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1. The Ni isotopic composition of Ryugu reveals a common accretion region for carbonaceous chondrites

Author

Spitzer, Fridolin, Kleine, Thorsten, Burkhardt, Christoph, Hopp, Timo, Yokoyama, Tetsuya, Abe, Yoshinari, Aléon, Jérôme, Alexander, Conel M. O'D., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, Morita, Mayu, Moynier, Fréderic, Motomura, Kazuko, Nakai, Izumi, Nagashima, Kazuhide, Nguyen, Ann, Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara S., Sakamoto, Naoya, Schönbächler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yoneda, Shigekazu, Young, Edward D., Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, and Yurimoto, Hisayoshi

Subjects
Astrophysics - Earth and Planetary Astrophysics
Abstract

The isotopic compositions of samples returned from Cb-type asteroid Ryugu and Ivuna-type (CI) chondrites are distinct from other carbonaceous chondrites, which has led to the suggestion that Ryugu and CI chondrites formed in a different region of the accretion disk, possibly around the orbits of Uranus and Neptune. We show that, like for Fe, Ryugu and CI chondrites also have indistinguishable Ni isotope anomalies, which differ from those of other carbonaceous chondrites. We propose that this unique Fe and Ni isotopic composition reflects different accretion efficiencies of small FeNi metal grains among the carbonaceous chondrite parent bodies. The CI chondrites incorporated these grains more efficiently, possibly because they formed at the end of the disk's lifetime, when planetesimal formation was also triggered by photoevaporation of the disk. Isotopic variations among carbonaceous chondrites may thus reflect fractionation of distinct dust components from a common reservoir, implying CI chondrites and Ryugu may have formed in the same region of the accretion disk as other carbonaceous chondrites., Comment: Published open access in Science Advances

Published
2024
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2. Water circulation in Ryugu asteroid affected the distribution of nucleosynthetic isotope anomalies in returned sample.

Author

Yokoyama, Tetsuya, Wadhwa, Meenakshi, Iizuka, Tsuyoshi, Rai, Vinai, Gautam, Ikshu, Hibiya, Yuki, Masuda, Yuki, Haba, Makiko, Fukai, Ryota, Hines, Rebekah, Phelan, Nicole, Abe, Yoshinari, Aléon, Jérôme, Alexander, Conel, Amari, Sachiko, Amelin, Yuri, Bajo, Ken-Ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard, Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew, Di Rocco, Tommaso, Fujiya, Wataru, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary, Ichida, Kiyohiro, Ireland, Trevor, Ishikawa, Akira, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko, Kitajima, Koki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander, Liu, Ming-Chang, McKeegan, Kevin, Morita, Mayu, Motomura, Kazuko, Moynier, Frédéric, Nakai, Izumi, Nagashima, Kazuhide, Nguyen, Ann, Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara, Sakamoto, Naoya, Schönbächler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Walker, Richard, Yamashita, Katsuyuki, Yoneda, Shigekazu, Young, Edward, Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-Ichiro, Yoshikawa, Makoto, Tachibana, Shogo, Yurimoto, Hisayoshi, and Yin, Qing-Zhu

Abstract

Studies of material returned from Cb asteroid Ryugu have revealed considerable mineralogical and chemical heterogeneity, stemming primarily from brecciation and aqueous alteration. Isotopic anomalies could have also been affected by delivery of exogenous clasts and aqueous mobilization of soluble elements. Here, we show that isotopic anomalies for mildly soluble Cr are highly variable in Ryugu and CI chondrites, whereas those of Ti are relatively uniform. This variation in Cr isotope ratios is most likely due to physicochemical fractionation between 54Cr-rich presolar nanoparticles and Cr-bearing secondary minerals at the millimeter-scale in the bulk samples, likely due to extensive aqueous alteration in their parent bodies that occurred [Formula: see text] after Solar System birth. In contrast, Ti isotopes were marginally affected by this process. Our results show that isotopic heterogeneities in asteroids are not all nebular or accretionary in nature but can also reflect element redistribution by water.

Published
2023

3. Igneous meteorites suggest Aluminium-26 heterogeneity in the early Solar Nebula.

Author

Krestianinov, Evgenii, Amelin, Yuri, Cary, Paige, Huyskens, Magdalena, Dey, Supratim, Hibiya, Yuki, Tang, Haolan, Young, Edward, Pack, Andreas, Di Rocco, Tommaso, Yin, Qing-Zhu, and Miller, Audrey

Abstract

The short-lived radionuclide aluminium-26 (26Al) isotope is a major heat source for early planetary melting. The aluminium-26 - magnesium-26 (26Al-26Mg) decay system also serves as a high-resolution relative chronometer. In both cases, however, it is critical to establish whether 26Al was homogeneously or heterogeneously distributed throughout the solar nebula. Here we report a precise lead-207 - lead-206 (207Pb-206Pb) isotopic age of 4565.56 ± 0.12 million years (Ma) for the andesitic achondrite Erg Chech 002. Our analysis, in conjunction with published 26Al-26Mg data, reveals that the initial 26Al/27Al in the source material of this achondrite was notably higher than in various other well-preserved and precisely dated achondrites. Here we demonstrate that the current data clearly indicate spatial heterogeneity of 26Al by a factor of 3-4 in the precursor molecular cloud or the protoplanetary disk of the Solar System, likely associated with the late infall of stellar materials with freshly synthesized radionuclides.

Published
2023

4. Abundant presolar grains and primordial organics preserved in carbon-rich exogenous clasts in asteroid Ryugu.

Author

Nguyen, Ann, Mane, Prajkta, Keller, Lindsay, Piani, Laurette, Abe, Yoshinari, Aléon, Jérôme, Alexander, Conel, Amari, Sachiko, Amelin, Yuri, Bajo, Ken-Ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard, Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew, Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko, Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary, Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor, Ishikawa, Akira, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko, Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander, Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin, Morita, Mayu, Motomura, Kazuko, Moynier, Frédéric, Nakai, Izumi, Nagashima, Kazuhide, Nesvorný, David, Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Qin, Liping, Russell, Sara, Sakamoto, Naoya, Schönbächler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard, Yamashita, Katsuyuki, Yokoyama, Tetsuya, Yoneda, Shigekazu, Young, Edward, Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-Ichiro, Yoshikawa, Makoto, Tachibana, Shogo, Yurimoto, Hisayoshi, and Yin, Qing-Zhu

Subjects
Carbon, Solar System, Meteoroids, Silicates
Abstract

Preliminary analyses of asteroid Ryugu samples show kinship to aqueously altered CI (Ivuna-type) chondrites, suggesting similar origins. We report identification of C-rich, particularly primitive clasts in Ryugu samples that contain preserved presolar silicate grains and exceptional abundances of presolar SiC and isotopically anomalous organic matter. The high presolar silicate abundance (104 ppm) indicates that the clast escaped extensive alteration. The 5 to 10 times higher abundances of presolar SiC (~235 ppm), N-rich organic matter, organics with N isotopic anomalies (1.2%), and organics with C isotopic anomalies (0.2%) in the primitive clasts compared to bulk Ryugu suggest that the clasts formed in a unique part of the protoplanetary disk enriched in presolar materials. These clasts likely represent previously unsampled outer solar system material that accreted onto Ryugu after aqueous alteration ceased, consistent with Ryugus rubble pile origin.

Published
2023

5. Presolar stardust in asteroid Ryugu

Author

Barosch, Jens, Nittler, Larry R., Wang, Jianhua, Alexander, Conel M. O'D., De Gregorio, Bradley T., Engrand, Cécile, Kebukawa, Yoko, Nagashima, Kazuhide, Stroud, Rhonda M., Yabuta, Hikaru, Abe, Yoshinari, Aléon, Jérôme, Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bejach, Laure, Bizzarro, Martin, Bonal, Lydie, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Cody, George D., Dartois, Emmanuel, Dauphas, Nicolas, Davis, Andrew M., Dazzi, Alexandre, Deniset-Besseau, Ariane, Di Rocco, Tommaso, Duprat, Jean, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hashiguchi, Minako, Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Ito, Motoo, Itoh, Shoichi, Kamide, Kanami, Kawasaki, Noriyuki, Kilcoyne, A. L. David, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Komatsu, Mutsumi, Krot, Alexander N., Liu, Ming-Chang, Martins, Zita, Masuda, Yuki, Mathurin, Jérémie, McKeegan, Kevin D., Montagnac, Gilles, Morita, Mayu, Mostefaoui, Smail, Motomura, Kazuko, Moynier, Frédéric, Nakai, Izumi, Nguyen, Ann N., Ohigashi, Takuji, Okumura, Taiga, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Quirico, Eric, Remusat, Laurent, Russell, Sara S., Sakamoto, Naoya, Sandford, Scott A., Schönbächler, Maria, Shigenaka, Miho, Suga, Hiroki, Tafla, Lauren, Takahashi, Yoshio, Takeichi, Yasuo, Tamenori, Yusuke, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Verdier-Paoletti, Maximilien, Wada, Sohei, Wadhwa, Meenakshi, Wakabayashi, Daisuke, Walker, Richard J., Yamashita, Katsuyuki, Yamashita, Shohei, Yin, Qing-Zhu, Yokoyama, Tetsuya, Yoneda, Shigekazu, Young, Edward D., Yui, Hiroharu, Zhang, Ai-Cheng, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nakazawa, Satoru, Nishimura, Masahiro, Okada, Tatsuaki, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yada, Toru, Yogata, Kasumi, Yoshikawa, Makoto, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Tachibana, Shogo, and Yurimoto, Hisayoshi

Subjects
Astrophysics - Earth and Planetary Astrophysics, Astrophysics - Solar and Stellar Astrophysics
Abstract

We have conducted a NanoSIMS-based search for presolar material in samples recently returned from C-type asteroid Ryugu as part of JAXA's Hayabusa2 mission. We report the detection of all major presolar grain types with O- and C-anomalous isotopic compositions typically identified in carbonaceous chondrite meteorites: 1 silicate, 1 oxide, 1 O-anomalous supernova grain of ambiguous phase, 38 SiC, and 16 carbonaceous grains. At least two of the carbonaceous grains are presolar graphites, whereas several grains with moderate C isotopic anomalies are probably organics. The presolar silicate was located in a clast with a less altered lithology than the typical extensively aqueously altered Ryugu matrix. The matrix-normalized presolar grain abundances in Ryugu are 4.8$^{+4.7}_{-2.6}$ ppm for O-anomalous grains, 25$^{+6}_{-5}$ ppm for SiC grains and 11$^{+5}_{-3}$ ppm for carbonaceous grains. Ryugu is isotopically and petrologically similar to carbonaceous Ivuna-type (CI) chondrites. To compare the in situ presolar grain abundances of Ryugu with CI chondrites, we also mapped Ivuna and Orgueil samples and found a total of SiC grains and 6 carbonaceous grains. No O-anomalous grains were detected. The matrix-normalized presolar grain abundances in the CI chondrites are similar to those in Ryugu: 23 $^{+7}_{-6}$ ppm SiC and 9.0$^{+5.3}_{-4.6}$ ppm carbonaceous grains. Thus, our results provide further evidence in support of the Ryugu-CI connection. They also reveal intriguing hints of small-scale heterogeneities in the Ryugu samples, such as locally distinct degrees of alteration that allowed the preservation of delicate presolar material., Comment: 12 pages, 3 figures, 2 tables. Published in ApJL

Published
2022
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6. Oxygen isotopes of anhydrous primary minerals show kinship between asteroid Ryugu and comet 81P/Wild2

