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1. Using Simple Educational Robots as a Technology for Teaching Early Childhood and Primary Education Literacy in the United States

Author

Holmquist, Stephanie, Catlin, Dave, Hicks, Frederick k, Kacprzyk, Janusz, Series Editor, Gomide, Fernando, Advisory Editor, Kaynak, Okyay, Advisory Editor, Liu, Derong, Advisory Editor, Pedrycz, Witold, Advisory Editor, Polycarpou, Marios M., Advisory Editor, Rudas, Imre J., Advisory Editor, Wang, Jun, Advisory Editor, Balogh, Richard, editor, Obdržálek, David, editor, and Fislake, Martin, editor

Published
2024
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12. Tentative Report of the Third A.L.A. Activities Committee

Author

Dudgeon, Matthew S., McDiarmid,, Errett Weir, Manley, Marian C., Morsch, Lucile M., Brown, Charles Harvey, Hicks, Frederick C., Lindsay, Alfred B., Price, Miles O., Lathrop, Olive C., Orman, Oscar C., Roalfe, William R., Ryan, Anna M., Stebbins, Howard L., McDaniel, Arthur S., and Beatty, Cora M.

Published
1939

15. An intramolecular titanium-catalyzed asymmetric Pauson-Khand type reaction

Author

Hicks, Frederick A. and Buchwald, Stephen L.

Subjects
Catalysis -- Research, Ring formation (Chemistry) -- Research, Transition metals -- Research, Titanium compounds -- Research, Chemistry
Abstract

The active catalyst (S,S)-(EBTHI)Ti(CO)2 was synthesized from (S,S)-(EBTHI)TiMe2 using the asymmetric Pauson-Khand type cyclization of enynes to examine the feasibility of the method. Results showed that various 1,6-enynes were converted to the corresponding cyclopentenones in high yields with excellent levels of enantioselectivity. However, the method was found to have limitations in terms of substrate structure due to the sterically hindered nature of the EBTHI ligand.

Published
1999

16. Titanocene-catalyzed cyclocarbonylation of omichron-allyl aryl ketones to gamma-butyrolactones

Author

Kablaoui, Natasha M., Hicks, Frederick A., and Buchwald, Stephen L.

Subjects
Catalysts -- Research, Chemical reactions -- Analysis, Chemistry
Abstract

Chemical research has discovered that an arylketone moiety with Cp2Ti(PMe3)2 or CP2Ti(CO)2 will act as catalyst in the production of gamma-butyrolactones from enones. Research is continuing to increase knowledge on the mechanics and kinetics of the chemical reaction. Further catalysis experiments using nonaryl ketone-containing substrates with electron transfer catalysts will be performed.

Published
1997

17. A practical titanium-catalyzed synthesis of bicyclic cyclopentenones and allylic amines

Author

Hicks, Frederick A., Berk, Scott C., and Buchwald, Stephen L.

Subjects
Amines -- Analysis, Organic compounds -- Synthesis, Biosynthesis -- Research, Biological sciences, Chemistry
Abstract

A useful synthesis of bicyclic cyclopentenones and allylic amines with titanium as catalyst converts enzyne substrates to iminocyclopentenes using 10 mol % of the air- and moisture-stable precatalyst Cp2TiCl2 in the presence of n-BuLi and triethylsilyl cyanide. A reduction that produces allylic amides in higher yields than hydrolysis to the cyclopentenones was also developed. The development of the intermolecular and asymmetric versions of these and related cyclizations should be the focus of future research.

