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Fabrication route of the antifogging coating. [Display omitted] Hydrophilic coating can prevent surface from fogging but its application is limited by low mechanical performance. In this study, a hydrophilic coating was prepared by crosslinking the Si-doped carbonized polymer dot (Si-CPD) with 3-glycidyloxypropyltrimethoxysilane (GPTMS) and ethylene oxide (EO). The hydrophilic coating can be used as robust hydrophilic anti-fogging coating. The Si-CPD derived from ethylene diamine tetraacetic acid (EDTA) and aminopropyl oligosiloxanes (APOS) was successfully prepared via one-step hydrothermal method. Then, a resin solution was prepared by mixing Si-CPD, GPTMS and EO. Epoxy group of GPTMS and EO can react with amino group of Si-CPD. Finally, a composite coating with antifogging function can be obtained by simple heating curing. Due to the introduction of hydroxyl which derived from EO, the coating shows excellent antifogging performance. Meanwhile, the presence of inorganic component endows the coating with outstanding mechanical performance. The coating has great potential in related applications, such as optical lenses, mirrors and other transparency substrates. [ABSTRACT FROM AUTHOR]

Organic–inorganic hybrid thermoelectric (TE) materials have attracted tremendous interest for harvesting waste heat energy. Due to their mechanical flexibility, inorganic‐organic hybrid TE materials are considered to be promising candidates for flexible energy harvesting devices. In this work, enhanced TE properties of Tellurium (Te) nanowires (NWs)‐ poly (3‐hexylthiophene‐2, 5‐diyl) (P3HT) hybrid materials are reported by improving the charge transport at interfacial layer mediated via controlled oxidation. A power factor of ≈9.8 µW (mK2)−1 is obtained at room temperature for oxidized P3HT‐TeNWs hybrid materials, which increases to ≈64.8 µW (mK2)−1 upon control of TeNWs oxidation. This value is sevenfold higher compared to P3HT‐TeNWs‐based hybrid materials reported in the literature. MD simulation reveals that oxidation‐free TeNWs demonstrate better templating for P3HT polymer compared to oxidized TeNWs. The Kang–Snyder model is used to study the charge transport in these hybrid materials. A large σE0 value is obtained which is related to better templating of P3HT on oxygen‐free TeNWs. This work provides evidence that oxidation control of TeNWs is critical for better interface‐driven charge transport, which enhances the thermoelectric properties of TeNWs‐P3HT hybrid materials. This work provides a new avenue to improve the thermoelectric properties of a new class of hybrid thermoelectric materials. [ABSTRACT FROM AUTHOR]

Calcium phosphates (CaPs) and their substituted derivatives encompass a large number of compounds with a vast presence in nature that have aroused a great interest for decades. In particular, hydroxyapatite (HAp, Ca10(OH)2(PO4)6) is the most abundant CaP mineral and is significant in the biological world, at least in part due to being a major compound in bones and teeth. HAp exhibits excellent properties, such as safety, stability, hardness, biocompatibility, and osteoconductivity, among others. Even some of its drawbacks, such as its fragility, can be redirected thanks to another essential feature: its great versatility. This is based on the compound's tendency to undergo substitutions of its constituent ions and to incorporate or anchor new molecules on its surface and pores. Thus, its affinity for biomolecules makes it an optimal compound for multiple applications, mainly, but not only, in biological and biomedical fields. The present review provides a chemical and structural context to explain the affinity of HAp for biomolecules such as proteins and nucleic acids to generate hybrid materials. A size-dependent criterium of increasing complexity is applied, ranging from amino acids/nucleobases to the corresponding macromolecules. The incorporation of metal ions or metal complexes into these functionalized compounds is also discussed. [ABSTRACT FROM AUTHOR]

Novel fibrous cellulosic substrates impregnated with meta-polybenzimidazole (PBI)-stabilized carbon nanotubes/zinc oxide with different weight content of ZnO and with the use of dimethylacetamide as dispersant media. The pristine ZnO nanoparticle powder was prepared by plant extract-mediated synthesis using Vaccinium vitis-idaea L. The green synthesized ZnO possesses an average crystallite size of 15 nm. The formation of agglomerates from ZnO NPs with size 250 nm–350 nm in the m-PBI@CNTs/ZnO was determined. The prepared materials were investigated by PXRD analysis, XPS, SEM, EDS, AFM, and TEM in order to establish the phase and surface composition, structure, and morphology of the hybrids. The potential of the synthesized hybrid composites to degrade methylene blue (MB) dye as a model contaminant in aqueous solutions under UV illumination was studied. The photocatalytic results show that in the course of the photocatalytic reaction, the m-PBI@CNTs/ZnO 1:3 photocatalyst leads to the highest degree of degradation of the methylene blue dye (67%) in comparison with the other two studied m-PBI@CNTs/ZnO 1:1 and 1:2 composites (48% and 41%). The antibacterial activity of ZnO nanoparticles and the hybrid CNT materials was evaluated by the RMDA and the dynamic contact method, respectively. The profound antibacterial effect of the m-PBI@CNTs/ZnO hybrids was monitored for 120 h of exposition in dark and UV illumination regimes. The photocatalytic property of ZnO nanoparticles significantly shortens the time for bactericidal action of the composites in both regimes. The m-PBI@CNTs/ZnO 1:2 combination achieved complete elimination of 5.105 CFU/mL E. coli cells after 10 min of UV irradiation. [ABSTRACT FROM AUTHOR]

A method for the preparation of a hybrid material by modifying the surface of carbon fiber with barium hexaferrite particles using ultrasonic treatment was proposed. Scanning electron microscopy, Raman spectroscopy, and X-ray diffraction were used to identify the barium hexaferrite and to reveal the structural specific features, degree of ordering and homogeneity of the carbon fibers modified with barium hexaferrite. A vibrating magnetometer was used to determine the specific magnetic moment of the obtained hybrid, which was found to be equal to ∼2.03 A m2 kg−1. [ABSTRACT FROM AUTHOR]

This work focuses on the development of a hybrid material based on SBA-15 silica with a molecularly imprinted polymer (MIP), using spiramycin (SPI) as a template, for use as sorbent in solid-phase extraction (SPE). Characterization techniques such as nitrogen gas adsorption–desorption isotherms, infrared spectroscopy and scanning electron microscopy confirmed the structure and properties of the SBA-15@MIP-SPI material. SPE conditions using SBA-15@MIP-SPI as sorbent were optimized, which allowed us to demonstrate the high selectivity and adsorption capacity of SPI on the synthesized material. The best conditions were 50 mg of sorbent, loading with 1 mL of standard solution or sample of cow milk previously extracted in acetonitrile and eluting with 3 mL of methanol with 1% acetic acid. After the optimization process, the material demonstrated recovery percentages of 81 ± 3% in SPI standard solutions and showed its potential in cow milk samples (71 ± 6%). The novelty of the research consists of the combination of MIPs with SBA-15, which could offer important advantages in terms of specific surface area and porous structure, thus improving performance and reducing the amount of sorbent compared to other traditional methods. [ABSTRACT FROM AUTHOR]

Organic-inorganic hybrids are next-generation materials for use in high-performance optoelectronic devices owing to their adaptabilities in terms of design and properties. This article reviews the application of hybrid materials and layers in several widely used optoelectronic devices, i.e., light amplification by stimulated emission of radiation (LASER), solar cells, and light-emitting diodes (LEDs). The effects of the incorporation of inorganic particles on photostability and optical gain are analyzed in the first section with reference to dye and perovskite lasers. Second, the strategies used in blending inorganic nanostructures into organic solar cells and bulk heterojunctions are analyzed. The use of various organic layers as electron- and hole-transport materials in Si heterojunction solar cells is reviewed in detail. Finally, the benefits of the presence of organic components in quantum-dot- and perovskite-based LEDs are derived from the analysis. The integration of organic and inorganic components with optimal interfaces and morphologies is a challenge in developing hybrid materials with improved efficiencies.

