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2. Promoting Effect and Role of Alkaline Earth Metal Added to Supported Ag Catalysts in the Gas-Phase Catalytic Oxidation of Benzyl Alcohol

Author

Shigeru Tsuruya, Yo-suke Sawayama, Hiroshi Shibahara, Satoru Nishiyama, and Yuichi Ichihashi

Subjects
Alkaline earth metal, General Chemical Engineering, Inorganic chemistry, General Chemistry, Toluene, Industrial and Manufacturing Engineering, Catalysis, Benzaldehyde, chemistry.chemical_compound, chemistry, Catalytic oxidation, Benzyl alcohol, Partial oxidation, Benzene
Abstract

The effect and the role of alkaline earth metals added to Ag/SiO2 catalyst were studied in the gas-phase catalytic oxidation of benzyl alcohol. The main oxidation product was benzaldehyde, together with only small amounts of CO2, benzene, and toluene, depending on the reaction conditions. The influence of the method regarding how to add the alkaline earth metal to the supported Ag catalyst, and the amount of the added alkaline earth metal on the partial oxidation activity, was investigated, along with the analyses of these alkaline earth metal added Ag/SiO2 catalysts by diffuse reflectance (DR) spectroscopy, XRD, thermal gravimetric−differential thermal analyses (TG−DTA), and extended X-ray absorption fine structure (EXAFS). The addition of alkaline earth metals such as Ca, Sr, and Ba to the Ag/SiO2 catalyst by a coimpregnation method significantly promoted the catalytic activity of the partial oxidation of benzyl alcohol. The surface oxygen species on the supported Ag played an important role in the part...

Published
2006

3. Promoted partial oxidation activity of supported Ag catalysts in the gas-phase catalytic oxidation of benzyl alcohol

Author

Satoru Nishiyama, Shigeru Tsuruya, Yuichiro Ichihashi, Ryohei Yamamoto, Hiroshi Shibahara, and Yo-suke Sawayama

Subjects
Chemistry, Catalyst support, Inorganic chemistry, Catalysis, law.invention, Benzaldehyde, chemistry.chemical_compound, Transition metal, Catalytic oxidation, Benzyl alcohol, law, Calcination, Partial oxidation, Physical and Theoretical Chemistry
Abstract

The gas-phase catalytic oxidation of benzyl alcohol was carried out using Ag catalysts impregnated on a SiO 2 or CaO support, as well as a potassium-added counterpart (K/Ag/SiO 2 ), to clarify the surface state of the Ag species active in the oxidation reaction, the effect of the basic support and the added alkali metal. Benzaldehyde was obtained as the main oxidation product. The effects of the calcination temperature of the Ag/SiO 2 catalyst and the reaction temperature on oxidation activity were investigated. The benzaldehyde yield markedly increased between 553 and 593 K. Increasing the calcination temperature from 773 to 1173 K also caused a significant increase in partial oxidation activity. Both a CaO support for the Ag species and potassium added to the Ag/SiO 2 catalyst promoted partial oxidation at a comparatively low reaction temperature. X-ray diffraction and extended X-ray absorption fine structure demonstrated that a high calcination temperature, a basic support, and addition of an alkali metal led to a more ready reduction of the supported Ag to metallic Ag. Oxidized surface Ag species on the metallic Ag were inferred to be the active Ag components for the partial oxidation of benzyl alcohol based on the amount of O 2 uptake and the diffuse reflectance spectra of the supported Ag catalysts.

Published
2005

4. Combination Therapy with Angiotensin-Converting Enzyme Inhibitor and Oral Adsorbent of Uremic Toxins Can Delay the Appearance of Glomerular Sclerosis and Interstitial Fibrosis in Established Renal Failure

Author

Koichi Matsumoto, Erina Okawa, Noriaki Maruyama, Susumu Takahashi, Hiroshi Shibahara, Kazuyoshi Okada, and Takashi Maruyama

