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[Display omitted] • We present new zircon U-Pb, Hf, O isotopes from the Paleoproterozoic Karrat Group. • With provenance analysis of Karrat Group and Rinkian fold belt supracrustal rocks. • Zircon Hf isotopes identify new, abundant ca. 2.15–1.9 Ga juvenile magmatism. • Karrat Group sourced dominantly from orogenies involving the Rae craton. We use zircon U-Pb, Hf and O isotopes to constrain the depositional ages and provenance of metasedimentary rocks of the Paleoproterozoic Karrat Group of West Greenland and to understand the tectonic processes leading to basin development on the eastern Rae craton. An older supracrustal assemblage (Qeqertarssuaq complex) deposited after ca. 2.6 Ga is separated by an unconformity with a younger supracrustal assemblage (the Karrat Group). The Qaarsukassak Formation at the base of the Karrat Group was deposited after ca. 2.0 Ga, with dominantly Archean age modes. The youngest siliciclastic rocks (Nûkavsak and Mârmorilik formations) in the Karrat Group have maximum depositional ages ranging from ca. 1980 to 1950 to 1900 Ma and contain dominant detrital zircon age modes between ca. 2.50 and 1.93 Ga. A ca. 1.92 Ga supracrustal assemblage referred to as the northern domain (Karrat Group, sensu lato) is geographically separated from the Karrat Group (sensu stricto) by the Prøven igneous complex. The stratigraphy and detrital zircon profiles are compared to broadly coeval sedimentary units on the Rae craton and a unifying model of their deposition is presented. The Rae craton is the dominant detritus source; initially these sources were mostly local, changing to a mix of local and distal sources including the western Rae craton. The tectonic setting of the Karrat basin transitioned from extensional to convergent to collisional during its basin evolution, reflecting Wilson cycle phases within an epeiric sea. Accordingly, zircon Hf isotopes in our dataset track the evolution of the opening and closing of the Manikewan Ocean. Detrital zircon Hf isotopes in our dataset reveal a greater proportion of juvenile detritus (especially ca. 2.15–1.95 Ga) than is known from the currently exposed crustal record, pointing to the importance of the detrital zircon record for understanding Paleoproterozoic crustal and tectonic evolution. [ABSTRACT FROM AUTHOR]

Research on the geological process of the Xing'an -- Mongolia Orogenic Belt has attracted the attention of scholars both domestically and internationally. Its genesis and tectonic location may help revealing the geological processes asscoaited with the evolution of the Xing'an -- Mongolia Orogenic Belt. This study focuses on the development of the Permian granitic complex in Jielin Ranch, and we conduct systematic geological, petrographic, zircon U-Pb chronology, Hf isotope, and geochemical tracing of rock elements for evidence. The results show that the granitic complex is mainly composed of monzogranite and syenogranite, which obtained zircon U-Pb ages of 291.1 ± 1.1 Ma and 260.8 ± 1.1 Ma, respectively. The monzogranite and syenogranite are all acidic and aluminum rich rocks, and the monzogranite is a potassium rich, high potassium calcium alkaline rock series with relatively low REE content, high degree of fractionation, and insignificant europium anomalies, enriched with LILE (Rb, Th, U, K), deficient elements such as Ba, Sr, Nb, Ti, and P, εHf(t) values are from +4.1 to +7.0 (TDM2=1130-920 Ma). Geochemistry shows that the monzogranite belongs to high fractionation of I-type granite, which formed in a subduction-compressional or extension tectonic environment, and Middle Neoproterozoic lower crust rocks as the major source material of magma. The syenogranite is a potassium high potassium transitional rock series with a high rare earth content (214 x 10-6~325 x 10-6), low LREE/HREE (2.54-6.41), δEu (0.04-0.15) and the typical "four component effect" fractionation mode is enriched in large ion lithophilic elements such as Rb, Th, K, and strongly depleted in elements such as Ba, Sr, Nb, Ta, Ti, P, εHf(t) values are from +4.2 to +8.6 (TDM2=738-1228 Ma), suggesting the characteristics of an "A2 type" granite. The magma originated from partial melting of the lower crust of the Middle and Neoproterozoic with the participation of mantle derived melts, and was formed in a back-arc extensional environment. This suggests that the study area experienced a subduction-compressional or extension tectonic environment during the early Permian and a brief backarc extension process in the late Permian. [ABSTRACT FROM AUTHOR]

This study presents U-Pb zircon ages and Lu-Hf zircon isotope data for Cretaceous-Paleocene plutonic rocks along a W-E transect in northwestern Mexico. These data are combined with tectonic reconstruction that restores Late Cenozoic extensional deformation and shows the position of magmatism at 36 Ma. Zircon U-Pb ages results span from 142 to 58 Ma and demonstrate that the continental arc migrated northeastward at 1–2.5 km/Myr. These rates are slower than previously interpreted, but consistent with landward arc migration rates observed in the Andes. Weighted mean initial epsilon hafnium (εHf(t)) values of plutonic rocks along the transect range from + 8.8 to −9.1. The heterogeneity in the zircon εHf(t) is spatially related to the pre-Cretaceous basement provinces that the intrusive rocks were emplaced into. Zircon εHf(t) values of western Baja California display positive values ranging from + 8.8 to + 2.6 suggesting they were formed from a moderately depleted mantle and were emplaced into the Guerrero-Alisitos-Vizcaino terrane. Zircon εHf(t) values in the eastern part of Baja California and most of Sonora are heterogeneous ranging between −0.7 and −9.1 and may be formed from a relatively slightly more evolved mantle source and end up more evolved after crustal assimilation of metasediments. Zircon εHf(t) values ranging from + 8.7 to + 2.9 in Chihuahua are consistent with a depleted-mantle derived melt and assimilation of Grenville lithospheric province. Our results highlight how Hf isotopic signatures help to constrain the pre-Cretaceous basement configuration in northwestern Mexico despite the few exposed outcrops along the transect. [ABSTRACT FROM AUTHOR]

Xenoliths recovered from the post-Variscan Bode dike system of the eastern Harz Mountains provide evidence for the existence of an Early Devonian magmatic arc system hidden beneath very low-grade metasedimentary rocks of the Rhenohercynian Zone, but also for Late Carboniferous–Early Permian crust reworking. This interpretation is based on petrographic observations and whole-rock geochemical analyses of granite xenoliths, in addition to results of zircon U–Pb dating and Hf isotope analyses. Zircon grains recovered from variably deformed granite xenoliths yield ages between 419 and 393 Ma, interpreted to reflect the timing of granite intrusion. Rare zircon xenocrysts of Archean (ca. 2.92–2.65 Ga) and Proterozoic age (ca. 1.5 to 0.56 Ga), all with subchondritic εHf420 Ma values (− 0.8 to − 5.5) indicate reworking of older crust. Compilation of age-Hf isotope data further suggests that the pre-Variscan granitoids beneath the Harz Mountains belong to the same magmatic arc system exposed widespread in the adjacent Mid-German Crystalline Zone, and interpreted to result from NW-ward subduction of the Rheic Ocean beneath Avalonia-Baltica. Zircon in xenoliths with granophyric texture yields ages at 400 Ma and 295–310 Ma, indicating re-melting of Devonian granitoid basement during post-Variscan rift-related magmatism, immediately prior to Bode dike intrusion. Left: Late Devonian intrusion of magmatic arc granites during NW-ward subduction of the Rheic ocean beneath Avalonia-Baltica. Right: Formation of the Bode dike system and Harz granites during Late Carboniferous-Permian extension. [ABSTRACT FROM AUTHOR]

Abstract With the development of detrital zircon U–Pb ages and Hf isotope analysis as conventional sedimentological research methods, a large number of studies have been conducted in the Tarim, West Kunlun, Tajik, Pamir and Tianshuihai regions and abundant data have been accumulated. Summarizing these data to characterize sedimentary units and source regions is more important than local studies of specific geological epochs; therefore, we compiled a database of detrital zircon U–Pb ages and Hf isotope analyses from the Tarim, West Kunlun, Pamir, Tajik and Tianshuihai terranes. The database contains data from 90 papers, including 35,281 individual U–Pb ages and 4,181 Hf isotope analyses. The database records the literature source, petrologic sample information, regional geological information, geographic coordinates and analytical parameters for each data point in as much detail as possible to allow readers to review, process, analyse and use the data. The database relies on the Deep‐time Digital Earth (DDE) platform and uses an open database update system to enable sharing and collaborative building. We encourage other researchers to contribute relevant published data to facilitate wider use.

With the development of detrital zircon U–Pb ages and Hf isotope analysis as conventional sedimentological research methods, a large number of studies have been conducted in the Tarim, West Kunlun, Tajik, Pamir and Tianshuihai regions and abundant data have been accumulated. Summarizing these data to characterize sedimentary units and source regions is more important than local studies of specific geological epochs; therefore, we compiled a database of detrital zircon U–Pb ages and Hf isotope analyses from the Tarim, West Kunlun, Pamir, Tajik and Tianshuihai terranes. The database contains data from 90 papers, including 35,281 individual U–Pb ages and 4,181 Hf isotope analyses. The database records the literature source, petrologic sample information, regional geological information, geographic coordinates and analytical parameters for each data point in as much detail as possible to allow readers to review, process, analyse and use the data. The database relies on the Deep‐time Digital Earth (DDE) platform and uses an open database update system to enable sharing and collaborative building. We encourage other researchers to contribute relevant published data to facilitate wider use. [ABSTRACT FROM AUTHOR]

The stable Zr isotope ratios in zircon yield a novel geochemical tracer that, together with the Lu‐Hf and U‐Pb radiogenic isotope systems, allows for a better understanding of the magmatic evolution of silicate melts. We present a solution‐based procedure for coupled stable Zr, Lu‐Hf and U‐Pb isotope ratio determinations for individual zircons using a 91Zr‐96Zr tracer purified from Hf and a late‐spiking protocol for Zr. This method yields high‐precision Zr and Hf isotope results while maintaining low blank levels for U‐Pb isotope and Lu/Hf ratio determinations. With a two‐fold improvement on the precision relative to previous solution‐based work, we report δ94ZrIPGP‐Zr values (deviation of the 94Zr/90Zr ratio in the sample relative to the IPGP‐Zr reference material) and associated intermediate precisions (2s) for the zircon reference materials 91500, Mud Tank, Plešovice and Penglai of ‐0.041 ± 0.015‰, 0.018 ± 0.013‰, 0.089 ± 0.020‰ and ‐0.117 ± 0.021‰, respectively. Furthermore, this method yields un‐biased δ94ZrIPGP‐Zr and 176Hf/177Hf results for 25‐ng Zr and 0.56‐ng Hf aliquots of the Mud Tank zircon with intermediate precisions (2s) of 0.027‰ and 1.7 ε (parts per ten thousand), respectively. Thus, the presented method is applicable for the analysis of extremely small and rare zircon grains. [ABSTRACT FROM AUTHOR]