Published
1996

25. COMMITTEE REPORTS, 1926-27

Author

Richardson, Ernest C., Keogh, Andrew, Lane, William C., Lomer, G. R., McCombs, Charles F., Meyer, H. H. B., Smith, C. W., Wheelock, Mary E., Archer, John, Fulton, Joseph, Miller, Zana K., Stiles, Gertrude, Raney, M. Llewellyn, Cannon, Carl L., Dickinson, Asa Don, Willman, Hiller C., Wright, Purd B., Walter, Frank K., Barrette, Lydia M., Granniss, Ruth S., Landon, Fred, Moore, Anne Carroll, Stevens, Edward F., Tyler, Alice S., Wellman, Hiller C., Lydenberg, H. M., Bishop, William W., Gerould, James Thayer, Price, Miles O., Kelly, Frances H., Mann, Margaret, Bowerman, George F., Hirshberg, Herbert S., McClelland, Ellwood H., Wheelock, Webster, Dale, J. R., Jennings, J. T., Levin, Nathan R., Bostwick, Arthur E., Hicks, Frederick C., Overton, Florence, Ranck, Samuel H., Rathbone, Josephine A., Wyer, Malcolm G., Cunningham, J., Porter, Annabel, Herbert, Clara W., Pope, Mildred, Wilkinson, Mary S., Utley, George B., Wood, Harriet A., Bailey, Louis J., Eaton, Anne T., Jones, Perrie, Carey, Miriam E., Frost, Virginia, Gravett, Nettie K., Hickman, Margaret, Jones, E. Kathleen, Leitch, Harriet E., Miller, M. P. D., Pomeroy, Elizabeth, Prouty, Edythe, Reed, Elizabeth, Rodgers, Ruth Plumb, Askew, Sarah B., Koopman, H. L., Hopper, Franklin F., Gilchrist, Donald B., Munn, Ralph, MacDonald, Anna A., McCollough, Ethel F., Yust, William F., Smith, Elva S., Latimer, Louise P., Power, Effie L., Smith, Lillian H., Unger, Nell, Shearer, A. H., Howland, Anne W., Chase, Frank H., Barnett, Claribel R., Guerrier, Edith, Cannon, C. L., Donnelly, June Richardson, Prouty, Louise, Gerould, J. T., Compton, Charles H., Booth, Mary J., Brigham, Harold F., Calhoun, Alexander, Howard, Clara E., Hyde,, Dorsey W., McAfee, Georgie G., Mitchell, Sydney B., Rathbone, Josephine Adams, Bailey, A. L., Countryman, Gratia A., Hinsdale, Louise G., Lowe, John A., Rose, Grace D., Rush, Charles E., Smith, Elizabeth, Windsor, P. L., Williamson, C. C., Dudgeon, M. S., Ideson, Julia, Crimmins, Nora, Rockwood, Eleanor R., Rothrock, Mary U., Scott, Carrie E., Milam, Carl H., Wyer, James I., and Davis, Grace D.

Published
1927

26. COMMITTEE REPORTS, 1923-24

Author

Craver, Harrison W., Tweedell, Edward D., Meyer, H. H. B., Richardson, Ernest C., Carlton, W. N. C., Cole, George W., Keogh, Andrew, Raney, M. Llewellyn, Cannon, Carl L., Dickinson, Asa Don, Wellman, Hiller C., Wright, Purd B., Lydenberg, H. M., Mann, Margaret, Bowerman, George F., Bostwick, Arthur E., Overton, Florence, Ranck, Samuel H., Rathbone, Josephine A., Walter, Frank K., Wyer, Malcolm G., Andrews, C. W., Wood, Harriet A., Avery, Harriet K., Bascom, Elva L., Britton, Jasmine, Certain, C. C., Cutter, Annie S., Eaton, Anne T., Hazeltine, Alice I., Hull, Edna M., Ingles, May, Lewis, Lucy M., Morgan, Joy E., Pritchard, Martha C., Robbins, Mary E., Searson, J. W., Smith, Lillian H., Zachert, Adeline B., Koch, Theodore W., New, Harry S., Wyer, J. I., Barnett, Claribel R., Brigham, Johnson, Dudgeon, Matthew S., Thompson, C. S., West, Elizabeth H., Wiley, Edwin, Jones, E. Kathleen, Askew, Sarah B., Bassett, W. S., Curtis, Florence R., Emerson, Ralf P., Patterson, J. R., Robinson, Julia A., Templeton, Charlotte, Williams, Nellie, Carey, Miriam E., Putnam, Herbert, Yust, William F., Hopper, Franklin F., Goldsmith, Peter H., Sullivan, Maud Durlin, Hicks, Frederick C., Gerould, James Thayer, Butlin, Iva M., Gerould, J. T., Howard, Clara, Kerr, W. H., McCardle, Sarah E., Kaiser, John B., Root, Azariah S., Smith, Bessie Sargeant, Hazeltine, Mary Emogene, Lowe, John A., Power, Effie L., Scott, Carrie E., Chapman, Lila May, Dougherty, Harold T., Hughes, Howard L., Johnson, Esther C., Mulheron, Anne M., Reese, Rena, Stewart, Roberta D., Thompson, J. A., Bailey, L. J., Day, Mary B., Marvin, Cornelia, Reece, Ernest J., Warren, Althea, Wilson, Louis R., Vitz, Carl, Levin, N. R., Dickerson, L. L., Shearer, Augustus H., Kobetich, Mary R., Hyde,, Dorsey W., Smith, Elizabeth M., Mitchell, Sydney B., Grumpelt, H. J., Compton, Charles H., Rathbone, Josephine Adams, Bailey, A. L., Countryman, Gratia A., Lowe, John Adams, Rose, Grace D., Rush, Charles E., Watson, William R., Windsor, P. L., Strohm, Adam, Milam, Carl H., Austen, Willard, Bostwick, A. E., Goldthwaite, Lucille A., Ledbetter, Eleanor E., Farrar, Ida, Gratiaa, Josephine, Hurlbert, Dorothy, Johnson, Esther, Quigley, Margery, and Wetmore, Marguerite