In this study, we synthesized a range of spinel ferrite ZnxMg1-xFe2O4 (x = 0, 0.3) forms using the sol-gel method. Additionally, polypyrrole nanosphere supported by magnesium and zinc ferrites (ZnxMg1-xFe2O4@PPy) were synthesized through in-situ polymerisation. The surfaces of ZnxMg1-xFe2O4 (x = 0, 0.3) and ZnxMg1-xFe2O4@PPy were subjected to spectroscopic analysis. The data obtained from X-ray diffraction (XRD) confirmed the formation of Zn-Mg spinel ferrite. The electrochemical analysis results demonstrated that the Zn0.3Mg0.7Fe2O4@PPy nanocomposites exhibited enhanced redox activity and a higher current intensity. This study highlights the development of hybrid Zn0.3Mg0.7Fe2O4@PPy type nanospheres with substantial and effective electrochemical properties, which could be a suitable option for industrial applications. [ABSTRACT FROM AUTHOR]

Organic-inorganic hybrids are next-generation materials for use in high-performance optoelectronic devices owing to their adaptabilities in terms of design and properties. This article reviews the application of hybrid materials and layers in several widely used optoelectronic devices, i.e., light amplification by stimulated emission of radiation (LASER), solar cells, and light-emitting diodes (LEDs). The effects of the incorporation of inorganic particles on photostability and optical gain are analyzed in the first section with reference to dye and perovskite lasers. Second, the strategies used in blending inorganic nanostructures into organic solar cells and bulk heterojunctions are analyzed. The use of various organic layers as electron- and hole-transport materials in Si heterojunction solar cells is reviewed in detail. Finally, the benefits of the presence of organic components in quantum-dot- and perovskite-based LEDs are derived from the analysis. The integration of organic and inorganic components with optimal interfaces and morphologies is a challenge in developing hybrid materials with improved efficiencies. [ABSTRACT FROM AUTHOR]

A parameter investigation for manufacturing a hybrid system through the prepreg pressing process was carried out within the scope of this work to achieve optimal adhesion properties. The hybrid specimen comprises an aluminium sheet of alloy EN AW 6082 in T6 condition and a thermoset Carbon Fibre Reinforced Plastics prepreg. The prepreg pressing process allows the curing reaction of epoxy resin and the joining process to occur simultaneously to avoid an additional bonding process step. The surface of the aluminium sheet was pretreated in advance using a pulsed Nd:YAG laser to enhance the bonding properties. In the first step, the shear edge tests investigated the adhesion properties achieved with different consolidation (temperature, time and pressure) and laser parameters. Then, 3-point bending tests were carried out to investigate the influence of the consolidation parameters on the mechanical properties of the Carbon Fibre Reinforced Plastics-laminate. In this way, the optimal parameter sets for manufacturing hybrid structures were determined. [ABSTRACT FROM AUTHOR]

Abstract Organic–inorganic hybrid thermoelectric (TE) materials have attracted tremendous interest for harvesting waste heat energy. Due to their mechanical flexibility, inorganic‐organic hybrid TE materials are considered to be promising candidates for flexible energy harvesting devices. In this work, enhanced TE properties of Tellurium (Te) nanowires (NWs)‐ poly (3‐hexylthiophene‐2, 5‐diyl) (P3HT) hybrid materials are reported by improving the charge transport at interfacial layer mediated via controlled oxidation. A power factor of ≈9.8 µW (mK2)−1 is obtained at room temperature for oxidized P3HT‐TeNWs hybrid materials, which increases to ≈64.8 µW (mK2)−1 upon control of TeNWs oxidation. This value is sevenfold higher compared to P3HT‐TeNWs‐based hybrid materials reported in the literature. MD simulation reveals that oxidation‐free TeNWs demonstrate better templating for P3HT polymer compared to oxidized TeNWs. The Kang–Snyder model is used to study the charge transport in these hybrid materials. A large σE0 value is obtained which is related to better templating of P3HT on oxygen‐free TeNWs. This work provides evidence that oxidation control of TeNWs is critical for better interface‐driven charge transport, which enhances the thermoelectric properties of TeNWs‐P3HT hybrid materials. This work provides a new avenue to improve the thermoelectric properties of a new class of hybrid thermoelectric materials.

This study investigates the incorporation of hafnium (Hf) into polyurethane foams (PUs), an underexplored area in polymer materials research. The synthesis of Hf-containing PU foams was conducted, and their characterization was performed using Fourier Transform Infrared Spectroscopy (FTIR), X-ray diffraction (XRD), optical microscopy (OM), and dynamic mechanical analysis (DMA). The results revealed a significant increase in the stiffness of PU foams due to the potential formation of hafnium isocyanate. Quantitative values obtained through DMA tests demonstrated an approximate increase of 95.97% for PU Hf 0.5% and 342.72% for PU Hf 3%, compared to the sample without Hf. These data highlight the influence of hafnium on enhancing the mechanical properties of polyurethane foams.

Natural and artificial cells are two common chassis in synthetic biology. Natural cells can perform complex tasks through synthetic genetic constructs, but their autonomous replication often causes safety concerns for biomedical applications. In contrast, artificial cells based on nonreplicating materials, albeit possessing reduced biochemical complexity, provide more defined and controllable functions. Here, for the first time, the authors create hybrid material-cell entities termed Cyborg Cells. To create Cyborg Cells, a synthetic polymer network is assembled inside each bacterium, rendering them incapable of dividing. Cyborg Cells preserve essential functions, including cellular metabolism, motility, protein synthesis, and compatibility with genetic circuits. Cyborg Cells also acquire new abilities to resist stressors that otherwise kill natural cells. Finally, the authors demonstrate the therapeutic potential by showing invasion into cancer cells. This work establishes a new paradigm in cellular bioengineering by exploiting a combination of intracellular man-made polymers and their interaction with the protein networks of living cells.