Author

Kawasaki, Noriyuki, Nagashima, Kazuhide, Sakamoto, Naoya, Matsumoto, Toru, Bajo, Ken-ichi, Wada, Sohei, Igami, Yohei, Miyake, Akira, Noguchi, Takaaki, Yamamoto, Daiki, Russell, Sara S, Abe, Yoshinari, Aléon, Jérôme, Alexander, Conel M O’D, Amari, Sachiko, Amelin, Yuri, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W, Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M, Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K, Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R, Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R, Ishikawa, Akira, Ito, Motoo, Itoh, Shoichi, Kita, Noriko T, Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N, Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D, Morita, Mayu, Motomura, Kazuko, Moynier, Frédéric, Nakai, Izumi, Nguyen, Ann, Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Schönbächler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wadhwa, Meenakshi, Walker, Richard J, Yamashita, Katsuyuki, Yin, Qing-Zhu, Yokoyama, Tetsuya, Yoneda, Shigekazu, Young, Edward D, Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, and Yurimoto, Hisayoshi

Subjects
Earth Sciences, Physical Sciences, Space Sciences, Geology, Prevention
Abstract

The extraterrestrial materials returned from asteroid (162173) Ryugu consist predominantly of low-temperature aqueously formed secondary minerals and are chemically and mineralogically similar to CI (Ivuna-type) carbonaceous chondrites. Here, we show that high-temperature anhydrous primary minerals in Ryugu and CI chondrites exhibit a bimodal distribution of oxygen isotopic compositions: 16O-rich (associated with refractory inclusions) and 16O-poor (associated with chondrules). Both the 16O-rich and 16O-poor minerals probably formed in the inner solar protoplanetary disk and were subsequently transported outward. The abundance ratios of the 16O-rich to 16O-poor minerals in Ryugu and CI chondrites are higher than in other carbonaceous chondrite groups but are similar to that of comet 81P/Wild2, suggesting that Ryugu and CI chondrites accreted in the outer Solar System closer to the accretion region of comets.

Published
2022

7. Hydrothermal activities on C-complex asteroids induced by radioactivity

Author

Fujiya, Wataru, Higashi, Hisato, Hibiya, Yuki, Sugawara, Shingo, Yamaguchi, Akira, Kimura, Makoto, and Hashizume, Ko

Subjects
Astrophysics - Earth and Planetary Astrophysics
Abstract

C-complex asteroids, rich in carbonaceous materials, are potential sources of Earth's volatile inventories. They are spectrally dark resembling primitive carbonaceous meteorites, and thus, C-complex asteroids are thought to be potential parent bodies of carbonaceous meteorites. However, the substantial number of C-complex asteroids exhibits surface spectra with weaker hydroxyl absorption than water-rich carbonaceous meteorites. Rather, they best correspond to meteorites showing evidence for dehydration, commonly attributed to impact heating. Here, we report an old radiometric age of 4564.7 million years ago for Ca-carbonates from the Jbilet Winselwan meteorite analogous to dehydrated C-complex asteroids. The carbonates are enclosed by a high-temperature polymorph of Ca-sulfates, suggesting thermal metamorphism at >300{\deg}C subsequently after aqueous alteration. This old age indicates the early onset of aqueous alteration and subsequent thermal metamorphism driven by the decay of short-lived radionuclides rather than impact heating. The breakup of original asteroids internally heated by radioactivity should result in asteroid families predominantly consisting of thermally metamorphosed materials. This explains the common occurrence of dehydrated C-complex asteroids., Comment: 19 pages, 8 figures, 2 tables

Published
2022
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8. Pyrrhotites in asteroid 162173 Ryugu: Records of the initial changes on their surfaces with aqueous alteration

Author

Yui, Hiroharu, Urashima, Shu-hei, Onose, Morihiko, Morita, Mayu, Komatani, Shintaro, Nakai, Izumi, Abe, Yoshinari, Terada, Yasuko, Homma, Hisashi, Motomura, Kazuko, Ichida, Kiyohiro, Yokoyama, Tetsuya, Nagashima, Kazuhide, Aléon, Jérôme, M. O’D. Alexander, Conel, Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Hoppe, Peter, Huss, Gary R., Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Krot, Sasha, Liu, Ming-Chang, Masuda, Yuki, Moynier, Frédéric, Nguyen, Ann, Nittler, Larry, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Di Rocco, Tommaso, Russell, Sara S., Sakamoto, Naoya, Schönbächler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yoneda, Shigekazu, Young, Edward D., Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, and Yurimoto, Hisayoshi

Published
2024
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9. Pervasive aqueous alteration in the early Solar System revealed by potassium isotopic variations in Ryugu samples and carbonaceous chondrites

Author

Hu, Yan, Moynier, Frédéric, Dai, Wei, Paquet, Marine, Yokoyama, Tetsuya, Abe, Yoshinari, Aléon, Jérôme, Alexander, Conel M. O'D., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Koki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, Morita, Mayu, Motomura, Kazuko, Nakai, Izumi, Nagashima, Kazuhide, Nesvorný, David, Nguyen, Ann, Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara S., Sakamoto, Naoya, Schönbächler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yoneda, Shigekazu, Young, Edward D., Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, and Yurimoto, Hisayoshi

Published
2024
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10. Contribution of Ryugu-like material to Earth’s volatile inventory by Cu and Zn isotopic analysis

Author

Paquet, Marine, Moynier, Frederic, Yokoyama, Tetsuya, Dai, Wei, Hu, Yan, Abe, Yoshinari, Aléon, Jérôme, O’D. Alexander, Conel M., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Ito, Motoo, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Nakai, Izumi, Nagashima, Kazuhide, Nesvorný, David, Nguyen, Ann N., Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara S., Sakamoto, Naoya, Schönbächler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yoneda, Shigekazu, Young, Edward D., Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, and Yurimoto, Hisayoshi

Published
2023
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11. The origin of the unique achondrite Northwest Africa 6704: Constraints from petrology, chemistry and Re–Os, O and Ti isotope systematics

Author

Hibiya, Yuki, Archer, Gregory J, Tanaka, Ryoji, Sanborn, Matthew E, Sato, Yuya, Iizuka, Tsuyoshi, Ozawa, Kazuhito, Walker, Richard J, Yamaguchi, Akira, Yin, Qing-Zhu, Nakamura, Tomoki, and Irving, Anthony J

Subjects
NWA 6704, Primitive achondrite, Nucleosynthetic anomalies, Highly siderophile elements, Impact melting, Geochemistry, Geology, Physical Geography and Environmental Geoscience, Geochemistry & Geophysics
Abstract

Northwest Africa (NWA) 6704 is a unique achondrite characterized by a near-chondritic major element composition with a remarkably intact igneous texture. To investigate the origin of this unique achondrite, we have conducted a combined petrologic, chemical, and 187Re-187Os, O, and Ti isotopic study. The meteorite consists of orthopyroxene megacrysts (En55-57Wo3-4Fs40-42; Fe/Mn = 1.4) up to 1.7 cm in length with finer interstices of olivine (Fa50-53; Fe/Mn = 1.1-2.1), chromite (Cr# ~ 0.94), awaruite, sulfides, plagioclase (Ab92An5Or3) and merrillite. The results of morphology, lattice orientation analysis, and mineral chemistry indicate that orthopyroxene megacrysts were originally hollow dendrites that most likely crystallized under high super-saturation and super-cooling conditions (1-102 °C/h), whereas the other phases crystallized between branches of the dendrites in the order of awaruite, chromite → olivine → merrillite → plagioclase. In spite of the inferred high supersaturation, the remarkably large size of orthopyroxene can be explained as a result of crystallization from a melt containing a limited number of nuclei that are preserved as orthopyroxene megacryst cores having high Mg# or including vermicular olivine. The Re-Os isotope data for bulk and metal fractions yield an isochron age of 4576 ± 250 Ma, consistent with only limited open system behavior of highly siderophile elements (HSE) since formation. The bulk chemical composition is characterized by broadly chondritic absolute abundances and only weakly fractionated chondrite-normalized patterns for HSE and rare earth elements (REE), together with substantial depletion of highly volatile elements relative to chondrites. The HSE and REE characteristics indicate that the parental melt and its protolith had not undergone significant segregation of metals, sulfides, or silicate minerals. These combined results suggest that a chondritic precursor to NWA 6704 was heated well above its liquidus temperature so that highly volatile elements were lost and the generated melt initially contained few nuclei of relict orthopyroxene, but the melting and subsequent crystallization took place on a timescale too short to allow magmatic differentiation. Such rapid melting and crystallization might occur as a result of impact on an undifferentiated asteroid. The O-Ti isotope systematics (Δ17O = -1.052 ± 0.004, 2 SD; ε50Ti = 2.28 ± 0.23, 2 SD) indicate that the NWA 6704 parent body sampled the same isotopic reservoirs in the solar nebula as the carbonaceous chondrite parent bodies. This is consistent with carbonaceous chondrite-like refractory element abundances and oxygen fugacity (FMQ = -2.6) in NWA 6704. Yet, the Si/Mg ratio of NWA 6704 is remarkably higher than those of carbonaceous chondrites, suggesting significant nebular fractionation of forsterite in its provenance.

Published
2019

12. Radial transport and nebular thermal processing of millimeter‐sized solids in the Solar protoplanetary disk inferred from Cr‐Ti‐O isotope systematics of chondrules.

Author

Fukuda, Kohei, Hibiya, Yuki, Kastelle, Craig R., Suzuki, Katsuhiko, Iizuka, Tsuyoshi, Yamashita, Katsuyuki, Helser, Thomas E., and Kita, Noriko T.

Subjects
*SOLAR system, *CHONDRULES, *CORE materials, *ISOTOPE exchange reactions, *ISOTOPIC signatures, *PROTOPLANETARY disks
Abstract

Understanding the material transport and mixing processes in the Solar protoplanetary disk provides important constraints on the origin of chemical and isotopic diversities of our planets. The limited extent of radial transport and mixing between the inner and outer Solar System has been suggested based on a fundamental isotopic dichotomy between non‐carbonaceous (NC) and carbonaceous (CC) meteorite groups. The limited transport and mixing could be further tested by tracing the formation regions of individual meteoritic components, such as Ca‐Al‐rich inclusions (CAIs) and chondrules. Here, we show further evidence for the outward transport of CAIs and chondrules from the inner and subsequent thermal processing in the outer region of the protoplanetary disk based on the petrography and combined Cr‐Ti‐O isotope systematics of chondrules from the Vigarano‐like (CV) carbonaceous chondrite Allende. One chondrule studied consists of an olivine core that exhibits NC‐like Ti and O, but CC‐like Cr isotopic signatures, which is enclosed by a pyroxene igneous rim with CC‐like O isotope ratios. These observations indicate that the olivine core formed in the inner Solar System. The olivine core then migrated into the outer Solar System and experienced nebular thermal processing that generated the pyroxene igneous rim. The nebular thermal processing would result in Cr isotope exchange between the olivine core and CC‐like materials, but secondary alteration effects on the parent body are also responsible for the CC‐like Cr isotope signature. By combining previously reported Cr‐Ti‐O isotope systematics of CV chondrules, we show that some CV chondrules larger than ~1 mm would have formed in the inner Solar System. The accretion of the millimeter‐sized, inner Solar System solids onto the CV carbonaceous chondrite parent body would require their very early migration into the outer Solar System within the first 1 million years after the Solar System formation. [ABSTRACT FROM AUTHOR]

Published
2024
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13. Disequilibrium oxygen isotope distribution among aqueously altered minerals in Ryugu asteroid returned samples