Magmatism is a critical component in sustaining hydrothermal convection and metal transport during the formation of volcanogenic massive sulfide (VMS) deposits. Previous studies of magmatic petrogenesis in VMS systems have demonstrated that ore-related volcanic rocks have distinct whole-rock geochemical and isotopic signatures (i.e., high HFSE, REE, Th, εHf-Nd, zircon saturation T) relative to barren volcanic rocks, which supports models of elevated crustal heat flow during periods of ore deposition; however, the petrologic characteristics and intrinsic parameters (e.g., T, fO2) related to these magmatic events in VMS districts remain poorly understood. Arc–back-arc assemblages from the mid-Paleozoic Yukon-Tanana terrane are well-characterized and include the Finlayson Lake VMS district, which is host to several felsic-hosted deposits (e.g., Kudz Ze Kayah, GP4F, Wolverine) that were generated in a peri-Laurentian continental back-arc tectonic setting. In this study, zircon from back-arc and coeval arc rocks in the Yukon-Tanana terrane was used as a proxy for primary magma formation conditions that generated VMS-proximal and VMS-distal stratigraphy. Our results indicate that zircon grains in VMS-proximal environments have unique textural, geochemical, and isotopic characteristics (e.g., low-aspect ratios, greater abundance of zircon-phosphate intergrowths, Th/U > 1, Zr/Hf > 80, Tzrc > 780 °C, εHfi > –7) that are clearly distinguished from zircon in VMS-distal rocks in both the back-arc and arc settings (Th/U < 1, Zr/Hf < 80, Tzrc < 780 °C, εHfi < –7). These signatures correlate to VMS-proximal magmas that were hotter, less fractionated, and contained greater juvenile melt contributions compared to VMS-distal magmas and reflect a series of high-flux magmatic events that directly correspond to the early tectonic development of Yukon-Tanana terrane. Moreover, this study underscores the importance of mineral-scale petrology, geochemistry, and geochronology in defining the primary magmatic conditions that generated VMS-related felsic rocks and highlights the utility of zircon as a prospectivity tool in both grassroots and brownfields VMS exploration. [ABSTRACT FROM AUTHOR]

The Anshan–Benxi area, situated in the northeast of the North China Craton (NCC), is home to not only the oldest rocks in China (~3.8 Ga) but also a diverse range of granitoids dated between 3.8 and 2.5 Ga. The Lianshanguan batholith, covering an area of approximately 250 km2 with an east–west trend, predominantly consists of syenogranites (K2O > 4 wt. % and K2O/Na2O ratios > 1.3). Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U-Pb analyses of the two syenogranites yielded concordant ages of 2541 ± 22 and 2512 ± 13 Ma, respectively. These syenogranites had zircon εHf(t) values ranging from −20 to +4.9 with two-stage Hf model ages (TDM2(Hf)) spanning 3.9–2.7 Ga. Based on petrological, geochemical, and isotopic characteristics, we conclude that the Lianshanguan syenogranites are mainly resulted from the reworking of complicated Eoarchean–Mesoarchean crustal materials, possibly with a small proportion of ~2.7 Ga juvenile crustal materials. When compared with coeval syenogranites from the Northern Liaoning and Western Liaoning–Eastern Hebei areas, ~2.5 Ga syenogranites from the Anshan–Benxi area displayed more complicated TDM2(Hf) ages, hinting at a pronounced late Neoarchean reworking of the Eoarchean to Mesoarchean continental crust (including metasedimentary sources) primarily in the Anshan–Benxi region of the North China Craton. This scenario significantly bolsters the arc–continent collision model. [ABSTRACT FROM AUTHOR]

Unlike oceanic hotspot tracks, continental hotspot tracks are difficult to recognise, although they can provide unique insights into crustal deformation and intraplate magmatism. Here, we present whole‐rock geochemical and Sr–Nd isotope, and zircon U–Pb age and Hf isotope data for a tuff from the E'Xi rift basin in the South China Block. The zircons yielded a 206Pb/238U age of 267.0 ± 2.0 Ma, which coincides with the Roadian–Wordian boundary. The whole‐rock geochemical and Sr–Nd isotope data for the tuff indicate it had a mixed mantle–crust source. The zircon trace element and εHf(t) (−6.32 to +7.06) data are also consistent with such a source. Based on the sedimentological and tectonic history, and the geochronology and geochemistry of the tuff, we propose the tuff erupted in a rift and records the hidden hotspot track of the Emeishan mantle plume beneath the northern SCB. [ABSTRACT FROM AUTHOR]

Active and passive continental rifts are generally attributed to plume and subduction mechanisms, respectively. However, controversy surrounding the role of the two mechanisms continues, especially for the mid-Neoproterozoic rifts in the South China Craton. Here, we use geochemical and zircon Hf isotope data from the craton's rift successions to examine the mechanism of rifting. The compiled geochemical data support the existence of subduction-related magmatic belts along the Jiangnan Orogen and western Yangtze margin of the craton during the mid-Neoproterozoic, consistent with a conventional subduction-related passive rift mechanism. But evidence of asthenospheric upwelling and subsequent lithospheric uplift, metamorphism, volcanism and magma-rich rift infill indicate rifting was active. Compiled zircon εHf(t) values and crustal incubation times suggest a ca. 830–780 Ma transition from advancing to retreating subduction that coincides with rifting across the craton. We therefore propose a subduction-related active rifting model in which the onset of transitionalsubduction triggered mantle convection and plume activity that led to the mid-Neoproterozoic initiation of active rifting in the South China Craton. This suggests a mixed mechanism for rifting rather than two distinct end-members. [ABSTRACT FROM AUTHOR]

The Tibetan Plateau is a key region to understand the evolution of the Tethys Oceans. To better constrain the tectonic evolution of the Proto-Tethys Ocean on the western margin of the Yangtze plate, we present an integrated petrography, geochemistry, and zircon U-Pb-Lu-Hf isotope study on newly recognized early Silurian gabbro and serpentinite rocks from the eastern Yidun terrane of the Tibetan Plateau. Zircon U-Pb dating of the gabbro yields an Early Silurian age of 438.2 ± 2.8 Ma. Zircon εHf(t) values of 5.4 to 8.5 suggest a single-stage model age (TDM1) ranging from 729 to 858 Ma. The gabbros exhibit low total rare earth element abundances but are moderately enriched in the light rare earth elements and the large-ion lithophile elements (e.g. Rb, Ba, and Sr), and display representative negative high-field strength elemental anomalies for Nb, Ta, Zr, and Hf on spidergrams. The gabbro and serpentinites were derived from a depleted mantle-like source made of garnet-spinel lherzolite composition, from a sub-arc mantle wedge that was metasomatized by slab dehydration. Thus, the gabbro and serpentinites record an Early Silurian subduction event of the Proto-Tethys Ocean under the Yangtze plate. Furthermore, this study confirms that the Yidun terrane on the western margin of the Yangtze plate is underlined by a Precambrian crystalline basement. [ABSTRACT FROM AUTHOR]

The Shaolang River metallogenic belt in Inner Mongolia is one of the main lead‐zinc polymetallic belt on the northern margin of the North China Plate. The granodiorites, which are closely coexisting with lead‐zinc veins in deposit, are extensively developed. Previous geochronological research results show that the dikes and veins in the metallogenic belt belong to the products of magmatic hydrothermal activity in the middle Yanshanian, so the genesis of the metallogenic belt deposit is generally considered to be a hydrothermal vein type deposit related to sub‐volcanic dikes. We obtained zircon LA‐ICP‐MS U–Pb ages and Hf isotopic compositions of granodiorites, which are widely distributed in the deposit and were considered to be closely connected with the genesis of the deposits. The zircon U–Pb ages are 419.4 ± 1.4 Ma and 424.5 ± 4.1 Ma for the granodiorites, respectively, and they formed in the late Silurian. The geological and geochemical data indicate that the granodiorites are consistent with the geochemical characteristics of typical adakite. All εHf(t) values of the granodiorites are minus, on the zircon Hf isotope age diagram, εHf(t) are below the evolution curve of chondrite. The two‐stage model ages (tDM2) are 2.45 ~ 2.79 Ga and 1.87 ~ 2.29 Ga, respectively, showing rock‐forming materials mainly derived from the Paleoproterozoic and earlier crustal partial melting, and there may have been mantle‐derived magma underplating of the lower crust. Combining with the previous regional research, it is concluded that the granodiorites were formed during the extinction of the island arc under the background of subduction of the Paleo‐Asian Ocean and North China Craton. Because of the 125 ~ 170 Ma metallogenic age, we concluded that the granodiorites in the ore areas have no obvious relationship with the deposit genesis. However, it provided the advantageous space for the formation of the lead‐zinc veins, it can be regarded as an important prospecting indicator in metallogenic belt. [ABSTRACT FROM AUTHOR]

The Almogholagh Intrusive Complex (AIC) in the central part of the Sanandaj-Sirjan zone (C-SaSZ) includes gabbros to granites. Zircon U-Pb dating of mafic, intermediate, and felsic intrusions yield age of 146 to 141 Ma (Late Jurassic-Early Cretaceous). Bulk chemistry shows a wide range for SiO2 (46.8 to 73.3 wt.%), MgO (0.08 to 8.95 wt.%), and Fe2O3(T) (0.47 to 9.25 wt.%) and also alkali elements ranging from 3.59 to 10.12 wt.%. These rocks are characterized by a high content of large-ion lithophile elements (LILEs; e.g. Rb, U, Th, and K) and LREEs with weak Nb and Ta negative anomalies, showing many similarities to an extensional setting. The 176Hf/177Hf ratios vary from 0.282802 to 0.282985 with positive εHf(t) values from + 1.67 to +10.74 (avg: 7.85). Trace-element and isotope ratios modelling indicate that the AIC mafic-intermediate rocks were generated by partial melting of spinel lherzolite and then underwent considerable crustal contamination. The present work in combination with previous data confirm an extensional tectonic regime for the northern part of the C-SaSZ during the Late Jurassic to Early Cretaceous. Magmatic differentiation with crustal contamination played a fundamental role in the wide compositional range from mafic to felsic types that formed the AIC. [ABSTRACT FROM AUTHOR]