The analysis of a critical buckling temperature is dependent on the new displacement function field provided in the literature and uses third-order shear deformation theory. The value of the parameter “m,” which determines the new displacement function, closed with the three-dimensional (3D) elasticity results. Thermal critical buckling is analyzed for thick and thin laminated plates by using the Navier solution for symmetric and anti-symmetric cross-ply simply supported boundary conditions. Several design parameters are considered such as extension thermal coefficient ratio (α 1⁄α 2), number of schemes, thickness ratio (a/h), aspect ratio (a/b), and modular ratio (E 1/E 2) when analyzing the dynamic behavior of the critical buckling temperature for different materials, including composite (glass/epoxy) and hybrid (glass/carbon/epoxy), under uniformly distributed temperature load. The accuracy for theoretical results by using Matlab R2019b was checked with other results for different researchers and gave good agreement. Increasing orthotropic ratio and aspect ratio resulted in increasing critical buckling temperature in M1 than M2, whereas increasing thickness ratio, thermal coefficient expansion, and number of layers resulted in decrease in critical buckling temperature in M2 than M1.

Recent innovations in nanomaterials inspire abundant novel tumor-targeting CRISPR-based gene therapies. However, the therapeutic efficiency of traditional targeted nanotherapeutic strategies is limited by that the biomarkers vary in a spatiotemporal-dependent manner with tumor progression. Here, we propose a self-amplifying logic-gated gene editing strategy for gene/H2O2-mediated/starvation multimodal cancer therapy. In this approach, a hypoxia-degradable covalent-organic framework (COF) is synthesized to coat a-ZIF-8 in which glucose oxidase (GOx) and CRISPR system are packaged. To intensify intracellular redox dyshomeostasis, DNAzymes which can cleave catalase mRNA are loaded as well. When the nanosystem gets into the tumor, the weakly acidic and hypoxic microenvironment degrades the ZIF-8@COF to activate GOx, which amplifies intracellular H+ and hypoxia, accelerating the nanocarrier degradation to guarantee available CRISPR plasmid and GOx release in target cells. These tandem reactions deplete glucose and oxygen, leading to logic-gated-triggered gene editing as well as synergistic gene/H2O2-mediated/starvation therapy. Overall, this approach highlights the biocomputing-based CRISPR delivery and underscores the great potential of precise cancer therapy.

Amorphous CoO/Al 2 O 3 /C hybrids were synthesized using a simple pyrolysis method at various temperatures and reagent ratios. At 500 °C, CoO localized from homogenous distribution to quantum dots (∼10 nm) on the Al 2 O 3 /C matrix. X-ray photoelectron spectroscopy results suggested that the feed nitrate ions doped the hybrids with pyridinic (398.8 eV) and pyrrolic (400.55 eV) N, which ameliorated the electrochemical performance of the hybrids. The optimum pyrolysis temperature to obtain a reversible capacity of 0.45 Ah g−1 at the 1000th cycle at a current density of 1 A g−1 was 500 °C. However, owing to the polarization electrode, the specific capacity decreased by 54 % after increasing the material mass loading (0.5–3 mg cm−2), which resulted in a maximum areal capacity of 0.78 mAh cm−2. After regulating the C content in the hybrid, the loss in reversible capacity was only 29 % for an eight-fold gain in the mass-loading (0.4–3.2 mg cm−2) and the areal capacity was up to 1.13 mAh cm−2. The specific capacity of the optimized electrode was 0.52 Ah g−1 at the 1000th cycle. In addition, it only lost 28 % of its capacity along with a ten-fold increase in current density (0.2–2 A g−1). In a full cell test involving a LiNi 0.8 Mn 0.1 Co 0.1 O 2 -based cathode and a CoO/Al 2 O 3 /C-based anode, 91 % of the maximum theoretical specific capacity was obtained, whereas the capacity retention at the 100th cycle was 97 %. Electrochemical impedance spectra suggested that small resistances (<38 Ω) and high Li+ diffusivity (5.5–6.8 × 10−11 cm2 s−1) supported the fast-charging properties of the hybrid. [Display omitted] • Pyrolysis temperature affects CoO/Al 2 O 3 /C hybrid's cyclability via CoO's distribution. • Increasing C content in the hybrid improves electrode's polarization. • Current density, capacity balance, and electrolyte affects a full-cell's performance. [ABSTRACT FROM AUTHOR]

The hybrid material AlCo2P3O4·1/2H2O: DIMPPZ (AlCoP-DIMPPZ; 1, 4-Dimethyl piperazine: DIMPPZ) was synthesized hydrothermally at 453 K and characterized by X-ray diffraction (XRD), FT-IR and diffuse reflectance spectroscopies, SEM / EDX analysis. The crystal symmetry is rhombohedral and the XRD pattern is consistent with a single phase (S.G. R 3 -) isotypic to ACP-CHA9 (C4) AlCo2P3O4·1/2H2O with cell parameters in the hexagonal description: a = 13.5494 Å and c = 15.2795 Å. The optical study revealed a direct electronic transition at 1.82 eV, assigned to lift of degeneracy of CoII in a low spin configuration tetrahedrally bonded. The SEM image showed a more or less homogeneous morphology with similar grain sizes ranging from 3.5 to 6 μm whereas the FT-IR spectrum exhibits characteristic peaks of (PO4)3− units and C=C bonds. To our knowledge, no photo-electrochemistry has been reported to date and the low exchange current density (~ 2 mA cm−2) is consistent with the electrochemical stability in Na2SO4 (0.1 M) solution. The dependence of the interfacial capacitance (C−2) on the potential (E) is typical of n-type behaviour with an electron density (ND) of 2.14 × 1018 cm−3 and a flat band potential (Efb) of 0.59 VSCE. The valence band with an energy of 7.10 eV /vacuum (2.35 VSCE) derives from 3d wave function originating from Co2+ ion. The semicircle at high frequencies in the electrochemical spectroscopy with an impedance of 910 Ω cm2 is due to the intrinsic property, which decreases to 750 Ω cm2 under visible light, corroborating the semi conductivity of the material. As application, the hybrid material was tested for the first time for the oxidation of Methyl Violet (MV), with an abatement of 65% under visible light (15 mW cm−2) for 420 min while the adsorption of 33%. Based on the energy diagram, the title compound will be used as O2 photo electrode. [ABSTRACT FROM AUTHOR]

Carbon nanotubes (CNTs), as one-dimensional nanomaterials, have excellent electrical, thermal and mechanical properties, and are widely used as reinforcing agents for composite materials. Herein, the electrical and mechanical properties of different types of hybrid structure based on carbon nanotubes are reviewed, i.e., carbon/particles, carbon nanotube/fiber, carbon nanotube/pieces of foam layer, carbon nanotube/lightweight materials, where the underline mechanism for the enhancement of the electrical and mechanical properties are analyzed, in together with the advantages of different hybrid structures. The present review shed lights on the construction and design of carbon nanotube-based hybrid materials in the future. [ABSTRACT FROM AUTHOR]