Author

Kita, Noriko T., primary, Kitajima, Kouki, additional, Nagashima, Kazuhide, additional, Kawasaki, Noriyuki, additional, Sakamoto, Naoya, additional, Fujiya, Wataru, additional, Abe, Yoshinari, additional, Aléon, Jérôme, additional, Alexander, Conel M. O'D., additional, Amari, Sachiko, additional, Amelin, Yuri, additional, Bajo, Ken‐ichi, additional, Bizzarro, Martin, additional, Bouvier, Audrey, additional, Carlson, Richard W., additional, Chaussidon, Marc, additional, Choi, Byeon‐Gak, additional, Dauphas, Nicolas, additional, Davis, Andrew M., additional, Di Rocco, Tommaso, additional, Fukai, Ryota, additional, Gautam, Ikshu, additional, Haba, Makiko K., additional, Hibiya, Yuki, additional, Hidaka, Hiroshi, additional, Homma, Hisashi, additional, Hoppe, Peter, additional, Huss, Gary R., additional, Ichida, Kiyohiro, additional, Iizuka, Tsuyoshi, additional, Ireland, Trevor R., additional, Ishikawa, Akira, additional, Itoh, Shoichi, additional, Kleine, Thorsten, additional, Komatani, Shintaro, additional, Krot, Alexander N., additional, Liu, Ming‐Chang, additional, Masuda, Yuki, additional, McKeegan, Kevin D., additional, Morita, Mayu, additional, Motomura, Kazuko, additional, Moynier, Frédéric, additional, Nakai, Izumi, additional, Nguyen, Ann, additional, Nittler, Larry, additional, Onose, Morihiko, additional, Pack, Andreas, additional, Park, Changkun, additional, Piani, Laurette, additional, Qin, Liping, additional, Russell, Sara S., additional, Schönbächler, Maria, additional, Tafla, Lauren, additional, Tang, Haolan, additional, Terada, Kentaro, additional, Terada, Yasuko, additional, Usui, Tomohiro, additional, Wada, Sohei, additional, Wadhwa, Meenakshi, additional, Walker, Richard J., additional, Yamashita, Katsuyuki, additional, Yin, Qing‐Zhu, additional, Yokoyama, Tetsuya, additional, Yoneda, Shigekazu, additional, Young, Edward D., additional, Yui, Hiroharu, additional, Zhang, Ai‐Cheng, additional, Nakamura, Tomoki, additional, Naraoka, Hiroshi, additional, Noguchi, Takaaki, additional, Okazaki, Ryuji, additional, Sakamoto, Kanako, additional, Yabuta, Hikaru, additional, Abe, Masanao, additional, Miyazaki, Akiko, additional, Nakato, Aiko, additional, Nishimura, Masahiro, additional, Okada, Tatsuaki, additional, Yada, Toru, additional, Yogata, Kasumi, additional, Nakazawa, Satoru, additional, Saiki, Takanao, additional, Tanaka, Satoshi, additional, Terui, Fuyuto, additional, Tsuda, Yuichi, additional, Watanabe, Sei‐ichiro, additional, Yoshikawa, Makoto, additional, Tachibana, Shogo, additional, and Yurimoto, Hisayoshi, additional

Published
2024
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14. Author Correction: Contribution of Ryugu-like material to Earth’s volatile inventory by Cu and Zn isotopic analysis

Author

Paquet, Marine, Moynier, Frederic, Yokoyama, Tetsuya, Dai, Wei, Hu, Yan, Abe, Yoshinari, Aléon, Jérôme, O’D. Alexander, Conel M., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Ito, Motoo, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Nakai, Izumi, Nagashima, Kazuhide, Nesvorný, David, Nguyen, Ann N., Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara S., Sakamoto, Naoya, Schönbächler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yoneda, Shigekazu, Young, Edward D., Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, and Yurimoto, Hisayoshi

Published
2023
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15. Analysis of Cation Composition in Dolomites on the Intact Particles Sampled from Asteroid Ryugu

Author

Morita, Mayu, Yui, Hiroharu, Urashima, Shu Hei, Onose, Morihiko, Komatani, Shintaro, Nakai, Izumi, Abe, Yoshinari, Terada, Yasuko, Homma, Hisashi, Motomura, Kazuko, Ichida, Kiyohiro, Yokoyama, Tetsuya, Nagashima, Kazuhide, Aléon, Jérôme, Conel, Conel M., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Hoppe, Peter, Huss, Gary R., Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Krot, Sasha, Liu, Ming-Chang, Masuda, Yuki, Moynier, Frédéric, Nguyen, Ann, Nittler, Larry, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Rocco, Tommaso Di, Russell, Sara S., Sakamoto, Naoya, Schönbächler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yoneda, Shigekazu, Young, Edward D., Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, Yurimoto, Hisayoshi, Morita, Mayu, Yui, Hiroharu, Urashima, Shu Hei, Onose, Morihiko, Komatani, Shintaro, Nakai, Izumi, Abe, Yoshinari, Terada, Yasuko, Homma, Hisashi, Motomura, Kazuko, Ichida, Kiyohiro, Yokoyama, Tetsuya, Nagashima, Kazuhide, Aléon, Jérôme, Conel, Conel M., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Hoppe, Peter, Huss, Gary R., Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Krot, Sasha, Liu, Ming-Chang, Masuda, Yuki, Moynier, Frédéric, Nguyen, Ann, Nittler, Larry, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Rocco, Tommaso Di, Russell, Sara S., Sakamoto, Naoya, Schönbächler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yoneda, Shigekazu, Young, Edward D., Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, and Yurimoto, Hisayoshi

Abstract

Characterization of the elemental distribution of samples with rough surfaces has been strongly desired for the analysis of various natural and artificial materials. Particularly for pristine and rare analytes with micrometer sizes embedded on specimen surfaces, non-invasive and matrix effect-free analysis is required without surface polishing treatment. To satisfy these requirements, we proposed a new method employing the sequential combination of two imaging modalities, i.e., microenergy-dispersive X-ray fluorescence (micro-XRF) and Raman micro-spectroscopy. The applicability of the developed method is tested by the quantitative analysis of cation composition in micrometer-sized carbonate grains on the surfaces of intact particles sampled directly from the asteroid Ryugu. The first step of micro-XRF imaging enabled a quick search for the sparsely scattered and micrometer-sized carbonates by the codistributions of Ca2+ and Mn2+ on the Mg2+- and Fe2+-rich phyllosilicate matrix. The following step of Raman micro-spectroscopy probed the carbonate grains and analyzed their cation composition (Ca2+, Mg2+, and Fe2+ + Mn2+) in a matrix effect-free manner via the systematic Raman shifts of the lattice modes. The carbonates were basically assigned to ferroan dolomite bearing a considerable amount of Fe2+ + Mn2+ at around 10 atom %. These results are in good accordance with the assignments reported by scanning electron microscopy-energy-dispersive X-ray spectroscopy, where the thin-sectioned and surface-polished Ryugu particles were applicable. The proposed method requires neither sectioning nor surface polishing; hence, it can be applied to the remote sensing apparatus on spacecrafts and planetary rovers. Furthermore, the non-invasive and matrix effect-free characterization will provide a reliable analytical tool for quantitative analysis of the elemental distrib

Published
2024

16. Neodymium‐142 deficits and samarium neutron stratigraphy of C‐type asteroid (162173) Ryugu

Author

Torrano, Zachary A., primary, Jordan, Michelle K., additional, Mock, Timothy D., additional, Carlson, Richard W., additional, Gautam, Ikshu, additional, Haba, Makiko K., additional, Yokoyama, Tetsuya, additional, Abe, Yoshinari, additional, Aléon, Jérôme, additional, Alexander, Conel, additional, Amari, Sachiko, additional, Amelin, Yuri, additional, Bajo, Ken‐ichi, additional, Bizzarro, Martin, additional, Bouvier, Audrey, additional, Chaussidon, Marc, additional, Choi, Byeon‐Gak, additional, Dauphas, Nicolas, additional, Davis, Andrew M., additional, Di Rocco, Tommaso, additional, Fujiya, Wataru, additional, Fukai, Ryota, additional, Hibiya, Yuki, additional, Hidaka, Hiroshi, additional, Homma, Hisashi, additional, Hoppe, Peter, additional, Huss, Gary R., additional, Ichida, Kiyohiro, additional, Iizuka, Tsuyoshi, additional, Ireland, Trevor, additional, Ishikawa, Akira, additional, Itoh, Shoichi, additional, Kawasaki, Noriyuki, additional, Kita, Noriko T., additional, Kitajima, Koki, additional, Kleine, Thorsten, additional, Komatani, Shintaro, additional, Krot, Alexander N., additional, Liu, Ming‐Chang, additional, Masuda, Yuki, additional, McKeegan, Kevin D., additional, Morita, Mayu, additional, Motomura, Kazuko, additional, Moynier, Frédéric, additional, Nakai, Izumi, additional, Nagashima, Kazuhide, additional, Nguyen, Ann, additional, Nittler, Larry, additional, Onose, Morihiko, additional, Pack, Andreas, additional, Park, Changkun, additional, Piani, Laurette, additional, Qin, Liping, additional, Russell, Sara, additional, Sakamoto, Naoya, additional, Schönbächler, Maria, additional, Tafla, Lauren, additional, Tang, Haolan, additional, Terada, Kentaro, additional, Terada, Yasuko, additional, Usui, Tomohiro, additional, Wada, Sohei, additional, Wadhwa, Meenakshi, additional, Walker, Richard J., additional, Yamashita, Katsuyuki, additional, Yin, Qing‐Zhu, additional, Yoneda, Shigekazu, additional, Young, Edward D., additional, Yui, Hiroharu, additional, Zhang, Ai‐Cheng, additional, Nakamura, Tomoki, additional, Naraoka, Hiroshi, additional, Noguchi, Takaaki, additional, Okazaki, Ryuji, additional, Sakamoto, Kanako, additional, Yabuta, Hikaru, additional, Abe, Masanao, additional, Miyazaki, Akiko, additional, Nakato, Aiko, additional, Nishimura, Masahiro, additional, Okada, Tatsuaki, additional, Yada, Toru, additional, Yogata, Kasumi, additional, Nakazawa, Satoru, additional, Saiki, Takanao, additional, Tanaka, Satoshi, additional, Terui, Fuyuto, additional, Tsuda, Yuichi, additional, Watanabe, Sei‐ichiro, additional, Yoshikawa, Makoto, additional, Tachibana, Shogo, additional, and Yurimoto, Hisayoshi, additional

Published
2023
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19. The Magnesium Isotope Composition of Samples Returned from Asteroid Ryugu

