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The stellar initial mass function (IMF) is critical to our understanding of star formation and the effects of young stars on their environment. On large scales, it enables us to use tracers such as UV or Halpha emission to estimate the star formation rate of a system and interpret unresolved star clusters across the universe. So far, there is little firm evidence of large-scale variations of the IMF, which is thus generally considered universal. Stars form from cores and it is now possible to estimate core masses and compare the core mass function (CMF) with the IMF, which it presumably produces. The goal of the ALMA-IMF large program is to measure the core mass function at high linear resolution (2700 au) in 15 typical Milky Way protoclusters spanning a mass range of 2500 to 32700 Msun. In this work, we used two different core extraction algorithms to extract about 680 gravitationally bound cores from these 15 protoclusters. We adopt per core temperature using the temperature estimate from the PPMAP Bayesian method. A power-law fit to the CMF of the sub-sample of cores above the 1.64 Msun completeness limit, 330 cores, through the maximum likelihood estimate technique yields a slope of 1.97 +/- 0.06, significantly flatter than the 2.35 Salpeter slope. Assuming a self-similar mapping between the CMF and the IMF, this result implies that these 15 high-mass protoclusters will generate atypical IMFs. This sample is the largest to date produced and analysed self-consistently, derived at matched physical resolution, with per-core temperature estimates and cores as massive as 150 Msun. We provide the raw source extraction catalogues and the source derived size, temperature, mass, and spectral indices in the 15 protoclusters., Comment: Accepted by A&A

Binary interactions have been proposed to explain a variety of circumstellar structures seen around evolved stars, including asymptotic giant branch (AGB) stars and planetary nebulae. Studies resolving the circumstellar envelopes of AGB stars have revealed spirals, discs and bipolar outflows, with shaping attributed to interactions with a companion. For the first time, we have used a combined chemical and dynamical analysis to reveal a highly eccentric and long-period orbit for W Aquilae, a binary system containing an AGB star and a main sequence companion. Our results are based on anisotropic SiN emission, the first detections of NS and SiC towards an S-type star, and density structures observed in the CO emission. These features are all interpreted as having formed during periastron interactions. Our astrochemistry-based method can yield stringent constraints on the orbital parameters of long-period binaries containing AGB stars, and will be applicable to other systems., Comment: This version of the article has been accepted for publication, after peer review (when applicable) and is subject to Springer Nature's AM terms of use, but is not the Version of Record and does not reflect post-acceptance improvements, or any corrections. The Version of Record is available online at: https://doi.org/10.1038/s41550-023-02154-y

Both magnetic fields and photospheric/atmospheric dynamics can be involved in triggering the important mass loss observed in evolved cool stars. Previous works have revealed that these objects exhibit a magnetic field extending beyond their surface. The origin of this magnetic field is still under debate with mechanisms involving a turbulent dynamo, convection, stellar pulsation, and cool spots. Our goal is to estimate the magnetic field strength in the inner circumstellar envelope of six evolved cool stars (five Miras and one Red Supergiant). Combining this work with previous studies, we tentatively constrain the global magnetic field type observed and shed light on the mechanisms at its origin. Using the XPOL polarimeter installed at the IRAM-30 m telescope, we observed the 28 SiO v = 1, J = 2-1 maser line emission and obtained simultaneous spectroscopic measurements of the four Stokes parameters. Applying a careful calibration method for Stokes Q, U, and V, we derive estimates of the magnetic field strength from the circular and linear polarization fractions considering the saturated and unsaturated maser cases under the Zeeman hypothesis. Magnetic field strengths from several Gauss up to several tens of Gauss are derived. These new and more accurate measurements constraining the field strength in the 2-5 stellar radii region better than previous studies and seem to exclude a global poloidal magnetic field type. A combination of a toroidal and a poloidal field is nevertheless not excluded. A variation of the magnetic field strength over a two-months timescale is observed in one Mira star which suggests a possible link to the stellar phase, i.e. with pulsation/photospheric activity., Comment: 18 pages, 12 figures, Accepted in A&A

