1. On Ni-Sb-Sn based skutterudites
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Paschinger, W., Rogl, P. F., Rogl, G., Grytsiv, A., Bauer, E., Michor, H., Eisenmenger-Sitter, Ch., Royanian, E., Heinrich, P. R., Zehetbauer, M., Horky, J., Puchegger, S., Reinecker, M., Giester, G., Broz, P., and Bismarck, A.
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Condensed Matter - Materials Science - Abstract
Novel filled skutterudites EpyNi4Sb12-xSnx (Ep = Ba and La) have been prepared by arc melting followed by annealing at 250C, 350C and 450C up to 30 days in sealed quartz vials. A maximum filling level of y = 0.93 and y = 0.65 was achieved for the Ba and La filled skutterudite, respectively. Single-phase samples with the composition Ni4Sb8.2Sn3.8, Ba0.42Ni4Sb8.2Sn3.8 and Ba0.92Ni4Sb6.7Sn5.3 were employed for measurements of the physical properties i.e. temperature dependent electrical resistivity, Seebeck coefficient and thermal conductivity. Resistivity data showed a crossover from metallic to semiconducting behaviour. The corresponding gap width was extracted from maxima in the Seebeck coefficient data as a function of temperature. Temperature dependent single crystal X-ray structure analyses (at 100 K, 200 K and 300 K) revealed the thermal expansion coefficients, Einstein and Debye temperatures for two selected samples Ba0.73Ni4Sb8.1Sn3.9 and Ba0.95Ni4Sb6.1Sn5.9. These data compare well with Debye temperatures from measurements of specific heat (4.4 K < T < 200 K). Several mechanical properties were measured and evaluated. Thermal expansion coefficients are 11.8.10-6 K-1 for Ni4Sb8.2Sn3.8 to 13.8.10-6 K-1 for Ba0.92Ni4Sb6.7Sn5.3. Room temperature Vicker's hardness values (up to a load of 24.5 mN) vary within the range of 2.6 GPa to 4.7 GPa. Severe plastic deformation (SPD) via high-pressure torsion (HPT) was used to introduce nanostructuring. Physical properties before and after HPT were compared, showing no significant effect on the material's thermoelectric behaviour.
- Published
- 2017
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