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ZnO-Al2O3 nanocomposite was synthesized and developed as a high performance sensitive and selective layer for surface acoustic wave (SAW) sensor, aiming for in-situ detection of H2S gas in ppb level operated at room temperature. ZnO-Al2O3 nanocomposite, synthesized though a sol-gel method, was spin-coated onto a quartz based SAW resonator. This composite layer inherits the mesoporous structure of the Al2O3 layer and good affinity to H2S gas molecules of the ZnO layer, and thus can selectively adsorb and react with H2S gas molecules to form ZnS compounds on its surface. This reaction leads to significant decreases of both pore sizes and total pore volume of the layer, an increase of layer’s elastic modulus, thus causing a large positive shift of the frequency responses of the SAW sensor. The sensor operated at room temperature shows a frequency response of ∼500 Hz to 10 ppb H2S, with an excellent selectivity and good recovery property.

Silicon disulfide, ${\mathrm{SiS}}_{2}$, is thought to occur in interstellar dust and is of fundamental interest more generally among the silicon chalcogenides as a comparator to ${\mathrm{SiO}}_{2}$, an important component of terrestrial planets. However, the high-pressure behaviors of silicon sulfides are unclear. Here, using an efficient structure search method, we systematically explore the structural evolution of different Si-S stoichiometries up to 250 GPa. ${\mathrm{SiS}}_{2}$ is found to be stable below 155 GPa, above which it decomposes into two compounds, SiS and ${\mathrm{SiS}}_{3}$. SiS adopts a high-symmetry cubic structure consisting of eightfold-coordinated silicon in face-sharing ${\mathrm{SiS}}_{8}$ polyhedra, while ${\mathrm{SiS}}_{3}$ crystallizes in a rhombohedral structure containing ninefold-coordinated ${\mathrm{SiS}}_{9}$ polyhedra. Analyses suggest that the Si eightfold-coordination environment could be a common feature for group IV--VI compounds under high pressure. Our findings provide insights on the nature of Si-S compounds under ultrahigh pressure.

By the gyrokinetic integral eigenmode equation, we numerically investigate the short-wavelength ion-temperature-gradient (SWITG) mode in tokamak plasmas with hollow density profiles. This paper finds that the critical ion temperature gradient (ITG) R / L TiC exists for the hollow density profile. Over such a gradient, the SWITG mode is unstable. The R / L TiC for a hollow density profile is slightly lower than that for a peaked density profile, though far away from the threshold, the mode in the latter case is more unstable. Furthermore, the scaling of the ITG threshold increasing with ion-to-electron temperature ratio T i / T e has been calculated, suggesting that the SWITG mode is more difficult to excite in hot ion plasmas as compared with that in hot electron plasmas. For the slightly hollow density profiles, it is shown that in the case of flat (peaked) electron temperature profiles, the SWITG modes are destabilized (stabilized) by the trapped electrons. For the steep hollow density profiles, however, the trapped electrons reduce the growth rate substantially, and thus, the SWITG stability threshold is raised significantly. In addition, the dependence of the threshold on local plasma parameters is analyzed in detail. It is found that the SWITG modes become more unstable for the high safety factor, small Larmor radius, weak magnetic shear, and high electron-to-ion temperature ratio.

We report that cellulose nano-crystals (CNCs) can be used as a sensitive and selective layer in surface acoustic wave (SAW) sensors for in-situ HCl gas detection. CNCs were prepared through directly hydrolysis of cotton fiber and were spin-coated on quartz SAW resonators to form the sensitive layer. The CNCs have been identified to have abundant hydroxyl groups on their surfaces, which can act as the perfect adsorption sites for H2O, which can further act as the active sites for HCl gas adsorption. The absorption of HCl on the CNCs layer, thus leads to an increase of its mass, causing negative responses of the SAW sensors. Ambient humidity and thickness of CNCs layer are found to have significant influences on the responses of the SAW sensor. With an 80-nm-thick CNCs layer, the sensor shows a response of −2 kHz to 1 ppm HCl at 25 °C and relative humidity of 50 % with an excellent selectivity and recovery characteristics.

