1. Multiobjective‐Optimization MoS2/Cd‐ZnIn2S4/CdS Composites Prepared by In Situ Structure‐Tailored Technique for High‐Efficiency Hydrogen Generation
- Author
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Wenxue Zhao, Aihua Yan, Zigao Su, Fei Huang, Quande Wang, Shihang Li, Shijian Lu, Chuanjian Wang, Tongyang Zhang, Jixu Zhang, Ye Gao, and Huaqi Yuan
- Subjects
in situ structure‐tailored technique ,MoS2/Cd‐ZnIn2S4/CdS composites ,multiobjective optimization ,photocatalytic water splitting ,synergistic feature ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
Photocatalytic water splitting into hydrogen production provides a new avenue to produce clean chemical fuels. However, developing high‐efficiency photocatalytic materials still remains a challenge till now. Herein, multiobjective‐optimization MoS2/Cd‐ZnIn2S4/CdS (MS/CZIS/CS) composites are successfully constructed by an in situ structure‐tailored technique. Benefiting from the synergistic feature integrating sulfur vacancy, II‐type CZIS/CS heterojunction and Schottky‐type MS/CS heterojunction, such composites not only effectively steer photogenerated carrier transfer but also markedly expedite surface reaction kinetics for hydrogen reduction reaction. As a result, an optimal hydrogen evolution rate of 11.49 mmol g−1 h−1 is achieved over the MS/CZIS/CS catalysts, which is approximately 4.79 times higher than that of pristine ZIS (2.40 mmol g−1 h−1). This work provides some new inspirations for the steering of carrier transfer and the design of multiobjective‐optimization photocatalysts with high efficiency.
- Published
- 2024
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