16 results on '"Hunt S.W."'
Search Results
2. TOF-SIMS analysis of sea salt particles: imaging and depth profiling in the discovery of an unrecognized mechanism for pH buffering
- Author
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Gaspar, D.J., Laskin, A., Wang, W., Hunt, S.W., and Finlayson-Pitts, B.J.
- Published
- 2004
- Full Text
- View/download PDF
3. Correlation of Dative Bond Length and Donor Proton Affinity in Adducts of SO3: A Good Predictor for HCCCN–SO3
- Author
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Hunt, S.W., Fiacco, D.L., Craddock, M., and Leopold, K.R.
- Published
- 2002
- Full Text
- View/download PDF
4. Formation of molecular bromine from the reaction of ozone and deliquesced NaBr aerosol: Evidence for interface chemistry
- Author
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Hunt, S.W., Tobais D.J., Roeselova, M., Dabdub, D., W. Wang, Finlayson-Pitts, B.J., Wingen, L. M., and Knipping, M.
- Subjects
Aerosols -- Chemical properties ,Aerosols -- Research ,Ozone -- Chemical properties ,Ozone -- Research ,Bromine -- Research ,Chemicals, plastics and rubber industries - Abstract
The reaction of ozone with aqueous sodium bromide particles is investigated with a combination of aerosol chamber experiments, kinetics modeling, and molecular simulations. The results reveal that the majority of the observed Br2 production is due to the reaction of O3 with bromide ions at the air-water interface rather than reactions in the bulk aqueous solution.
- Published
- 2004
5. Molecular and electronic structure of C5H5N-SO3: correlation of ground state physical properties with orbital energy gaps in partially bound Lewis acid-base complexes
- Author
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Hunt, S.W. and Leopold, K.R.
- Subjects
Pyridine -- Chemical properties ,Pyridine -- Electric properties ,Carbon -- Chemical properties ,Hydrogen -- Chemical properties ,Nitrogen -- Chemical properties ,Chemicals, plastics and rubber industries - Abstract
A microwave rotational spectroscopic study of the gas-phase donor-acceptor complex formed from pyridine (C5H5N) and So3 is reported. The molecular structure and electronic properties of this partially bound Lewis acid-base type complex are described with focus on ground-state physical properties and computationally derived binding energies.
- Published
- 2001
6. Dipole moments of partially bound Lewis acid-base adducts
- Author
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Fiacco, D.L., Roberts, A., Mo Y., Hunt, S.W., Ott, M.E., and Leopold, K.R.
- Subjects
Acid-base chemistry -- Research ,Chemical reactions -- Research ,Sulfur compounds -- Chemical properties ,Chemicals, plastics and rubber industries - Abstract
Stark effect measurements are performed on six Lewis acid-base complexes containing (super 32)SO(sub 3) and (super 11)BF(sub 3). The results suggest that the induced moments of the series collectively approximate the induced dipole moment function for individual members of the series.
- Published
- 2001
7. Mitigating tunnel launch and reception challenges.
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Hunt S.W., North American Tunnelling 2008 San Francisco, California 8-11 June 2008, Finney A.J., Hunt S.W., North American Tunnelling 2008 San Francisco, California 8-11 June 2008, and Finney A.J.
- Abstract
Appropriate seals, portal ground improvement and compatible shaft construction techniques are vital elements for launching and receiving tunnels effectively in urban areas where adjacent property requires protection from excess ground movements. The seals, ground improvement and shaft wall types are discussed that are required to launch or receive tunnel boring machines within wet, permeable ground at the portal zone. The use of probing is considered to verify suitability before the tunnel eye is cut. Methods described include rubber gasket seals, soft eyes, double walls, top hats for reception and portal zone ground improvement including permeation grouting, jet grouting, unreinforced slurry diaphragm wall panels, ground freezing, deep soil mixing, dewatering and over-excavation and backfilling. The launch and reception of pressurised- face TBMs with precast concrete segment linings are also described., Appropriate seals, portal ground improvement and compatible shaft construction techniques are vital elements for launching and receiving tunnels effectively in urban areas where adjacent property requires protection from excess ground movements. The seals, ground improvement and shaft wall types are discussed that are required to launch or receive tunnel boring machines within wet, permeable ground at the portal zone. The use of probing is considered to verify suitability before the tunnel eye is cut. Methods described include rubber gasket seals, soft eyes, double walls, top hats for reception and portal zone ground improvement including permeation grouting, jet grouting, unreinforced slurry diaphragm wall panels, ground freezing, deep soil mixing, dewatering and over-excavation and backfilling. The launch and reception of pressurised- face TBMs with precast concrete segment linings are also described.