Results from recent trials assessing the effect of vitamin D supplementation on the prevention of childhood acute respiratory infections (ARI) have been inconsistent. In the present study, we determined whether vitamin D supplementation prevents ARI in healthy children and repeated infections in children with previous ARI. We conducted a systematic literature search using MEDLINE, EMBASE, and the Cochrane Central Register of Controlled Trials. The search included only randomised controlled clinical trials (RCT) comparing vitamin D supplementation with either placebo or no intervention in children younger than 18 years of age. We identified seven RCT and found that the summary estimates were not statistically significantly associated with a reduction in the risk of ARI (relative risk (RR) 0·79, 95 % CI 0·55, 1·13), all-cause mortality (RR 1·18, 95 % CI 0·71, 1·94), or the rate of hospital admission due to respiratory infection in healthy children (RR 0·95, 95 % CI 0·72, 1·26). However, in children previously diagnosed with asthma, vitamin D supplementation resulted in a 74 % reduction in the risk of asthma exacerbation (RR 0·26, 95 % CI 0·11, 0·59; test of heterogeneity, I2= 0·0 %). Our findings indicate a lack of evidence supporting the routine use of vitamin D supplementation for the prevention of ARI in healthy children; however, they suggest that such supplementation may benefit children previously diagnosed with asthma. Due to the heterogeneity of the included studies and possible publication biases related to this field, these results should be interpreted with caution.

A major challenge facing the design and operation of next-step high-power steady-state fusion devices is to develop a viable divertor solution with order-of-magnitude increases in power handling capability relative to present experience, while having acceptable divertor target plate erosion and being compatible with maintaining good core plasma confinement. A new initiative has been launched on DIII-D to develop the scientific basis for design, installation, and operation of an advanced divertor to evaluate boundary plasma solutions applicable to next step fusion experiments beyond ITER. Developing the scientific basis for fusion reactor divertor solutions must necessarily follow three lines of research, which we plan to pursue in DIII-D: (1) Advance scientific understanding and predictive capability through development and comparison between state-of-the art computational models and enhanced measurements using targeted parametric scans; (2) Develop and validate key divertor design concepts and codes through innovative variations in physical structure and magnetic geometry; (3) Assess candidate materials, determining the implications for core plasma operation and control, and develop mitigation techniques for any deleterious effects, incorporating development of plasma-material interaction models. These efforts will lead to design, installation, and evaluation of an advanced divertor for DIII-D to enable highly dissipative divertor operation at core density (n e/n GW), neutral fueling and impurity influx most compatible with high performance plasma scenarios and reactor relevant plasma facing components (PFCs). This paper highlights the current progress and near-term strategies of boundary/PMI research on DIII-D.

This study aims to perform gene diagnosis for nine patients with Duchenne/Becker muscular dystrophy (DMD/BMD) and their parents with multiplex ligation‐dependent probe amplification (MLPA), and to carry out prenatal gene diagnosis for one of them. Genomic DNA of the peripheral blood and fetal amniotic fluid cell was extracted from the pedigrees' members with DMD/BMD. Gene diagnosis was performed for theses pedigrees' members using a SALSA KIT. Short tandem repeats (STR) genotyping and X‐linkage analysis were performed for the pedigree members of the fetus, which was used in the prenatal diagnosis. MLPA analysis results show that five of nine patients (DMD‐1, DMD‐2, DMD‐4, DMD‐8, and DMD‐9) with DMD/BMD were found to have several hemizygous exon deletions in the dystrophin gene. The other patients and the fetus did not have any hemizygous deletion or duplication of any exons. The genomic DNA of the fetus was not contaminated by his mother's DNA as identified by STR genotyping. In addition, X‐linkage analysis results show that the only X chromosome of the fetus comes from one of his mother's normal X chromosomes. Combined with STR genotyping and X‐linkage analysis, MLPA is a convenient, highly effective and reliable gene diagnosis technique for congenital genetic disease. J. Clin. Lab. Anal. 23:380–386, 2009. © 2009 Wiley‐Liss, Inc.

