1. Sensitivity-Enhancing Modified Holographic Photopolymer of PQ/PMMA.
- Author
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Wu, Junhui, Jin, Junchao, Hu, Po, Li, Jinhong, Zeng, Zeyi, Li, Qingdong, Liu, Jie, Chen, Mingyong, Zhang, Zuoyu, Wang, Li, Lin, Xiao, and Tan, Xiaodi
- Subjects
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DENDRIMERS , *ANALYTICAL chemistry , *PHOTOSENSITIVITY , *ACTIVATION energy , *PHOTOPOLYMERS , *PENTAERYTHRITOL - Abstract
Phenanthrenequinone-doped poly(methyl methacrylate) (PQ/PMMA) photopolymers are potential holographic storage media owing to their high-density storage capacities, low costs, high stability, and negligible shrinkage in volume holographic permanent memory. However, because of the limitations of the substrate, conventional Plexiglas materials do not exhibit a good performance in terms of photosensitivity and molding. In this study, the crosslinked structure of PMMA was modified by introducing a dendrimer monomer, pentaerythritol tetraacrylate (PETA), which increases the photosensitivity of the material 2 times (from ~0.58 cm/J to ~1.18 cm/J), and the diffraction efficiency is increased 1.6 times (from ~50% to ~80%). In addition, the modified material has a superior ability to mold compared to conventional materials. Moreover, the holographic performance enhancement was evaluated in conjunction with a quantum chemical analysis. The doping of PETA resulted in an overall decrease in the energy required for the reaction system of the material, and the activation energy decreased by ~0.5 KJ/mol in the photoreaction stage. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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