe1−xMnxO3 0≤x≤0.4. Both the quasi-ferromagnetic resonance mode and the quasi-antiferromagnetic resonance mode in the weak ferromagnetic Γ4 phase disappear near the spin reorientation temperature, TSR, for the onset of the collinear antiferromagnetic Γ1 phase (x ≥ 0.1). Below TSR, an antiferromagnetic resonance mode emerges and exhibits a large blueshift with decreasing temperature. However, below 50 K, this mode softens considerably, and this tendency becomes stronger with Mn doping. We provide a deeper understanding of such behaviors of the antiferromagnetic resonance modes in terms of the influence of the Mn3+ ions on the magnetocrystalline anisotropy. Our results show that terahertz time-domain spectroscopy is a useful, complementary tool in tracking magnetic transitions and probing the interaction between disparate magnetic subsystems in antiferromagnetic materials with multiple ionic species.

Placenta is a special organ that contains many nutrients such as growth factors, minerals, and bioactive peptides. Dipeptides of glycine and leucine are major components of porcine placenta extracts (PPE) that has been used as an alternative of human placenta extracts. In this study, we investigated whether major peptides of PPE, Glycyl-L-Leucine (Gly-Leu), L-Leucyl-Glycine (Leu-Gly), and L-Leucyl-L-Leucine (Leu-Leu), affect skin hydration and elasticity in vitro and in vivo. We found that Gly-Leu and Leu-Gly dipeptides induced the expression of transglutaminase 1 in normal human epidermal keratinocytes (NHEKs) whereas Leu-Leu dipeptides did not. Treatment with Gly-Leu or Leu-Gly significantly increased hyaluronan (HA) synthesis in NHEKs and the upregulation of hyaluronan synthase 2 (HAS2) mRNA level was confirmed. In addition, elastase activity was inhibited in NHEKs treated with Gly-Leu or Leu-Gly dipeptides. Oral administration of Gly-Leu or Leu-Gly dipeptides increased skin hydration and elasticity in UVB-irradiated hairless mice. The significant upregulation of HA in UVB-irradiated hairless mice was observed in response to oral administration of Gly-Leu or Leu-Gly. These results suggest that the major dipeptides of porcine placenta, Gly-Leu and Leu-Gly, are potentially active ingredients for skin moisturization formulations.

This study examined the effects of collagen peptide intake extracted from the tilapia fish (TFCP) on UVB-induced skin in hairless mice. To cause photoaging, the hairless mice were exposed to UVB irradiation three times a week and TFCP was administered with 545 and 1090 mg/kg once a day for 12 weeks. The level of wrinkle formation, thickness of the skin, acute erythema, skin hydration, amount of hydroxyproline, expression of MMPs and filaggrin were measured. Wrinkle formation, thickness of the skin, and acute erythema were significantly lower and skin hydration was higher in the TFCP intake group compared to the UVB-control mice group. In addition, the amount of the collagen and hydroxyproline of the collagen peptide intake group were much higher than the UVB-control group. Oral administration of TFCP inhibited the expression of the MMP-3 and MMP-13 mRNA level as well as activated MMP-2 and MMP-9 induced by UV irradiation, and increased the protein expression of filaggrin in hairless mice skin. In summary, the oral administration of TFCP can inhibit wrinkle formation and protect the skin from UV-damage. Therefore, this study suggests that TFCP is a potential candidate material for skin functional foods.

CW Radar Sensors can be categorized into Single and Dual by its IF output type. Dual IF type is used for detecting the direction of moving objects. However, Dual IF type has more complicated circuitry than Single IF type and higher cost due to more parts required. In this paper, we propose an algorithm for Single IF type CW radar sensors to detect the direction of moving objects. It performs FFT on signals created at IF output when an object moves and determines approach, stop and recede according to amplitude variations. In order to verify the algorithm, a function generator is used to create a virtual signal and confirmed that it accurately detects the directions according to amplitude variations.

The CCTV is limited by weather conditions. To overcome this limitation, we develop a monitoring program that can sense the approach or recede of two or more objects within a surveillance system that uses a continuous-wave (CW) Doppler radar, and we proposed an algorithm to efficiently detect the approach or recede information of the object. The proposed algorithm separates the signal received by the CW Doppler radar into the real and imaginary parts using Fast Fourier Transform (FFT), and sums the amplitudes for each frequency to determine whether the objects are approaching or receding, using their locations. The algorithm is verified by simulations and experiments, which confirms that it successfully detects the approach or recede of two objects.

CPS is potential application in various fields, such as medical, healthcare, energy, transportation, and defense, as well as Industry 4.0 in Germany. Although studies on the equipment aging and prediction of problem have been done by combining CPS with Industry 4.0, such studies were based on small numbers and majority of the papers focused primarily on CPS methodology. Therefore, it is necessary to study active self-protection to enable self-management functions, such as self-healing by applying CPS in shop-floor. In this paper, we have proposed modeling of shop-floor and a dynamic reconfigurable CPS scheme that can predict the occurrence of anomalies and self-protection in the model. For this purpose, SVM was used as a machine learning technology and it was possible to restrain overloading in manufacturing process. In addition, we design CPS framework based on machine learning for Industry 4.0, simulate it, and perform. Simulation results show the simulation model autonomously detects the abnormal situation and it is dynamically reconfigured through self-healing.