Author

Bizzarro, Martin, primary, Schiller, Martin, additional, Yokoyama, Tetsuya, additional, Abe, Yoshinari, additional, Aléon, Jérôme, additional, Alexander, Conel M. O’D., additional, Amari, Sachiko, additional, Amelin, Yuri, additional, Bajo, Ken-ichi, additional, Bouvier, Audrey, additional, Carlson, Richard W., additional, Chaussidon, Marc, additional, Choi, Byeon-Gak, additional, Dauphas, Nicolas, additional, Davis, Andrew M., additional, Di Rocco, Tommaso, additional, Fujiya, Wataru, additional, Fukai, Ryota, additional, Gautam, Ikshu, additional, Haba, Makiko K., additional, Hibiya, Yuki, additional, Hidaka, Hiroshi, additional, Homma, Hisashi, additional, Hoppe, Peter, additional, Huss, Gary R., additional, Ichida, Kiyohiro, additional, Iizuka, Tsuyoshi, additional, Ireland, Trevor R., additional, Ishikawa, Akira, additional, Itoh, Shoichi, additional, Kawasaki, Noriyuki, additional, Kita, Noriko T., additional, Kitajima, Kouki, additional, Kleine, Thorsten, additional, Komatani, Shintaro, additional, Krot, Alexander N., additional, Liu, Ming-Chang, additional, Masuda, Yuki, additional, Morita, Mayu, additional, Moynier, Fréderic, additional, Motomura, Kazuko, additional, Nakai, Izumi, additional, Nagashima, Kazuhide, additional, Nesvorný, David, additional, Nguyen, Ann, additional, Nittler, Larry, additional, Onose, Morihiko, additional, Pack, Andreas, additional, Park, Changkun, additional, Piani, Laurette, additional, Qin, Liping, additional, Russell, Sara S., additional, Sakamoto, Naoya, additional, Schönbächler, Maria, additional, Tafla, Lauren, additional, Tang, Haolan, additional, Terada, Kentaro, additional, Terada, Yasuko, additional, Usui, Tomohiro, additional, Wada, Sohei, additional, Wadhwa, Meenakshi, additional, Walker, Richard J., additional, Yamashita, Katsuyuki, additional, Yin, Qing-Zhu, additional, Yoneda, Shigekazu, additional, Young, Edward D., additional, Yui, Hiroharu, additional, Zhang, Ai-Cheng, additional, Nakamura, Tomoki, additional, Naraoka, Hiroshi, additional, Noguchi, Takaaki, additional, Okazaki, Ryuji, additional, Sakamoto, Kanako, additional, Yabuta, Hikaru, additional, Abe, Masanao, additional, Miyazaki, Akiko, additional, Nakato, Aiko, additional, Nishimura, Masahiro, additional, Okada, Tatsuaki, additional, Yada, Toru, additional, Yogata, Kasumi, additional, Nakazawa, Satoru, additional, Saiki, Takanao, additional, Tanaka, Satoshi, additional, Terui, Fuyuto, additional, Tsuda, Yuichi, additional, Watanabe, Sei-ichiro, additional, Yoshikawa, Makoto, additional, Tachibana, Shogo, additional, and Yurimoto, Hisayoshi, additional

Published
2023
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20. The Oxygen Isotopic Composition of Samples Returned from Asteroid Ryugu with Implications for the Nature of the Parent Planetesimal

Author

Tang, Haolan, primary, Young, Edward D., additional, Tafla, Lauren, additional, Pack, Andreas, additional, Di Rocco, Tommaso, additional, Abe, Yoshinari, additional, Aléon, Jérôme, additional, M. O’D. Alexander, Conel, additional, Amari, Sachiko, additional, Amelin, Yuri, additional, Bajo, Ken-ichi, additional, Bizzarro, Martin, additional, Bouvier, Audrey, additional, Carlson, Richard W., additional, Chaussidon, Marc, additional, Choi, Byeon-Gak, additional, Dauphas, Nicolas, additional, Davis, Andrew M., additional, Fujiya, Wataru, additional, Fukai, Ryota, additional, Gautam, Ikshu, additional, Haba, Makiko K., additional, Hibiya, Yuki, additional, Hidaka, Hiroshi, additional, Homma, Hisashi, additional, Hoppe, Peter, additional, Huss, Gary R., additional, Ichida, Kiyohiro, additional, Iizuka, Tsuyoshi, additional, Ireland, Trevor R., additional, Ishikawa, Akira, additional, Ito, Motoo, additional, Itoh, Shoichi, additional, Kawasaki, Noriyuki, additional, Kita, Noriko T., additional, Kitajima, Kouki, additional, Kleine, Thorsten, additional, Komatani, Shintaro, additional, Krot, Alexander N., additional, Liu, Ming-Chang, additional, Masuda, Yuki, additional, McKeegan, Kevin D., additional, Morita, Mayu, additional, Motomura, Kazuko, additional, Moynier, Frédéric, additional, Nagashima, Kazuhide, additional, Nakai, Izumi, additional, Nguyen, Ann, additional, Nittler, Larry, additional, Onose, Morihiko, additional, Park, Changkun, additional, Piani, Laurette, additional, Qin, Liping, additional, Russell, Sara S., additional, Sakamoto, Naoya, additional, Schönbächler, Maria, additional, Terada, Kentaro, additional, Terada, Yasuko, additional, Usui, Tomohiro, additional, Wada, Sohei, additional, Wadhwa, Meenakshi, additional, Walker, Richard J., additional, Yamashita, Katsuyuki, additional, Yin, Qing-Zhu, additional, Yokoyama, Tetsuya, additional, Yoneda, Shigekazu, additional, Yui, Hiroharu, additional, Zhang, Ai-Cheng, additional, Nakamura, Tomoki, additional, Naraoka, Hiroshi, additional, Noguchi, Takaaki, additional, Okazaki, Ryuji, additional, Sakamoto, Kanako, additional, Yabuta, Hikaru, additional, Abe, Masanao, additional, Miyazaki, Akiko, additional, Nakato, Aiko, additional, Nishimura, Masahiro, additional, Okada, Tatsuaki, additional, Yada, Toru, additional, Yogata, Kasumi, additional, Nakazawa, Satoru, additional, Saiki, Takanao, additional, Tanaka, Satoshi, additional, Terui, Fuyuto, additional, Tsuda, Yuichi, additional, Watanabe, Sei-ichiro, additional, Yoshikawa, Makoto, additional, Tachibana, Shogo, additional, and Yurimoto, Hisayoshi, additional

Published
2023
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22. Curation protocol of Phobos sample returned by Martian Moons eXploration.

Author

Fukai, Ryota, Usui, Tomohiro, Fujiya, Wataru, Takano, Yoshinori, Bajo, Ken‐ichi, Beck, Andrew, Bonato, Enrica, Chabot, Nancy L., Furukawa, Yoshihiro, Genda, Hidenori, Hibiya, Yuki, Jourdan, Fred, Kleine, Thorsten, Koike, Mizuho, Matsuoka, Moe, Miura, Yayoi N., Moynier, Frédéric, Okazaki, Ryuji, Russell, Sara S., and Sumino, Hirochika

Subjects
LUNAR exploration, MARTIAN exploration, SPECTRAL imaging, MASS spectrometry, SPACE vehicles, INFRARED imaging
Abstract

Japan Aerospace Exploration Agency's Martian Moons eXploration (MMX) mission will launch a spacecraft in 2024 to return samples from Phobos in 2029. Curatorial work for the returned Phobos samples is critical for the sample allocation without degrading the sample integrity and subsequent sample analysis that will provide new constraints on the origin of Phobos and the evolution of the circum‐Mars environment. The Sample Analysis Working Team of the MMX is designing the sample curation protocol. The curation protocol consists of three phases: (1) quick analysis (extraction and mass spectrometry for gases), (2) pre‐basic characterization (bulk‐scale observation), and (3) basic characterization (grain‐by‐grain observation and allocation of the sample aliquots). Nondestructive analyses within the clean chamber (e.g., visible and near‐infrared spectral imaging) and outside the chamber (e.g., gas mass spectrometry) are incorporated into the curation flow in coordination with the MMX mission instrument teams for ground‐truthing the remote‐sensing data sets. The MMX curation/sample analysis flow enables the seamless integration between the sample and remote‐sensing data sets to maximize the scientific value of the collected Phobos samples. [ABSTRACT FROM AUTHOR]

Published
2024
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23. Hydrogen Isotopic Composition of Hydrous Minerals in Asteroid Ryugu

Author

Piani, Laurette, primary, Nagashima, Kazuhide, additional, Kawasaki, Noriyuki, additional, Sakamoto, Naoya, additional, Bajo, Ken-ichi, additional, Abe, Yoshinari, additional, Aléon, Jérôme, additional, O’D. Alexander, Conel M., additional, Amari, Sachiko, additional, Amelin, Yuri, additional, Bizzarro, Martin, additional, Bouvier, Audrey, additional, Carlson, Richard W., additional, Chaussidon, Marc, additional, Choi, Byeon-Gak, additional, Dauphas, Nicolas, additional, Davis, Andrew M., additional, Di Rocco, Tommaso, additional, Fujiya, Wataru, additional, Fukai, Ryota, additional, Gautam, Ikshu, additional, Haba, Makiko K., additional, Hibiya, Yuki, additional, Hidaka, Hiroshi, additional, Homma, Hisashi, additional, Hoppe, Peter, additional, Huss, Gary R., additional, Ichida, Kiyohiro, additional, Iizuka, Tsuyoshi, additional, Ireland, Trevor R., additional, Ishikawa, Akira, additional, Itoh, Shoichi, additional, Kita, Noriko T., additional, Kitajima, Kouki, additional, Kleine, Thorsten, additional, Komatani, Shintaro, additional, Krot, Alexander N., additional, Liu, Ming-Chang, additional, Masuda, Yuki, additional, McKeegan, Kevin D., additional, Morita, Mayu, additional, Motomura, Kazuko, additional, Moynier, Frédéric, additional, Nakai, Izumi, additional, Nguyen, Ann, additional, Nittler, Larry, additional, Onose, Morihiko, additional, Pack, Andreas, additional, Park, Changkun, additional, Qin, Liping, additional, Russell, Sara S., additional, Schönbächler, Maria, additional, Tafla, Lauren, additional, Tang, Haolan, additional, Terada, Kentaro, additional, Terada, Yasuko, additional, Usui, Tomohiro, additional, Wada, Sohei, additional, Wadhwa, Meenakshi, additional, Walker, Richard J., additional, Yamashita, Katsuyuki, additional, Yin, Qing-Zhu, additional, Yokoyama, Tetsuya, additional, Yoneda, Shigekazu, additional, Young, Edward D., additional, Yui, Hiroharu, additional, Zhang, Ai-Cheng, additional, Nakamura, Tomoki, additional, Naraoka, Hiroshi, additional, Okazaki, Ryuji, additional, Sakamoto, Kanako, additional, Yabuta, Hikaru, additional, Abe, Masanao, additional, Miyazaki, Akiko, additional, Nakato, Aiko, additional, Nishimura, Masahiro, additional, Okada, Tatsuaki, additional, Yada, Toru, additional, Yogata, Kasumi, additional, Nakazawa, Satoru, additional, Saiki, Takanao, additional, Tanaka, Satoshi, additional, Terui, Fuyuto, additional, Tsuda, Yuichi, additional, Watanabe, Sei-ichiro, additional, Yoshikawa, Makoto, additional, Tachibana, Shogo, additional, and Yurimoto, Hisayoshi, additional

Published
2023
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24. Carbonate record of temporal change in oxygen fugacity and gaseous species in asteroid Ryugu

Author

Fujiya, Wataru, Kawasaki, Noriyuki, Nagashima, Kazuhide, Sakamoto, Naoya, O'D. Alexander, Conel M., Kita, Noriko T., Kitajima, Kouki, Abe, Yoshinari, Aleon, Jerome, Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Itoh, Shoichi, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Moynier, Frederic, Nakai, Izumi, Nguyen, Ann, Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara S., Schonbachler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yokoyama, Tetsuya, Yoneda, Shigekazu, Young, Edward D., Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, Yurimoto, Hisayoshi, Fujiya, Wataru, Kawasaki, Noriyuki, Nagashima, Kazuhide, Sakamoto, Naoya, O'D. Alexander, Conel M., Kita, Noriko T., Kitajima, Kouki, Abe, Yoshinari, Aleon, Jerome, Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Itoh, Shoichi, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Moynier, Frederic, Nakai, Izumi, Nguyen, Ann, Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara S., Schonbachler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yokoyama, Tetsuya, Yoneda, Shigekazu, Young, Edward D., Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, and Yurimoto, Hisayoshi

Abstract

The Hayabusa2 spacecraft explored asteroid Ryugu and brought its surface materials to Earth. Ryugu samples resemble Ivuna-type (CI) chondrites-the most chemically primitive meteorites-and contain secondary phyllosilicates and carbonates, which are indicative of aqueous alteration. Understanding the conditions (such as temperature, redox state and fluid composition) during aqueous alteration is crucial to elucidating how Ryugu evolved to its present state, but little is known about the temporal changes in these conditions. Here we show that calcium carbonate (calcite) grains in Ryugu and Ivuna samples have variable O-18/O-16 and C-13/C-12 ratios that are, respectively, 24-46 & PTSTHOUSND; and 65-108 & PTSTHOUSND; greater than terrestrial standard values, whereas those of calcium-magnesium carbonate (dolomite) grains are much more homogeneous, ranging within 31-36 & PTSTHOUSND; for oxygen and 67-75 & PTSTHOUSND; for carbon. We infer that the calcite precipitated first over a wide range of temperatures and oxygen partial pressures, and that the proportion of gaseous CO2/CO/CH4 molecules changed temporally. By contrast, the dolomite formed later in a more oxygen-rich and thus CO2-dominated environment when the system was approaching equilibrium. The characteristic isotopic compositions of secondary carbonates in Ryugu and Ivuna are not observed for other hydrous meteorites, suggesting a unique evolutionary pathway for their parent asteroid(s). The asteroid Ryugu experienced aqueous alteration under changing temperature and redox conditions, according to an isotopic analysis of secondary calcite and dolomite grains in samples from Ryugu obtained by the Hayabusa2 spacecraft.