Slab rollback during subduction plays a key role in controlling continental growth at convergent plate boundaries. The dynamics of currently subducting slabs can be precisely constrained using geophysical techniques. In contrast, ancient episodes of slab rollback can be difficult to constrain, yet are critical to unlocking the tectonic evolution of long‐lived orogens such as the Phanerozoic Australian Tasmanides of eastern Gondwana. Recognition of ancient slab rollback relies on the identification of the progressive migration of magmatic arcs. Here, we investigate the timing and isotopic variation of ∼90 km of the trans‐orogen migration of the Carboniferous Bathurst Batholith as a potential indicator of slab rollback. U–Pb–Hf isotopes, combined with a regional zircon Hf isotope data set, suggest that the eastward migration of the batholith over ∼18 Myr, from 340.1 to 322.4 Ma, records a maximum slab steepening rate of ∼0.6–1.2° Myr−1 in a relatively stable trench setting. These results provide a magmatic record of Carboniferous slab rollback and establish a missing link between the long‐lived Lachlan and New England orogens of the eastern Gondwanan Tasmanides. Plain Language Summary: Slab rollback occurs at convergent plate boundaries, which is key to understanding the evolution of subduction processes. However, for ancient subduction zones where the geometry of long since subducted slabs no longer exists, the evolution of slab dynamics remains unclear. Occasionally though, the progressive migration of magmatic trends is observable and provides constraints on slab rollback, which aid in reconstructing the tectonic evolution of long‐lived orogens, such as the Phanerozoic orogens of eastern Australia. Here, we focus on how the unique magmatism of the Carboniferous Bathurst Batholith progressively migrated in the direction of the trench and analyze and interpret the geochronological and geochemical evolution of the batholith to better constrain subduction dynamics. We find that the Bathurst Batholith records the Carboniferous slab rollback of eastern Gondwana and reveals the relationship between the two key orogens of eastern Australia. Thus, the migration of magmatism in convergent settings can be used to track the slab rollback processes and evolution of the long‐lived orogens. Key Points: The Bathurst Batholith is part of a Carboniferous continental arc formed as a result of westward subduction in eastern GondwanaEastward migration of the batholith over ∼18 Myr recorded a maximum slab steepening rate of ∼0.6–1.2° Myr−1 in a stable trench settingThe batholith as a trans‐orogen "missing link" reveals continental arc magmatism extended across the Lachlan and New England orogens [ABSTRACT FROM AUTHOR]

Abstract Slab rollback during subduction plays a key role in controlling continental growth at convergent plate boundaries. The dynamics of currently subducting slabs can be precisely constrained using geophysical techniques. In contrast, ancient episodes of slab rollback can be difficult to constrain, yet are critical to unlocking the tectonic evolution of long‐lived orogens such as the Phanerozoic Australian Tasmanides of eastern Gondwana. Recognition of ancient slab rollback relies on the identification of the progressive migration of magmatic arcs. Here, we investigate the timing and isotopic variation of ∼90 km of the trans‐orogen migration of the Carboniferous Bathurst Batholith as a potential indicator of slab rollback. U–Pb–Hf isotopes, combined with a regional zircon Hf isotope data set, suggest that the eastward migration of the batholith over ∼18 Myr, from 340.1 to 322.4 Ma, records a maximum slab steepening rate of ∼0.6–1.2° Myr−1 in a relatively stable trench setting. These results provide a magmatic record of Carboniferous slab rollback and establish a missing link between the long‐lived Lachlan and New England orogens of the eastern Gondwanan Tasmanides.

The Anshan–Benxi area, situated in the northeast of the North China Craton (NCC), is home to not only the oldest rocks in China (~3.8 Ga) but also a diverse range of granitoids dated between 3.8 and 2.5 Ga. The Lianshanguan batholith, covering an area of approximately 250 km2 with an east–west trend, predominantly consists of syenogranites (K2O > 4 wt. % and K2O/Na2O ratios > 1.3). Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U-Pb analyses of the two syenogranites yielded concordant ages of 2541 ± 22 and 2512 ± 13 Ma, respectively. These syenogranites had zircon εHf(t) values ranging from −20 to +4.9 with two-stage Hf model ages (TDM2(Hf)) spanning 3.9–2.7 Ga. Based on petrological, geochemical, and isotopic characteristics, we conclude that the Lianshanguan syenogranites are mainly resulted from the reworking of complicated Eoarchean–Mesoarchean crustal materials, possibly with a small proportion of ~2.7 Ga juvenile crustal materials. When compared with coeval syenogranites from the Northern Liaoning and Western Liaoning–Eastern Hebei areas, ~2.5 Ga syenogranites from the Anshan–Benxi area displayed more complicated TDM2(Hf) ages, hinting at a pronounced late Neoarchean reworking of the Eoarchean to Mesoarchean continental crust (including metasedimentary sources) primarily in the Anshan–Benxi region of the North China Craton. This scenario significantly bolsters the arc–continent collision model.

The duration and extent of sediment routing systems are intrinsically linked to crustal‐ to mantle‐scale processes. Therefore, distinct changes in the geodynamic regime may be captured in the detrital record. This study attempts to reconstruct the sediment routing system of the Canning Basin (Western Australia) during the Early Cretaceous to decipher its depositional response to Mesozoic‐Cenozoic supercontinent dispersal. Specifically, we reconstruct source‐to‐sink relationships for the Broome Sandstone (Dampier Peninsula) and proximal modern sediments through multi‐proxy analysis of detrital zircon (U–Pb, Lu–Hf and trace elements) and detrital rutile (U–Pb and trace elements). Multi‐proxy comparison of detrital signatures and potential sources reveals that the majority of the detrital zircon and rutile grains are ultimately sourced from crystalline basement in central Australia (Musgrave Province and Arunta region) and that proximal sediment supply (i.e., Kimberley region) is negligible. However, a significant proportion of detritus might be derived from intermediate sedimentary sources in central Australia (e.g., Amadeus Basin) rather than directly from erosion of crystalline basement. Broome Sandstone data are consistent with a large‐scale drainage system with headwaters in central Australia. Contextualization with other broadly coeval drainage systems suggests that central Australia acted as a major drainage divide during the Early Cretaceous. Importantly, reorganization after supercontinent dispersal is characterized by the continuation of a sediment pathway remnant of an earlier transcontinental routing system originating in Antarctica that provided a template for Early Cretaceous drainage. Review of older Canning Basin strata implies a prolonged denudation history of central Australian lithologies. These observations are consistent with the long‐lived intracontinental tectonic activity of central Australia governing punctuated sediment generation and dispersion more broadly across Australia and emphasize the impact of deep Earth processes on sediment routing systems. [ABSTRACT FROM AUTHOR]

The number of subduction zones that facilitated the northward translation of the Anatolide‐Tauride continental terrane derived from Gondwana to the southern margin of Eurasia at the longitude of western Turkey is debated. We hypothesized that if two north dipping subduction zones facilitated incipient collision in western Turkey, a late Cretaceous arc would have formed within the Neotethys and along the southern margin of Eurasia. To determine if an island arc formed within the Neotethys we investigated the sedimentary record of the Central Sakarya basin, which was deposited along the southern margin of Eurasia from 85 to 45 million years ago. Detrital zircon deposited within the lower levels of the Central Sakarya basin (the Değirmenözü Formation) are associated with south to north‐directed paleocurrents and exhibit a unimodal late Cretaceous age peak sourced from isotopically juvenile mantle melts. Zircon maximum depositional ages from the Değirmenözü Formation cluster between 95 and 90 Ma and are 5–10 Myr older than biostratigraphic depositional ages. Between 95 and 80 Ma, a 12‐unit shift from mantle to crustal derived εHf values occurs in the overlying Yenipazar Formation. We explain the absence of Paleozoic, Eurasian‐sourced detrital zircon, the rapid shift from mantle to crustal derived εHf values, and lag time in terms of passive margin subduction within an isolated intra‐oceanic subduction zone, whose island arc was reworked from south to north into the Central Sakarya basin during incipient collision. Thus, widely outcropping late Cretaceous plutonic rocks within Eurasia must have belonged to an additional convergent margin. Key Points: We leveraged the isotopic signature of subducted passive margin to test incipient collision models in northwest TurkeyPassive margin subduction resulted in the development of an isolated intra‐oceanic basinTwo north dipping subduction zones facilitated incipient collision in the region [ABSTRACT FROM AUTHOR]

There existed an early Mesozoic tectonic regime transformation in the South China Block (SCB). Although it was believed that this transformation was closely related to the subduction of Paleo-Pacific Plate, the process and initial time of the subduction of the Paleo-Pacific Plate have been controversial for a long time. Based on the published Upper Triassic and Middle Jurassic succession detrital zircons geochronology from the southeastern margin of the SCB, the newly obtained Late Triassic to Middle Jurassic detrital zircons Hf isotope data, and the available magmatic age data and Hf isotope data, this study discussed the subduction of the Paleo-Pacific Plate. The Hf isotope composition of zircon grains selected from the Early Mesozoic strata of the SCB, spanning from the Late Triassic to the Middle Jurassic, exhibits a consistent temporal trend with that of the Triassic–Middle Jurassic magmatic rocks. Both display a transition from negative to positive ε Hf (t) values, indicative of a gradually increasing contribution of mantle-derived materials from the Triassic to the Middle Jurassic. Zircon trace elements indicate that a magmatic arc appeared outside the southeastern margin of the SCB at 200–190 Ma and continued to develop into the Middle Jurassic, which may have been generated by the Paleo-Pacific Plate subduction. This study proposed that the Paleo-Pacific Plate subduction was confined to the southeastern coast of the SCB in the Late Triassic, and the subduction of the flat slab was halted by obstruction at the end of the Late Triassic. In the Early Jurassic, the Paleo-Pacific Plate began to subduction again, and arc-related magmatic rocks were formed along the coast of SCB. At the same time, due to the remote effect of the subduction of the Paleo-Pacific Plate, the weak tectonic belt existing in the Nanling area was reactivated, resulting in the Nanling area in the intraplate extensional setting. Subsequently, the continuous subduction of the Paleo-Pacific Plate led to the thickening of the crust along the SCB in the Middle Jurassic, and the Nanling area was still under in the extensional setting. [ABSTRACT FROM AUTHOR]