Subjects
Male, medicine.medical_specialty, Combination therapy, Angiotensin-Converting Enzyme Inhibitors, Interstitial fibrosis, Blood Urea Nitrogen, Rats, Sprague-Dawley, Enalapril, Internal medicine, medicine, Animals, cardiovascular diseases, Uremia, biology, Glomerulosclerosis, Focal Segmental, business.industry, Glomerulosclerosis, Oxides, Angiotensin-converting enzyme, General Medicine, medicine.disease, Angiotensin II, Carbon, Rats, Endocrinology, Nephrology, Enzyme inhibitor, Creatinine, biology.protein, Uremic toxins, Kidney Failure, Chronic, Nephritis, Interstitial, Chronic renal failure, Drug Therapy, Combination, Sorption Detoxification, Adsorption, Cardiology and Cardiovascular Medicine, business
Abstract

Background/Aim: Angiotensin II plays a central role in the progression of chronic renal failure (CRF), and administration of angiotensin-converting enzyme inhibitor (ACEI) in rats delays the progression of CRF. However, ACEI has little effect on CRF progression in rats with established CRF. We therefore examined whether combination therapy with ACEI and oral adsorbent for uremic toxins in the gastrointestinal tract has the desired effect. Methods: Rats subjected to subtotal nephrectomy were given enalapril at 20 mg/kg (n = 10, group E), AST-120 at 5 g (n = 10, group A), enalapril and AST-120 together at the same doses (n = 10, group EA), or no treatment (n = 10, group C) 8 weeks after the operation. The substances were administered in 100 g rat chow. All animals were pair-fed, and all were killed after 8 weeks of pair-feeding. Results: Body weight did not differ between groups during the study. Blood pressure at week 8 was significantly lower in groups E and EA than in groups C and A (p < 0.05). Urinary protein excretion level and renal plasma flow rate at week 8 were significantly less in groups E and EA than in group C (p < 0.05, p < 0.01). The glomerular filtration rate at week 8 was significantly higher in group EA than in group C (p < 0.05). The glomerular sclerosis index and interstitial fibrosis area at week 8 were significantly less in group EA than in group C (p < 0.01). Conclusion: ACEI and AST-120 in combination can delay progression of established CRF in rats by inhibiting the appearance of glomerular sclerosis and interstitial fibrosis.

Published
2004

5. Body movement of patients with femoral vein catheterization using the double axial type catheter

Author

Hiroshi Shibahara, Koichi Matsumoto, Chihiro Hagi, Masanori Abe, Yoshiko Takahashi, Susumu Takahashi, Kazuyoshi Okada, Yuji Nagura, Terumi Higuchi, and Katsuo Kanmatsuse

Subjects
medicine.medical_specialty, Catheter, business.industry, medicine, Femoral vein, Body movement, Radiology, business, Surgery
Abstract

ブラッドアクセスカテーテルを鼠径部に留置する場合, 当院では, コアクシャル型UKカテーテルを使用する際には, 歩行が可能であったという報告に基づき歩行を許可しているが, ダブルアクシャル型カテーテルを使用する際には, 同様の報告がないため歩行禁止としている. 今回, 各種ダブルアクシャル型カテーテルの柔軟性に対する基礎的研究を施行し, その中で最も柔軟性のあるカテーテルを使用し, 鼠径部に留置した時の体動を中心とした臨床的研究を行った.基礎的研究: コアクシャル型ブラッドアクセスUKカテーテル (UK-C), ダブルアクシャル型ブラッドアクセスUKカテーテル (UK-D), ダブルアクシャル型Vas-cath Flexxicon, ダブルアクシャル型Quinton血管留置用カテーテルを用いて, カテーテルの硬度を常温と37℃の条件で測定した. 常温ではUK-Cが最も硬度が低かったが, 37℃の温水ではUK-Dが最も硬度が低下した.臨床的研究: ブラッドアクセスとして, 最も柔軟性のあるUK-Dを使用し, 観察期間は6回のHD施行後までとした. 内頸静脈からアプローチした症例 (IJV group, n=20) の体動は制限しなかったが, 大腿静脈からアプローチした症例 (FV group, n=20) には体動を制限した. 試験開始時と終了時の体温, 白血球数, CRP, 血流量は両groupとも試験開始時と終了時で有意差はなかった. 試験終了時のカテーテル挿入部と縫合部の発赤発生率は, 両groupで有意差はなかった.UK-Dを鼠径部に短期間留置した場合, 本研究で許可した体動では内頸静脈からのアプローチと比較し, 臨床上問題となる感染や血栓形成には明らかな差は認めなかった. よって, 柔軟性のあるUK-Dを使用した場合には, 短時間の歩行や座位などの体動は許容範囲内であると思われた.