The selective fixation of CO2 and epoxides into cyclic carbonates offers an atom-economical approach towards promising utilization of anthropogenic CO2 gas. This work demonstrates the development of recyclable organic–inorganic hybrid TBAI@CuO catalyst containing quaternary ammonium (TBAI) salt as active organic groups and CuO flowers as the inorganic component. Initially, CuO flowers was synthesized using a simple oxidation-precipitation method followed by immobilization of TBAI groups using impregnation method. The impregnated TBAI groups functioned as the active basic centers, whereas CuO flowers with effective surface area provided heterogeneity, Lewis acidic sites, facilitated better dispersion and strong interaction of TBAI. Resultantly, hybrid TBAI@CuO catalyst consisted of dual-active sites which played a decisive role in manipulating catalytic activity without requirement of a co-catalyst. With styrene oxide and CO2 as model substrates, the present catalyst system delivered 95% conversion and 97% selectivity towards styrene carbonate under solvent-free and milder reaction conditions when compared to other single metal oxide catalysts. The homogeneously dispersed TBAI groups in strong interaction with CuO flowers provided simultaneous access to both Lewis acidic as well as basic sites and hence resulted in superior catalytic activity. Meanwhile, hybrid TBAI@CuO catalyst showed catalytic adequacy for various terminal and internal epoxides. This catalytic system also presented good reusability without prominent loss in activity and no leaching of active TBAI groups. Based on characterization results, a plausible reaction mechanism was predicted to support the cycloaddition reaction with hybrid TBAI@CuO catalyst. It was proposed that inorganic Lewis acidic CuO activated the epoxide whereas the immobilized TBAI groups activated the inert CO2 molecule and stabilized the epoxide after ring opening. Therefore, the CuO flowers acting in concert with the immobilized TBAI groups showed exceptional acid–base cooperativity and provided high selectivity towards cyclic carbonates. The hybrid TBAI@CuO catalyst in this effort bridges the gap between homogeneous and heterogeneous catalysis for sustainable transformation of CO2 and epoxides to cyclic carbonates under solvent-free and comparatively mild reaction conditions [ABSTRACT FROM AUTHOR]

In this study, a cryogel/nanofiber hybrid material was developed using a new lotus-leaf-inspired strategy. The lotus effect was generated via beaded poly(ε-caprolactone) (PCL) nanofibers produced from the 9 wt% PCL solution with low viscosity and high surface tension via electrospinning. A poly(hydroxyethyl methacrylate) (PHEMA) cryogel layer was constructed through polymerization onto the beaded PCL nanofibrous mat. The thickness of the PHEMA cryogel/beaded PCL nanofiber hybrid material was 3.19 ± 0.07 mm. Morphological characterization studies of the hybrid material were conducted by scanning electron microscopy (SEM). The mean diameter of the beaded PCL nanofibers was 97.22 ± 21.18 nm. The lotus effect created by the beaded PCL nanofibers was investigated by water contact angle (WCA) measurements. The WCA of beadless and beaded PCL nanofibers was 93.42° ± 1.4° and 117.97° ± 5.04°, respectively. The PHEMA cryogel layer was chemically characterized via Fourier transform infrared spectroscopy (FTIR) analysis and the specific groups belonging to 2-hydroxyethyl methacrylate (HEMA) was observed. The porosity of the PHEMA cryogel layer was determined via mercury porosimetry. The total porosity of the PHEMA cryogel was 64.42%, and the pore sizes were in the range of 5–200 µm. Swelling kinetics of the PHEMA cryogel/beaded PCL nanofiber hybrid material were also investigated and compared to those of PHEMA cryogel and beaded PCL nanofibers. The maximum swelling ratio of the hybrid material was 509.69% and reached after 180 min. The developed PHEMA cryogel/beaded PCL nanofiber hybrid material met the criteria required for layered structures and biomedical applications whereby its eligible stability, morphology, porosity, and swelling capacity. Consequently, the lotus-leaf-inspired strategy was successful in constructing the cryogel/nanofiber hybrid materials. [ABSTRACT FROM AUTHOR]

Inorganic‐organic hybrid materials are a kind of multiduty materials with high crystallinity and definite structures, built from functional inorganic and organic components with highly tunable photochemical properties. Perylenediimides (PDIs) are a kind of strong visible light‐absorbing organic dyes with π‐electron‐deficient planes and photochemical properties depending on their micro‐environment, which provides a platform for designing tunable and efficient hybrid photocatalytic materials. Herein, four radical‐doped PDI‐based crystalline hybrid materials, Cl4‐PDI⋅SiW12O40 (1), Cl4‐PDI⋅SiMo12O40 (2), Cl4‐PDI⋅PW12O40 (3), and Cl4‐PDI⋅PMo12O40 (4), were attained by slow diffusion of polyoxometalates (POMs) into acidified Cl4‐PDI solutions. The obtained PDI‐based crystalline hybrid materials not only exhibited prominent photochromism, but also possessed reactive organic radicals under ambient conditions. Furthermore, all hybrid materials could be easily photoreduced to their radical anions (Cl4‐PDI⋅−), and then underwent a second photoexcitation to form energetic excited state radical anions (Cl4‐PDI⋅−*). However, experiments and theoretical calculations demonstrated that the formed energetic Cl4‐PDI⋅−* showed unusual POM‐dependent photocatalytic efficiencies toward the oxidative coupling of amines and the iodoperfluoroalkylation of alkenes; higher photocatalytic efficiencies were found for hybrid materials 1 (anion: SiW12O404−) and 2 (anion: SiMo12O404−) compared to 3 (anion: PW12O403−) and 4 (anion: PMo12O403−). The photocatalytic efficiencies of these hybrid materials are mainly controlled by the energy differences between the SOMO‐2 level of Cl4‐PDI⋅−* and the LUMO level of the POMs. The structure‐photocatalytic activity relationships established in present work provide new research directions to both the photocatalysis and hybrid material fields, and will promote the integration of these areas to explore new materials with interesting properties. [ABSTRACT FROM AUTHOR]

The major source of water pollution is industrial wastewater containing dyes. In the current study, the adsorptive removal of Golden Yellow-XGL dye using green hybrid materials was optimized in the batch approach. The characterization study through SEM, TGA–DSC and XRD showed good porosity, enhanced thermal stability and successful formation of materials while FTIR study confirmed efficient adsorption of dye. The highest adsorption potential for RH (36.9 mg/g), RH–ZnO–PTh (48.9 mg/g), RH–ZnO–PANI (57.8 mg/g) and RH–ZnO–PPy (64.9 mg/g) was obtained at optimized conditions. The adsorption data showed better fitness to pseudo-second-order kinetics and Langmuir sorption isotherm. Thermodynamic study showed exothermic nature of sorption. The mechanism of adsorption was proposed. Desorption and recycling study showed successful reusability of the material up to five cycles. All the results obtained proved these materials to be more efficient, cost effective, ecofriendly, stable and good alternative for dye removal. [ABSTRACT FROM AUTHOR]

[Display omitted] Metalenses have outstanding light-modulating performances, and studies have been conducted on them to not only replace conventional bulky and heavy refractive lenses but also to expand on them. However, their operating wavelengths have rarely covered the ultraviolet (UV) regime since UV-transparent materials are scarce and nanopatterning techniques have a small patterning area, high cost, and low throughput. These limitations are overcome in this study, and centimeter-scale and highly efficient UV metalenses are successfully mass-produced. The UV metalens is designed to operate at a wavelength of 325 nm, with a numerical aperture of 0.2. Argon fluoride photolithography is used to fabricate an 8-inch master stamp in which 300 metalenses are patterned in an array with a high resolution. The fabricated master stamp can be duplicated repeatedly using wafer-scale nanoimprint lithography. To improve efficiency, we developed a zirconium dioxide–polymer hybrid material that is scalable, easily manufacturable, UV-transparent, and high-index material. The experimental results confirm that the mass-produced metalenses operate as ideal imaging systems, exhibiting an average measured efficiency of 45.1 %. [ABSTRACT FROM AUTHOR]

