1. Discovery and identification of arsenic removal products from molten steel by adding rare earth
- Author
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Hongpo Wang, Jian Kang, and Yu Wang
- Subjects
Rare earth ,Steel ,Inclusion ,Precipitate ,Characterization ,Mining engineering. Metallurgy ,TN1-997 - Abstract
The use of scrap steel is bound to increase significantly in the following decades to reduce carbon emissions. However, the enrichment of residual elements in steel production has become a severe problem in recycling scrap steel. Arsenic compounds formed in La-added molten steel were investigated by simulation and experiments, and two of them were identified for the first time. The arsenic compounds turned out to be mainly La–S–As, La–As, and LaAsO4. The crystallographic system of La–S–As was certified cubic with a lattice constant of 0.6060 nm. La–S–As can be considered a solid solution resulting from randomly replacing S atoms of LaS with As, and its chemical formula was proved to be La4S3As. The La–As binary compound was identified as cubic with a lattice constant of 0.6162 nm, and its chemical formula was determined as LaAs. La4S3As started to form in molten steel and aggregated to generate large clusters that floated up mostly. It provides a new strategy for reducing residual elements represented by arsenic in molten steel. LaAsO4 and LaAs were initially generated during solidification and preferred to precipitate at grain boundaries.
- Published
- 2022
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