Published
2023

25. The Oxygen Isotopic Composition of Samples Returned from Asteroid Ryugu with Implications for the Nature of the Parent Planetesimal

Author

Tang, Haolan, Young, Edward D., Tafla, Lauren, Pack, Andreas, Di Rocco, Tommaso, Abe, Yoshinari, Aléon, Jérôme, Alexander, Conel M. O'D., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Ito, Motoo, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Moynier, Frédéric, Nagashima, Kazuhide, Nakai, Izumi, Nguyen, Ann, Nittler, Larry, Onose, Morihiko, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara S., Sakamoto, Naoya, Schönbächler, Maria, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yokoyama, Tetsuya, Yoneda, Shigekazu, Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, Yurimoto, Hisayoshi, Tang, Haolan, Young, Edward D., Tafla, Lauren, Pack, Andreas, Di Rocco, Tommaso, Abe, Yoshinari, Aléon, Jérôme, Alexander, Conel M. O'D., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Ito, Motoo, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Moynier, Frédéric, Nagashima, Kazuhide, Nakai, Izumi, Nguyen, Ann, Nittler, Larry, Onose, Morihiko, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara S., Sakamoto, Naoya, Schönbächler, Maria, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yokoyama, Tetsuya, Yoneda, Shigekazu, Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, and Yurimoto, Hisayoshi

Abstract

We present oxygen isotopic analyses of fragments of the near-Earth Cb-type asteroid Ryugu returned by the Hayabusa2 spacecraft that reinforce the close correspondence between Ryugu and CI chondrites. Small differences between Ryugu samples and CI chondrites in can be explained at least in part by contamination of the latter by terrestrial water. The discovery that a randomly sampled C-complex asteroid is composed of CI-chondrite-like rock, combined with thermal models for formation prior to significant decay of the short-lived radioisotope 26Al, suggests that if lithified at the time of alteration, the parent body was small (≪50 km radius). If the parent planetesimal was large (>50 km in radius), it was likely composed of high-permeability, poorly lithified sediment rather than consolidated rock., We present oxygen isotopic analyses of fragments of the near-Earth Cb-type asteroid Ryugu returned by the Hayabusa2 spacecraft that reinforce the close correspondence between Ryugu and CI chondrites. Small differences between Ryugu samples and CI chondrites in can be explained at least in part by contamination of the latter by terrestrial water. The discovery that a randomly sampled C-complex asteroid is composed of CI-chondrite-like rock, combined with thermal models for formation prior to significant decay of the short-lived radioisotope 26Al, suggests that if lithified at the time of alteration, the parent body was small (≪50 km radius). If the parent planetesimal was large (>50 km in radius), it was likely composed of high-permeability, poorly lithified sediment rather than consolidated rock.

Published
2023

26. Abundant presolar grains and primordial organics preserved in carbon-rich exogenous clasts in asteroid Ryugu

Author

Nguyen, Ann N., Mane, Prajkta, Keller, Lindsay P., Piani, Laurette, Abe, Yoshinari, Aléon, Jérôme, Alexander, Conel M. O'D., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Moynier, Frédéric, Nakai, Izumi, Nagashima, Kazuhide, Nesvorný, David, Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Qin, Liping, Russell, Sara S., Sakamoto, Naoya, Schönbächler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yokoyama, Tetsuya, Yoneda, Shigekazu, Young, Edward D., Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, Yurimoto, Hisayoshi, Nguyen, Ann N., Mane, Prajkta, Keller, Lindsay P., Piani, Laurette, Abe, Yoshinari, Aléon, Jérôme, Alexander, Conel M. O'D., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Moynier, Frédéric, Nakai, Izumi, Nagashima, Kazuhide, Nesvorný, David, Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Qin, Liping, Russell, Sara S., Sakamoto, Naoya, Schönbächler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yokoyama, Tetsuya, Yoneda, Shigekazu, Young, Edward D., Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, and Yurimoto, Hisayoshi

Abstract

Preliminary analyses of asteroid Ryugu samples show kinship to aqueously altered CI (Ivuna-type) chondrites, suggesting similar origins. We report identification of C-rich, particularly primitive clasts in Ryugu samples that contain preserved presolar silicate grains and exceptional abundances of presolar SiC and isotopically anomalous organic matter. The high presolar silicate abundance (104 ppm) indicates that the clast escaped extensive alteration. The 5 to 10 times higher abundances of presolar SiC (~235 ppm), N-rich organic matter, organics with N isotopic anomalies (1.2%), and organics with C isotopic anomalies (0.2%) in the primitive clasts compared to bulk Ryugu suggest that the clasts formed in a unique part of the protoplanetary disk enriched in presolar materials. These clasts likely represent previously unsampled outer solar system material that accreted onto Ryugu after aqueous alteration ceased, consistent with Ryugu's rubble pile origin.

Published
2023

27. Samples returned from the asteroid Ryugu are similar to Ivuna-type carbonaceous meteorites

Author

Yokoyama, Tetsuya, Nagashima, Kazuhide, Nakai, Izumi, Young, Edward D., Abe, Yoshinari, Aleon, Jerome, Alexander, Conel M. O'D., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Namiki, Noriyuki, Noda, Hirotomo, Noguchi, Rina, Ogawa, Naoko, Ogawa, Kazunori, Okada, Tatsuaki, Okamoto, Chisato, Ono, Go, Ozaki, Masanobu, Saiki, Takanao, Bouvier, Audrey, Sakatani, Naoya, Sawada, Hirotaka, Senshu, Hiroki, Shimaki, Yuri, Shirai, Kei, Sugita, Seiji, Takei, Yuto, Takeuchi, Hiroshi, Tanaka, Satoshi, Tatsumi, Eri, Carlson, Richard W., Terui, Fuyuto, Tsuda, Yuichi, Tsukizaki, Ryudo, Wada, Koji, Watanabe, Sei-ichiro, Yamada, Manabu, Yamada, Tetsuya, Yamamoto, Yukio, Yano, Hajime, Yokota, Yasuhiro, Chaussidon, Marc, Yoshihara, Keisuke, Yoshikawa, Makoto, Yoshikawa, Kent, Furuya, Shizuho, Hatakeda, Kentaro, Hayashi, Tasuku, Hitomi, Yuya, Kumagai, Kazuya, Miyazaki, Akiko, Nakato, Aiko, Choi, Byeon-Gak, Nishimura, Masahiro, Soejima, Hiromichi, Suzuki, Ayako, Yada, Toru, Yamamoto, Daiki, Yogata, Kasumi, Yoshitake, Miwa, Tachibana, Shogo, Yurimoto, Hisayoshi, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Ito, Motoo, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Moynier, Frederic, Nguyen, Ann, Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara S., Sakamoto, Naoya, Schoenbaechler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yoneda, Shigekazu, Yui, Hiroharu, Zhang, Ai-Cheng, Connolly Jr, Harold C., Lauretta, Dante S., Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Arakawa, Masahiko, Fujii, Atsushi, Hayakawa, Masahiko, Hirata, Naoyuki, Hirata, Naru, Honda, Rie, Honda, Chikatoshi, Hosoda, Satoshi, Iijima, Yu-ichi, Ikeda, Hitoshi, Ishiguro, Masateru, Ishihara, Yoshiaki, Iwata, Takahiro, Kawahara, Kosuke, Kikuchi, Shota, Kitazato, Kohei, Matsumoto, Koji, Matsuoka, Moe, Michikami, Tatsuhiro, Mimasu, Yuya, Miura, Akira, Morota, Tomokatsu, Nakazawa, Satoru, Yokoyama, Tetsuya, Nagashima, Kazuhide, Nakai, Izumi, Young, Edward D., Abe, Yoshinari, Aleon, Jerome, Alexander, Conel M. O'D., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Namiki, Noriyuki, Noda, Hirotomo, Noguchi, Rina, Ogawa, Naoko, Ogawa, Kazunori, Okada, Tatsuaki, Okamoto, Chisato, Ono, Go, Ozaki, Masanobu, Saiki, Takanao, Bouvier, Audrey, Sakatani, Naoya, Sawada, Hirotaka, Senshu, Hiroki, Shimaki, Yuri, Shirai, Kei, Sugita, Seiji, Takei, Yuto, Takeuchi, Hiroshi, Tanaka, Satoshi, Tatsumi, Eri, Carlson, Richard W., Terui, Fuyuto, Tsuda, Yuichi, Tsukizaki, Ryudo, Wada, Koji, Watanabe, Sei-ichiro, Yamada, Manabu, Yamada, Tetsuya, Yamamoto, Yukio, Yano, Hajime, Yokota, Yasuhiro, Chaussidon, Marc, Yoshihara, Keisuke, Yoshikawa, Makoto, Yoshikawa, Kent, Furuya, Shizuho, Hatakeda, Kentaro, Hayashi, Tasuku, Hitomi, Yuya, Kumagai, Kazuya, Miyazaki, Akiko, Nakato, Aiko, Choi, Byeon-Gak, Nishimura, Masahiro, Soejima, Hiromichi, Suzuki, Ayako, Yada, Toru, Yamamoto, Daiki, Yogata, Kasumi, Yoshitake, Miwa, Tachibana, Shogo, Yurimoto, Hisayoshi, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Ito, Motoo, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Moynier, Frederic, Nguyen, Ann, Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara S., Sakamoto, Naoya, Schoenbaechler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yoneda, Shigekazu, Yui, Hiroharu, Zhang, Ai-Cheng, Connolly Jr, Harold C., Lauretta, Dante S., Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Arakawa, Masahiko, Fujii, Atsushi, Hayakawa, Masahiko, Hirata, Naoyuki, Hirata, Naru, Honda, Rie, Honda, Chikatoshi, Hosoda, Satoshi, Iijima, Yu-ichi, Ikeda, Hitoshi, Ishiguro, Masateru, Ishihara, Yoshiaki, Iwata, Takahiro, Kawahara, Kosuke, Kikuchi, Shota, Kitazato, Kohei, Matsumoto, Koji, Matsuoka, Moe, Michikami, Tatsuhiro, Mimasu, Yuya, Miura, Akira, Morota, Tomokatsu, and Nakazawa, Satoru

Abstract

Carbonaceous meteorites are thought to be fragments of C-type (carbonaceous) asteroids. Samples of the C-type asteroid (162173) Ryugu were retrieved by the Hayabusa2 spacecraft. We measured the mineralogy and bulk chemical and isotopic compositions of Ryugu samples. The samples are mainly composed of materials similar to those of carbonaceous chondrite meteorites, particularly the CI (Ivuna-type) group. The samples consist predominantly of minerals formed in aqueous fluid on a parent planetesimal. The primary minerals were altered by fluids at a temperature of 37 degrees +/- 10 degrees C, about 5.2(-0.7)(+0.8) million (statistical) or 5.2(-2.1)(+1.6) million (systematic) years after the formation of the first solids in the Solar System. After aqueous alteration, the Ryugu samples were likely never heated above similar to 100 degrees C. The samples have a chemical composition that more closely resembles that of the Sun's photosphere than other natural samples do.

