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Your search keyword '"Hiromi Kunii"' showing total 2 results
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2 results on '"Hiromi Kunii"'

1. ChemInform Abstract: A Probe of Cieplak′s Proposal: Effect of 2-Axial Substitution on Reactivity in the LiAlH4 Reduction of Cyclohexanones

Author

Sigeru Nakano, Hiroki Itoh, Hiromi Kunii, and Yasuhisa Senda

Subjects
Allylic rearrangement, Chemistry, Alkane stereochemistry, Substitution (logic), Reactivity (chemistry), General Medicine, Medicinal chemistry
Abstract

The relative reactivities of cyclohexanones in which the 2-axial position is substituted by methyl or methoxy group in LiAlH4 reduction strongly support the Cieplak model which focuses on the importance of stabilisation of the transition state by antiperiplanar allylic bonds.

Published
2010
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2. A probe of Cieplak's proposal: effect of 2-axial substitution on reactivity in the LiAlH4 reduction of cyclohexanones

Author

Yasuhisa Senda, Hiromi Kunii, Hiroki Itoh, and Sigeru Nakano

Subjects
chemistry.chemical_classification, Allylic rearrangement, Ketone, chemistry, Stereochemistry, Alkane stereochemistry, Substitution (logic), Chemical reduction, Stereoselectivity, Reactivity (chemistry)
Abstract

The relative reactivities of cyclohexanones in which the 2-axial position is substituted by methyl or methoxy group in LiAlH4 reduction strongly support the Cieplak model which focuses on the importance of stabilisation of the transition state by antiperiplanar allylic bonds.

Published
1993
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