Published
2002

6. Cuff-Related Problems With a Tunneled Cuffed Venous Catheter

Author

Susumu Takahashi, Hiroshi Shibahara, and Nami Shibahara

Subjects
Equipment failure, Catheter, medicine.medical_specialty, Device removal, Nephrology, business.industry, Cuff, MEDLINE, Medicine, Hematology, business, Surgery
Published
2010

7. Contents, Vol. 76, 1997

Author

A. Grill, Yoichiro Kondo, Silvia Anna Ciafrè, Radovan Bogdanovic, Luigi Mansi, Rosemary A. Dodds, András Mogyorósi, Rosa Maria Pollastro, S. Ferrero, Giovanbattista Capasso, Marie Urabe, Yasuko Kato, Hyun Lee, Harald Fricke, Günther Zempel, Yon Su Kim, Erminio Di Paolo, Chikako Segawa, Lucia Spitali, Seung Hyup Kim, Hiroshi Shibahara, Gen Kuramochi, Yukimasa Hisada, José B. Lopes de Faria, Kazuyoshi Okada, Jin Suk Han, Idrac Neman, Jens Ditlevsen, Rogério Friedman, Susumu Takahashi, Eleonora Cirillo, Helmut Heinle, Matthew D. Carley, Chikao Yasunaga, Jung Sang Lee, Massimo Cirillo, Attilio Di Benedetto, Stefan Silbernagl, Frederic Dubois, Hitoshi Kubosawa, C. Canavese, Alois Sellmayer, Satoshi Ohta, Salvatore de Cosmo, Gakusen Nishihara, Marija Zlatković, Y. Vanrenterghem, P. Stratta, Matthias Hoch, Ying Yu, Jitsuo Higaki, Pietro Anastasio, Florian Lang, Francesco Paolo D’Armiento, Takashi Wada, G. Piccoli, Hitoshi Yokoyama, Toshio Ogihara, Chong-Guang Leng, Christoph Jeschke, Masahiro Nagano, Toshimitsu Niwa, Suhnggwon Kim, Nobuaki Nakano, Hiroshi Mikami, James J. Mortton, Tadanobu Goya, Kenzo Matsuo, Domenico Santoro, Teresa Posca, Ivica Stankovic, Giancarlo Viberti, Hisahiro Yu, Andreas Eigler, Masayoshi Takaeda, Shinichi Ohno, Helmut Schiffl, Michael Gekle, Milos Ognjanovic, Ken-ichi Kobayashi, Giuseppe Bruzzese, Alessandro Ferrara, Antonio Liguori, Obren Popovic, Ute Emerich, Pompeo Sorice, Kengo Furuichi, Yoshikage Yo, Masahiko Nakamoto, Dorotea Capodicasa, Njegica Jojic, Curie Ahn, Claudio Napoli, Pierre Schiavi, Kei Kamide, Natale G. De Santo, Kazuhito Takeda, Vesna Nikolić, Fernando Di Gregorio, and Atsushi Moriguchi

Subjects
Traditional medicine, Nephrology, business.industry, Medicine, General Medicine, business
Published
1997

8. Cuff-related problems with a tunneled cuffed venous catheter

Author

Hiroshi, Shibahara, Nami, Shibahara, and Susumu, Takahashi

Subjects
Aged, 80 and over, Male, Catheterization, Central Venous, Renal Dialysis, Humans, Kidney Failure, Chronic, Equipment Failure, Female, Equipment Design, Middle Aged, Device Removal, Aged
Published
2011

9. Cardiorenal protective effect of the oral uremic toxin absorbent AST-120 in chronic heart disease patients with moderate CKD

Author

Hiroshi, Shibahara and Nami, Shibahara

Subjects
Heart Failure, Male, Chronic Disease, Quality of Life, Humans, Female, Kidney Diseases, Oxides, Middle Aged, Protective Agents, Carbon, Aged
Abstract