Sites associated with high-mass star and cluster formation exhibit a so-called hot core phase, characterized by high temperatures and column densities of complex organic molecules. We built a comprehensive census of hot core candidates towards the ALMA-IMF protoclusters based on the detection of two CH3OCHO emission lines at 216.1 GHz. We used the source extraction algorithm GExt2D to identify peaks of methyl formate (CH3OCHO) emission that is a complex species commonly observed towards sites of star formation. We built up a catalog of 76 hot core candidates with masses ranging from about 0.2 to 80 Msun , of which 56 are new detections. A large majority of these objects are compact, rather circular, with deconvolved FWHM sizes of about 2300 au on average. About 30% of our sample of methyl formate sources have core masses above 8 Msun within sizes ranging from about 1000 au to 13400 au, which well correspond to archetypical hot cores. The origin of the CH3OCHO emission toward the lower-mass cores can be explained by a mixture of contribution from shocks, or may correspond to objects in a more evolved state, i.e. beyond the hot core stage. We find that the fraction of hot core candidates increases with the core mass. The large fraction of hot core candidates towards the most massive cores suggests that they rapidly enter the hot core phase and feedback effects from the forming protostar(s) impact their environment on short time-scales.

We aimed to measure the CMF in the evolved W33-Main star-forming protocluster to compare it with CMF recently obtained in other Galactic star-forming regions, including the ones included in the ALMA-IMF program. We used observations from the ALMA-IMF large program: 2'x2' maps of emission from the continuum and selected lines at 1.3mm and 3mm observed by the ALMA 12m only antennas. Our angular resolution was typically 1'', that is 2400au at a distance of 2.4kpc. The lines we analysed are CO(2-1), SiO(5-4), N2H+(1-0), H41alpha as well as He41alpha blended with C41alpha. We built a census of dense cores in the region, and we measured the associated CMF based on a core-dependent temperature value. We confirmed the 'evolved' status of W33-Main by identifiying three HII regions within the field, and to a lesser extent based on the number and extension of N2H+ filaments. We produced a filtered core catalog of 94 candidates, that we refined to take into account the contamination of the continuum by free-free and line emission, obtaining 80 cores with masses that range from 0.03 to 13.2Msun. We fitted the resulting high-mass end of the CMF with a single power law of the form N(log(M)) ~ M^alpha, obtaining alpha = -1.44(+0.16)(-0.22), slightly steeper but consistent with the Salpeter index. We categorized our cores in pre- and protostellar, mostly based on outlow activity and hot core nature. We found the prestellar CMF to be steeper than a Salpeter-like distribution, and the protostellar CMF to be slightly top heavy. We found a higher proportion of cores within the HII regions and their surroundings than in the rest of the field. We also found that the cores' masses were rather low (maximum mass of 13Msun).

The dusty winds of cool evolved stars are a major contributor of the newly synthesised material enriching the Galaxy and future generations of stars. However, the details of the physics and chemistry behind dust formation and wind launching have yet to be pinpointed. Recent spatially resolved observations show the importance of gaining a more comprehensive view of the circumstellar chemistry, but a comparative study of the intricate interplay between chemistry and physics is still difficult because observational details such as frequencies and angular resolutions are rarely comparable. Aiming to overcome these deficiencies, ATOMIUM is an ALMA Large Programme to study the physics and chemistry of the circumstellar envelopes of a diverse set of oxygen-rich evolved stars under homogeneous observing conditions at three angular resolutions between ~0.02"-1.4". Here we summarize the molecular inventory of these sources, and the correlations between stellar parameters and molecular content. Seventeen oxygen-rich or S-type asymptotic giant branch (AGB) and red supergiant (RSG) stars have been observed in several tunings with ALMA Band 6, targeting a range of molecules to probe the circumstellar envelope and especially the chemistry of dust formation close to the star. We systematically assigned the molecular carriers of the spectral lines and measured their spectroscopic parameters and the angular extent of the emission of each line from integrated intensity maps. Across the ATOMIUM sample, we detect 291 transitions of 24 different molecules and their isotopologues. This includes several first detections in oxygen-rich AGB/RSG stars: PO v=1, SO2 v1=1 and v2=2, and several high energy H2O transitions. We also find several first detections in S-type AGB stars: vibrationally excited HCN v2=2,3 and SiS v=4,5,6, as well as first detections of the molecules SiC, AlCl, and AlF in W Aql..., Comment: 19 pages plus appendices, forthcoming publication in Astronomy & Astrophysics

