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We report observations of molecular oxygen (O$_2$) rotational transitions at 487 GHz, 774 GHz, and 1121 GHz toward Orion Peak A. The O2 lines at 487 GHz and 774 GHz are detected at velocities of 10-12 km/s with line widths 3 km/s; however, the transition at 1121 GHz is not detected. The observed line characteristics, combined with the results of earlier observations, suggest that the region responsible for the O$_2$ emission is 9" (6e16 cm) in size, and is located close to the H2 Peak 1position (where vibrationally-excited H$_2$ emission peaks), and not at Peak A, 23" away. The peak O2 column density is 1.1e18/cm2. The line velocity is close to that of 621 GHz water maser emission found in this portion of the Orion Molecular Cloud, and having a shock with velocity vector lying nearly in the plane of the sky is consistent with producing maximum maser gain along the line-of-sight. The enhanced O$_2$ abundance compared to that generally found in dense interstellar clouds can be explained by passage of a low-velocity C-shock through a clump with preshock density 2e4/cm3, if a reasonable flux of UV radiation is present. The postshock O$_2$ can explain the emission from the source if its line of sight dimension is ~10 times larger than its size on the plane of the sky. The special geometry and conditions required may explain why O$_2$ emission has not been detected in the cores of other massive star-forming molecular clouds., Comment: 28 pages, 13 figures

We observed OH, H$_2$O, HN$_3$, C$^{18}$O, and C$_I$ towards the +50 km/s cloud (M-0.02-0.07), the CND and the +20 km/s (M-0.13-0.08) cloud in the Sgr A complex with the VLA, Odin and SEST. Strong OH absorption, H$_2$O emission and absorption lines were seen at all three positions. Strong C$^{18}$O emissions were seen towards the +50 and +20 km/s clouds. The CND is rich in H$_2$O and OH, and these abundances are considerably higher than in the surrounding clouds, indicating that shocks, star formation and clump collisions prevail in those objects. A comparison with the literature reveals that it is likely that PDR chemistry including grain surface reactions, and perhaps also the influences of shocks has led to the observed abundances of the observed molecular species studied here. In the redward high-velocity line wings of both the +50 and +20 km/s clouds and the CND, the very high H$_2$O abundances are suggested to be caused by the combined action of shock desorption from icy grain mantles and high-temperature, gas-phase shock chemistry. Only three of the molecules are briefly discussed here. For OH and H$_2$O three of the nine observed positions are shown, while a map of the C$^{18}$O emission is provided. An extensive paper was recently published with Open Access (Karlsson et al. 2013; http://www.aanda.org/articles/aa/pdf/2013/06/aa20471-12.pdf )., Comment: Proc. of a Conf. on IAU Symposium No.303: The Galactic Center: Feeding and Feedback in a Normal Galactic Nucleus 2013, Santa Fe, NM (USA)

We report the results of a search for molecular oxygen (O2) toward the Orion Bar, a prominent photodissociation region at the southern edge of the HII region created by the luminous Trapezium stars. We observed the spectral region around the frequency of the O2 N_J = 3_3 - 1_2 transition at 487 GHz and the 5_4 - 3_4 transition at 774 GHz using the Heterodyne Instrument for the Far Infrared on the Herschel Space Observatory. Neither line was detected, but the 3sigma upper limits established here translate to a total line-of-sight O2 column density < 1.5 10^16 cm^-2 for an emitting region whose temperature is between 30K and 250 K, or < 1 10^16 cm^-2 if the O2 emitting region is primarily at a temperature of ~< 100 K. Because the Orion Bar is oriented nearly edge-on relative to our line of sight, the observed column density is enhanced by a factor estimated to be between 4 and 20 relative to the face-on value. Our upper limits imply that the face-on O2 column density is less than 4 10^15 cm^-2, a value that is below, and possibly well below, model predictions for gas with a density of 10^4 - 10^5 cm^-3 exposed to a far ultraviolet flux 10^4 times the local value, conditions inferred from previous observations of the Orion Bar. The discrepancy might be resolved if: (1) the adsorption energy of O atoms to ice is greater than 800 K; (2) the total face-on Av of the Bar is less than required for O2 to reach peak abundance; (3) the O2 emission arises within dense clumps with a small beam filling factor; or, (4) the face-on depth into the Bar where O2 reaches its peak abundance, which is density dependent, corresponds to a sky position different from that sampled by our Herschel beams., Comment: 30 pages, 7 figures, 1 table. Accepted for publication in ApJ

We report observations of three rotational transitions of molecular oxygen (O2) in emission from the H2 Peak 1 position of vibrationally excited molecular hydrogen in Orion. We observed the 487 GHz, 774 GHz, and 1121 GHz lines using HIFI on the Herschel Space Observatory, having velocities of 11 km s-1 to 12 km s-1 and widths of 3 km s-1. The beam-averaged column density is N(O2) = 6.5\times1016 cm-2, and assuming that the source has an equal beam filling factor for all transitions (beam widths 44, 28, and 19"), the relative line intensities imply a kinetic temperature between 65 K and 120 K. The fractional abundance of O2 relative to H2 is 0.3 - 7.3\times10-6. The unusual velocity suggests an association with a ~ 5" diameter source, denoted Peak A, the Western Clump, or MF4. The mass of this source is ~ 10 M\odot and the dust temperature is \geq 150 K. Our preferred explanation of the enhanced O2 abundance is that dust grains in this region are sufficiently warm (T \geq 100 K) to desorb water ice and thus keep a significant fraction of elemental oxygen in the gas phase, with a significant fraction as O2. For this small source, the line ratios require a temperature \geq 180 K. The inferred O2 column density \simeq 5\times1018 cm-2 can be produced in Peak A, having N(H2) \simeq 4\times1024 cm-2. An alternative mechanism is a low-velocity (10 to 15 km s-1) C-shock, which can produce N(O2) up to 1017 cm-2.