Abstract The number of subduction zones that facilitated the northward translation of the Anatolide‐Tauride continental terrane derived from Gondwana to the southern margin of Eurasia at the longitude of western Turkey is debated. We hypothesized that if two north dipping subduction zones facilitated incipient collision in western Turkey, a late Cretaceous arc would have formed within the Neotethys and along the southern margin of Eurasia. To determine if an island arc formed within the Neotethys we investigated the sedimentary record of the Central Sakarya basin, which was deposited along the southern margin of Eurasia from 85 to 45 million years ago. Detrital zircon deposited within the lower levels of the Central Sakarya basin (the Değirmenözü Formation) are associated with south to north‐directed paleocurrents and exhibit a unimodal late Cretaceous age peak sourced from isotopically juvenile mantle melts. Zircon maximum depositional ages from the Değirmenözü Formation cluster between 95 and 90 Ma and are 5–10 Myr older than biostratigraphic depositional ages. Between 95 and 80 Ma, a 12‐unit shift from mantle to crustal derived εHf values occurs in the overlying Yenipazar Formation. We explain the absence of Paleozoic, Eurasian‐sourced detrital zircon, the rapid shift from mantle to crustal derived εHf values, and lag time in terms of passive margin subduction within an isolated intra‐oceanic subduction zone, whose island arc was reworked from south to north into the Central Sakarya basin during incipient collision. Thus, widely outcropping late Cretaceous plutonic rocks within Eurasia must have belonged to an additional convergent margin.

Open-system magmatic processes are expected to impart various sorts of isotopic heterogeneity upon the igneous rocks they produce. The range of processes under the “open-system” umbrella (e.g., simple two-component mixing, magma mingling, assimilation with fractional crystallization) cannot usually be uniquely identified using data from a single isotope system. The use of bulk-rock, mineral separate and in situ techniques and multiple isotope systems allows the characterization of isotopic variability at different sampling scales, illuminating details of the petrogenesis of a magmatic system. This approach has been applied to granitoids of the Wallundry Suite in the Lachlan Fold Belt, Australia. The Wallundry Suite exhibits variations in mineral assemblage, mineral composition and trends in bulk-rock major and trace element compositions consistent with the involvement of liquid-crystal sorting processes such as fractional crystallization. In situ paired O-Hf isotope data from zircon in six samples show an array indicating the isotopic evolution of the melt phase. Similarly, bulk-rock Sr-Nd-Hf isotope arrays support open-system magma evolution. These data combined with the petrographic observations and major and trace element geochemical variations suggest some form of assimilation-fractional crystallization process in the petrogenesis of the Wallundry Suite. Added complexity is revealed by two observations: 1) the isotopic variations are only weakly coupled to the lithology and major element compositions of the samples; and 2) there are distinguishable differences between the Hf isotope compositions of bulk-rock samples and those of the magmatic zircons they host. To varying degrees the rocks consistently show negative ΔεHfbulk-zrc values (i.e., the bulk-rock compositions have less radiogenic Hf isotope values than their coexisting zircons). The preservation of distinctly low Nd and Hf isotope ratios in an Fe-Ti oxide mineral separate suggests that the bulk-rock vs. zircon discrepancy is caused by the presence of unmelted components derived from a contaminant of continental origin (i.e., a rock with low Sm/Nd and Lu/Hf and thus unradiogenic Nd and Hf). Evidently, a complex interplay of assimilation, crystallization and melt segregation is required to account for the data. This investigation demonstrates that such complexity can, nevertheless, be disentangled through comparison of complementary isotope data at multiple sampling scales.

In the northwestern Korean Peninsula, Cretaceous volcanic rocks are composed of andesite, andesite-dacite and rhyolite intercalated with terrigenous clastic rocks. Zircon grains selected from these rocks are authigenic zircons with obvious crystal edges and oscillatory zoning, their Th/U ratios being generally larger than 0.4 (0.16–2.22), indicating magmatic origin. Most rocks were formed at Early Cretaceous Albian (113–103 Ma) and partially, at late Aptian, Prior to this time magmatism took place at 125 Ma and 135 Ma. All the negative εHf(t) values mean that these magma sources were contaminated by crust materials or derived from enriched mantle. Volcanic rocks belong to calc-alkaline series and partially to peraluminous series with relatively high alkali content. Chondrite-normalized REE patterns display right-lean LREE rich type and Primitive-mantle-normalized REE patterns do obvious negative anomalies in LILE (Ba, Sr), HFSE (Nb, Ta, P, Zr, Ti), but obvious positive anomalies in LIL (Rb, Pb) and HFS (Th, U, Nd). These volcanic rocks were formed in continental arc setting and their geochemical properties being similar to those of arc ADR (normal Island-Arc Andesite-Dacite-Rhyolite) suite rather than those of adakite. In the Late Early Cretaceous, west area of northeastern Asia including western Liaoning, China was in extensional setting but east area of northeastern Asia including northwestern Korean Peninsula, Jihei, eastern China and Far East areas, Russia were in continental arc setting.

The Wenjiaping granite, as one of the few Late Jurassic granites in the Songpan–Garzê fold belt (SGFB), can provide an important clue for comprehensively recognizing the tectonic evolution and mineralization of this belt. In this contribution, we present new age and geochemical data for this pluton to better constrain its petrogenesis and discuss the tectonic and metallogenic implications. LA‐ICP‐MS zircon U–Pb dating shows that the Wenjiaping pluton was emplaced at ~159 Ma. The granite contains minor amphibole, and exhibits slightly peraluminous characteristics (A/CNK = 1.03–1.10) and lower initial Sr–Pb isotope ratios than those of the Liwu Group, which excludes the possibility that the Wenjiaping granite was derived from partial melting of the metasedimentary rock‐dominated Liwu Group as previously suggested. Significantly, high Sr/Y (40.93–54.30), LaN/YbN (39.64–56.64), and K2O/NaO (0.77–1.11) ratios, low MgO (0.47%–0.86%) and Cr (25.1–41.3 ppm) contents, and relatively enriched Sr–Nd–Pb–Hf isotope compositions of the Wenjiaping granite are comparable to those of the Late Triassic adakitic rocks in the SGFB, indicating that they probably share a similar source. Combined with previous researches, we propose that large‐scale detachment of the Jianglang dome caused by post‐collisional lithospheric extension in the SGFB‐induced decompressional partial melting of the Precambrian basement rocks can account for the generation of the Late Jurassic Wenjiaping pluton. In addition, our results also suggest that the Wenjiaping pluton probably cannot supply abundant metal elements for the Liwu‐type Cu‐polymetallic deposits in the Jianglang dome, SGFB. [ABSTRACT FROM AUTHOR]

Junggar Basin is an important exploration zone for sandstone‐hosted uranium deposits in north‐west China. However, neither the provenance of the host sandstone nor the uranium supply capacity of the potential source rocks have been well evaluated. To determine the provenances of the Mesozoic to Cenozoic sandstone grains and to evaluate relationships between the uranium source and the detritus provenances, a field investigation was performed at the Honggou section in the southern Junggar Basin. U–Pb geochronology and Hf isotopes were obtained from populations of detrital zircons from Jurassic through Palaeogene sandstones. The detrital zircon U–Pb ages display three main groups: 145–190 Ma, 250–360 Ma, and 360–460 Ma. The detrital zircon age distributions and the Hf isotopic characteristics of the sandstones correspond to different igneous rock units within the North and Central Tianshan Mountains. Therefore, the changes in the relative proportions of the zircon age populations indicate that there were major shifts of the provenance areas for the sandstones throughout the Early Jurassic to Palaeogene interval. The majority (92%) of Hf isotope εHf(t) values are positive and in the range of +0.7 to +15.5, which indicates that the majority of the zircons had crystallized in igneous rocks that were mainly derived from juvenile crust or depleted mantle. The majority (93%) of the two‐stage model ages (TDM2) are less than 1.8 Ga, thereby indicating the source of the majority of the igneous rocks was from the melting of ancient Meso‐Proterozoic juvenile crust. Carboniferous–Permian intermediate‐felsic igneous rocks in the Tianshan Mountains may be the primary source of released mobilized uranium and uranium‐enriched siliciclastics into the southern Junggar Basin. This study will assist in future uranium prospecting in this region. [ABSTRACT FROM AUTHOR]

The relationship between plutonic and volcanic components of magmatic plumbing systems continues to be a question of intense debate. The Oki-Dōzen Islands, Sea of Japan, preserve outcrops of temporally associated plutonic, hypabyssal, and volcanic rocks. Post-intrusion uplift juxtaposed Miocene syenites in inferred faulted contact with volcanic trachytes that are cut by rhyolite hypabyssal dikes. This provides a window deep into the timing and origins of magma storage architecture and dynamics. Zircon is ubiquitous in all samples; our aim is to determine what its age and composition can reveal about the plutonic-volcanic connection. Here we show magma source characteristics are recorded in zircon Hf isotopes; source composition and assimilation of heterogeneous hydrothermally altered crust in zircon O isotopes; and extensive fractional crystallization in zircon trace elements. Combined with new U-Th-Pb SHRIMP zircon ages, 6.4–5.7 Ma, compositional data show pluton formation was by protracted amalgamation of discrete magma pulses. The rhyolite dike preserves an evolved fraction segregated from these discrete magmas. Synchronous with plutonism was a volcanic eruption of trachyte magma derived from the same source, which may have stalled at a relatively shallow depth prior to eruption. Stalling occurred at least above the amphibole stability zone because amphibole-compatible Sc and Ti were not depleted in the trachyte melt resulting in elevated values of these in volcanic compared to plutonic zircon. Identifying smaller episodic magma pulses in a larger magmatic complex places constraints on potential magma fluxes and eruptible volumes. High-flux, large volume, plume-related ocean island magmatic systems may have extensive vertically distributed multi-stage magmatic reservoirs and subduction-related systems transcrustal magma reservoirs. By contrast, Oki-Dōzen was a low-flux system with incremental pluton growth and small- to moderate-scale eruptions. [ABSTRACT FROM AUTHOR]