The detailed mechanisms and treatment methods of chronic kidney disease (CKD) in patients with chronic heart failure (CHF) are not fully understood. We conducted a prospective study in CHF patients manifesting CKD to examine if AST-120 (Kremezin) improves cardiac and renal functions.Twenty outpatients with CHF manifesting moderate CKD (serum creatinine 1.3-2.0 mg/dL) were studied. The patients had received AST-120 at a dosage of 6 g/day in combination with existing medications for 24 months. Some parameters of kidney and heart function were monitored. Also the cumulative length of hospital stay and number of admissions for the 2-year periods before and after initiation of AST-120 treatment were calculated.Results of renal function tests, atrial natriuretic peptide, edema, cardiothoracic ratio and hospital stay indicated significant improvements in patients treated with AST-120. The length of hospital stay and number of admissions both decreased significantly during the 2 years of AST-120 treatment compared with the 2 years before treatment, from 39.7 ± 12.9 days to 4.14 ± 2.5 days, and from 0.79 ± 0.21 admissions to 0.21 ± 0.11 admissions, respectively.AST-120 contributes to the improvement of cardiac and renal functions, and consequently improves the quality of life of patients.

Published
2009

11. Relationship between insulin resistance and uremic toxins in the gastrointestinal tract

Author

Terumi Higuchi, Kyoko Aoki, Katsuo Kanmatsuse, Erina Okawa, Chihiro Hagi, Hiroshi Shibahara, Kazuyoshi Okada, Yoshihiko Onishi, Yoshiko Takahashi, Yuji Nagura, and Susumu Takahashi

Subjects
Blood Glucose, Male, medicine.medical_specialty, medicine.medical_treatment, Renal function, Blood Urea Nitrogen, Diabetic nephropathy, Rats, Sprague-Dawley, Enterotoxins, Insulin resistance, Internal medicine, Medicine, Animals, Insulin, Diabetic Nephropathies, Blood urea nitrogen, Uremia, Gastrointestinal tract, business.industry, Body Weight, Oxides, medicine.disease, Nephrectomy, Carbon, Rats, Disease Models, Animal, Proteinuria, Endocrinology, Creatinine, Adsorption, Insulin Resistance, business, Digestive System, Kidney disease
Abstract

The relationship between insulin resistance and local uremic toxins was examined using an oral adsorbent. Fourteen rats demonstrating a diabetic state underwent two-thirds, nephrectomy and were divided into two groups. The control group was fed standard rat chow, and the test group was fed standard rat chow containing 5% AST-120. The target level of blood glucose was achieved by controlling the dosage of exogenous insulin. All rats were sacrificed at week 6. Body weight, blood glucose level, and renal function at week 6 were not significantly different between both groups. However, the mean blood glucose level and the mean dose of exogenous insulin in the AST-120-fed group were significantly reduced as compared with the control group. The results of the present study indicate that administration of an oral adsorbent in diabetic nephropathy decreases the doses of exogenous insulin and improves insulin resistance, and that uremic toxins which exist in the gastrointestinal tract play important roles.

Published
2001

12. Effect of oral adsorbent on the progression of diabetic nephropathy

Author

Kazuyoshi Okada, Susumu Takahashi, and Hiroshi Shibahara

Subjects
Male, medicine.medical_specialty, business.industry, Urology, Oxides, General Medicine, medicine.disease, Carbon, Diabetes Mellitus, Experimental, Rats, Diabetic nephropathy, Rats, Sprague-Dawley, Nephrology, Disease Progression, Medicine, Animals, Diabetic Nephropathies, Adsorption, business
Published
1997