ALMA-IMF is an Atacama Large Millimeter/submillimeter Array (ALMA) Large Program designed to measure the core mass function (CMF) of 15 protoclusters chosen to span their early evolutionary stages. It further aims to understand their kinematics, chemistry, and the impact of gas inflow, accretion, and dynamics on the CMF. We present here the first release of the ALMA-IMF line data cubes (DR1), produced from the combination of two ALMA 12m-array configurations. The data include 12 spectral windows, with eight at 1.3mm and four at 3mm. The broad spectral coverage of ALMA-IMF (~6.7 GHz bandwidth coverage per field) hosts a wealth of simple atomic, molecular, ionised, and complex organic molecular lines. We describe the line cube calibration done by ALMA and the subsequent calibration and imaging we performed. We discuss our choice of calibration parameters and optimisation of the cleaning parameters, and we demonstrate the utility and necessity of additional processing compared to the ALMA archive pipeline. As a demonstration of the scientific potential of these data, we present a first analysis of the DCN (3-2) line. We find that DCN traces a diversity of morphologies and complex velocity structures, which tend to be more filamentary and widespread in evolved regions and are more compact in the young and intermediate-stage protoclusters. Furthermore, we used the DCN (3-2) emission as a tracer of the gas associated with 595 continuum cores across the 15 protoclusters, providing the first estimates of the core systemic velocities and linewidths within the sample. We find that DCN (3-2) is detected towards a higher percentage of cores in evolved regions than the young and intermediate-stage protoclusters and is likely a more complete tracer of the core population in more evolved protoclusters. The full ALMA 12m-array cubes for the ALMA-IMF Large Program are provided with this DR1 release., Comment: 75 pages (21 main body; 54 appendix), 37 figures. The ALMA-IMF DR1 line release is hosted at https://dataverse.harvard.edu/dataverse/alma-imf

Water and the hydroxyl radical are major constituents of the envelope of O-rich late-type stars. Transitions involving energy levels that are highly excited have been observed in both H$_2$O and OH. These and more recently discovered transitions can now be observed at a high sensitivity and angular resolution with the ALMA Array. Spectra and maps of H$_2$O and OH observed with an angular resolution of 20 to $\sim$200 mas were obtained at two epochs with the ALMA array. Observations with the Compact Array were also used to check for time variability of water transitions. Radiative transfer models of water were revisited to characterize masing conditions and up-to-date chemical models were used for comparison with our observations. Ten rotational transitions of H$_2$O with energies up to 9000 K were observed in various vibrational states. All but one are new detections in space, and from these we have derived accurate rest frequencies. Hyperfine split $\Lambda$-doubling transitions in v = 0, J = 27/2 and 29/2 levels of the $^2\Pi_{3/2}$ state and, $J = 33/2$ and 35/2 of the $^2\Pi_{1/2}$ state of OH with excitation energies up to 8900 K were also observed. Four of these transitions are new detections in space. Combining our measurements with earlier observations of OH, the v = 0 and v = 1 $\Lambda$-doubling frequencies have been improved. Our H$_2$O maps show compact emission and extensions up to twelve stellar radii or more. The 268.149 GHz emission line of water in the v$_2$ = 2 state is time variable, tends to be masing with dominant radiative pumping, and is widely excited. The widespread but weaker 262.898 GHz water line in v$_2$ = 1 also shows signs of maser emission. Emission and absorption of both H$_2$O and OH reveal an infall of matter and complex kinematics influenced by binarity. From our observed column densities, we derived OH/H$_2$O abundance ratios in a few stars., Comment: 41 pages with references and 25 figures in main text. 4 Tables in Appendix A. 10 figures in Appendix B. 2 figures in Appendix C. 14 figures in Appendix D. 5 figures in Appendix E. 2 figures in Appendix F

The origin of the stellar initial mass function (IMF) and its relation with the core mass function (CMF) are actively debated issues with important implications in astrophysics. Recent observations in the W43 molecular complex of top-heavy CMFs, with an excess of high-mass cores compared to the canonical mass distribution, raise questions about our understanding of the star formation processes and their evolution in space and time. We aim to compare populations of protostellar and prestellar cores in three regions imaged in the ALMA-IMF Large Program. We created an homogeneous core catalogue in W43, combining a new core extraction in W43-MM1 with the catalogue of W43-MM2&MM3 presented in a previous work. Our detailed search for protostellar outflows enabled us to identify between 23 and 30 protostellar cores out of 127 cores in W43-MM1 and between 42 and 51 protostellar cores out of 205 cores in W43-MM2&MM3. Cores with neither outflows nor hot core emission are classified as prestellar candidates. We found a similar fraction of cores which are protostellar in the two regions, about 35%. This fraction strongly varies in mass, from 15-20% at low mass, between 0.8 and 3$M_{\odot} $ up to about 80% above 16$M_{\odot}$. Protostellar cores are found to be, on average, more massive and smaller in size than prestellar cores. Our analysis also revealed that the high-mass slope of the prestellar CMF in W43, $\alpha=-1.46_{-0.19}^{+0.12}$, is consistent with the Salpeter slope, and thus the top-heavy form measured for the global CMF, $\alpha=-0.96$, is due to the protostellar core population. Our results could be explained by clump-fed models in which cores grow in mass, especially during the protostellar phase, through inflow from their environment. The difference between the slopes of the prestellar and protostellar CMFs moreover implies that high-mass cores grow more in mass than low-mass cores., Comment: 28 pages, 18 figures. Accepted for publication in A&A. Title and appendices updated