We utilized the Neoma™, a recently released MC-ICP-MS platform offered by ThermoFisher Scientific, to assess the behavior of the Lu-Yb-Hf system during laser ablation analyses of various zircon standards as well as solution-based analyses of the JMC-475 Hf standard doped with varying quantities of Yb and Lu. The primary goal of this work was to characterize the behavior of the Yb interference correction on the Neoma™ platform since this is one of the biggest issues in the Hf isotope analysis community and because the Neoma™ platform will supplant the Neptune™ series instrument. During laser ablation analysis, we found that the overall data quality scales proportionally with the total Hf signal intensity, with higher signal analyses producing extremely accurate (within 1 εHf unit) and precise (sub εHf unit within-run standard errors) data. At low Yb signals (<0.1 V 173Yb), we were not able to produce an accurate internal Yb mass bias factor. However, utilizing an empirical approach allows for the application of session-specific relationships between the Yb and Hf mass bias factors, determined by analysis of standards of varying Yb content, to produce accurate εHf values from zircons with higher Yb/Hf ratios even where the total Hf signal intensity is relatively low. Similar behavior was observed in the solution analyses. Lastly, while the behavior of the Yb interference correction on the Neoma™ platform appears comparable to the Neptune™ series MC-ICP-MS, further work will help refine the understanding of the controls on mass bias behavior, oxide formation, session-to-session stability, etc. [ABSTRACT FROM AUTHOR]

The Jinba deposit is an orogenic gold deposit located in the Markakuli shear zone, in the southern part of the Altay orogenic belt, northwestern China. Several granite and diorite dykes are present in the area of the mine, with ore bodies occurring in the diorite dykes. However, the diagenetic age, genesis, and evolution of these magmas, and the tectonic setting of the dyke emplacement process, remain unclear. The present study is based on a detailed geological survey, zircon U–Pb dating, Lu–Hf isotopes, and geochemical analysis of the granitic and diorite dykes. The crystallization ages of the granitic and diorite dykes are 384.5 ± 1.2 Ma and 393.9 ± 3.5 Ma, respectively, which indicates formation in the Early to Middle Devonian. Zircon εHf(t) values of the granitic and diorite dykes are 1.43 to 5.2 and −4.47 to −1.18, respectively, with a corresponding two-stage model of depleted mantle (TDM2) ages of 1046 to 1285 Ma and 1242 to 2623 Ma, respectively. This indicates that the granitic and diorite dykes were formed by the mixing of mantle magma and crustal materials to varying degrees, and diorite dykes are more obviously contaminated by the lower crust. Geochemical analysis shows that the granite dykes have a high SiO2 (72.51%–74.87%) and moderate Al2O3 (12.88%–14.04%) content, a total alkali of (K2O + Na2O = 5.51%–6.44%), and aluminous (A/CNK = 1.0–1.02). Granite dykes are enriched in LREE and Th, U, and Pb, and depleted in P, Sr, and Nb elements, with clear Eu negative anomalies (δEu = 0.62~0.66). The SiO2 content of diorite dykes is 51.48%–53.71%, Al2O3 contents are high (14.70%–15.99%), K2O is 1.94%–2.54%, Na2O is 2.97%–3.96%, MgO contents are high (5.15%–6.46%), and TFe2O3 is (13.42%–15.13%), enriched Sr, U, Pb, deficient Th elements, rare earth fractionation is not obvious, and Eu anomaly is not obvious (δEu = 0.93~1.1). We conclude that the Early to Middle Devonian magmatism in the southern margin of Altay (which corresponds to the Jinba gold deposit) may have formed in an island arc-related subduction environment. [ABSTRACT FROM AUTHOR]

[Display omitted] • We report the first reliable age data for Karoo rift magmatism in Mozambique. • Our U/Pb ages prove Karoo rift magmatism started during ca. 185 – 190 Ma. • Eruption of 182–178 Ma rift magmas released abundant volatiles into atmosphere. New U-Pb ages for zircons constrain the duration of silicic magmatism and timing of coeval mafic magmatism across the main rift zone of the Karoo large igneous province in Mozambique. Our 190 ± 2 Ma, 188.4 ± 0.9 Ma, 181.7 ± 1.0 Ma, 180 ± 3 Ma, 178 ± 2 Ma and 172 ± 2 Ma ages support periodicity of Karoo magmatism previously inferred from 40Ar/39Ar age data. The ∼ 190–188 Ma ages confirm early onset of magmatism and the ∼ 182–178 Ma ages correlate the bimodal volcanic successions of the Lower Zambezi and the Movene Formation with widespread silicic magmatism across the rift zone. The ∼ 172 Ma age corresponds to waning magmatic activity. The age range and Hf isotopic compositions of zircons indicate up to ∼9 Ma lifespan for the Jurassic silicic magma chambers and suggest that the ∼2700–400 Ma xenocrysts represent crustal sources of the host rocks. The available chronological data indicate that the ∼183 Ma main phase magmatism was largely confined within the main Karoo and Kalahari basins and that the preceding and subsequent phases were mainly associated with the Karoo rift zone. Judging from geochemical literature, different kinds of magmas were erupted during the successive magmatic phases. We calculate from published geochemical data that the mafic main phase magmas were relatively poor in CO 2 and SO 2 and the lava stacking patterns point to low eruption rates, which suggests that degassing of sedimentary wall-rocks of intrusions probably triggered the coeval Pliensbachian-Toarcian extinction. In contrast, the mafic late phase magmas were rich in CO 2 and SO 2 and at least some of the lavas indicate high eruption rates. We propose that efficient degassing from widespread mafic magmatism and explosive eruption of over 30,000 km3 of silicic magmas in the Karoo rift zone linked the ∼182–178 Ma late phase magmatism with contemporaneous global biosphere crises. [ABSTRACT FROM AUTHOR]

• Three units make up the Piedra Alta Terrane: arc-related igneous basement, intra-arc basins and late intrusive granites. • U-Pb ages in zircon restrict the formation of the three units that make up the PAT to the Rhyacian. • Largely predominant positive εHf (T) values attest to the juvenile nature of PAT's crustal segment. • The development of the PAT is related to the evolution of an intraoceanic magmatic arc. This work delves into the intricate Paleoproterozoic geological setting of Uruguay, focusing on the Rio de la Plata Craton (RPC) and its prominent constituent Piedra Alta Terrane (PAT). The PAT constitutes the core of the RPC, characterized as a complex geological entity that encompasses a granite-migmatite basement, metamorphic belts, granite intrusions, and Proterozoic magmatism. To the west, it interfaces with the Transbrasiliano-Kandi tectonic corridor, bounded by the Late-Neoproterozoic Pampia Terrane. The PAT s southeastern boundary extends to Sierra de Tandil and perhaps to Sierra de La Ventana, demarcating its limits with Phanerozoic rocks of the North Patagonian Massif. The Sarandí del Yí shear zone defines the eastern limit of the PAT. Despite varied interpretations of the Piedra Alta Terrane's significance, it is important to note that consensus prevails regarding its four major associations: a granite-gneiss-migmatitic basement complex, three volcanosedimentary belts of low to medium metamorphic grade, diverse late igneous intrusions, and extensional Statherian magmatism (1.79 Ga), represented by tholeiitic gabbroic dikes. In this study, a novel tectonic model for the PAT evolution emerges, supported by an extensive zircon dataset comprising new U-Pb ages, Hf isotopes, and trace element geochemistry. The analytical core involves U-Pb analyses on zircon for dating igneous rocks and establishing the provenance and maximum age of deposition of metavolcanosedimentary sequences. Lu-Hf isotopic analyses on the same zircon crystals provide petrogenetic insights, revealing episodes of crustal growth and minor recycling. Trace element geochemistry and zircon εHf(t) data further accentuate these findings, hinting at mantle source enrichment due to subduction within an intraoceanic magmatic-arc arc setting. [ABSTRACT FROM AUTHOR]

The Cambrian–Ordovician Tiñú Formation of southern Mexico is key for identifying sediment sources along the northern margin of Gondwana, enhancing our understanding of early Paleozoic paleogeography and linking it with age-equivalent units in terranes with Gondwanan affinity. This study integrates detrital zircon U–Pb ages, Hf isotope signatures, and heavy mineral chemical data. U–Pb detrital zircon ages indicate sources from Stenian–Tonian (900–1200 Ma) to Calymmian (1400–1600 Ma) ages. The Stenian to Tonian zircon population, with peak ages around 1.0 Ga and model ages ranging from 1.68 to 1.90 Ga, suggests a provenance from the metaigneous rocks of the Oaxacan and Guichicovi complexes. The presence of the Calymmian zircon population, tourmaline crystals, and rutile grains displaying lower crystallization temperatures compared to the high-temperature rutile from the Oaxacan Complex suggests additional sources. Hf isotope signatures from Calymmian-aged zircon grains, with model ages between 1.95 and 2.30 Ga, match well with the Paleo-Mesoproterozoic Catarina Unit in the southern Chiapas Massif Complex. Further potential sources may include the basement of the Putumayo Province in Colombia and igneous rocks from the western Guiana Shield and the Rio Negro-Juruena Province. The Tiñú Formation provenance is comparable to coeval metasedimentary units across the northwestern margin of Gondwana found in Belize, the southern Chiapas Massif Complex, and Guatemala. The Tiñú Formation was likely deposited adjacent to the rifted margin of the Rheic Ocean. The results also emphasize combining U–Pb–Hf isotope analysis and trace elements in detrital zircon and rutile as effective provenance tracers. [ABSTRACT FROM AUTHOR]