- Published
- 2008
8. Microtunnelling below clarifiers past pipe piles.
- Author
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Hunt S.W., Rapid excavation and tunnelling conference 2001 San Diego, California 11-Jun-0113-Jun-01, Baker G.C., Rorison G.J., Hunt S.W., Rapid excavation and tunnelling conference 2001 San Diego, California 11-Jun-0113-Jun-01, Baker G.C., and Rorison G.J.
- Abstract
Settlement-damaged sludge drain lines at the Jones Island wastewater treatment plant in Milwaukee, Wisconsin, were replaced by microtunnelling under the pile-supported clarifier basins. To minimise the risk of a microtunnel boring machine being blocked against piles or construction debris, a Soltau RVS 80 was utilised; this allowed initial boring of the alignment with guided rods of 114 mm diameter, followed by jacking of 1 m lengths of 305 mm diameter clay pipe along the rods behind an auger head. Precast concrete pipe of 2.4 m diameter was also used as a one-pass sinking caisson for workshafts and new cleanout manholes., Settlement-damaged sludge drain lines at the Jones Island wastewater treatment plant in Milwaukee, Wisconsin, were replaced by microtunnelling under the pile-supported clarifier basins. To minimise the risk of a microtunnel boring machine being blocked against piles or construction debris, a Soltau RVS 80 was utilised; this allowed initial boring of the alignment with guided rods of 114 mm diameter, followed by jacking of 1 m lengths of 305 mm diameter clay pipe along the rods behind an auger head. Precast concrete pipe of 2.4 m diameter was also used as a one-pass sinking caisson for workshafts and new cleanout manholes.
- Published
- 2001
9. Microwave observation of H3N–SO3⋯H2O using a concentric, dual-injection nozzle source
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Hunt, S.W., primary, Brauer, C.S., additional, Craddock, M.B., additional, Higgins, K.J., additional, Nienow, A.M., additional, and Leopold, K.R., additional
- Published
- 2004
- Full Text
- View/download PDF
10. Gasoline explosion in East Lansing sewer tunnel.
- Author
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Doyle B.R., Rapid excavation and tunnelling conference Las Vegas, Nevada 22-Jun-9725-Jun-97, Hunt S.W., Kettler J.A., Doyle B.R., Rapid excavation and tunnelling conference Las Vegas, Nevada 22-Jun-9725-Jun-97, Hunt S.W., and Kettler J.A.
- Abstract
The tunnel through an urban commercial area in East Lansing, Michigan, passed the site of a former petrol station known to have contained leaking underground storage tanks. An environmental assessment of soils was carried out and measure taken to handle the expected contaminants. An explosion still occurred in the heading, however, when liquid gasoline was encountered. The immediate cause of the explosion was combustion of petrol vapours inside the wheel chamber of the TBM, initiated by a friction spark from the cutterhead striking a boulder. It was calculated that less than 1 l of petrol was enough to generate an explosive concentration of vapours inside the wheel chamber. Examinations were also made of the ventilation, atmospheric monitoring and electrical systems along with the effectiveness of the OSHA code on controlling the tunnel atmosphere. The factors which contributed to the explosion were a lack of clear understanding of subsurface conditions, failure to identify the explosion hazard and lack of a clear understanding of the hazardous properties of the contaminant., The tunnel through an urban commercial area in East Lansing, Michigan, passed the site of a former petrol station known to have contained leaking underground storage tanks. An environmental assessment of soils was carried out and measure taken to handle the expected contaminants. An explosion still occurred in the heading, however, when liquid gasoline was encountered. The immediate cause of the explosion was combustion of petrol vapours inside the wheel chamber of the TBM, initiated by a friction spark from the cutterhead striking a boulder. It was calculated that less than 1 l of petrol was enough to generate an explosive concentration of vapours inside the wheel chamber. Examinations were also made of the ventilation, atmospheric monitoring and electrical systems along with the effectiveness of the OSHA code on controlling the tunnel atmosphere. The factors which contributed to the explosion were a lack of clear understanding of subsurface conditions, failure to identify the explosion hazard and lack of a clear understanding of the hazardous properties of the contaminant.