Aims. Through the ATOMIUM project, based on an ALMA large program, we aim to present a consistent view of a sample of 17 nearby cool evolved stars (Aymptotic Giant Branch and red supergiant stars). Methods. Here we present VLT/SPHERE-ZIMPOL polarimetric maps obtained in the visible of 14 out of the 17 ATOMIUM sources. They were obtained contemporaneously with the ALMA high spatial resolution data. To help interpret the polarized signal, we produced synthetic maps of light scattering by dust, through 3D radiative transfer simulations with the RADMC3D code. Results. The degree of linear polarization (DoLP) observed by ZIMPOL spreads across several optical filters. We infer that it primarily probes dust located just outside of the point spread function, and in or near the plane of the sky, with a total optical depth close to unity in the line of sight, representing only a fraction of the total circumstellar dust. The maximum DoLP ranges from 0.03-0.38 depending on the source, fractions that can be reproduced by our 3D pilot models for grains composed of common dust species. The spatial structure of the DoLP shows a diverse set of shapes. Only for three sources do we note a correlation between the ALMA CO and SiO lines, which trace the gas density, and the DoLP, which traces the dust. Conclusion. The clumpiness of the DoLP and the lack of a consistent correlation between the gas and the dust location show that, in the inner circumstellar environment (CSE), dust formation occurs at very specific sites. This has potential consequences for the derived mass-loss rates and dust-to-gas ratio in the inner region of the CSE. Except for $\pi^1$~Gru and perhaps GY Aql, we do not detect interactions between the circumstellar wind and the hypothesized companions that shape the wind at larger scales. This suggests that the orbits of any other companions are tilted out of the plane of the sky., Comment: Accepted for publication in Astronomy & Astrophysics. 22 pages, 15 figures, 5 tables

Among the most central open questions regarding the initial mass function (IMF) of stars is the impact of environment on the shape of the core mass function (CMF) and thus potentially on the IMF. The ALMA-IMF Large Program aims to investigate the variations in the core distributions with cloud characteristics, as diagnostic observables of the formation process and evolution of clouds. The present study focuses on the W43-MM2&MM3 mini-starburst, whose CMF has recently been found to be top-heavy with respect to the Salpeter slope. W43-MM2&MM3 harbors a rich cluster that contains a statistically significant number of cores, which was previously characterized in Paper III. We applied a multi-scale decomposition technique to the ALMA 1.3 mm and 3 mm continuum images to define six subregions. For each subregion we characterized the high column density probability distribution function, n-PDF, and the shape of the cloud gas using the 1.3 mm image. Using the core catalog, we investigate correlations between the CMF and cloud and core properties. We classify the subregions into different stages of evolution, from quiescent to burst to post-burst, based on the surface number density of cores, number of outflows, and UCHii presence. The high-mass end of the subregion CMFs varies from being close to the Salpeter slope (quiescent) to top-heavy (burst and post-burst). Moreover, the second tail of the n-PDF varies from steep, to flat like observed for the high mass star-forming clouds. We found that subregions with flat second n-PDF tails display top-heavy CMFs. The CMF may evolve from Salpeter to top-heavy throughout the star formation process from the quiescent to the burst phase. This scenario raises the question of if the CMF might revert again to Salpeter as the cloud approaches the end of its star formation stage, a hypothesis that remains to be tested., Comment: Accepted for publication in A&A (december, 5th 2022) after language editing; 25 pages, 14 figures