The general configuration of the main continental blocks in the Gondwana supercontinent and the Ediacaran–early Paleozoic tectonic evolution of its northern margin are widely accepted. However, reconstruction of the original positions and the question of potential separation of the Gondwana-derived crustal segments that are now included in the Variscan and Alpine orogenic belts remain controversial. The Western Carpathians, part of the Alpine–Carpathian belt, represents an important crustal segment broken-off from northern Gondwana and later incorporated into both the Variscan and Alpine collisional orogens. The earliest tectonic evolution and paleogeography of the pre-Variscan basement of the Western Carpathians remains poorly known, due to insufficient age data and intense polyphase tectonometamorphic overprints, both Variscan and Alpine. This paper provides new results of U–Pb dating and Hf isotopic analysis of detrital zircons as well as a whole-rock geochemical study from metavolcanic-sedimentary basement units of the Western Carpathians. The obtained age spectra suggest that the sedimentary succession was supplied dominantly by Ediacaran (c. 600 Ma) zircons, with a relatively minor role for Stenian–Tonian (c. 1.2–0.9 Ga) and Paleoproterozoic cratonic (c. 2.2–1.8 Ga) zircons. The mixed Hf isotopic signature (ε Hf(t) values ranging from −20 to +12) of the Ediacaran zircons indicates substantial mixing of mantle-derived magmas with mature crustal material, typical of continental magmatic arcs. In contrast, the mostly negative ε Hf(t) values (−15 to +4) of the cratonic zircons suggest recycling of an older continental crust. The presumably youngest part of the sequence is also characterised by high proportion of early Paleozoic zircons with generally negative ε Hf(t) values (−10 to −2). The zircon U–Pb age spectra, Hf isotopic patterns and whole-rock geochemical signatures of the studied Western Carpathians sequences are interpreted as reflecting deposition at a progressively developing Cambrian–Silurian passive margin setting. The West Carpathian data have been correlated with a comprehensive detrital zircon U–Pb age and Hf isotope data set compiled from possible source areas and other Gondwana-derived units to test the possibility of their primary linkages. These correlations indicate strong similarity in both zircon U–Pb age spectra and Hf isotopic compositions to other parts of the Ediacaran (Cadomian) continental magmatic arc. Older, cratonic sources are linked to the Saharan or East African parts of northern Gondwana, whereas the early Paleozoic detritus must represent a local volcanic source. Taken together, our new data from the Western Carpathians provide constraints for a new paleogeographic model of the northern African part of the Gondwana passive margin. • Cambrian–Silurian formation of Western Carpathians in the Gondwana passive margin. • Detrital zircon ages and Hf isotopic data record temporal variations in sources. • Affinity of the Western Carpathians to the central Saharan segment of Gondwana. • Provenance shift from the Saharan province to the East African province. • New paleogeographic reconstruction of the African part of Gondwana margin. [ABSTRACT FROM AUTHOR]

Carbonate rocks, as one of the magmatic rocks with little but significant geological significance in nature, are generally considered to be mantle-derived causes, and shell-derived causes are rarely reported. The exposed dioprosene carbonate in the Annamba area of the southeast edge of the Tarim Basin is irregular and vein-like intrusive into the surrounding rock, and the surrounding rock trapper body can be seen inside the rock, and has a dense block structure and fine grain structure, indicating that it is an igneous carbonate rather than a sedimentary carbonate rock. The geochemical characteristics of rocks show that the carbonate-rich CaO (content (mass fraction, the same below) is 24.63%-33.20%), SiO (33.11%-40.07%), poor MgO (2.25%-3.21%), FeO (1.38%-2.03%), the total rare earth element content ((45.44-91.47) ×10) and the total light rare earth element content ((42.83-86.06)×10) are significantly lower, and the relative enrichment Rb is significantly lower Large ionic lithophilic elements such as Ba, Th, Sr, etc., with losses of Nb, Ta, Zr, Hf and other high field strength elements, are obviously different from mantle-derived carbonate rocks, and similar to shell-derived carbonate rocks. Zircon in the dioprose carbonate develops oscillating ring band structure, with obvious Ce positive anomaly, weak Eu negative anomaly and low Th/U value (average value 0.24), indicating that it is metamorphic deep molten zircon. The study of the U-Pb-Lu-Hf isotope of zircon zircon showed that the age of the zircon Hf isotope pattern had an age peak of about 2.59 Ga, and the age of lithogenesis was (1 910±13) Ma, which was consistent with the formation era of the Milan rock group and the era of hemp grain phase metamorphism, respectively. Combined with the comprehensive analysis of the previous research results, it is believed that the dipyrene carbonate in the Annamba area may be the product of the deep melting action of the Diopline Dali rock of the Milan rock group under the condition of hemp granular phase metamorphism, which is the response of the Columbia supercontinent aggregation event in the southeast edge of the Tarim Basin [ABSTRACT FROM AUTHOR]

Zircon xenocrysts from two diamond-barren kimberlite pipes (Leningrad and Ruslovaya) in the West Ukukit kimberlite field opened a 'window' to the buried crustal basement in the northern Siberian craton. Zircon U-Pb ages reveal a close affinity of the basement of the Khapchan belt to the Archaean Anabar province and a significant tectonomagmatic reworking in the Paleoproterozoic (~2.1–1.8 Ga) due to collision between the Anabar province and the Olenek province. The West Ukukit kimberlite field experienced multiple tectonomagmatic reactivation from ~670 to 144 Ma, which can be attributed to interaction of the deep crust with mantle-derived melts. Hf isotope composition of zircon xenocrysts reveals significant addition of juvenile material into the crust during the Paleoproterozoic orogeny in diamond-barren kimberlite fields, which is different from the reworking crust in the southern Yakutia diamondiferous kimberlite fields. Eruption of the Leningrad and Ruslovaya pipes were constrained as the Late Jurassic, much later than the well-known Late Silurian-Earth Devonian kimberlites in the West Ukukit kimberlite field. A NE-trending, >2000 km long kimberlite corridor is proposed to account for a prolonged lithospheric channel for episodic eruption of kimberlites in the Siberian craton. The diamond storage in the lithosphere beneath the West Ukukit kimberlite field may have been largely reduced by the Paleoproterozoic orogeny and Phanerozoic reworking. [ABSTRACT FROM AUTHOR]

In order to determine the provenance and variation characteristics of sandstone-type uranium deposits located in the southwest Ordos Basin, U−Pb geochronology and Hf isotope analyses were conducted on detrital zircons from the Late Mesozoic strata of the SD01 well in the Zhenyuan area. The detrital zircon U−Pb ages of four samples exhibited four main peaks at 250–330, 420–500, 1 720–2 000, and 2 340–2 580 Ma, with a small number of zircons dated at 770–1 100 Ma. The detrital zircon age spectrum and further restriction provided by the in-situ Hf isotopic data suggest that the provenance of each stratum was mainly derived from the crystalline basement rock series (Khondalites, intermediate-acidic intrusive rocks, and metamorphic rocks) of the Alxa Block to the northwest and the Yinshan Block to the north, with minor amounts of Caledonian magmatic rocks and Jingning Period rocks from the western part of the northern Qilian orogenic belt to the west and the northern Qinling orogenic belt to the south. The provenance of the sandbody has not changed significantly and is of the Middle Jurassic-Early Cretaceous. The clear variations in the zircon ages of the samples from the Zhiluo and Anding formations were likely influenced by climate change during the Middle-Late Jurassic. The Triassic zircon age (<250 Ma) first appeared in Early Cretaceous strata, suggesting that tectonic activity was relatively strong in the northern Qinling orogenic belt during the Late Jurassic and produced extensive outcrops of Indo-Chinese granite, which were a source of basin sediments. [ABSTRACT FROM AUTHOR]

Extensive magmatism in NE China, eastern Central Asian Orogenic Belt, has produced multi-stage granitic plutons and accompanying W mineralization. The Narenwula complex in the southwestern Great Xing'an Range provides important insights into the petrogenesis, geodynamic processes and relationship with W mineralization. The complex comprises granodiorites, monzogranites and granite porphyry. Mafic microgranular enclaves are common in the granodiorites, and have similar zircon U–Pb ages as their host rocks (258.5–253.9 Ma), whereas the W-bearing granitoids yield emplacement ages of 149.8–148.1 Ma. Permian granodiorites are I-type granites that are enriched in large-ion lithophile elements and light rare earth elements, and depleted in high field strength elements and heavy rare earth elements. Both the mafic microgranular enclaves and granodiorites have nearly identical zircon Hf isotopic compositions. The results suggest that the mafic microgranular enclaves and granodiorites formed by the mixing of mafic and felsic magmas. W-bearing granitoids are highly fractionated A-type granites, enriched in Rb, Th, U and Pb, and depleted in Ba, Sr, P, Ti and Eu. They have higher W concentrations and Rb/Sr ratios, and lower Nb/Ta, Zr/Hf and K/Rb ratios than the W-barren granodiorites. These data and negative ϵHf(t) values (–6.0 to –2.1) suggest that they were derived from the partial melting of ancient lower crust and subsequently underwent extreme fractional crystallization. Based on the regional geology, we propose that the granodiorites were generated in a volcanic arc setting related to the subduction of the Palaeo-Asian Ocean, whereas the W-bearing granitoids and associated deposits formed in a post-orogenic extensional setting controlled by the Mongol–Okhotsk Ocean and Palaeo-Pacific Ocean tectonic regimes. [ABSTRACT FROM AUTHOR]

Continental flood basalt lavas often contain deeply-sourced, thermo-chemically anomalous material that can provide a potential probe of inaccessible reservoirs. However, continental flood basalts interact with geochemically diverse domains within the continental lithosphere, which may complicate interpretations of deep mantle signatures. We examine the role of continental lithospheric mantle in continental flood basalts erupted as part of the 1.1 Ga Keweenawan large igneous province, centered on the Lake Superior region of North America. We show that flood basalts at Mamainse Point exhibit a range of εHf 1100 from −14.1 to +6, plotting along the global εHf—εNd mantle array. Lithospheric mantle melts represented by alkaline rocks from the Coldwell and Seabrook Lake Complexes yield positive εNd 1100 (+0.7 to +4.3) and εHf 1100 from −6.9 to +2.4, placing them below the mantle array. Mamainse Point lavas are interpreted to be variably crustally contaminated melts of the Keweenawan plume and ambient upper mantle; there is no clear evidence for contributions from an enriched lithospheric mantle. [ABSTRACT FROM AUTHOR]

