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Drawing upon Édouard Glissant's notion of the 'archipel' and Gene Youngblood's concept of the 'expanded cinema,' this study examines recent examples of screen-based public art showcased in densely populated Chinese metropolises. Focusing on the artworks' potential to reconfigure the spaces they inhabit and engage the spectators within the context of urban landscapes, screens in these artworks are portrayed as integral components of an archipelago, elucidating the mobility of cultural communication. We introduce a methodological framework, termed 'World-Archipelago' and 'Archipelago-World.' The former scenario involves artworks that remain central and interact with their surroundings as extensions, merging virtual experiences with reality, while the latter blurs the boundaries between the artwork and its context, harmonizing with local culture and seamlessly integrating into the urban fabric. Thus, this study posits that applying archipelagic thinking provides a substantial and analytical understanding of screens as an artistic medium within public art, involving a rhizomatic interplay that transcends the conventional centre–periphery paradigm and demands an exploration of the evolving relationships between screen-based public art and spatial critical awareness within metropolitan contexts. [ABSTRACT FROM AUTHOR]

Under the background of "carbon peaking and carbon neutrality", the carbon emissions produced by the public’s daily consumption cannot be ignored. However, the data show that there is a disunity of knowing and doing in low-carbon consumption. How to get out of the dilemma, and how to guide the public to the low-carbon consumption mode has become an urgent issue to be solved. This study uses the research method of in-depth interview and the grounded theory to build a research model suitable for the analysis of low-carbon consumption behavior, and explains the disunity of knowing and doing. The results show that low-carbon knowledge, personal benefits, moral image and social norms have significant effects on low-carbon consumption behavior, and the mechanisms and paths of their effects are different. On this basis, this study explores and integrates the "knowledge-cognition-behavior" model to analyse low-carbon consumption behaviors, which can provide targeted policy ideas and implementation paths for relevant institutions.

Comprehensive Summary: Cooperative NHC/photoredox catalysis has emerged as an important research field in recent years. Herein, this article describes the use of cesium salt derivatives of tert‐alcohols as alkyl radical precursors in a three‐component reaction with styrene and aromatic acyl fluorides to synthesize α‐arylalkyl aryl ketones. The aroyl fluoride reacts with the NHC catalyst, leading to the formation of an acyl azolium ion. This acyl azolium ion can then be reduced by the photoredox catalyst, generating the corresponding ketyl radical anion. The C‐radical generated from oxalate oxidation undergoes an addition reaction with the styrene derivative, followed by cross‐coupling of the addition radical with the ketone radical, which is fragmented by NHC to give the target ketone. [ABSTRACT FROM AUTHOR]

A visible-light-mediated glycosylation reaction between glycosyl redox-active esters and disulfides has been reported, through which a series of S-aryl glycosides were obtained in good yields with satisfactory stereoselectivity. The preliminary mechanistic studies revealed that this transformation proceeded via an EDA complex. Moreover, the potential application value was demonstrated in the late-stage functionalisation of drug molecules and a gram-scale experiment. [ABSTRACT FROM AUTHOR]

A transition-metal-catalyzed C-H activation cascade strategy to rapidly construct diverse quinazolinone derivatives in a one-pot manner is reported. The catalysts play an important role in the different transformations. Additionally, the procedure is scalable, proceeds with high efficiency and good chemo-/regio-selectivity, and tolerates a range of functional groups., (© 2021 Wiley-VCH GmbH.)