13. Subject Index Vol. 88, 2001

Author

Hiroko Yamasaki, David A. Sampson, Aydan Ikinciogullari, Janice Green, Gavin J. Becker, Cüneyt Ensari, Hassane Izzedine, Hiroshi Shibahara, Yoshihiko Kawarada, Yuji Nagura, Masahiro Hiraoka, F. Grases, Kazuo Fujisawa, Seiki Ito, Chikahide Hori, Katsuo Suyama, Mitsufumi Mayumi, Yusei Ohshima, D. Grekas, Norishige Yoshikawa, Tim D. Hewitson, Kazuo Tsuzuki, Muhammad Salmanullah, Masatomo Yashiro, Tadashi Kamata, Nigel Wardle, Takuma Narita, O. Söhnel, Z. Wang, Koichi Matsumoto, Adrian Williams, Michael K. Hise, Toshiko Yaginuma, Hiroki Fujita, Hirofumi Makino, Yoshihiko Onishi, Kathleen M. Nicholls, D. Stratakis, Eri Muso, Olivier Pajot, Sydney Benchetrit, Terumi Higuchi, Gilbert Deray, Toshihiro Sugiyama, Shigetake Sasayama, Masami Kawagoe, Jacques Bernheim, Hiroyuki Ohi, Eugenia Pedagogos, Donald Richardson, A. Makedou, H. Schiffl, Hélène Beaufils, Erina Okawa, Yoshiyuki Yoshida, A. Tourkantonis, Richard B. Parsons, Mariko Tamano, Arzu Ensari, E. Kassimatis, Kazuyoshi Okada, Mesiha Ekim, Shigeki Miyawaki, Fumiaki Nogaki, Chihiro Hagi, Kazuo Yoshioka, G. Bamichas, Sahare Fongoro, Haruyoshi Yoshida, Atsushi Oyama, Kyoko Aoki, Katsuo Kanmatsuse, Richard M. Rohan, D. Bacharaki, David B. Ramsden, S.M. Lang, Bernard Katz, A. Costa-Bauzá, Ikei Kobayashi, Necmiye Tümer, M. Ramis, Yoshio Nagake, Hurokazu Tsukahara, Susumu Takahashi, Velibor Tasic, Takahiko Ono, Eduardo Podjarny, Gloria S. Tannenbaum, Petar Korneti, Hiroyuki Matsushima, Yoshiko Takahashi, Rosemary H. Waring, and Cerys C. Huggins

Subjects
Index (economics), business.industry, Statistics, Medicine, Subject (documents), business
Published
2001

14. Bloody Discoloration of Peritoneal Dialysate Bags

Author

Terumi Higuchi, Katsuo Kanmatsuse, Susumu Takahashi, Chihiro Hagi, Y Onishi, Kazuyoshi Okada, K Aoki, M Suzuki, Hiroshi Shibahara, Tsutomu Kuno, and Yuji Nagura

Subjects
Bloody, medicine.medical_specialty, Nephrology, business.industry, medicine.medical_treatment, medicine, General Medicine, business, Peritoneal dialysate, Surgery, Peritoneal dialysis
Published
1999

15. Subject Index Vol. 76,1997

Author

Matthew D. Carley, Satoshi Ohta, Masahiro Nagano, Teresa Posca, Ken-ichi Kobayashi, Giuseppe Bruzzese, Michael Gekle, Hitoshi Yokoyama, Nobuaki Nakano, Harald Fricke, Stefan Silbernagl, Matthias Hoch, Jung Sang Lee, Eleonora Cirillo, Florian Lang, Njegica Jojic, Francesco Paolo D’Armiento, C. Canavese, S. Ferrero, Pompeo Sorice, Giancarlo Viberti, Andreas Eigler, Natale G. De Santo, Yasuko Kato, Kei Kamide, Yoichiro Kondo, Pietro Anastasio, Chikao Yasunaga, Chikako Segawa, P. Stratta, Antonio Liguori, Hyun Lee, Alessandro Ferrara, Seung Hyup Kim, Obren Popovic, Toshio Ogihara, Toshimitsu Niwa, Attilio Di Benedetto, Milos Ognjanovic, Kazuyoshi Okada, Dorotea Capodicasa, Frederic Dubois, Silvia Anna Ciafrè, Curie Ahn, Chong-Guang Leng, Fernando Di Gregorio, Ying Yu, Hiroshi Mikami, Yon Su Kim, James J. Mortton, Tadanobu Goya, Susumu Takahashi, Erminio Di Paolo, Kengo Furuichi, Yoshikage Yo, Claudio Napoli, Masayoshi Takaeda, Massimo Cirillo, Hiroshi Shibahara, José B. Lopes de Faria, Hitoshi Kubosawa, Helmut Schiffl, Pierre Schiavi, Jin Suk Han, Gen Kuramochi, Salvatore de Cosmo, A. Grill, Rogério Friedman, Atsushi Moriguchi, Ute Emerich, Lucia Spitali, Helmut Heinle, Kazuhito Takeda, András Mogyorósi, Vesna Nikolić, Günther Zempel, Marie Urabe, Luigi Mansi, Giovanbattista Capasso, Radovan Bogdanovic, Rosemary A. Dodds, Rosa Maria Pollastro, Idrac Neman, Jens Ditlevsen, Christoph Jeschke, Shinichi Ohno, Jitsuo Higaki, Masahiko Nakamoto, Gakusen Nishihara, Y. Vanrenterghem, Hisahiro Yu, Suhnggwon Kim, Kenzo Matsuo, Domenico Santoro, Ivica Stankovic, Alois Sellmayer, Marija Zlatković, Takashi Wada, Yukimasa Hisada, and G. Piccoli