Published
2023

28. Contribution of Ryugu-like material to Earth’s volatile inventory by Cu and Zn isotopic analysis:[Inkl. Correction]

Author

Paquet, Marine, Moynier, Frederic, Yokoyama, Tetsuya, Dai, Wei, Hu, Yan, Abe, Yoshinari, Aléon, Jérôme, Alexander, Conel M. O'D., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Ito, Motoo, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Nakai, Izumi, Nagashima, Kazuhide, Nesvorný, David, Nguyen, Ann N., Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara S., Sakamoto, Naoya, Schönbächler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yoneda, Shigekazu, Young, Edward D., Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, Yurimoto, Hisayoshi, Paquet, Marine, Moynier, Frederic, Yokoyama, Tetsuya, Dai, Wei, Hu, Yan, Abe, Yoshinari, Aléon, Jérôme, Alexander, Conel M. O'D., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Ito, Motoo, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Nakai, Izumi, Nagashima, Kazuhide, Nesvorný, David, Nguyen, Ann N., Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara S., Sakamoto, Naoya, Schönbächler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yoneda, Shigekazu, Young, Edward D., Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, and Yurimoto, Hisayoshi

Abstract

Initial analyses showed that asteroid Ryugu’s composition is close to CI (Ivuna-like) carbonaceous chondrites (CCs) – the chemically most primitive meteorites, characterized by near-solar abundances for most elements. However, some isotopic signatures (for example, Ti, Cr) overlap with other CC groups, so the details of the link between Ryugu and the CI chondrites are not yet fully clear. Here we show that Ryugu and CI chondrites have the same zinc and copper isotopic composition. As the various chondrite groups have very distinct Zn and Cu isotopic signatures, our results point at a common genetic heritage between Ryugu and CI chondrites, ruling out any affinity with other CC groups. Since Ryugu’s pristine samples match the solar elemental composition for many elements, their Zn and Cu isotopic compositions likely represent the best estimates of the solar composition. Earth’s mass-independent Zn isotopic composition is intermediate between Ryugu/CC and non-carbonaceous chondrites (NCs), suggesting a contribution of Ryugu-like material to Earth’s budgets of Zn and other moderately volatile elements.

Published
2023

29. Samples returned from the asteroid Ryugu are similar to Ivuna-type carbonaceous meteorites

Author

Yokoyama, Tetsuya, primary, Nagashima, Kazuhide, additional, Nakai, Izumi, additional, Young, Edward D., additional, Abe, Yoshinari, additional, Aléon, Jérôme, additional, Alexander, Conel M. O’D., additional, Amari, Sachiko, additional, Amelin, Yuri, additional, Bajo, Ken-ichi, additional, Bizzarro, Martin, additional, Bouvier, Audrey, additional, Carlson, Richard W., additional, Chaussidon, Marc, additional, Choi, Byeon-Gak, additional, Dauphas, Nicolas, additional, Davis, Andrew M., additional, Di Rocco, Tommaso, additional, Fujiya, Wataru, additional, Fukai, Ryota, additional, Gautam, Ikshu, additional, Haba, Makiko K., additional, Hibiya, Yuki, additional, Hidaka, Hiroshi, additional, Homma, Hisashi, additional, Hoppe, Peter, additional, Huss, Gary R., additional, Ichida, Kiyohiro, additional, Iizuka, Tsuyoshi, additional, Ireland, Trevor R., additional, Ishikawa, Akira, additional, Ito, Motoo, additional, Itoh, Shoichi, additional, Kawasaki, Noriyuki, additional, Kita, Noriko T., additional, Kitajima, Kouki, additional, Kleine, Thorsten, additional, Komatani, Shintaro, additional, Krot, Alexander N., additional, Liu, Ming-Chang, additional, Masuda, Yuki, additional, McKeegan, Kevin D., additional, Morita, Mayu, additional, Motomura, Kazuko, additional, Moynier, Frédéric, additional, Nguyen, Ann, additional, Nittler, Larry, additional, Onose, Morihiko, additional, Pack, Andreas, additional, Park, Changkun, additional, Piani, Laurette, additional, Qin, Liping, additional, Russell, Sara S., additional, Sakamoto, Naoya, additional, Schönbächler, Maria, additional, Tafla, Lauren, additional, Tang, Haolan, additional, Terada, Kentaro, additional, Terada, Yasuko, additional, Usui, Tomohiro, additional, Wada, Sohei, additional, Wadhwa, Meenakshi, additional, Walker, Richard J., additional, Yamashita, Katsuyuki, additional, Yin, Qing-Zhu, additional, Yoneda, Shigekazu, additional, Yui, Hiroharu, additional, Zhang, Ai-Cheng, additional, Connolly, Harold C., additional, Lauretta, Dante S., additional, Nakamura, Tomoki, additional, Naraoka, Hiroshi, additional, Noguchi, Takaaki, additional, Okazaki, Ryuji, additional, Sakamoto, Kanako, additional, Yabuta, Hikaru, additional, Abe, Masanao, additional, Arakawa, Masahiko, additional, Fujii, Atsushi, additional, Hayakawa, Masahiko, additional, Hirata, Naoyuki, additional, Hirata, Naru, additional, Honda, Rie, additional, Honda, Chikatoshi, additional, Hosoda, Satoshi, additional, Iijima, Yu-ichi, additional, Ikeda, Hitoshi, additional, Ishiguro, Masateru, additional, Ishihara, Yoshiaki, additional, Iwata, Takahiro, additional, Kawahara, Kosuke, additional, Kikuchi, Shota, additional, Kitazato, Kohei, additional, Matsumoto, Koji, additional, Matsuoka, Moe, additional, Michikami, Tatsuhiro, additional, Mimasu, Yuya, additional, Miura, Akira, additional, Morota, Tomokatsu, additional, Nakazawa, Satoru, additional, Namiki, Noriyuki, additional, Noda, Hirotomo, additional, Noguchi, Rina, additional, Ogawa, Naoko, additional, Ogawa, Kazunori, additional, Okada, Tatsuaki, additional, Okamoto, Chisato, additional, Ono, Go, additional, Ozaki, Masanobu, additional, Saiki, Takanao, additional, Sakatani, Naoya, additional, Sawada, Hirotaka, additional, Senshu, Hiroki, additional, Shimaki, Yuri, additional, Shirai, Kei, additional, Sugita, Seiji, additional, Takei, Yuto, additional, Takeuchi, Hiroshi, additional, Tanaka, Satoshi, additional, Tatsumi, Eri, additional, Terui, Fuyuto, additional, Tsuda, Yuichi, additional, Tsukizaki, Ryudo, additional, Wada, Koji, additional, Watanabe, Sei-ichiro, additional, Yamada, Manabu, additional, Yamada, Tetsuya, additional, Yamamoto, Yukio, additional, Yano, Hajime, additional, Yokota, Yasuhiro, additional, Yoshihara, Keisuke, additional, Yoshikawa, Makoto, additional, Yoshikawa, Kent, additional, Furuya, Shizuho, additional, Hatakeda, Kentaro, additional, Hayashi, Tasuku, additional, Hitomi, Yuya, additional, Kumagai, Kazuya, additional, Miyazaki, Akiko, additional, Nakato, Aiko, additional, Nishimura, Masahiro, additional, Soejima, Hiromichi, additional, Suzuki, Ayako, additional, Yada, Toru, additional, Yamamoto, Daiki, additional, Yogata, Kasumi, additional, Yoshitake, Miwa, additional, Tachibana, Shogo, additional, and Yurimoto, Hisayoshi, additional

Published
2023
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32. Contribution of Ryugu-like material to Earth’s volatile inventory by Cu and Zn isotopic analysis

Author

Paquet, Marine, primary, Moynier, Frederic, additional, Yokoyama, Tetsuya, additional, Dai, Wei, additional, Hu, Yan, additional, Abe, Yoshinari, additional, Aléon, Jérôme, additional, O’D. Alexander, Conel M., additional, Amari, Sachiko, additional, Amelin, Yuri, additional, Bajo, Ken-ichi, additional, Bizzarro, Martin, additional, Bouvier, Audrey, additional, Carlson, Richard W., additional, Chaussidon, Marc, additional, Choi, Byeon-Gak, additional, Dauphas, Nicolas, additional, Davis, Andrew M., additional, Di Rocco, Tommaso, additional, Fujiya, Wataru, additional, Fukai, Ryota, additional, Gautam, Ikshu, additional, Haba, Makiko K., additional, Hibiya, Yuki, additional, Hidaka, Hiroshi, additional, Homma, Hisashi, additional, Hoppe, Peter, additional, Huss, Gary R., additional, Ichida, Kiyohiro, additional, Iizuka, Tsuyoshi, additional, Ireland, Trevor R., additional, Ishikawa, Akira, additional, Ito, Motoo, additional, Itoh, Shoichi, additional, Kawasaki, Noriyuki, additional, Kita, Noriko T., additional, Kitajima, Kouki, additional, Kleine, Thorsten, additional, Komatani, Shintaro, additional, Krot, Alexander N., additional, Liu, Ming-Chang, additional, Masuda, Yuki, additional, McKeegan, Kevin D., additional, Morita, Mayu, additional, Motomura, Kazuko, additional, Nakai, Izumi, additional, Nagashima, Kazuhide, additional, Nesvorný, David, additional, Nguyen, Ann N., additional, Nittler, Larry, additional, Onose, Morihiko, additional, Pack, Andreas, additional, Park, Changkun, additional, Piani, Laurette, additional, Qin, Liping, additional, Russell, Sara S., additional, Sakamoto, Naoya, additional, Schönbächler, Maria, additional, Tafla, Lauren, additional, Tang, Haolan, additional, Terada, Kentaro, additional, Terada, Yasuko, additional, Usui, Tomohiro, additional, Wada, Sohei, additional, Wadhwa, Meenakshi, additional, Walker, Richard J., additional, Yamashita, Katsuyuki, additional, Yin, Qing-Zhu, additional, Yoneda, Shigekazu, additional, Young, Edward D., additional, Yui, Hiroharu, additional, Zhang, Ai-Cheng, additional, Nakamura, Tomoki, additional, Naraoka, Hiroshi, additional, Noguchi, Takaaki, additional, Okazaki, Ryuji, additional, Sakamoto, Kanako, additional, Yabuta, Hikaru, additional, Abe, Masanao, additional, Miyazaki, Akiko, additional, Nakato, Aiko, additional, Nishimura, Masahiro, additional, Okada, Tatsuaki, additional, Yada, Toru, additional, Yogata, Kasumi, additional, Nakazawa, Satoru, additional, Saiki, Takanao, additional, Tanaka, Satoshi, additional, Terui, Fuyuto, additional, Tsuda, Yuichi, additional, Watanabe, Sei-ichiro, additional, Yoshikawa, Makoto, additional, Tachibana, Shogo, additional, and Yurimoto, Hisayoshi, additional