Pollution of water is mainly due to industrial wastewater. In current research work, Blue-XGRRL dye removal using green hybrid materials was optimized via batch and column study. The characterization study of prepared materials was carried out via scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), Fourier transform infra-red (FTIR) spectroscopy, and thermal analysis. The pH for maximum adsorption capacity of wheat straw (WS), wheat straw-zinc oxide-polythiophene (WS-ZnO-PTh), wheat straw-zinc oxide-polyaniline (WS-ZnO-PANI), and wheat straw-zinc oxide-polypyrrole (WS-ZnO-PPY) was determined to be 10 (14.6 mg g−1), 10 (31 mg g−1), 10 (37.8 mg g−1), and 11 (43.9 mg g−1) correspondingly and optimum dosage was determined to be 0.05 g/50 mL. The highest adsorption potential for all hybrid materials was achieved within a time duration of 60 min and highest adsorption potential for WS (30.7 mg g−1), WS-ZnO-PTh (43.8 mg g−1), WS-ZnO-PANI (55.8 mg g−1), and WS-ZnO-PPy (66.8 mg g−1) was obtained utilizing 100 mg L−1 dye at 30 °C. The data obtained through adsorption experiments presented the best fitness to pseudo-second-order kinetics and Langmuir sorption isotherm giving significant R2 values of 0.94–0.99 and 0.994–0.9994 respectively. Thermodynamic study showed exothermic nature of sorption. During column approach, optimal adsorbent bed height, dye flow rate, and inlet initial dye concentration to attain highest adsorption (30 mg g−1) were determined to be cm, 1.8 mL min−1, and 70 mg L−1 respectively indicating these materials a good alternative for dye removal. [ABSTRACT FROM AUTHOR]

Featured Application: Application of some hybrid materials as coagulation–flocculation agents in single or combined treatment steps for colored wastewater (industrial dye-containing effluents). Polluting species released in industrial-colored effluents contaminate water, degrading its quality and persisting in the aquatic environment; therefore, it must be treated for safe discharge or onsite reuse/recycling to ensure a fresh water supply. This review has the principal goal of facilitating understanding of some important issues concerning wastewater (WW) treatment systems, mainly based on a coagulation–flocculation step, as follows: (i) the significance of and facilities offered by specialized treatment processes, including the coagulation–flocculation step as a single or associated step (i.e., coagulation–flocculation followed by sedimentation/filtration or air flotation); (ii) the characteristics of industrial-colored WW, especially WW from the textile industry, which can be reduced via the coagulation–flocculation step; (iii) primary and secondary groups of hybrid materials and their characteristics when used as coagulants–flocculants; (iv) the influence of different process operating variables and treatment regimens on the efficiency of the studied treatment step; and (v) the benefits of using hybrid materials in colored WW treatment processes and its future development perspectives. The consulted scientific reports underline the benefits of applying hybrid materials as coagulants–flocculants in colored textile WW treatment, mainly fresh, natural hybrid materials that can achieve high removal rates, e.g., dye and color removal of >80%, heavy metals, COD and BOD of >50%, or turbidity removal of >90%. All of the reported data underline the feasibility of using these materials for the removal of colored polluting species (especially dyes) from industrial effluents and the possibility of selecting the adequate one for a specific WW treatment system. [ABSTRACT FROM AUTHOR]

Herein, the well-designed hybrid materials composed of Fe2O3 nanoparticles embedded in hierarchical porous carbon matrix (HPCs/Fe2O3) were prepared by a two-step approach, involving a salt template route followed by hydrothermal treatment. The hierarchical porous structure not only serves as a buffer matrix to alleviate the volume expansion of Fe2O3 nanoparticles, but also provides a large surface area and high electrical conductivity, resulting in significant improvement of electrochemical performance. HPCs/Fe2O3-2 anode delivers a high reversible capacity of 1357.60 mAh g−1 after 100 cycles at 0.2 A g−1 and an outstanding rate behavior. It also exhibits an excellent cycling-life stability of 472.3 mAh g−1 after 1000 cycles at a high current density of 5 A g−1, suggesting its potential application in LIBs anode. [ABSTRACT FROM AUTHOR]

High-performance biomaterials were aimed to be prepared for bone regeneration by hybridizing borosilicate with poly-(vinyl alcohol)-s (PVAs), incorporating Ca-(II) sources, and formulating the resulting composites into mesoporous aerogels. The hybridization of borosilicate with different molecular weight PVAs was realized in a sol–gel procedure, yielding homogeneous hydrogels. These gels were functionalized in the sol–gel process by microcrystalline Ca-(II) sources [CaCl2, β-Ca3(PO4)2, hydroxyapatite/Ca10(PO4)6(OH)2], and finally converted to nanostructured monolithic aerogels by solvent exchange and drying in supercritical CO2. The chemical structures of the solid backbones were elucidated by infrared spectroscopy and solid-state NMR. Energy-dispersive X-ray spectroscopy, elemental analysis, and X-ray diffraction were used to characterize the incorporated Ca-(II) sources. The nanoscale morphological features of the functionalized hybrid aerogels were characterized using scanning and transmission electron microscopy, N2 porosimetry, and small-angle neutron scattering (SANS). Contrast variation SANS measurements confirmed the formation of a homogeneous yet nanostructured hybrid from borosilicate and PVA in all cases. In vitro tests were performed in the presence of suspended aerogel microparticles using the MG-63 osteosarcoma cell line and dental pulp stem cells. Quantitative time-lapse video microscopy measurements demonstrated the biocompatibility and biostimulating effect of the hybrid aerogel particles. These beneficial properties are attributed to the carefully designed chemical composition, porosity, and negative ζ-potential of the aerogel particles. [ABSTRACT FROM AUTHOR]

The synthesis and twin polymerization (TP) of Si(OCH2py)4 (3 a, py=2‐cC5H4N; 3 b, py=3‐cC5H4N; 3 c, py=4‐cC5H4N) is discussed. The solid state structures of 3 b, c were confirmed by single‐crystal X‐ray crystallography showing non‐conventional H‐bonding, forming 2D chains (3 b) or 3D networks (3 c). Thermally induced TP of 3 a–c and their simultaneous polymerization with 2,2'‐spiro‐bi[4H‐1,3,2‐benzodioxasiline] (4) is described. The resulting hybrid materials were characterized by 1H, 13C{1H}, and 29Si{1H} CP MAS NMR spectroscopy confirming the transformation of the SiOCH2 moieties into CH2 groups enabling the formation of the respective polymers. These results were supported by HAADF‐STEM studies, displaying micro‐structuring. Nitrogen‐containing porous carbon materials C_1–C_3 show surface areas of 1300 and 1700 m2 g−1, large pore volumes between 0.6–1.2 cm3 g−1, and nitrogen contents of up to 3.1 at‐%. X‐ray photoemission spectroscopy reveal that pyrrolic, pyridine, and pyridone nitrogen atoms are present. If equimolar amounts of 3 a–c and 4 are simultaneously polymerized in the presence of [Pd(OAc)2] (5), then the Pd nanoparticle‐decorated material Pd@C_3 (900 m2 g−1) was obtained, which showed k values of −0.083 and −0.066 min−1 in the reduction of methylene blue and methyl orange, proving the accessibility of the Pd NPs. [ABSTRACT FROM AUTHOR]