Published
1924

28. COMMITTEE REPORTS, 1925-26

Author

Richardson, E. C., Strohm, Adam, Wheelock, Mary E., Archer, John, Gulledge, J. R., Fulton, Joseph, Stiles, Gertrude, Raney, M. Llewellyn, Cannon, Carl L., Wellman, Hiller C., Dickinson, Asa Don, Wright, Purd B., Walter, Frank K., Barrette, Lydia M., Stevens, Edward F., Granniss, Ruth S., Tyler, Alice S., Moore, Anne Carroll, Lydenberg, H. M., Bishop, William W., Price, Miles O., Gerould, James T., Kelly, Frances H., Currier, T. Franklin, Bowerman, George F., Andrews, Clement W., Bostwick, Arthur E., Ranck, Samuel H., Hicks, Frederick C., Overton, Florence, Wyer, Malcolm G., Rathbone, Josephine A., Jennings, J. T., Dudgeon, M. S., Belden, C. F. D., Bishop, W. W., Carson, W. O., Eastman, Linda A., Rush, C. E., Cunningham, J., Hyde,, Dorsey W., Shaw, Robert K., Porter, Annabel, Countryman, Gratia A., Herbert, Clara W., Wilkinson, Mary S., Pope, Mildred, Utley, George B., Wood, Harriet A., Koch, Theodore W., Bailey, Louis J., Roden, Carl B., Eaton, Anne T., Jones, Perrie, Carey, Miriam E., Pomeroy, Elizabeth, Frost, Virginia, Miller, M. P. D., Gravett, N. K., Rodgers, Ruth P., Prouty, Edythe, Jones, E. K., Leitch, Harriet E., Hickman, Margaret, Askew, Sarah B., Putnam, Herbert, Yust, William F., Koopman, H. L., Jeffers, LeRoy, Joeckei, Carleton B., Hopper, Franklin F., Drake, Jeannette M., MacDonald, Anna A., Gilchrist, Donald B., McCollough, Ethel F., Sullivan, Maud Durlin, Lester, C. B., Black, Mary J. L., Paine, Paul M., Ferguson, M. J., Templeton, Charlotte, Merrill, Julia W., Shearer, Augustus H., Howland, Anne W., Chase, Frank H., Barnett, Claribel R., Vitz, Carl, Prouty, Louise, Johnston, Esther, Andrus, Gertrude, Josselyn, Lloyd W., Gerould, James Thayer, Compton, Charles H., Fargo, Lucile F., Booth, Mary J., Brigham, Harold F., Calhoun, Alexander, Mitchell, Sydney B., Rathbone, Josephine Adams, Bailey, A. L., Rose, Grace D., Rush, Charles E., Hinsdale, Louise G., Smith, Elizabeth, Windsor, P. L., Lowe, John A., Meyer, H. H. B., Andrews, C. W., Austen, Willard, Goldthwaite, Lucille A., and Ledbetter, Eleanor E.