W43-MM1 is a young region, very rich in terms of high-mass star formation. We aim to systematically identify the massive cores which contain a hot core and compare their molecular composition. We used ALMA high-spatial resolution (2500 au) data of W43-MM1 to identify line-rich protostellar cores and make a comparative study of their temperature and molecular composition. The identification of hot cores is based on both the spatial distribution of the complex organic molecules and the contribution of molecular lines relative to the continuum intensity. We rely on the analysis of CH3CN and CH3CCH to estimate the temperatures of the selected cores. Finally, we rescale the spectra of the different hot cores based on their CH3OCHO line intensities to directly compare the detections and line intensities of the other species. W43-MM1 turns out to be a region rich in massive hot cores with at least 1 less massive and 7 massive hot cores. The excitation temperature of CH3CN is of the same order for all of them (120-160 K). There is a factor of up to 30 difference in the intensity of the complex organic molecules (COMs) lines. However the molecular emission of the hot cores appears to be the same within a factor 2-3. This points towards both a similar chemical composition and excitation of most of the COMs over these massive cores, which span about an order of magnitude in core mass. In contrast, CH3CCH emission is found to preferentially trace more the envelope, with a temperature ranging from 50 K to 90 K. Core 1, the most massive hot core of W43-MM1, shows a richer line spectrum than the other cores. In core 2, the emission of O-bearing molecules does not peak at the dust continuum core center; the blue and red shifted emission correspond to the outflow lobes, suggesting a formation via the sublimation of the ice mantles through shocks or UV irradiation on the walls of the cavity., Comment: 19 pages, 17 figures. Accepted for publication in A&A

The ALMA-IMF Large Program observed the W43-MM2-MM3 ridge, whose 1.3mm and 3mm ALMA 12m array continuum images reach a 2500au spatial resolution. We used both the best-sensitivity and the line-free ALMA-IMF images, reduced the noise with the multi-resolution segmentation technique MnGSeg, and derived the most complete and most robust core catalog possible. Using two different extraction software packages, getsf and GExt2D, we identified 200 compact sources, whose 100 common sources have on average fluxes consistent to within 30%. We filtered sources with non-negligible free-free contamination and corrected fluxes from line contamination, resulting in a W43-MM2-MM3 catalog of 205 getsf cores. With a median deconvolved FWHM size of 3400au, core masses range from 0.1Msun to 70Msun and the getsf catalog is 90% complete down to 0.8Msun. The high-mass end of the core mass function (CMF) of W43-MM2-MM3 is top-heavy compared to the canonical IMF. Fitting the cumulative CMF with a single power law of the form N(>logM)\propto M^a, we measured a=-0.95\pm0.04, compared to the canonical a=-1.35 Salpeter IMF slope. The slope of the CMF is robust with respect to map processing, extraction software package, and reasonable variations in the assumptions taken to estimate core masses. We explore several assumptions on how cores transfer their mass to stars and sub-fragment to predict the IMF resulting from the W43-MM2-MM3 CMF. In stark contrast to the commonly accepted paradigm, our result argues against the universality of the CMF shape. More robust functions of the star-formation efficiency and core sub-fragmentation are required to better predict the resulting IMF, here suggested to remain top-heavy at the end of the star-formation phase. If confirmed, the IMFs emerging from starburst events could inherit their top-heavy shape from their parental CMFs, challenging the IMF universality., Comment: 28 pages, 16 figures, 6 tables, A&A accepted on 02/08/22, revised following the language referee report

We present the first data release of the ALMA-IMF Large Program, which covers the 12m-array continuum calibration and imaging. The ALMA-IMF Large Program is a survey of fifteen dense molecular cloud regions spanning a range of evolutionary stages that aims to measure the core mass function (CMF). We describe the data acquisition and calibration done by the Atacama Large Millimeter/submillimeter Array (ALMA) observatory and the subsequent calibration and imaging we performed. The image products are combinations of multiple 12m array configurations created from a selection of the observed bandwidth using multi-term, multi-frequency synthesis imaging and deconvolution. The data products are self-calibrated and exhibit substantial noise improvements over the images produced from the delivered data. We compare different choices of continuum selection, calibration parameters, and image weighting parameters, demonstrating the utility and necessity of our additional processing work. Two variants of continuum selection are used and will be distributed: the "best-sensitivity" data, which include the full bandwidth, including bright emission lines that contaminate the continuum, and "cleanest", which select portions of the spectrum that are unaffected by line emission. We present a preliminary analysis of the spectral indices of the continuum data, showing that the ALMA products are able to clearly distinguish free-free emission from dust emission, and that in some cases we are able to identify optically thick emission sources. The data products are made public with this release., Comment: Data released on Zenodo at https://zenodo.org/record/5702966. Accepted for publication in A&A