Published
2022
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34. Ryugu's nucleosynthetic heritage from the outskirts of the Solar System

Author

Hopp, Timo, Dauphas, Nicolas, Abe, Yoshinari, Aléon, Jérôme, O, Conel, Alexander, D, Amari, Sachiko, Amelin, Yuri, Bajo, Ken-Ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard, Chaussidon, Marc, Choi, Byeon-Gak, Davis, Andrew, Di, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko, Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary, Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor, Ishikawa, Akira, Ito, Motoo, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko, Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander, Liu, Ming-Chang, Masuda, Yuki, Mckeegan, Kevin, Morita, Mayu, Motomura, Kazuko, Moynier, Frédéric, Nakai, Izumi, Nagashima, Kazuhide, Nesvorný, David, Nguyen, Ann, Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara, Sakamoto, Naoya, Schönbächler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard, Yamashita, Katsuyuki, Yin, Qing-Zhu, Yokoyama, Tetsuya, Yoneda, Shigekazu, Young, Edward, Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-Ichiro, Yoshikawa, Makoto, Tachibana, Shogo, Yurimoto, Hisayoshi, Department of the Geophysical Sciences, University of Chicago, Cosmochimie [IMPMC] (IMPMC_COSMO), Institut de minéralogie, de physique des matériaux et de cosmochimie (IMPMC), Muséum national d'Histoire naturelle (MNHN)-Institut de recherche pour le développement [IRD] : UR206-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Muséum national d'Histoire naturelle (MNHN)-Institut de recherche pour le développement [IRD] : UR206-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Institut de Physique du Globe de Paris (IPGP (UMR_7154)), Institut national des sciences de l'Univers (INSU - CNRS)-Université de La Réunion (UR)-Institut de Physique du Globe de Paris (IPG Paris)-Centre National de la Recherche Scientifique (CNRS)-Université Paris Cité (UPCité), Centre de Recherches Pétrographiques et Géochimiques (CRPG), and Institut national des sciences de l'Univers (INSU - CNRS)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS)

Subjects
Multidisciplinary, [SDU]Sciences of the Universe [physics]
Abstract

Little is known about the origin of the spectral diversity of asteroids and what it says about conditions in the protoplanetary disk. Here, we show that samples returned from Cb-type asteroid Ryugu have Fe isotopic anomalies indistinguishable from Ivuna-type (CI) chondrites, which are distinct from all other carbonaceous chondrites. Iron isotopes, therefore, demonstrate that Ryugu and CI chondrites formed in a reservoir that was different from the source regions of other carbonaceous asteroids. Growth and migration of the giant planets destabilized nearby planetesimals and ejected some inward to be implanted into the Main Belt. In this framework, most carbonaceous chondrites may have originated from regions around the birthplaces of Jupiter and Saturn, while the distinct isotopic composition of CI chondrites and Ryugu may reflect their formation further away in the disk, owing their presence in the inner Solar System to excitation by Uranus and Neptune., Science Advances, 8 (46), ISSN:2375-2548

Published
2022

36. Presolar Stardust in Asteroid Ryugu

Author

Barosch, Jens, primary, Nittler, Larry R., additional, Wang, Jianhua, additional, O’D. Alexander, Conel M., additional, De Gregorio, Bradley T., additional, Engrand, Cécile, additional, Kebukawa, Yoko, additional, Nagashima, Kazuhide, additional, Stroud, Rhonda M., additional, Yabuta, Hikaru, additional, Abe, Yoshinari, additional, Aléon, Jérôme, additional, Amari, Sachiko, additional, Amelin, Yuri, additional, Bajo, Ken-ichi, additional, Bejach, Laure, additional, Bizzarro, Martin, additional, Bonal, Lydie, additional, Bouvier, Audrey, additional, Carlson, Richard W., additional, Chaussidon, Marc, additional, Choi, Byeon-Gak, additional, Cody, George D., additional, Dartois, Emmanuel, additional, Dauphas, Nicolas, additional, Davis, Andrew M., additional, Dazzi, Alexandre, additional, Deniset-Besseau, Ariane, additional, Di Rocco, Tommaso, additional, Duprat, Jean, additional, Fujiya, Wataru, additional, Fukai, Ryota, additional, Gautam, Ikshu, additional, Haba, Makiko K., additional, Hashiguchi, Minako, additional, Hibiya, Yuki, additional, Hidaka, Hiroshi, additional, Homma, Hisashi, additional, Hoppe, Peter, additional, Huss, Gary R., additional, Ichida, Kiyohiro, additional, Iizuka, Tsuyoshi, additional, Ireland, Trevor R., additional, Ishikawa, Akira, additional, Ito, Motoo, additional, Itoh, Shoichi, additional, Kamide, Kanami, additional, Kawasaki, Noriyuki, additional, David Kilcoyne, A. L., additional, Kita, Noriko T., additional, Kitajima, Kouki, additional, Kleine, Thorsten, additional, Komatani, Shintaro, additional, Komatsu, Mutsumi, additional, Krot, Alexander N., additional, Liu, Ming-Chang, additional, Martins, Zita, additional, Masuda, Yuki, additional, Mathurin, Jérémie, additional, McKeegan, Kevin D., additional, Montagnac, Gilles, additional, Morita, Mayu, additional, Mostefaoui, Smail, additional, Motomura, Kazuko, additional, Moynier, Frédéric, additional, Nakai, Izumi, additional, Nguyen, Ann N., additional, Ohigashi, Takuji, additional, Okumura, Taiga, additional, Onose, Morihiko, additional, Pack, Andreas, additional, Park, Changkun, additional, Piani, Laurette, additional, Qin, Liping, additional, Quirico, Eric, additional, Remusat, Laurent, additional, Russell, Sara S., additional, Sakamoto, Naoya, additional, Sandford, Scott A., additional, Schönbächler, Maria, additional, Shigenaka, Miho, additional, Suga, Hiroki, additional, Tafla, Lauren, additional, Takahashi, Yoshio, additional, Takeichi, Yasuo, additional, Tamenori, Yusuke, additional, Tang, Haolan, additional, Terada, Kentaro, additional, Terada, Yasuko, additional, Usui, Tomohiro, additional, Verdier-Paoletti, Maximilien, additional, Wada, Sohei, additional, Wadhwa, Meenakshi, additional, Wakabayashi, Daisuke, additional, Walker, Richard J., additional, Yamashita, Katsuyuki, additional, Yamashita, Shohei, additional, Yin, Qing-Zhu, additional, Yokoyama, Tetsuya, additional, Yoneda, Shigekazu, additional, Young, Edward D., additional, Yui, Hiroharu, additional, Zhang, Ai-Cheng, additional, Abe, Masanao, additional, Miyazaki, Akiko, additional, Nakato, Aiko, additional, Nakazawa, Satoru, additional, Nishimura, Masahiro, additional, Okada, Tatsuaki, additional, Saiki, Takanao, additional, Tanaka, Satoshi, additional, Terui, Fuyuto, additional, Tsuda, Yuichi, additional, Watanabe, Sei-ichiro, additional, Yada, Toru, additional, Yogata, Kasumi, additional, Yoshikawa, Makoto, additional, Nakamura, Tomoki, additional, Naraoka, Hiroshi, additional, Noguchi, Takaaki, additional, Okazaki, Ryuji, additional, Sakamoto, Kanako, additional, Tachibana, Shogo, additional, and Yurimoto, Hisayoshi, additional

Published
2022
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37. Oxygen isotopes of anhydrous primary minerals show kinship between asteroid Ryugu and comet 81P/Wild2

Author

1000050770278, Kawasaki, Noriyuki, Nagashima, Kazuhide, Sakamoto, Naoya, Matsumoto, Toru, Bajo, Ken-Ichi, Wada, Sohei, Igami, Yohei, Miyake, Akira, Noguchi, Takaaki, Yamamoto, Daiki, Russell, Sara S., Abe, Yoshinari, Aleon, Jerome, Alexander, Conel M. O'd, Amari, Sachiko, Amelin, Yuri, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Ito, Motoo, Itoh, Shoichi, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Moynier, Frederic, Nakai, Izumi, Nguyen, Ann, Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Schonbachler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yokoyama, Tetsuya, Yoneda, Shigekazu, Young, Edward D., Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-Ichiro, Yoshikawa, Makoto, Tachibana, Shogo, Yurimoto, Hisayoshi, 1000050770278, Kawasaki, Noriyuki, Nagashima, Kazuhide, Sakamoto, Naoya, Matsumoto, Toru, Bajo, Ken-Ichi, Wada, Sohei, Igami, Yohei, Miyake, Akira, Noguchi, Takaaki, Yamamoto, Daiki, Russell, Sara S., Abe, Yoshinari, Aleon, Jerome, Alexander, Conel M. O'd, Amari, Sachiko, Amelin, Yuri, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Ito, Motoo, Itoh, Shoichi, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Moynier, Frederic, Nakai, Izumi, Nguyen, Ann, Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Schonbachler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yokoyama, Tetsuya, Yoneda, Shigekazu, Young, Edward D., Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-Ichiro, Yoshikawa, Makoto, Tachibana, Shogo, and Yurimoto, Hisayoshi

Abstract

The extraterrestrial materials returned from asteroid (162173) Ryugu consist predominantly of low-temperature aqueously formed secondary minerals and are chemically and mineralogically similar to CI (Ivuna-type) carbonaceous chondrites. Here, we show that high-temperature anhydrous primary minerals in Ryugu and CI chondrites exhibit a bimodal distribution of oxygen isotopic compositions: 16O-rich (associated with refractory inclusions) and 16O-poor (associated with chondrules). Both the 16O-rich and 16O-poor minerals probably formed in the inner solar protoplanetary disk and were subsequently transported outward. The abundance ratios of the 16O-rich to 16O-poor minerals in Ryugu and CI chondrites are higher than in other carbonaceous chondrite groups but are similar to that of comet 81P/Wild2, suggesting that Ryugu and CI chondrites accreted in the outer Solar System closer to the accretion region of comets.

