1. Activation of H2O2 by carbonaceous iron sludge-derived catalyst for methylene blue wastewater treatment
- Author
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WANG Lia, WU Shuang, CHENG Xiaoshuang, LIANG Lan, LI Ning, CHEN Guanyi, and HOU Li’an
- Subjects
waste iron sludge ,fenton-like ,dye wastewater ,Environmental technology. Sanitary engineering ,TD1-1066 - Abstract
Resource utilization of waste iron sludge from wastewater treatment plants can be achieved by leveraging iron sludge-based catalysts to construct Fenton-like systems. Notably,the pyrolysis temperature modulates the composition of metal and non-metal sites on the catalyst surface,thus affecting the activation of hydrogen peroxide(H2O2). The catalysts prepared at different pyrolysis temperatures(400-700 ℃) were analyzed in terms of morphology,composition,structure and activity. It was found that the degradation efficiency of methylene blue(MB) could reach 92.0% within 100 min with the activation of H2O2 by the catalyst obtained at 700 °C. Additionally,the specific surface area and C content of the catalyst increased as the pyrolysis temperature increased from 400 ℃ to 700 ℃. The mechanistic investigation revealed that Fe0,C̿ C/C—C and C̿ O active sites on the catalyst surface were critical for the activation of H2O2,which facilitated MB degradation. Moreover,hydroxyl radicals(·OH) and singlet oxygen(1O2) were the dominant active species in the iron sludge-derived catalyst/H2O2 system,with superoxide radicals(O2·-) playing a minor role.
- Published
- 2024
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