The main objective of this study was to discover new packaging materials that could integrate one of the most expected properties, such as UV protection, with a self-cleaning ability defined as photocatalytic performance. Accordingly, new hybrid additives were used to transform LDPE films into materials with complex performance properties. In this study, titanium dioxide–lignin (TL) hybrid systems with a weight ratio of inorganic to organic precursors of 5-1, 1-1, and 1-5 were prepared using a mechanical method. The obtained materials and pristine components were characterized using measurement techniques and research methods, such as Fourier-transform infrared spectroscopy (FTIR), thermal stability analysis (TGA/DTG), measurement of the electrokinetic potential as a function of pH, scanning electron microscopy (SEM), and particle size distribution measurement. It was found that hydrogen bonds were formed between the organic and inorganic components, based on which the obtained systems were classified as class I hybrid materials. In the next step, inorganic–organic hybrid systems and pristine components were used as fillers for a low-density polyethylene (LDPE) composite, 5 and 10% by weight, in order to determine their impact on parameters such as tensile elongation at break. Polymer composites containing titanium dioxide in their matrix were then subjected to a test of photocatalytic properties, based on which it was found that all materials with TiO2 in their structure exhibit photocatalytic properties, whereby the best results were obtained for samples containing the TiO2–lignin hybrid system (1-1). The mechanical tests showed that the thin sheet films had a strong anisotropy due to chill-roll extrusion, ranging from 1.98 to 3.32. UV–Vis spectroscopy revealed four times higher light absorption for composites in which lignin was present than for pure LDPE, in the 250–450 nm range. On the other hand, the temperature at 5% and 30% weight loss revealed by TGA testing increased the highest performance for LDPE/TiO2 materials (by 20.4 °C and 8.7 °C, respectively). [ABSTRACT FROM AUTHOR]

To evaluate the effect of CAD/CAM materials surface treatments for bonding of different cementing systems on shear bond strength, including conventional and silane-containing resin cements, after 24 h and one year of water storage. Samples (12 mm × 6 mm × 1 mm) of each CAD/CAM material (IPS E.Max; Suprinity; Enamic; Cerec Bloc; IPS Empress) were divided into 4 groups: G1) 4.5% hydrofluoric acid (HFA) + silane + adhesive + RelyX Veneer (conventional); G2) HFA + Clearfil Ceramic Primer + Tooth Primer + Panavia V5 (conventional); G3) HFA + Panavia SA Cement Universal; G4) blasting with Al2O3 + Panavia SA Cement Universal. After the bonding procedures, two resin cement cylinders (1.5 mm × 1.5 mm) were constructed on each sample and tested after 24 h or one year of water-storage, using shear bond strength testing (n = 10). Data were submitted to generalized linear models' analysis (p <.05). The conventional treatment for glass ceramics with HFA and silanization or priming (G1 and G2) did not necessarily yielded higher bond strength than the simplified technique (G3 and G4). For IPS E.Max and Suprinity, all protocols had bond strength reduction after one year. For Enamic, Cerec Bloc and IPS Empress, G3 did not reduced statistically at one year. Panavia SA Cement Universal seemed not appropriate when IPS E.Max and Suprinity were blasted with Al2O3. On the other hand, the bond strength to etched or blasted with Al2O3 Enamic, Cerec Bloc and IPS Empress showed no difference or was higher than conventional luting protocols. [ABSTRACT FROM AUTHOR]

Recent innovations in nanomaterials inspire abundant novel tumor-targeting CRISPR-based gene therapies. However, the therapeutic efficiency of traditional targeted nanotherapeutic strategies is limited by that the biomarkers vary in a spatiotemporal-dependent manner with tumor progression. Here, we propose a self-amplifying logic-gated gene editing strategy for gene/H 2 O 2 -mediated/starvation multimodal cancer therapy. In this approach, a hypoxia-degradable covalent-organic framework (COF) is synthesized to coat a-ZIF-8 in which glucose oxidase (GOx) and CRISPR system are packaged. To intensify intracellular redox dyshomeostasis, DNAzymes which can cleave catalase mRNA are loaded as well. When the nanosystem gets into the tumor, the weakly acidic and hypoxic microenvironment degrades the ZIF-8@COF to activate GOx, which amplifies intracellular H+ and hypoxia, accelerating the nanocarrier degradation to guarantee available CRISPR plasmid and GOx release in target cells. These tandem reactions deplete glucose and oxygen, leading to logic-gated-triggered gene editing as well as synergistic gene/H 2 O 2 -mediated/starvation therapy. Overall, this approach highlights the biocomputing-based CRISPR delivery and underscores the great potential of precise cancer therapy. Hypoxia "AND" acid responsive CRISPR delivery system with self-amplifying degradation were constructed for early cancer treatment where less biomarker existed in the tumor microenvironment. [Display omitted] [ABSTRACT FROM AUTHOR]

A supramolecular structure is formed during the synthesis of a dihydrogen phosphate hybrid salt with the organic aromatic amine molecule 6-amino-1H-indazole. This work looks into the interactions between 6-amino-1H-indazole molecules and dihydrogen phosphate ions, which sheds light on the formation mechanisms and stability of the resulting crystal lattice. A slow evaporation process resulted in single crystal formation of [C7H9N3][H2PO4]2. The compound crystallizes in the centrosymmetric space group of the monoclinic system, with dimensions a = 7.074(13)Å, b = 14.134(3)Å, c = 12.716(3)Å, β = 91.231(15)°, and Z=4. Hydrogen bonds are essential for connecting the dihydrogen phosphate anions [H2PO4]- and the organic cations [C7H9N3]2+ in the mineral structure. According to Hirshfeld’s analysis oxygen-hydrogen interactions are the most important in the crystal of all potential chemical linkages. The IR and Raman spectra of the chemical collected at room temperature were analyzed in relation to literature data and theoretical groupings. Photoluminescence and UV measurements are linked to a number of electrical activities in the title chemical.

Calcium phosphates (CaPs) and their substituted derivatives encompass a large number of compounds with a vast presence in nature that have aroused a great interest for decades. In particular, hydroxyapatite (HAp, Ca10(OH)2(PO4)6) is the most abundant CaP mineral and is significant in the biological world, at least in part due to being a major compound in bones and teeth. HAp exhibits excellent properties, such as safety, stability, hardness, biocompatibility, and osteoconductivity, among others. Even some of its drawbacks, such as its fragility, can be redirected thanks to another essential feature: its great versatility. This is based on the compound’s tendency to undergo substitutions of its constituent ions and to incorporate or anchor new molecules on its surface and pores. Thus, its affinity for biomolecules makes it an optimal compound for multiple applications, mainly, but not only, in biological and biomedical fields. The present review provides a chemical and structural context to explain the affinity of HAp for biomolecules such as proteins and nucleic acids to generate hybrid materials. A size-dependent criterium of increasing complexity is applied, ranging from amino acids/nucleobases to the corresponding macromolecules. The incorporation of metal ions or metal complexes into these functionalized compounds is also discussed.