The ALMA-IMF Large Program imaged a total noncontiguous area of 53pc2, covering 15 extreme, nearby protoclusters of the Milky Way. They were selected to span relevant early protocluster evolutionary stages. Our 1.3mm and 3mm observations provide continuum images that are homogeneously sensitive to point-like cores with masses of 0.2 and 0.6Msun, respectively, with a matched spatial resolution of 2000au. We also detect lines that probe the protocluster structure, kinematics, chemistry, and feedback over scales from clouds to filaments to cores. We classify ALMA-IMF protoclusters as Young, Intermediate, or Evolved based on the amount of dense gas in the cloud that has potentially been impacted by HII regions. The ALMA-IMF catalog contains 700 cores that span a mass range of 0.15-250Msun at a typical size of 2100au. We show that this core sample has no significant distance bias and can be used to build core mass functions at similar physical scales. Significant gas motions, which we highlight here in the G353.41 region, are traced down to core scales and can be used to look for inflowing gas streamers and to quantify the impact of the possible associated core mass growth on the shape of the CMF with time. Our first analysis does not reveal any significant evolution of the matter concentration from clouds to cores or from the youngest to more evolved protoclusters, indicating that cloud dynamical evolution and stellar feedback have for the moment only had a slight effect on the structure of high-density gas in our sample. Furthermore, the first-look analysis of the line richness toward bright cores indicates that the survey encompasses several tens of hot cores, of which we highlight the most massive in the G351.77 cloud. Their homogeneous characterization can be used to constrain the emerging molecular complexity in protostars of high to intermediate masses., Comment: 27 pages, 9 figures, accepted for publication by A&A

This overview paper presents ATOMIUM, a Large Programme in Cycle 6 with the Atacama Large Millimeter-submillimeter Array (ALMA). The goal of ATOMIUM is to understand the dynamics and the gas phase and dust formation chemistry in the winds of evolved asymptotic giant branch (AGB) and red supergiant (RSG) stars. A more general aim is to identify chemical processes applicable to other astrophysical environments. 17 oxygen-rich AGB and RSG stars spanning a range in (circum)stellar parameters and evolutionary phases were observed in a homogeneous observing strategy allowing for an unambiguous comparison. Data were obtained between 213.83 and 269.71 GHz at high (0.025-0.050 arcsec), medium (0.13-0.24 arcsec), and low (about 1 arcsec) angular resolution. The sensitivity per 1.3 km/s channel was 1.5-5 mJy/beam. 13 molecules were designated as primary molecules in the survey: CO, SiO, AlO, AlOH, TiO, TiO2, HCN, SO, SO2, SiS, CS, H2O, and NaCl. The scientific motivation, survey design, sample properties, data reduction, and an overview of the data products are described; and we highlight one scientific result - the wind kinematics of the ATOMIUM sources. The ATOMIUM sources often have a slow wind acceleration, and a fraction of the gas reaches a velocity which can be up to a factor of two times larger than previously reported terminal velocities assuming isotropic expansion, and the wind kinematic profiles establish that the radial velocity described by the momentum equation for a spherical wind structure cannot capture the complexity of the velocity field. In 15 sources, some molecular transitions other than 12CO v=0 J=2-1 reach a higher outflow velocity, with a spatial emission zone that is often greater than 30 stellar radii, but much less than the extent of CO. Binary interaction with a (sub)stellar companion might (partly) explain the non-monotonic behaviour of the projected velocity field.