Mesozoic granitic magmatism in Northeastern Jiangxi, China is of tectonic significance for the evolution of the South China Block. Whole-rock geochemical and zircon U–Pb geochronological and Lu–Hf isotopic data for Mesozoic Zhuxi granites in the Jingdezhen area of Northeastern Jiangxi were presented. The Zhuxi granites are composed of granodiorite, biotite granite, and two-mica granite. Zircon LA–ICP–MS U–Pb isotopic analyses indicated emplacement at 159–147 Ma. The granites are characterized by a strongly peraluminous nature with high A/CNK values (>1.1), high SiO2 (66.09–74.46 wt.%) and K2O (3.50–5.52 wt.%) contents, depletion in Ba, Nb, Ce, Sr, and Ti, moderately negative Eu anomalies (Eu/Eu* = 0.40–0.63), enrichment in LREE, and depletion in HREE ((La/Yb)N > 7.43). The A/CNK > 1.1, widespread aluminum-rich minerals (e.g., muscovite and tourmaline), indicating they are S–type granites and belong to muscovite–bearing peraluminous granites (MPG). The Zhuxi granites exhibited negative εHf(t) values (−9.9 to −3.7) and the TDM2 model ages of 1840–1442 Ma indicated derivation from ancient crustal sources. The magma is possibly caused by the subsequent process of intracontinental subduction. It is inferred that the Mesozoic magmatism in Northeastern Jiangxi was associated with oceanic–continental convergence of the Paleo–Pacific and Eurasian plates as well as the intracontinental subduction of the Yangtze and Cathaysia blocks. The Zhuxi granites highlight the primary role of oceanic–continental convergence and intracontinental subduction in early Yanshanian granitoid magmatism in South China. [ABSTRACT FROM AUTHOR]

To investigate the evolution of the continental crust in the northern Tibetan Plateau, detrital zircon U–Pb geochronology and Hf isotopes analysis were performed on two fluvial sand samples from North Qaidam (the Yuka and Shaliu rivers). A total of 443 detrital zircon U–Pb ages and 244 Hf isotopic results were obtained and reveal that the South Qilian, North Qaidam, and East Kunlun terranes show affinity to the western Yangtze Block. Age distributions of detrital zircons from the Yuka River cluster mainly in two age intervals of 1,000–700 and 480–400 Ma. The corresponding εHf(t) values are mostly negative, with depleted two-stage Hf model ages (TDM2) of 2.1–1.6 Ga. In contrast, age data for the Shaliu River fall in the ranges of 1,000–700, 460–380, and 260–200 Ma, with TDM2 ages of 2.0–1.6 and 1.6–1.2 Ga. In addition, zircons with Neoproterozoic ages from both river samples possess common Paleoproterozoic TDM2 ages (2.0–1.6 Ga, with a peak of 1.8–1.7 Ga), indicating that the South Qilian, North Qaidam and East Kunlun terranes were probably part of the same Neoproterozoic continent. The East Kunlun and North Qaidam terranes are inferred to include Mesoproterozoic continental crust (1.6–1.0 Ga), suggesting differences in crustal evolution between the East Kunlun–North Qaidam and Qilian terranes. Phanerozoic magmatism in these three terranes was sourced mainly from the recycling of ancient continental crust with minor contributions from the juvenile crust.

The Bushveld Large Igneous Province (BLIP) was emplaced in three stages (I, II, and III) over some 19 m.y. (c. 2061–2042 Ma). The Bushveld Complex is the main constituent of the BLIP and hosts the world's largest ferroan granite (Lebowa Granite Suite) and several granophyres (Rashoop Granophyre Suite) directly overlying the world's largest layered mafic intrusion (Rustenburg Layered Suite). New zircon U–Pb ages (measured by ID-TIMS) for the Lebowa Granite Suite and a textural variant termed Zwartbank Pseudogranophyre yield identical crystallization ages ranging from 2054.3 ± 0.7 to 2056.5 ± 0.9 Ma. Zircons from the uppermost Rustenburg Layered Suite (Upper Zone) yield an indistinguishable age of 2055.1 ± 2.1 Ma. These ages demonstrate that the Bushveld granitoids, together with the Rustenburg Layered Suite belong to BLIP Stage II. Additionally, most Lebowa Granite Suite samples contain zircons with primary growth zonation that yield ages up to 2064 Ma. We interpret these as antecrysts originating from BLIP Stage I. Isotope compositions of Hf in zircon (measured by LA-MC-ICPMS in situ and on solutions) are essentially uniform at εHf (2055 Ma) = − 7.2 to − 5.6, and indistinguishable from published data for the uppermost Rustenburg Layered Suite. We interpret the indistinguishable ages and similar isotopic compositions of the Lebowa Granite Suite and the Rustenburg Layered Suite as support for direct petrogenetic linkages. The Hf isotopic composition of the Rustenburg Layered Suite has been attributed to enriched mantle sources, but we show that crustal assimilation by mantle-derived magmas can also explain these compositions for both the Lebowa Granite Suite and Rustenburg Layered Suite. We propose that the Lebowa Granite Suite formed during Stage II, but zircon antecrysts indicate that some remobilization of granitic material formed during Stage I was also involved. [ABSTRACT FROM AUTHOR]

The mechanism and timing of crustal growth and differentiation on early Earth are debated. Evidence of crustal differentiation is detectable as deviations from Earth's assumed chondritic uniform reservoir (CHUR) as crust is extracted from the mantle leading to a melt-depleted reservoir. For the long-lived zircon Lu-Hf system, no incontrovertible evidence of significant mantle depletion >3.8 Ga exists. We conduct combined U-Pb and Lu-Hf isotopic analyses for the detrital zircon from the Caozhuang supracrustal sequence in North China. The zircon Hf isotopic compositions are broadly scattered along the CHUR evolution line. However, given the possibility of potential systematic biases in zircon petrogenesis and the unique tectonic setting of early Earth, we posit that magmatism controlled by the nascent forms of plate tectonics during the Eoarchean could have likely hidden the degree of ancient crust-mantle differentiation. The non-depleted zircon Hf isotopes observed in North China and globally during early Earth may in verity imply the existence of ubiquitous depleted mantle domains at that time. [ABSTRACT FROM AUTHOR]

Provenance analysis including sandstone modal compositions, heavy mineral assemblages, and LA-ICP-MS U-Pb dating with in-situ Hf isotopic compositions of detrital zircons defines two types of Late Cretaceous-Eocene turbiditic sequences separated by the Siah Cheshmeh-Khoy-Misho-Tabriz Fault in the Azerbaijan Province, Northwest Iran: (1) Volcaniclastic turbidites to the southwest and (2) terrigenous turbidites to the northeast. The first appearance of Cr-spinel in Upper Cretaceous sandstones of both sequences indicates the erosion of ophiolites at that time. The southwestern volcaniclastic sandstones contain few Late Triassic and dominantly Late Cretaceous zircon grains whose Hf isotopic compositions suggest a continental magmatic arc provenance. In the northeastern terrigenous sandstones, detrital zircon U-Pb ages cluster in five main age groups from Paleoproterozoic-Neoproterozoic with Hf isotopic compositions typical of continental crust to Late Cretaceous-Palaeocene zircon grains with Hf isotopic compositions similar to those of the southwest turbidites. The provenance characteristics define, along with sedimentary structures, two separate basins, a marginal basin to the northeast, and a deep oceanic basin to the southwest. We conclude that the Siah Cheshmeh-Khoy-Misho-Tabriz Fault overprints a boundary between two lithospheres separated by ophiolite outcrops; therefore, the Siah Cheshmeh-Khoy-Misho-Tabriz Fault is a reworked suture. The Cretaceous arc, witnessed by clastic material, has been largely eroded and/or subducted. [ABSTRACT FROM AUTHOR]

[Display omitted] • New U–Pb, geochemical and Lu–Hf data of basement rocks from North Wulan terrane. • 2.57 Ga granites and 2.0–1.72 Ga metamorphism recognized in the North Wulan terrane. • Origin and multi-stage evolution processes of the North Wulan terrane. • Proterozoic paleogeographic reconstruction for microcontinents in northwestern China. The occurrence of pre-existing crust in orogenic belts has important implications for constraining and testing models of orogenic processes and for making paleogeographic reconstructions. Asynchronous magmatic–metamorphic rocks provide an opportunity to reconstruct the positions and constituent blocks of certain Precambrian fragments. Here we report Neoarchean to Neoproterozoic crustal rocks preserved in the North Wulan Terrane (NWT), northwestern China. Our new zircon geochronological data reveal the ca. 2.57 Ga magmatic and 2.0–1.72 Ga metamorphic events in the NWT, implying its involvement in the formation of Columbia supercontinent. Meanwhile, the NWT also recorded the 1.5–1.3, 1.1, 0.9–0.8 and 0.51–0.48 Ga magmatic-metamorphic activities, corresponding to the involvement of regional Precambrian fragments in cyclic supercontinent-related processes from Columbia to Greater Gondwana. Most of the ca. 2.57 and 0.9–0.8 Ga granites are characterized by enriched zircon ε Hf (t) values of –5.7 to +0.9 and –5.2 to +7.1. Moreover, some of these granites show fractionated characteristics, with high silica contents (80.3–82.3 wt% and 73.9–75.2 wt%), indicating that these rocks were derived mainly from remelting of 3.6–2.7 Ga mature crustal materials and 1.6–2.0 Ga crustal materials without or with minor contribution of juvenile materials, respectively. On the basis of these new results, regional stratigraphy, and previously determined geochemical data and tectonic signatures, it is concluded that the Quanji Massif and the Central Qilian, Hualong and North Wulan terranes probably formed a coherent Qilian–Quanji block as the southeastern extension of the Tarim Craton initiated from the Neoarchean. We propose that from the Neoarchean to early Paleoproterozoic, the primal Qilian–Quanji block was formed by long-term arc-related magma emplacement and reworking of ancient mature crustal materials in southeastern Tarim Craton. Subsequently, the juvenile Tarim–Qilian–Quanji continent was involved in tectonic cycles during its involvement in the supercontinents of Columbia and Rodinia. [ABSTRACT FROM AUTHOR]