Many tunnels are under construction and have been completed due to the topographical characteristic in Korea. Also, further construction will be carried out. Meanwhile, it has been shown that for the fire trend over last 10 years, approximately 13% of overall fire accidents was caused by cars so that the tunnel has the potential risk factor at all times. Therefore, in order to reduce the fire damage of tunnel structures, various studies are under execution in the world but even regulations relating to the evaluation of the fire resistance performance is rarely settled on the tunnel lining in Korea. Therefore, in the study, the explosive spalling and thermal damage will be figured out by the fire resistance test of the concrete tunnel lining so that the results will be utilized as the basic data on the fire resistance design of the tunnel structure. As a result of that, it has been shown that for each case of the test adding the fiber and also without the fiber, the fire damage scope has been reduced as much as approximate 10~30 mm for the concrete and 20~40 mm for the reinforcement.

Quantitative risk assessment (QRA) of railway is to create a variety of scenario and to quantify the degree of risk by a result of the product of accident frequency and accident. Quantitative risk Assessment is affected by various factors such as tunnel specifications, characteristics of the fire, and relation of smoke control and evacuation direction. So in this study, it is conducted that how the way of smoke control and the relation of smoke control and evacuation direction affect quantitative risk assessment with variables (the tunnel length (2, 3, 4, 5, 6 km) and the slope (5, 15, 25‰)). As the result, in a train fire at the double track tunnel (Area

An image sensor can measure only one color per pixel through the color filter array. Missing pixels are estimated using an interpolation process. For this reason, a captured pixel and interpolated pixel have different statistical characteristics. Because the pattern of a color filter array is changed when the image is manipulated or forged, this pattern change can be a clue to detect image forgery. However, the majority of forgery detection algorithms assume that they know the color filter array pattern. Therefore, estimating the configuration of the color filter array can have an important role as a precondition for image forgery detection. In this paper, we propose an efficient algorithm for estimating the Bayer color filter array configuration. We first construct a color difference image to reflect the characteristics of different demosaicing methods. To identify the color filter array pattern, we employ singular value decomposition. The truncated sum of the singular values is used to distinguish the color filter array pattern. Experimental results confirm that the proposed method generates acceptable estimation results in identifying color filter array patterns. Compared with conventional methods, the proposed method provides superior performance.

In the location estimation technology using WLAN, RSSI coming from each AP has a large deviation due to complicated and varying indoor environments. Especially when a laptop is used for work inside a building or when a location-based service is required, the AP needs to be changed depending on RSSI coming from the laptop or the type of work. However, most studies are about hand-over technology between different types of devices based on mobile devices with good portability. Hand-over technology is generally controlled and managed at the server to identify the AP information and select a network quickly. Though this is the best choice to select network and connect communication quickly, any mobile device that is not registered in the server cannot be provided with the service. The current paper proposes a network selection algorithm at the starting point of mobile device as a way to solve the problem through simulation and performance evaluation.

Fire Research Center, Korea Institute of Construction Technology, Hwasung 445-861, KoreaABSTRACT Recently, the trend toward larger architectural structures continues and accelerates demand for Ultra High Strength Concrete (UHSC) which satisfies structural performance. However, UHSC has weakness in fire and the performance tests are required. In this paper, the change of mechanical properties of 100 MPa grade UHSC exposed to high temperatures (20℃~800℃) was observed to develop high temperature ma terial model of UHSC: residual compressive strength, modulus of elasticity, property of stress-strain on monotonous loading and property of stress-strain on cyclic loading. In addition, TG/DTA and SEM Images analyse s were performed to investigate chemical and physical characteristics of UHSC, and the results of this research were compared with those of previous studies. As a result, UHSC at the heating temperature of 300℃ showed a sharp decrease of residual compressive strength and modulus of elasticity . And It was shown that UHSC had a plastic behavior at more than 400 ℃ on the cyclic loading and revealed a same tendency in both monotonous and cyclic loading of all heating temperatures. In addition, through TG/DTA and SEM images analyses compared with those from previous studies, it was shown that the deterioration of concrete inner tissue, water evaporation and chemical reaction caused the decrease of residual compressive strength and modulus of elasticity.Keywords : sultra high-strength concrete, high temperature, cyclic loading, stress-strain curve

In the present study, we successfully developed an eco-friendly chemical etching solution and proper condition for plating on ABS material. The mechanism of forming Ni plating layer on ABS substrate is known as following. In general, the etching solution used for the etching process is a solution of chromic acid and sulfuric acid. The etching solution is given to the surface resulting in elution of butadiene group, so-called anchor effect. Such a rough surface can easily adsorb catalyst resulting in the increase of adhesion between ABS substrate and Ni plating layer. However a use of chromic acid is harmful to environment. It is, therefore, essential to develop a new alternative solution. In the present study, we proposed an eco-friendly etching solution composed of potassium permanganate, sulfuric acid and phosphoric acid. This solution was testified to observe the surface microstructure and the pore size of electrical Ni plating layer, and the adhesive correlation between deposited layers fabricated by electro Ni plating was confirmed. The result of the present study, the newly developed, eco-friendly etching solution, which is a mixture of potassium permanganate 25 g/L, sulfuric acid 650ml/L and phosphoric acid 250ml/L, has a similar etching effect and adhesion property, compared with the commercially used chromium acid solution in the condition at for 5 min.

The modern tunnel tends to be long and deep and therefore has a lot of difficulties for effective smoke ventilation on fire due to the semi-hermetic structure. Also, it has difficulty on evacuation and fire fighting by toxic gases together with high increase rate of temperature. The smoke occurring on fire is to avoid spreading over adjacent area and secure a escape road for prolonging the escape time. Accordingly, test on performance evaluation has been carried out applying air curtain, local smoke extraction facilities, in this study. As a result of the test, it can be seen that the smoke barrier formed by the air curtain has an effect on prevention of the smoke layer spreading. In addition, in the result of the measurement on the carbon monoxide inside and outside the barrier by the air curtain, there was difference of 40-time carbon monoxide inside and outside. Therefore, it has been shown that the effect to prevent the smoke from spreading is expected on fire of the tunnel applying the air curtain.