Subjects
Index (economics), Nephrology, business.industry, Statistics, Medicine, Subject (documents), General Medicine, business
Published
1997

16. Synergetic Effect of Low Protein Diet Combined with Oral Adsorbent on the Progression of Chronic Renal Failure

Author

Susumu Takahashi, Kazuyoshi Okada, Terumi Higuchi, and Hiroshi Shibahara

Subjects
Male, medicine.medical_specialty, business.industry, medicine.medical_treatment, Disease progression, Administration, Oral, Drug Synergism, Oxides, Pharmacology, Carbon, Drug synergism, Rats, Adsorption, Endocrinology, Low-protein diet, Internal medicine, Diet, Protein-Restricted, Disease Progression, medicine, Animals, Kidney Failure, Chronic, Chronic renal failure, business
Published
1996

17. Contents Vol. 88, 2001

Author

Kazuo Yoshioka, Katsuo Kanmatsuse, D. Grekas, Tadashi Kamata, D. Stratakis, Mesiha Ekim, Masami Kawagoe, Takuma Narita, Donald Richardson, Sydney Benchetrit, Terumi Higuchi, Adrian Williams, Bernard Katz, Koichi Matsumoto, Hirofumi Makino, Yoshihiko Onishi, Norishige Yoshikawa, Takahiko Ono, Yoshihiko Kawarada, Atsushi Oyama, Shigeki Miyawaki, Eduardo Podjarny, Chikahide Hori, Seiki Ito, Shigetake Sasayama, Eugenia Pedagogos, Erina Okawa, Kazuyoshi Okada, Olivier Pajot, Hiroyuki Matsushima, M. Ramis, H. Schiffl, Hurokazu Tsukahara, Hiroshi Shibahara, Eri Muso, Yusei Ohshima, Haruyoshi Yoshida, Nigel Wardle, Hiroyuki Ohi, Hiroko Yamasaki, David A. Sampson, Jacques Bernheim, Gloria S. Tannenbaum, Kathleen M. Nicholls, Mitsufumi Mayumi, G. Bamichas, Kyoko Aoki, A. Tourkantonis, Richard B. Parsons, D. Bacharaki, Kazuo Fujisawa, Masahiro Hiraoka, O. Söhnel, David B. Ramsden, Chihiro Hagi, Toshiko Yaginuma, S.M. Lang, Yoshio Nagake, Yoshiyuki Yoshida, Cerys C. Huggins, Toshihiro Sugiyama, F. Grases, E. Kassimatis, Rosemary H. Waring, Hiroki Fujita, Masatomo Yashiro, Hélène Beaufils, A. Makedou, Richard M. Rohan, Petar Korneti, Tim D. Hewitson, Kazuo Tsuzuki, Gavin J. Becker, Katsuo Suyama, Gilbert Deray, Hassane Izzedine, Z. Wang, Mariko Tamano, Janice Green, Aydan Ikinciogullari, Fumiaki Nogaki, Cüneyt Ensari, Velibor Tasic, A. Costa-Bauzá, Necmiye Tümer, Arzu Ensari, Ikei Kobayashi, Susumu Takahashi, Yuji Nagura, Muhammad Salmanullah, Michael K. Hise, Sahare Fongoro, and Yoshiko Takahashi

Subjects
Traditional medicine, business.industry, Medicine, business
Published
2001

18. Vasoactive Intestinal Contractor as a Genesis of Renal Hypertension

Author

Terumi Higuchi, Kazuyoshi Okada, Hiroshi Shibahara, and Susumu Takahashi

Subjects
Male, medicine.medical_specialty, Hypertension, Renal, business.industry, Vasoactive intestinal contractor, Gastroenterology, Rats, Rats, Sprague-Dawley, Endocrinology, Internal medicine, medicine, Animals, Intercellular Signaling Peptides and Proteins, Peptides, business
Published
1995

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