- Published
- 1997
11. Bottom stability of shafts with cohesive soil plugs overlying an artesian aquifer.
- Author
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Hunt S.W., Rapid excavation and tunnelling conference Las Vegas, Nevada 22-Jun-9725-Jun-97, Gill S.A., Hunt S.W., Rapid excavation and tunnelling conference Las Vegas, Nevada 22-Jun-9725-Jun-97, and Gill S.A.
- Abstract
Methods of evaluating the stability of shaft bottom plugs overlying an artesian aquifer include analysis of heave by piping through granular soils, boils or blows through discontinuities within cohesive plugs, cohesive plug heave ignoring side shear, cohesive plug heave with side shear and cohesive plug buckling or cracking. Methods of considering plug perimeter shear, plug buckling and pressure relief are discussed and minimum factors of safety suggested. Case histories are discussed of bottom plug failures at the Milwaukee NS-10 junction structure shaft, the Milwaukee Jones Island siphon shaft and a press foundation shaft on an alluvial plain along the Mississippi River., Methods of evaluating the stability of shaft bottom plugs overlying an artesian aquifer include analysis of heave by piping through granular soils, boils or blows through discontinuities within cohesive plugs, cohesive plug heave ignoring side shear, cohesive plug heave with side shear and cohesive plug buckling or cracking. Methods of considering plug perimeter shear, plug buckling and pressure relief are discussed and minimum factors of safety suggested. Case histories are discussed of bottom plug failures at the Milwaukee NS-10 junction structure shaft, the Milwaukee Jones Island siphon shaft and a press foundation shaft on an alluvial plain along the Mississippi River.
- Published
- 1997
12. Casing collapse at the CT-8 dropshaft in Milwaukee.
- Author
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Hunt S.W., Rapid excavation and tunnelling conference San Francisco, California 18-Jun-9521-Jun-95, Gill S.A., Heuer R.E., Hunt S.W., Rapid excavation and tunnelling conference San Francisco, California 18-Jun-9521-Jun-95, Gill S.A., and Heuer R.E.
- Abstract
The CT-8 dropshaft in glacial soils was designed to convey combined stormwater runoff and sewage from near surface collectors into a deep tunnel conveyance and temporary storage system, and construction was carried out from 1985 to 1988. Auger drilling with a bentonite-soil slurry followed by placement and grouting of a thin metal casing was attempted for the dropshaft, but was not successful. Annulus grouting was not properly completed and a significant section of the casing was not fully grouted. The casing was also not socketed into rock to help seal the bottom. Bottom plug leaks led to remedial contact grouting of the annulus outside of the stiffened steel casing at the section where it was surrounded by fluid grout and slurry. The head of fluid grout resulted in sufficient pressure to initiate buckling of the casing and subsequently a complete rupture occurred in July 1985., The CT-8 dropshaft in glacial soils was designed to convey combined stormwater runoff and sewage from near surface collectors into a deep tunnel conveyance and temporary storage system, and construction was carried out from 1985 to 1988. Auger drilling with a bentonite-soil slurry followed by placement and grouting of a thin metal casing was attempted for the dropshaft, but was not successful. Annulus grouting was not properly completed and a significant section of the casing was not fully grouted. The casing was also not socketed into rock to help seal the bottom. Bottom plug leaks led to remedial contact grouting of the annulus outside of the stiffened steel casing at the section where it was surrounded by fluid grout and slurry. The head of fluid grout resulted in sufficient pressure to initiate buckling of the casing and subsequently a complete rupture occurred in July 1985.
- Published
- 1995
13. Pre-excavation grouting effectiveness for controlling shaft inflows in rock.
- Author
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Hunt S.W., Rapid excavation and tunnelling conference Boston, Massachusetts 13-Jun-9317-Jun-93, Ilsley R.C., Santacroce P.U., Hunt S.W., Rapid excavation and tunnelling conference Boston, Massachusetts 13-Jun-9317-Jun-93, Ilsley R.C., and Santacroce P.U.