Novel fibrous cellulosic substrates impregnated with meta-polybenzimidazole (PBI)-stabilized carbon nanotubes/zinc oxide with different weight content of ZnO and with the use of dimethylacetamide as dispersant media. The pristine ZnO nanoparticle powder was prepared by plant extract-mediated synthesis using Vaccinium vitis-idaea L. The green synthesized ZnO possesses an average crystallite size of 15 nm. The formation of agglomerates from ZnO NPs with size 250 nm–350 nm in the m-PBI@CNTs/ZnO was determined. The prepared materials were investigated by PXRD analysis, XPS, SEM, EDS, AFM, and TEM in order to establish the phase and surface composition, structure, and morphology of the hybrids. The potential of the synthesized hybrid composites to degrade methylene blue (MB) dye as a model contaminant in aqueous solutions under UV illumination was studied. The photocatalytic results show that in the course of the photocatalytic reaction, the m-PBI@CNTs/ZnO 1:3 photocatalyst leads to the highest degree of degradation of the methylene blue dye (67%) in comparison with the other two studied m-PBI@CNTs/ZnO 1:1 and 1:2 composites (48% and 41%). The antibacterial activity of ZnO nanoparticles and the hybrid CNT materials was evaluated by the RMDA and the dynamic contact method, respectively. The profound antibacterial effect of the m-PBI@CNTs/ZnO hybrids was monitored for 120 h of exposition in dark and UV illumination regimes. The photocatalytic property of ZnO nanoparticles significantly shortens the time for bactericidal action of the composites in both regimes. The m-PBI@CNTs/ZnO 1:2 combination achieved complete elimination of 5.105 CFU/mL E. coli cells after 10 min of UV irradiation.

This work focuses on the development of a hybrid material based on SBA-15 silica with a molecularly imprinted polymer (MIP), using spiramycin (SPI) as a template, for use as sorbent in solid-phase extraction (SPE). Characterization techniques such as nitrogen gas adsorption–desorption isotherms, infrared spectroscopy and scanning electron microscopy confirmed the structure and properties of the SBA-15@MIP-SPI material. SPE conditions using SBA-15@MIP-SPI as sorbent were optimized, which allowed us to demonstrate the high selectivity and adsorption capacity of SPI on the synthesized material. The best conditions were 50 mg of sorbent, loading with 1 mL of standard solution or sample of cow milk previously extracted in acetonitrile and eluting with 3 mL of methanol with 1% acetic acid. After the optimization process, the material demonstrated recovery percentages of 81 ± 3% in SPI standard solutions and showed its potential in cow milk samples (71 ± 6%). The novelty of the research consists of the combination of MIPs with SBA-15, which could offer important advantages in terms of specific surface area and porous structure, thus improving performance and reducing the amount of sorbent compared to other traditional methods.

A lacunary polyoxometalate-based hybrid material, wherein Cr (acac) 3 complex is covalently tethered through aminopropyltrimethoxysilyl groups to a Keggin-type lacunary phosphomolybdate anion, [PMo 11 O 39 ]7-, is reported as a new heterogeneous electrocatalyst for the efficient electrocatalytic hydrogen evolution process. Physicochemical characterization techniques, like FT-IR spectroscopy, X-ray diffraction (XRD), and energy dispersive X-ray (EDX) analyses confirmed the successful functionalization and synthesis of desired material. The prepared hybrid material revealed eminent hydrogen evolution activity with a low overpotential of 330 mV to attain a 10 mA cm−2 current density and a Tafel slope of 150 mV.dec−1. Additionally, it also exhibited outstanding electrochemical stability in H 2 SO 4 (0.5 M) over 8 h and catalytic activity retention even after 2000 catalytic cycles. This work introduces an appropriate procedure for preparing inexpensive and highly active electrocatalysts for replacing precious Pt counterparts in hydrogen evolution process. [Display omitted] • Design of a new electrocatalyst is reported for utilization in electrocatalytic hydrogen evolution reaction. • The electrocatalyst was based on the interaction of a lacunary polyoxometalate and Cr (acac) 3 complex. • The prepared electrocatalyst exhibited high efficiency in hydrogen evolution for a prolonged-time span. [ABSTRACT FROM AUTHOR]

Since Cu2+ ions play a pivotal role in both ecosystems and human health, the development of a rapid and sensitive method for Cu2+ detection holds significant importance. Fluorescent mesoporous silica materials (FMSMs) have garnered considerable attention in the realm of chemical sensing, biosensing, and bioimaging due to their distinctive structure and easily functionalized surfaces. As a result, numerous Cu2+ sensors based on FMSMs have been devised and extensively applied in environmental and biological Cu2+ detection over the past few decades. This review centers on the recent advancements in the methodologies for preparing FMSMs, the mechanisms underlying sensing, and the applications of FMSMs‐based sensors for Cu2+ detection. Lastly, we present and elucidate pertinent perspectives concerning FMSMs‐based Cu2+ sensors. [ABSTRACT FROM AUTHOR]

Microbial diseases are believed to be a global health challenge. The evolution of carbon-based nanocomposites with antimicrobial properties has played a crucial feature in controlling the growth of microorganisms. By the way, the present investigation emphasizes a sustainable, harmless, cost-effective fabrication of CuO–MgO@rGO (CMG) nanocomposite. The phase structure, morphology, and stability of the fabricated CMG nanocomposite are implemented via precise standard systematic techniques like XRD, SEM, HR-TEM, and TG analyses. The crystallite size value of the prepared nanocomposite is enumerated to be about 18.82 nm. Electron microscopy evaluation corroborates that the CMG nanocomposite divulges the formation of wrinkled nanosheet-supported nanosphere-like morphology. The cytocompatibility of the CMG nanocomposite is assessed using RAW 264.7 cells. The nanocomposite exhibits over 80 % cell viability at a concentration of 10 μg/mL. [Display omitted] • CuO–MgO@rGO (CMG) nanocomposite prepared via co-precipitation method. • CMG exhibits rGO nanosheet-supported nanosphere-like morphology. • CMG displays a crystallite size value of 18.82 nm. • CMG exposes a cell viability value of >80 % at 10 μg/mL. [ABSTRACT FROM AUTHOR]