S-type asymptotic giant branch (AGB) stars are thought to be intermediates in the evolution of oxygen- to carbon-rich AGB stars. The chemical compositions of their circumstellar envelopes are also intermediate, but have not been studied in as much detail as their carbon- and oxygen-rich counterparts. We aim to determine the abundances of AlCl and AlF from rotational lines, which have been observed for the first time towards an S-type AGB star, W Aql. In combination with models based on PACS observations, we aim to update our chemical kinetics network based on these results. We analyse ALMA observations towards W Aql of AlCl in the ground and first two vibrationally excited states and AlF in the ground vibrational state. Using radiative transfer models, we determine the abundances and spatial abundance distributions of Al$^{35}$Cl, Al$^{37}$Cl, and AlF. We also model HCl and HF emission and compare these models to PACS spectra to constrain the abundances of these species. AlCl is found in clumps very close to the star, with emission confined within 0.1$^{\prime\prime}$ of the star. AlF emission is more extended, with faint emission extending 0.2$^{\prime\prime}$ to 0.6$^{\prime\prime}$ from the continuum peak. We find peak abundances, relative to H$_2$, of $1.7\times 10^{-7}$ for Al$^{35}$Cl, $7\times 10^{-8}$ for Al$^{37}$Cl and $1\times 10^{-7}$ for AlF. From the PACS spectra, we find abundances of $9.7\times 10^{-8}$ and $\leq 10^{-8}$, relative to H$_2$, for HCl and HF, respectively. The AlF abundance exceeds the solar F abundance, indicating that fluorine synthesised in the AGB star has already been dredged up to the surface of the star and ejected into the circumstellar envelope. From our analysis of chemical reactions in the wind, we conclude that AlF may participate in the dust formation process, but we cannot fully explain the rapid depletion of AlCl seen in the wind., Comment: Accepted for publication in Astronomy & Astrophysics

Binary interactions dominate the evolution of massive stars, but their role is less clear for low- and intermediate-mass stars. The evolution of a spherical wind from an asymptotic giant branch (AGB) star into a nonspherical planetary nebula (PN) could be due to binary interactions. We observed a sample of AGB stars with the Atacama Large Millimeter/submillimeter Array (ALMA) and found that their winds exhibit distinct nonspherical geometries with morphological similarities to planetary nebulae (PNe). We infer that the same physics shapes both AGB winds and PNe; additionally, the morphology and AGB mass-loss rate are correlated. These characteristics can be explained by binary interaction. We propose an evolutionary scenario for AGB morphologies that is consistent with observed phenomena in AGB stars and PNe., Comment: 19 pages main journal, 97 pages Supplementary Information

Aims: From a coherent interpretation of the linear polarisation detected in the spectral lines of the Mira star $\chi$ Cyg, we derive information about the dynamics of the stellar photosphere, including pulsation. Methods: From spectropolarimetric observations of $\chi$ Cyg, we perform careful analysis of the polarisation signals observed in atomic and molecular lines, both in absorption and emission, using the radiative transfer in the polarisation context, through two mechanisms: intrinsic polarisation and continuum depolarisation. We also explain the observed line doubling phenomenon in terms of an expanding shell in spherical geometry, which allows us to pinpoint the coordinates over the stellar disk with enhanced polarisation. Results: We find that the polarised spectrum of $\chi$ Cyg is dominated by intrinsic polarisation, with a negligible continuum depolarisation. The observed polarised signals can only be explained by assuming that this polarisation is locally enhanced by velocity fields. During the pulsation, radial velocities are not homogeneous over the disk. We map these regions of enhanced velocities. Conclusions: We have set an algorithm to distinguish in any stellar spectra of linear polarisation the origin of this polarisation and the way to increase signal by coherently adding many lines with an appropriated weight. Applied to the Mira star $\chi$ Cyg, we reached the unexpected result that during the pulsation, velocities are radial but not homogeneous over the disk. The reason for these local velocity enhancements are probably related to the interplay between the atmospheric pulsation dynamics and the underlying stellar convection., Comment: Accepted for publication in A&A

High-mass analogues of low-mass prestellar cores are searched for to constrain the models of high-mass star formation. Several high-mass cores, at various evolutionary stages, have been recently identified towards the massive star-forming region W43-MM1 and amongst them a high-mass prestellar core candidate. We aim to characterise the chemistry in this high-mass prestellar core candidate, referred to as W43-MM1 core #6, and its environment. Using ALMA high-spatial resolution data of W43-MM1, we have studied the molecular content of core #6 and a neighbouring high-mass protostellar core, referred to as #3, which is similar in size and mass to core #6. We first subtracted the continuum emission using a method based on the density distribution of the intensities on each pixel. Then, from the distribution of detected molecules, we identified the molecules centred on the prestellar core candidate (core #6) and those associated to shocks related to outflows and filament formation. Then we constrained the column densities and temperatures of the molecules detected towards the two cores. While core #3 appears to contain a hot core with a temperature of about 190 K, core #6 seems to have a lower temperature in the range from 20 K to 90 K from a rotational diagram analysis. We have considered different source sizes for core #6 and the comparison of the abundances of the detected molecules towards the core with various interstellar sources shows that it is compatible with a core of size 1000 au with $T = 20-90$ K or a core of size 500 au with $T \sim 80$ K. Core #6 of W43-MM1 remains one of the best high-mass prestellar core candidates even if we cannot exclude that it is at the very beginning of the protostellar phase of high-mass star formation., Comment: 18 pages, 8 figures, Accepted for publication in Astronomy & Astrophysics