- Abstract
Consolidation grouting from the surface prior to mining a shaft is commonly performed to reduce groundwater inflows to a manageable rate. A description is presented of the inflow reductions obtained within dolomite and limestone formations at several shafts and chambers due to grouting programmes for the Milwaukee water pollution abatement programme. The resulting inflow reduction factors are compared with values reported in the literature. Post-grouting pump tests are also evaluated as an aid to grouting assessment. Important considerations for estimating shaft inflows from pump test results are discussed. These considerations include loss of grouted mass during mining and influence of blasting and rock features on grouting effectiveness., Consolidation grouting from the surface prior to mining a shaft is commonly performed to reduce groundwater inflows to a manageable rate. A description is presented of the inflow reductions obtained within dolomite and limestone formations at several shafts and chambers due to grouting programmes for the Milwaukee water pollution abatement programme. The resulting inflow reduction factors are compared with values reported in the literature. Post-grouting pump tests are also evaluated as an aid to grouting assessment. Important considerations for estimating shaft inflows from pump test results are discussed. These considerations include loss of grouted mass during mining and influence of blasting and rock features on grouting effectiveness.
- Published
- 1993
14. Use of recharge wells to maintain groundwater levels during excavation of the Milwaukee deep tunnels.
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Ilsley R.C., Rapid excavation and tunnelling conference Seattle, Washington 16-Jun-9120-Jun-91, Hunt S.W., Powers J.P., Ilsley R.C., Rapid excavation and tunnelling conference Seattle, Washington 16-Jun-9120-Jun-91, Hunt S.W., and Powers J.P.
- Published
- 1991
15. Genetic and molecular mapping of the Hmt region of mouse.
- Author
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Richards, S., Bucan, M., Brorson, K., Kiefer, M.C., Hunt, S.W., Lehrach, H., and Lindahl, K.F.
- Abstract
We have mapped a new region of the mouse major histocompatibility complex (MHC) that contains the nuclear gene, Hmt, for the maternally transmitted antigen, Mta. The Hmt region of chromosome 17 lies between a recombinational breakpoint distal to Tla and another proximal to Tpx‐1, thus including Pgk‐2. A novel MHC class I gene fragment, R4B2, was cloned and mapped to this region as was another new class I gene, Thy19.4. Both lie proximal to Pgk‐2, within the distal inversion in t‐haplotypes. The presence of several other MHC class I genes in the Hmt region is predicted from analysis of the recombinants that define the region.
- Published
- 1989
- Full Text
- View/download PDF
16. Experience with deep shaft construction in Milwaukee.
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Hunt S.W., Fradkin S.B., Maurer R.J., Hunt S.W., Fradkin S.B., and Maurer R.J.
- Abstract
During the 1980s and 1990s, twenty deep shafts were constructed in Milwaukee, Wisconsin, USA, as part of the Milwaukee Water Pollution Abatement Program. Depths ranged from 85 to 91 m through soil and weak rock with thicknesses ranging from 37 to 69 m. Adjacent compressible soils, settlement-sensitive structures and high groundwater levels required that shafts be constructed without dewatering. Contractors attempted several methods of ground support and groundwater cutoff. Significant problems developed during construction of eleven of twenty shafts: one collapsed, groundwater blow-ins occurred at five of the shafts; and seepage caused unfrozen windows at three of the freezewalls. Ultimately, combinations of grouting and ground freezing were used to complete all the shafts into bedrock. The main problems and solutions are described., During the 1980s and 1990s, twenty deep shafts were constructed in Milwaukee, Wisconsin, USA, as part of the Milwaukee Water Pollution Abatement Program. Depths ranged from 85 to 91 m through soil and weak rock with thicknesses ranging from 37 to 69 m. Adjacent compressible soils, settlement-sensitive structures and high groundwater levels required that shafts be constructed without dewatering. Contractors attempted several methods of ground support and groundwater cutoff. Significant problems developed during construction of eleven of twenty shafts: one collapsed, groundwater blow-ins occurred at five of the shafts; and seepage caused unfrozen windows at three of the freezewalls. Ultimately, combinations of grouting and ground freezing were used to complete all the shafts into bedrock. The main problems and solutions are described.
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