Background No systematic review of prevention of mother to child transmission (PMTCT) in China has been performed. We aimed to estimate the uptake of PMTCT programs services in China. Methods We searched MEDLINE, EMBASE, Cochrane Central Register of Controlled Trials, China National Knowledge Infrastructure, Chinese Biomedical Literature Database, and Wanfang (Chinese) to identify research studies. Only descriptive epidemiological studies were eligible for this study. Results A total of 57 eligible cross-section studies were finally included. We estimated that the mean HIV-positive rate of exposed infants was 4.4% (95% CI = 3.2–5.5), and more than 33% of exposed infants had not undergone HIV diagnostic testing. The percentage of initiating antiretroviral therapy (ART) in HIV-positive women was 71.0% (95% CI = 66.3–75.8), and that for initiating antiretroviral prophylaxis (ARP) in exposed infants was 78.3% (95% CI = 74.9–81.8); also, 31.3% (95% CI = 15.5–47.0) of women with HIV and < 1% of exposed infants received the combination of three antiretroviral drugs. There were bigger gap of uptake of PMTCT programs between income levels, and cities with a low income level had a higher percentage of initiating ART in HIV-positive women (80%) and ARP in exposed infants (85%) compared to cities with high-middle income (57% and 65%, respectively) (P

We perform a numerical study of linear stability of the ion temperature gradient (ITG) mode and the trapped electron mode (TEM) in tokamak plasmas with inverted density profiles. A local gyrokinetic integral equation is applied for this study. From comprehensive parametric scans, we obtain stability diagrams for ITG modes and TEMs in terms of density and temperature gradient scale lengths. The results show that, for the inverted density profile, there exists a normalized threshold temperature gradient above which the ITG mode and the TEM are either separately or simultaneously unstable. The instability threshold of the TEM for the inverted density profile is substantially different from that for normal and flat density profiles. In addition, deviations are found on the ITG threshold from an early analytic theory in sheared slab geometry with the adiabatic electron response [T. S. Hahm and W. M. Tang, Phys. Fluids B 1, 1185 (1989)]. A possible implication of this work on particle transport in pellet fueled tokamak plasmas is discussed.

The ion temperature gradient (ITG) modes in transport barriers (TBs) of tokamak plasmas are numerically studied with a code solving gyrokinetic integral eigenvalue equations in toroidal configurations. It is found that multiple ITG modes with conventional and unconventional ballooning mode structures can be excited simultaneously in TBs with steep gradients of ion temperature and density. The characteristics of the modes, including the dependence of the mode frequencies, growth rate and structure on plasma parameters, are systematically investigated. Unconventional modes with large mode-number (where denotes a certain parity and peak number in ballooning space) dominate in the large region (), while the conventional mode with dominates in the medium region (), and unconventional modes with small mode-number dominate in the small region (). Thus, the spectra of these conventional and unconventional modes at steep gradients are qualitatively different from those of the conventional ITG modes at small or medium gradients, in which the growth rate of the only ITG mode with reaches maximum at the medium value . Through scanning ion temperature gradient and density gradient separately, it is proven that the synergetic effect of and , rather than alone, drives the unconventional ITG modes in TBs. Moreover, it is found that the critical value of for driving the unconventional ITG modes with large l number increases with increasing . In addition, the effects of magnetic shear on conventional and unconventional ITG modes in the high confinement regime (H-mode) are analyzed in detail, and compared with equivalent effects on conventional modes in the low and intermediate gradient regimes (L- and I- modes). Finally, the effects of the poloidal wave number and gradients of ion temperature and density on radial transport are analyzed based on quasi-linear mixing length estimations.