Published
2022

38. Contribution of Ryugu-like material to Earth's volatile inventory by Cu and Zn isotopic analysis

Author

Paquet, Marine, Moynier, Frederic, Yokoyama, Tetsuya, Dai, Wei, Hu, Yan, Abe, Yoshinari, Aleon, Jerome, O'D. Alexander, Conel M., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Ito, Motoo, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Nakai, Izumi, Nagashima, Kazuhide, Nesvorny, David, Nguyen, Ann N., Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara S., Sakamoto, Naoya, Schoenbaechler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yoneda, Shigekazu, Young, Edward D., Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, 1000080191485, Yurimoto, Hisayoshi, Paquet, Marine, Moynier, Frederic, Yokoyama, Tetsuya, Dai, Wei, Hu, Yan, Abe, Yoshinari, Aleon, Jerome, O'D. Alexander, Conel M., Amari, Sachiko, Amelin, Yuri, Bajo, Ken-ichi, Bizzarro, Martin, Bouvier, Audrey, Carlson, Richard W., Chaussidon, Marc, Choi, Byeon-Gak, Dauphas, Nicolas, Davis, Andrew M., Di Rocco, Tommaso, Fujiya, Wataru, Fukai, Ryota, Gautam, Ikshu, Haba, Makiko K., Hibiya, Yuki, Hidaka, Hiroshi, Homma, Hisashi, Hoppe, Peter, Huss, Gary R., Ichida, Kiyohiro, Iizuka, Tsuyoshi, Ireland, Trevor R., Ishikawa, Akira, Ito, Motoo, Itoh, Shoichi, Kawasaki, Noriyuki, Kita, Noriko T., Kitajima, Kouki, Kleine, Thorsten, Komatani, Shintaro, Krot, Alexander N., Liu, Ming-Chang, Masuda, Yuki, McKeegan, Kevin D., Morita, Mayu, Motomura, Kazuko, Nakai, Izumi, Nagashima, Kazuhide, Nesvorny, David, Nguyen, Ann N., Nittler, Larry, Onose, Morihiko, Pack, Andreas, Park, Changkun, Piani, Laurette, Qin, Liping, Russell, Sara S., Sakamoto, Naoya, Schoenbaechler, Maria, Tafla, Lauren, Tang, Haolan, Terada, Kentaro, Terada, Yasuko, Usui, Tomohiro, Wada, Sohei, Wadhwa, Meenakshi, Walker, Richard J., Yamashita, Katsuyuki, Yin, Qing-Zhu, Yoneda, Shigekazu, Young, Edward D., Yui, Hiroharu, Zhang, Ai-Cheng, Nakamura, Tomoki, Naraoka, Hiroshi, Noguchi, Takaaki, Okazaki, Ryuji, Sakamoto, Kanako, Yabuta, Hikaru, Abe, Masanao, Miyazaki, Akiko, Nakato, Aiko, Nishimura, Masahiro, Okada, Tatsuaki, Yada, Toru, Yogata, Kasumi, Nakazawa, Satoru, Saiki, Takanao, Tanaka, Satoshi, Terui, Fuyuto, Tsuda, Yuichi, Watanabe, Sei-ichiro, Yoshikawa, Makoto, Tachibana, Shogo, 1000080191485, and Yurimoto, Hisayoshi

Abstract

Initial analyses showed that asteroid Ryugu's composition is close to CI (Ivuna-like) carbonaceous chondrites (CCs) - the chemically most primitive meteorites, characterized by near-solar abundances for most elements. However, some isotopic signatures (for example, Ti, Cr) overlap with other CC groups, so the details of the link between Ryugu and the CI chondrites are not yet fully clear. Here we show that Ryugu and CI chondrites have the same zinc and copper isotopic composition. As the various chondrite groups have very distinct Zn and Cu isotopic signatures, our results point at a common genetic heritage between Ryugu and CI chondrites, ruling out any affinity with other CC groups. Since Ryugu's pristine samples match the solar elemental composition for many elements, their Zn and Cu isotopic compositions likely represent the best estimates of the solar composition. Earth's mass-independent Zn isotopic composition is intermediate between Ryugu/CC and non-carbonaceous chondrites (NCs), suggesting a contribution of Ryugu-like material to Earth's budgets of Zn and other moderately volatile elements.

Published
2022

39. Cr and Ti isotope systematics of Ryugu samples

Author

Yokoyama, Tetsuya, primary, Iizuka, Tsuyoshi, additional, Gautam, Ikshu, additional, Masuda, Yuki, additional, Hibiya, Yuki, additional, Haba, Makiko, additional, Fukai, Ryota, additional, and Yurimoto, Hisayoshi, additional

Published
2022
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43. 外側太陽系におけるニオブ92の初生存在度

Author

Hibiya, Yuki

Abstract

学位の種別: 課程博士, 審査委員会委員 : （主査）東京大学教授 橘 省吾, （副査）東京工業大学教授 横山 哲也, 東京大学准教授 比屋根 肇, 東京大学准教授 飯塚 毅, 東京大学教授 平田 岳史

Published
2019

45. The origin of the unique achondrite Northwest Africa 6704: Constraints from petrology, chemistry and Re–Os, O and Ti isotope systematics

Author

Hibiya, Yuki, primary, Archer, Gregory J., additional, Tanaka, Ryoji, additional, Sanborn, Matthew E., additional, Sato, Yuya, additional, Iizuka, Tsuyoshi, additional, Ozawa, Kazuhito, additional, Walker, Richard J., additional, Yamaguchi, Akira, additional, Yin, Qing-Zhu, additional, Nakamura, Tomoki, additional, and Irving, Anthony J., additional

Published
2019
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47. Sequential Chemical Separation of Cr and Ti from a Single Digest for High‐Precision Isotope Measurements of Planetary Materials.

Author

Hibiya, Yuki, Iizuka, Tsuyoshi, Yamashita, Katsuyuki, Yoneda, Shigekazu, and Yamakawa, Akane

Subjects
*SEPARATION (Technology), *ION exchange resins, *BIOLOGICAL evolution, *PLANETARY science, TITANIUM isotopes
Abstract

Combined determination of Cr and Ti isotopes of planetary materials offers a means with which to investigate their genetic relationship and the evolution of the protoplanetary disk. Here, we report the new sequential chemical separation procedure for combined Cr and Ti isotope ratio measurements. It comprises three steps: (a) Fe removal using AG1‐X8 anion exchange resin, (b) Ti separation using TODGA resin and (c) Cr separation using AG50W‐X8 cation exchange resin (with one additional step of Ti purification using AG1‐X8 anion exchange resin for samples having high Cr/Ti and Ca/Ti ratios). We applied the proposed procedure to terrestrial and meteorite samples with various compositions. Typical recovery rates of 90–100% were achieved with total procedural Cr and Ti blanks of 3–5 and 2–3 ng, respectively. We measured the Cr and Ti isotope compositions of the separated samples using thermal ionisation mass spectrometry and multiple collector‐inductively coupled plasma‐mass spectrometry, respectively. Our Cr and Ti isotope data were found to be consistent with those of previous studies of individual Cr and Ti isotopic compositions of the meteorites. These results demonstrate the capability of our separation method when applied to combined high‐precision Cr and Ti isotope analyses for single digests of planetary materials. Key Points: Sequential chemical separation for combined Cr and Ti isotope ratio measurements has been developed. Our new method enables isotope analyses of 3 μg of Cr and 1.5 μg of Ti. The combined isotope analyses of primitive meteorite components will facilitate understanding of the evolution of the proto‐planetary disk. [ABSTRACT FROM AUTHOR]

Published
2019
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49. Analysis of Cation Composition in Dolomites on the Intact Particles Sampled from Asteroid Ryugu.

Author

Morita M, Yui H, Urashima SH, Onose M, Komatani S, Nakai I, Abe Y, Terada Y, Homma H, Motomura K, Ichida K, Yokoyama T, Nagashima K, Aléon J, O'D Alexander CM, Amari S, Amelin Y, Bajo KI, Bizzarro M, Bouvier A, Carlson RW, Chaussidon M, Choi BG, Dauphas N, Davis AM, Fujiya W, Fukai R, Gautam I, Haba MK, Hibiya Y, Hidaka H, Hoppe P, Huss GR, Iizuka T, Ireland TR, Ishikawa A, Itoh S, Kawasaki N, Kita NT, Kitajima K, Kleine T, Krot S, Liu MC, Masuda Y, Moynier F, Nguyen A, Nittler L, Pack A, Park C, Piani L, Qin L, Rocco TD, Russell SS, Sakamoto N, Schönbächler M, Tafla L, Tang H, Terada K, Usui T, Wada S, Wadhwa M, Walker RJ, Yamashita K, Yin QZ, Yoneda S, Young ED, Zhang AC, Nakamura T, Naraoka H, Noguchi T, Okazaki R, Sakamoto K, Yabuta H, Abe M, Miyazaki A, Nakato A, Nishimura M, Okada T, Yada T, Yogata K, Nakazawa S, Saiki T, Tanaka S, Terui F, Tsuda Y, Watanabe SI, Yoshikawa M, Tachibana S, and Yurimoto H

Abstract

Characterization of the elemental distribution of samples with rough surfaces has been strongly desired for the analysis of various natural and artificial materials. Particularly for pristine and rare analytes with micrometer sizes embedded on specimen surfaces, non-invasive and matrix effect-free analysis is required without surface polishing treatment. To satisfy these requirements, we proposed a new method employing the sequential combination of two imaging modalities, i.e., microenergy-dispersive X-ray fluorescence (micro-XRF) and Raman micro-spectroscopy. The applicability of the developed method is tested by the quantitative analysis of cation composition in micrometer-sized carbonate grains on the surfaces of intact particles sampled directly from the asteroid Ryugu. The first step of micro-XRF imaging enabled a quick search for the sparsely scattered and micrometer-sized carbonates by the codistributions of Ca 2+ and Mn 2+ on the Mg 2+ - and Fe 2+ -rich phyllosilicate matrix. The following step of Raman micro-spectroscopy probed the carbonate grains and analyzed their cation composition (Ca 2+ , Mg 2+ , and Fe 2+ + Mn 2+ ) in a matrix effect-free manner via the systematic Raman shifts of the lattice modes. The carbonates were basically assigned to ferroan dolomite bearing a considerable amount of Fe 2+ + Mn 2+ at around 10 atom %. These results are in good accordance with the assignments reported by scanning electron microscopy-energy-dispersive X-ray spectroscopy, where the thin-sectioned and surface-polished Ryugu particles were applicable. The proposed method requires neither sectioning nor surface polishing; hence, it can be applied to the remote sensing apparatus on spacecrafts and planetary rovers. Furthermore, the non-invasive and matrix effect-free characterization will provide a reliable analytical tool for quantitative analysis of the elemental distribution on the samples with surface roughness and chemical heterogeneity at a micrometer scale, such as art paintings, traditional crafts with decorated shapes, as well as sands and rocks with complex morphologies in nature.

Published
2024
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50. Ryugu's nucleosynthetic heritage from the outskirts of the Solar System.

Author

Hopp T, Dauphas N, Abe Y, Aléon J, O'D Alexander CM, Amari S, Amelin Y, Bajo KI, Bizzarro M, Bouvier A, Carlson RW, Chaussidon M, Choi BG, Davis AM, Di Rocco T, Fujiya W, Fukai R, Gautam I, Haba MK, Hibiya Y, Hidaka H, Homma H, Hoppe P, Huss GR, Ichida K, Iizuka T, Ireland TR, Ishikawa A, Ito M, Itoh S, Kawasaki N, Kita NT, Kitajima K, Kleine T, Komatani S, Krot AN, Liu MC, Masuda Y, McKeegan KD, Morita M, Motomura K, Moynier F, Nakai I, Nagashima K, Nesvorný D, Nguyen A, Nittler L, Onose M, Pack A, Park C, Piani L, Qin L, Russell SS, Sakamoto N, Schönbächler M, Tafla L, Tang H, Terada K, Terada Y, Usui T, Wada S, Wadhwa M, Walker RJ, Yamashita K, Yin QZ, Yokoyama T, Yoneda S, Young ED, Yui H, Zhang AC, Nakamura T, Naraoka H, Noguchi T, Okazaki R, Sakamoto K, Yabuta H, Abe M, Miyazaki A, Nakato A, Nishimura M, Okada T, Yada T, Yogata K, Nakazawa S, Saiki T, Tanaka S, Terui F, Tsuda Y, Watanabe SI, Yoshikawa M, Tachibana S, and Yurimoto H

Abstract

Little is known about the origin of the spectral diversity of asteroids and what it says about conditions in the protoplanetary disk. Here, we show that samples returned from Cb-type asteroid Ryugu have Fe isotopic anomalies indistinguishable from Ivuna-type (CI) chondrites, which are distinct from all other carbonaceous chondrites. Iron isotopes, therefore, demonstrate that Ryugu and CI chondrites formed in a reservoir that was different from the source regions of other carbonaceous asteroids. Growth and migration of the giant planets destabilized nearby planetesimals and ejected some inward to be implanted into the Main Belt. In this framework, most carbonaceous chondrites may have originated from regions around the birthplaces of Jupiter and Saturn, while the distinct isotopic composition of CI chondrites and Ryugu may reflect their formation further away in the disk, owing their presence in the inner Solar System to excitation by Uranus and Neptune.

Published
2022
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