Ten samples of felsic plutonic rocks from the Eastern Segment of the Sveconorwegian Orogen in southern Sweden, previously dated by ID-TIMS on zircon, have been dated anew using SIMS spot analysis of individual zircon grains, leading to more reliable and in most cases also more precise revised magmatic crystallization ages. A gneissic monzonite within the Protogine Zone in Småland yields a revised U-Pb age of ca. 1725 Ma, four samples of orthogneiss from Skåne all yield revised ages between 1700 and 1690 Ma, while two samples of coarse-grained granitic gneiss in the same region yield ages between 1690 and 1680 Ma. These revised ages are between 15 and 250 m.y. older than previously obtained TIMS ages. Two samples of the Gumlösa-Glimåkra granite along the Protogine Zone in northern Skåne and one sample of related syenite yield ages around 1220 Ma, similar but more precise compared to the previous ages. The U-Pb zircon data have been complemented by Hf isotope analysis by LA-ICP-MS on the same grains, and previously obtained initial Sr and Nd whole-rock isotope data have been recalculated to the revised crystallization ages. The Sr isotope data scatter, while the revised initial εNd values fall between +1 and +2 for the older rocks, and close to 0 for the younger intrusives along the Protogine Zone. Initial εHf in magmatic undisturbed zircons shows relatively little spread within each sample, between 2 and 4 Epsilon units, disregarding a few outliers, with average values for the 1725 to 1680 Ma rocks between +3 and +5.5 and for the 1220 Ma rocks at ca. +1.5. Covariation between initial εNd and initial εHf in the older rocks suggests either mixing between two isotopically distinct magma sources or one magma source which was isotopically heterogeneous. The isotopic signatures of the 1220 Ma intrusive rocks along the Protogine Zone are indicative of juvenile mantle input to their magmas, rather than pure crustal melting. [ABSTRACT FROM AUTHOR]

When the Neo-Tethys subduction initiated has been a subject of debate, perhaps due to the lack of reliable evidence. This paper reports geochronological, geochemical, and Hf isotopic data for recently identified gabbro as well as diorite exposed in the Chanv area of the Gangdese in the southernmost margin of the western Lhasa block, western China. Zircon U–Pb dating indicates the Chanv magmatic rocks formed in two stages: latest Permian (gabbro, 254.8 ± 1.5 Ma) and Late Triassic (gabbro, 214.2 ± 2.0 Ma; diorite, 202.8 ± 1.1 Ma). Geochemical and Hf isotopic analyses reveal that the Chanv magmatic rocks of both stages have contrasting characters. The latest Permian gabbro has apparently higher TiO2 concentrations (> 3 wt.%) than the Late Triassic gabbro (0.86–1.24 wt.%). Although they all are enriched in light rare-earth elements (LREEs), the latest Permian gabbro displays no depletions in Nb and Ta, while the Late Triassic gabbro and diorite are apparently depleted in these two elements. In addition, the zircons from the latest Permian gabbro are all characterized by positive εHf(t) values whereas those from the Late Triassic gabbro dominantly by negative εHf(t) values. Conventional plots using multi-elements or elemental ratios all indicate the latest Permian gabbro has inherent resemblance to intraplate oceanic-island basalt (OIB) whereas the Late Triassic gabbro and diorite are of distinct arc affinity. Therefore, The Chanv latest Permian–Late Triassic magmatic rocks testify a switch of the tectonic environment in the southernmost Eurasian margin from latest Permian post-break-up to Late Triassic arc-related setting and thus constrain the initiation of the Neo-Tethys subduction between 255 Ma and 214 Ma. [ABSTRACT FROM AUTHOR]

In this study, zircon grains are applied for U–Pb dating, Hf isotopes and trace elements to reveal the origin of magmatism and tectonic evolution of Late Paleozoic rocks of the Indian plate, Northern Pakistan. Most of the zircons are characterized by oscillatory zoning, depletion of light rare earth elements (LREE) and enrichment of heavy rare earth elements (HREE) with Ce and Eu anomalies. The yielded ages for these rocks are 256 ± 1.9 Ma and are plotted in the zones defined for the continental setting with few deviated toward the mid-oceanic ridge and the oceanic arc setting. Deviated zircons are recognized as inherited zircons by displaying a high concentration of normalized primitive La and Pr values, while others are plotted in the continental zones. Rare earth elements (REE) and trace elements including Th, Hf, U, Nb, Sc and Ti discriminate Swat orthogneisses into the within plate setting and the inherited zircons are plotted in the orogenic or the arc-related setting. The LREE discriminated these zircons into a magmatic zone with inherited zircons deviated toward the hydrothermal zone. The temperature calculated for these rocks based on the Ti content in zircon ranges from 679 to 942°C. The εHf(t) ranging from −11.1 to +1.4 reveals that the origin is the continental crust with the minute input of the juvenile mantle.

Results of a study of U-Pb and Hf isotope systematics and trace element concentrations in five zircon crystals separated from the Devonian Petrivske kimberlite are reported in the paper. Four zircons have yielded Paleoproterozoic and Archean ages, while one zircon grain gave a Devonian age of 383.6±4.4 Ma (weighted mean 206Pb/238U age). The Precambrian zircons have been derived from terrigenous rocks of the Mykolaivka Suite that is cut by kimberlite, or directly from the Precambrian rock complexes that constitute continental crust in the East Azov. The Devonian zircon crystal has the U-Pb age that corresponds to the age of kimberlite emplacement. It is 14 m.y. younger than zircon megacrysts found in the Novolaspa kimberlite pipe in the same area. In addition, Petrivske zircon is richer in trace elements than its counterparts from the Novolaspa pipe. Petrivske and Novolaspa zircons crystallized from two different proto-kimberlite melts, whereas the process of kimberlite formation was very complex and possibly included several episodes of formation of proto-kimberlite melts, separated by extended (over 10 M.y.) periods of time. [ABSTRACT FROM AUTHOR]

The effects of the Sibumasu–Indochina Terranes collision created several kinds of mineral deposits in Thailand, which include porphyry–skarn copper–gold, epithermal gold and antimony, orogenic gold–antimony–tungsten and tin‐tungsten mineralization among others. The deposits show a distinct spatial zonal distribution and occur in specific tectonic terranes. Combining regional geological data and ore deposit distribution data with Hf‐isotopic data of zircons in igneous rocks can be used to investigate the relationship between crustal construction processes and metallogeny. In this study, we investigated the Sukhothai Fold Belt, which is composed of quartz monzodiorite, granodiorite, syenogranite, and monzogranite of I‐ and S‐type affinities. All granitoids were analyzed for zircon U–Pb geochronology and Lu–Hf isotopic analysis. The granitoids of the Sukhothai Fold Belt yielded U–Pb zircon ages ranging from ~243 to 202 Ma, which mark the timing of subduction to the syn‐collisional stage between the Sibumasu–Indochina terranes at ~243–237 Ma and the timing of post‐collision between the Sibumasu–Indochina terranes during 230–202 Ma. In addition, an age of ~43 Ma in the south of the Sukhothai Fold Belt may indicate intrusion during the sinistral movement of the Klaeng and Mae Ping fault zones resulted from the Indian–Eurasian plate collision. The Doi Tung quartz monzodiorite provided an age of ~350 Ma as a timing of formation of the Sukhothai Fold Belt. The negative and positive initial εHf values (−8.0 to +9.2) with two‐stage depleted mantle model ages (TDMC of 2.2–0.6 Ga) of zircons from the Sukhothai Fold Belt granitoids indicate that the sources of their magma derived from partial melting of old continental crust and young oceanic crust, which probably mixed with a mantle‐derived magma. A zircon Hf‐isotope compilation including the data obtained in this study and previously reported values was used to prepare a map that allows a comparison between magmatic source and mineral deposit distribution in Thailand. The spatial distribution of Hf isotopic data reveals a distinct zonation, with initial εHf values decreasing from the east to the west, that is, from the western margin of the Indochina Terrane or the Loei Fold Belt to the Sukhothai Fold Belt, the Inthanon Zone and the Sibumasu Terrane. The magmatic source for the granitoids in the Loei Fold Belt is dominated by mantle‐derived components, as shown by positive average initial εHf values (+1.0 to +12.7), and contributed to porphyry‐related skarn copper–gold and iron and epithermal gold mineralization. In contrast, magmas in the Sibumasu Terrane and the Inthanon Zone originated from melting of old crustal materials, as indicated by mostly negative average initial εHf values (−15.1 to +0.8), and are responsible for S‐type granite‐related tin‐tungsten mineralization. The average initial εHf values (−5.0 to +11.0) from the intrusions in the Sukhothai Fold Belt suggest mixed sources, including evolved and juvenile magmatic materials, which generated the orogenic gold deposits and other vein‐type antimony, tungsten, fluorite, and base metal deposits. These results imply a close spatial correlation between the source of magmatism in each tectonic terrane of Thailand and different metal ore deposits. These isotope maps can be used as a powerful tool in the exploration for various commodities at the regional scale. [ABSTRACT FROM AUTHOR]

The Trans‐North China Orogen (TNCO) is a part of the North China Craton (NCC) and together provides a classic example of lithospheric destruction. The Pandao granites outcropping in the Wutai Mountains area provide a window to investigate the Mesozoic magmatism in the TNCO. Here, this paper presents the new zircon geochronology, whole‐rock geochemistry, and zircon Hf isotope data for the Pandao granites to discuss their petrogenesis and tectonic implications. The Pandao granites are mainly composed of light‐red medium‐ to coarse‐grained biotite granite and light‐grey fine‐ to medium‐grained biotite granite. Zircon U–Pb ages of 110.05 ± 0.67 Ma and 108.35 ± 0.81 Ma suggest that the Pandao granites were crystallized in the Early Cretaceous. The Pandao granites are classified as high‐K calc‐alkaline and weak peraluminous series. The rocks display abundance in large‐ion lithophile elements (LILE) and light rare‐earth elements (LREE) but show depletion in high‐field‐strength elements (HFSE) and heavy rare‐earth elements (HREE), with strong negative Eu anomalies. The classification diagrams indicate that the Pandao granites are A‐type granites and thus belong to the A1 subtype, formed in an intraplate extensional environment. The Pandao granites have homogeneous zircon Hf isotopic compositions. Their zircons have negative εHf(t) values (−19.1 to −17.1) and old Hf isotope crustal model ages (2,250–2,375 Ma), suggesting that the Pandao granites were formed by partial melting of the Paleoproterozoic lower crustal material. Therefore, it is suggested that the Pandao granites were formed under an intraplate extensional tectonic environment of remote effect due to the ancient Pacific Plate subduction and retreat beneath the Eurasian continent. The TNCO was influenced by the subduction and retreat of the ancient Pacific Plate in the late Early Cretaceous. [ABSTRACT FROM AUTHOR]