The effects of impurity ions on the trapped electron mode (TEM) in tokamak plasmas are numerically investigated with the gyrokinetic integral eigenmode equation. It is shown that in the case of large electron temperature gradient ( ηe), the impurity ions have stabilizing effects on the TEM, regardless of peaking directions of their density profiles for all normalized electron density gradient R/Lne. Here, R is the major radius and Lne is the electron density gradient scale length. In the case of intermediate and/or small ηe, the light impurity ions with conventional inwardly (outwardly) peaked density profiles have stabilizing effects on the TEM for large (small) R/Lne, while the light impurity ions with steep inwardly (outwardly) peaked density profiles can destabilize the TEM for small (large) R/Lne. Besides, the TEM driven by density gradient is stabilized (destabilized) by the light carbon or oxygen ions with inwardly (outwardly) peaked density profiles. In particular, for flat and/or moderate R/Lne, ...

In HL-2A and J-TEXT ohmic confinement regimes, an electrostatic turbulence with quasi-coherent characteristics in spectra of density fluctuations was observed by multi-channel microwave reflectometers. These quasi-coherent modes (QCMs) were detectable in a large plasma region ( r / a ∼ 0.3 − 0.8). The characteristic frequencies of QCMs were in the range of 30–140 kHz. The mode is rotated in the electron diamagnetic direction. In the plasmas with QCMs, trapped electron mode (TEM) was predicted to be unstable by gyrokinetic simulations. The combined experimental results show that the TEM is survived in the linear ohmic confinement regime of plasmas. The quasi-coherent TEM was replaced by broad-band fluctuations when the plasma transits from linear to saturated ohmic confinement regime. The observation was strongly related to the turbulence transition from TEM to ion temperature gradient mode. A critical gradient threshold for TEM excitation in electron temperature gradient was directly found. The effect of ...

Ion internal transport barriers (iITBs) are first observed in neutral beam injection (NBI) heated plasmas at the HL-2A tokamak. The position of the barrier foot, in the stationary state, coincides with the q = 1 surface within its uncertainty of measurement. iITBs can develop more easily at the beginning of NBI heating. Also, iITBs are unstable for the sawtooth plasma. Simulations reveal that the thermal diffusivity of ions (χ i) inside the barrier can be as low as the neoclassical level. It is observed that the flow shear in the stationary iITB state reaches the level required for suppressing the ion temperature gradient mode instability, which indicates the important role of flow shear in sustaining the iITB.

The effects of impurity ions on the short wavelength ion temperature gradient (SWITG) driven instability in elongated tokamak plasmas are numerically investigated with the gyrokinetic integral eigenmode equation. It is found that for a moderate electron density gradient, the SWITG mode is first destabilized and then stabilized with increasing elongation κ, which is different from the conventional long wavelength ITG mode. For a large electron density gradient, the elongation can effectively stabilize the SWITG mode. Moreover, the low Z impurity ions with inwardly (outwardly) peaked density profiles have stabilizing (destabilizing) effects on the SWITG modes in elongated plasmas. Interestingly, the high Z tungsten impurity ions with inwardly peaked density profiles play a stronger stabilizing role in the SWITG modes than the low Z impurity ions (such as carbon and oxygen) do. In particular, the high Z tungsten impurity ions with a weakly outwardly peaked density profile still have a stabilizing effect. Finally, the critical threshold of impurity density gradient scale length for exciting impurity mode is also numerically obtained, indicating that the impurity mode is harder to be excited in elongated plasmas than in circular ones.

The coupling of ion temperature gradient (ITG or ηi) mode and trapped electron mode (TEM) in the presence of impurity ions is numerically investigated in toroidal collisionless plasmas, using the gyrokinetic integral eigenmode equation. A framework for excitations of the ITG modes and TEMs with respect to their driving sources is formulated first, and then the roles of impurity ions played in are analyzed comprehensively. In particular, the characteristics of the ITG and TEM instabilities in the presence of impurity ions are emphasized for both strong and weak coupling (hybrid and coexistent) cases. It is found that the impurity ions with inwardly (outwardly) peaked density profiles have stabilizing (destabilizing) effects on the hybrid (namely the TE-ITG) modes in consistence with previous works. A new finding of this work is that the impurity ions have stabilizing effects on TEMs in small ηi (ηi≤1) regime regardless of peaking directions of their density profiles whereas the impurity ions with density g...