In this study, the preparation and characterisation of a new adsorbent prepared by hetero-coagulation of Algerian bentonite and double hydroxide are reported. The nanocomposite BNa/LDH is used as an adsorbent for the removal of copper ions. The XRD and FTIR analyse show that the BNa/LDH material is formed of LDH particles enveloped by layers of bentonite. Batch experiments were carried out to study the relationship between copper removal and various parameters such as pH solution, copper concentration, contact time and temperature. The maximum amount of copper adsorbed by the BNa/LDH hybrid material is recorded at pH 4 (67 mg/g). Adsorption equilibrium is reached after 30 minutes of contact for an initial copper concentration varying between 50 and 250 mg/L. The kinetic study indicates that the limiting step of copper adsorption by the BNa/LDH material is chemical. The intraparticle diffusion models and Elovich confirm this result. The adsorption of copper by the hybrid material in the presence of anions of different nature follows the sequence: SO42-> Ac−> Cl−. A comparison of the adsorption isotherms of nickel and iron with that of copper shows that the latter has an affinity for the hybrid material. The recycling of the adsorbents was carried out by calcining the adsorption products at 500°C and the results showed a progressive reduction of the adsorption capacity. In general, we could conclude that the adsorbents studied here could be successfully applied in the cleaning of the wastewaters. The characteristics of this new material encourage promising future use in wastewater treatment applications. [ABSTRACT FROM AUTHOR]

The use of the organic aromatic amine molecule 5-amino-3-methyl-1-phenyl-1H-1,2,4-triazole to synthesize a dihydrogen arsenate hybrid salt leads to a supramolecular structure type. Single crystals of (C9H11N4)H2AsO4 were grown through slow evaporation in solution. The synthesized compound crystallizes in the monoclinic system with the non-centrosymmetric P21 space group according to the following parameters; a = 9.655 (3) Å, b = 4.7090 (15) Å, c = 14.022 (4) Å, β = 108.147 (5)° and Z = 4. The mineral part building from dihydrogen arsenate anions [H2AsO4]− is linked together and to the organic cations [C9H11N4]+ by hydrogen bonds only. The results of Hirshfeld's analysis show that in all possible molecular contacts, the hydrogen–hydrogen and the oxygen–hydrogen are the most important interaction in the crystal (37.5 and 31.9%, respectively). The Fourier transform infrared (FT-IR) confirms the existence of vibrational modes corresponding to the organic amine molecule and mineral arsenate tetrahedron. The optimized molecular structure and the vibrational spectra were calculated by the density functional theory DFT methods and the semi-empirical PM3 calculations. Dielectric study of this compound has been measured in order to determine the electrical conductivity type giving rise to an activation energy of ΔEσ = 0.17 eV. [ABSTRACT FROM AUTHOR]

The use of the organic aromatic amine molecule 5-amino-3-methyl-1-phenyl-1H-1,2,4-triazole to synthesize a dihydrogen arsenate hybrid salt leads to a supramolecular structure type. Single crystals of (C9H11N4)H2AsO4 were grown through slow evaporation in solution. The synthesized compound crystallizes in the monoclinic system with the non-centrosymmetric P21 space group according to the following parameters; a = 9.655 (3) Å, b = 4.7090 (15) Å, c = 14.022 (4) Å, β = 108.147 (5)° and Z = 4. The mineral part building from dihydrogen arsenate anions [H2AsO4]− is linked together and to the organic cations [C9H11N4]+ by hydrogen bonds only. The results of Hirshfeld's analysis show that in all possible molecular contacts, the hydrogen–hydrogen and the oxygen–hydrogen are the most important interaction in the crystal (37.5 and 31.9%, respectively). The Fourier transform infrared (FT-IR) confirms the existence of vibrational modes corresponding to the organic amine molecule and mineral arsenate tetrahedron. The optimized molecular structure and the vibrational spectra were calculated by the density functional theory DFT methods and the semi-empirical PM3 calculations. Dielectric study of this compound has been measured in order to determine the electrical conductivity type giving rise to an activation energy of ΔEσ = 0.17 eV. [ABSTRACT FROM AUTHOR]

This work describes the fabrication of CuO-ZnO (CZO) and CuO-ZnO/g-C3N4 (CZO/GCN) nanocomposite via an expeditious and cost-effective co-precipitation approach. The prepared nanomaterials have been characterized with XPS, TEM, elemental mapping, SEM with EDX, XRD, and FT-IR. Morphological analysis proves that the synthesized CZO/GCN nanocomposite shows nanospheres decorated with a nanosheet-like structure. The antimicrobial ability of the CZO and CZO/GCN nanocomposite has been evaluated using the well-diffusion method. Compared to Gram-positive bacterial and fungal strains, excellent activity has been noted for Gram-negative bacterial strains. The synthesized CZO/GCN nanocomposite tested against MDA-MB-231 epithelial human breast cancer cell line at various concentrations. It shows cytotoxicity activity at an inhibitory concentration (IC50) of 124.4 μg/ml. The results prove that the synthesized CZO/GCN nanocomposite demonstrates a new and effective route for the development of biomedical applications. [ABSTRACT FROM AUTHOR]

The CoO-Co3O4/C and CoO-Co3O4/N-C composites were synthesized from β-cyclodextrin (CD)-cobalt acetate and β-CD-Zeolitic imidazolate framework-67 (ZIF-67) via adduct and coordination interactions, respectively. The transformation of the composition and structure of their precursors as well as the composites were studied. The two composites were employed as catalysts for the oxidative degradation of Bisphenol A in the presence of potassium persulfate. The catalytic results confirmed that the CoO-Co3O4/C and CoO-Co3O4/N-C composites demonstrated about 5.2 and 3.7-fold higher degradation rates than that of Co3O4 obtained by cobalt acetate, respectively, and also displayed a robust reusability, which could be due to the unique oxidation-reduction property between CoO and Co3O4 and the small particle size of cobalt oxides with carbonaceous species. The possible degradation mechanism was also investigated by controlled experiments. This work provided new development for the synthesis of functional materials by the assistance of supramolecules as well as their potential applications in the environmental catalysis. Highlights: β-CD–Co(Ac)2 adduct and β-CD-ZIF-67 were synthesized. CoO-Co3O4/C and CoO-Co3O4/N-C composites were obtained by calcination. Efficient catalytic abilities for Bisphenol A degradation were achieved. [ABSTRACT FROM AUTHOR]

Abstract In this paper, we report on the synthesis of a new hybrid photocatalytic material activated by natural sunlight irradiation. The material consists of multiferroic nanoparticles of bismuth ferrite (BFO) modified through the growth of the Fe-based MIL-101 framework. Material characterization, conducted using various techniques (X-ray diffraction, transmission electron microscopy, FTIR, and X-ray photoelectron spectroscopies), confirmed the growth of the MIL-101 metal–organic framework on the BFO surface. The obtained system possesses the intrinsic photo-degradative properties of BFO nanoparticles significantly enhanced by the presence of MIL-101. The photocatalytic activity of this material was tested in antibacterial experiments conducted under natural sunlight exposure within the nanocomposite concentration range of 100–0.20 µg/ml. The MIL-modified BFO showed a significant decrease in both Minimum Inhibiting Concentration and Minimum Bactericide Concentration values compared to bare nanoparticles. This confirms the photo-activating effect of the MIL-101 modification. In particular, they show an increased antimicrobial activity against the tested Gram-positive species and the ability to begin to inhibit the growth of the four Escherichia coli strains, although at the maximum concentration tested. These results suggest that the new nanocomposite BiFeO3@MOF has been successfully developed and has proven to be an effective antibacterial agent against a wide range of microorganisms and a potential candidate in disinfection processes.