Published
1926

29. NATIONAL ASSOCIATION OF STATE LIBRARIES

Author

Corliss, John B., Hitt, John M., Lester, Clarence B., Brown, Demarchus C., Fertig, John H., Fitzpatrick, John T., Hicks, Frederick C., Woodard, Gertrude Elstner, Dullard, John P., Sherwood, Grace M., Brigham, Herbert O., and Hochstein, Irma

Published
1922

32. REPORT OF FINANCE COMMITTEE May 25, 1920

Author

McGlachin, Summerall, Ely, Humphrey, Arrangements Committee, ANDREWS, CLEMENT W., Wyer,, J. I., Anderson, Edwin H., Belden, Charles F. D., Bowker, R. R., Doren, Electra C., Hill, Frank P., Titcomb, Mary L., MILAM, CARL H., Stevenson, Burton T., Utley, George B., PUTNAM, HERBERT, Milam, Carl H., Putnam, Herbert, Countryman, Gratia A., Belden, C. F. D., Hadley, Chalmers, Gillis, Mabel R., Goldthwaite, Lucille A., Sawyer, Laura M., Hopper, Franklin F., Compton, Charles H., Hubbard, Anna G., Stiles, Gertrude, Perry, Everett R., Jennings, Judson T., Wheelock, Mary E., Tyler, Alice S., Baldwin, Clara F., Bogle, Sarah C. N., Carpenter, George O., Krause, Louise B., Sanborn, Henry N., Walter, F. K., Wyer, Malcolm G., Meyer, H. H. B., Compton, C. H., Bailey, Louis J., Dana, John Cotton, Earl, Elizabeth Claypool, Hirshberg, Herbert S., Humble, Marion, Yust, William F., Ranck, Samuel H., Meyer, Milton W., Paine, Paul M., Spaulding, Forrest B., Wheeler, Joseph L., Kerr, W. H., Rush, Charles E., Shearer, A. H., Bishop, Wm. W., Carlton, W. N. C., Brown, Walter L., Godard, George S., Hicks, Frederick C., Andrews, C. W., Kingsland, Grace E., Lee, George W., Sawyer, Harriet P., Watson, William R., Webster, Caroline, Williamson, C. C., Anderson, E. H., Keogh, Andrew, Lydenberg, H. M., Chivers, Cedric, Lee, G. W., Moulton, J. G., Tripp, G. H., Wellman, H. C., Whitmore, F. H., Walter, Frank K., Zachert, Adeline B., and Root, A. S.

Published
1920

35. [Equality of nations]

Author

HICKS, FREDERICK C., Foster, John W., Evans, L. B., Harris, N. Dwight, Aymar, F. W., Ion, Theodore P., Stowell, E. C., Montague, A. J., and Abbott, Lyman

Published
1909

36. The Enabling Technologies Consortium (ETC): Fostering Precompetitive Collaborations on New Enabling Technologies for Pharmaceutical Research and Development

Author

Welch, Christopher J., primary, Faul, Margaret M., additional, Tummala, Srinivas, additional, Papageorgiou, Charles D., additional, Hicks, Frederick, additional, Hawkins, Joel M., additional, Thomson, Nicholas, additional, Cote, Aaron, additional, Bordawekar, Shailendra, additional, Wittenberger, Steven J., additional, Laffan, David, additional, Purdie, Mark, additional, Boulas, Pierre, additional, Irdam, Erwin, additional, Horspool, Keith, additional, Yang, Bing-Shiou, additional, Tom, Jean, additional, Fernandez, Paul, additional, Ferretti, Antonio, additional, May, Scott, additional, Seibert, Kevin, additional, Wells, Kenneth, additional, and McKeown, Rahn, additional

Published
2017
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39. A Nitrogen-Assisted One-Pot Heteroaryl Ketone Synthesis from Carboxylic Acids and Heteroaryl Halides

Author

Demkiw, Krystyna, primary, Araki, Hirofumi, additional, Elliott, Eric L., additional, Franklin, Christopher L., additional, Fukuzumi, Yoonjoo, additional, Hicks, Frederick, additional, Hosoi, Kazushi, additional, Hukui, Tadashi, additional, Ishimaru, Yoichiro, additional, O’Brien, Erin, additional, Omori, Yoshimasa, additional, Mineno, Masahiro, additional, Mizufune, Hideya, additional, Sawada, Naotaka, additional, Sawai, Yasuhiro, additional, and Zhu, Lei, additional

Published
2016
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44. The Use of Chloroformamidine Hydrochloride as a Reagent for the Synthesis of Guanidines from Electron Deficient.

Author

Armitage, Ian, Fu, Mingkun, Hicks, Frederick, Kattuboina, Adiseshu, Li, Jennifer S. N., McCarron, Ashley, and Zhu, Lei

Subjects
CHEMICAL reagents, FORMAMIDINES, GUANIDINES, ORGANIC synthesis, ELECTRON-deficient compounds
Abstract

In efforts to optimize a manufacturing process for an internal development compound, a clean, efficient approach to guanidine synthesis using chloroformamidine hydrochloride was identified. To investigate the general utility of this methodology towards electron-deficient , a set of favorable conditions were developed from a series of screens, and the scope of the reaction was probed. The successful application of this chemistry to a variety of pyridines, anilines, and heterocyclic compounds highlights its use as an improved, alternative guanylation method for this often challenging set of . [ABSTRACT FROM AUTHOR]

Published
2017
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48. Highly enantioselective catalytic Pauson-Khand type formation of bicyclic cyclopentenones

Author

Hicks, Frederick A. and Buchwald, Stephen L.

Subjects
Ring formation (Chemistry) -- Research, Catalysts -- Research, Cyclic compounds -- Research, Chemistry
Abstract

The enantiomerically pure analog (S,S)-(EBTHI)Ti(CO)2 of Cp2Ti(CO)2 has been observed to act as a highly enantioselective catalyst for the conversion of enynes to cyclopentenones in asymmetric Pauson-Khand type cyclizations. Attempts to produce cyclization at temperatures below 90 degrees C resulted in reduced conversion to product. The appropriate choice of CO pressure was also significant. At CO pressures both higher and lower than 14 psig, conversion to cyclopentenone was less efficient.

Published
1996

49. Titanocene-catalyzed cyclocarbonylation of enynes to cyclopentenones

Author

Hicks, Frederick A., Kablaoui, Natasha M., and Buchwald, Stephen L.

Subjects
Transition metals -- Analysis, Ring formation (Chemistry) -- Research, Chemical reactions -- Research, Chemistry
Abstract

The first early transition metal-catalyzed carbonylation of enynes, which uses Cp2Ti(CO)2(super 6) and CO to produce cyclopentenones, is reported. The Cp2Ti(CO)2 system demonstrates a new reactivity mode for an early transition metal carbonyl as well as manifests an unexpectedly higher level of functional group compatibility compared with other group 4 metallocene cyclizations and puzzling mechanistic differences from the related iminocyclopentene synthesis. Moreover, it displays a higher tolerance for substituted alkenes than related cobalt procedures.

Published
1996

50. Diastereoselective synthesis of gamma-butyrolactones from enones mediated or catalyzed by a titanocene complex

Author

Kablaoui, Natasha M., Hicks, Frederick A., and Buchwald, Stephen L.

Subjects
Lactones -- Research, Organic compounds -- Synthesis, Catalysts -- Research, Chemistry
Abstract

A diastereoselective and high-yielding synthesis of gamma-butyrolactones is described. The scheme uses enones as starting material and is either by Cp2Ti(PMe3)2 or uses Cp2Ti(PMe3)2 as a pre-catalyst. The formation of a fused butenolide from an ynone utilizing the same metal reagent is also described. The optimum conditions and mechanisms for the reactions are presented.

Published
1996

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