Betelgeuse is an M-type supergiant that presents a circularly polarized (Stokes V) signal in its line profiles, interpreted in terms of a surface magnetic field. The weak circular polarization signal has been monitored over 7.5 years in order to follow its evolution on different timescales, and eventually to determine its physical origin. Linear polarization measurements have also been obtained regularly in the last few years. We used both the ESPaDOnS and Narval spectropolarimeters to obtain high signal-to-noise ratio (S/N) spectra, which were processed by means of the least-squares deconvolution (LSD) method. In order to ensure the reality of the very weak circular polarization, special care has been taken to limit instrumental effects. In addition, several tests were performed on the Stokes V signal to establish its stellar and Zeeman origin. We confirm the magnetic nature of the circular polarization, pointing to a surface magnetic field of the order of 1G. The Stokes V profiles present variations over different timescales, the most prominent one being close to the long secondary period (LSP; around 2000d for Betelgeuse) often invoked in red evolved stars. This long period is also dominant for all the other Stokes parameters. The circular polarization is tentatively modeled by means of magnetic field concentrations mimicking spots, showing in particular that the velocity associated with each "spot" also follows the long timescale, and that this signal is nearly always slightly redshifted. From the coupled variations of both linear and circular polarization signatures in amplitude, velocity and timescale, we favour giant convection cells as the main engine at the origin of polarization signatures and variations in all the Stokes parameters. This strengthens support for the hypothesis that large convective cells are at the origin of the LSP.

The "Square Kilometre Array" (SKA) is a large international radio telescope project characterised, as suggested by its name, by a total collecting area of approximately one square kilometre, and consisting of several interferometric arrays to observe at metric and centimetric wavelengths. The deployment of the SKA will take place in two sites, in South Africa and Australia, and in two successive phases. From its Phase 1, the SKA will be one of the most formidable scientific machines ever deployed by mankind, and by far the most impressive in terms of data throughput and required computing power. With the participation of almost 200 authors from forty research institutes and six private companies, the publication of this French SKA white paper illustrates the strong involvement in the SKA project of the French astronomical community and of a rapidly growing number of major scientific and technological players in the fields of Big Data, high performance computing, energy production and storage, as well as system integration., Comment: Editor in chief: C. Ferrari; Editors: M. Alves, S. Bosse, S. Corbel, A. Ferrari, K. Ferri\`ere, S. Gauffre, E. Josselin, G. Lagache, S. Lambert, G. Marquette, J.-M. Martin, M.-A. Miville-Desch\^enes, L. Montier, B. Semelin, G. Theureau, S. Vergani, N. Vilmer, P. Zarka; Original file with high resolution figures at SKA-France link: https://ska-france.oca.eu/images/SKA-France-Media/FWB_051017.pdf

The SPICA mid and far-infrared telescope will address fundamental issues in our understanding of star formation and ISM physics in galaxies. A particular hallmark of SPICA is the outstanding sensitivity enabled by the cold telescope, optimized detectors, and wide instantaneous bandwidth throughout the mid- and far-infrared. The spectroscopic, imaging and polarimetric observations that SPICA will be able to collect will help in clarifying the complex physical mechanisms which underlie the baryon cycle of galaxies. In particular: (i) The access to a large suite of atomic and ionic fine-structure lines for large samples of galaxies will shed light on the origin of the observed spread in star formation rates within and between galaxies. (ii) Observations of HD rotational lines (out to $\sim$10 Mpc) and fine structure lines such as [CII] 158 $\mu$m (out to $\sim$100 Mpc) will clarify the main reservoirs of interstellar matter in galaxies, including phases where CO does not emit. (iii) Far-infrared spectroscopy of dust and ice features will address uncertainties in the mass and composition of dust in galaxies, and the contributions of supernovae to the interstellar dust budget will be quantified by photometry and monitoring of supernova remnants in nearby galaxies. (iv) Observations of far-infrared cooling lines such as [OI] 63 $\mu$m from star-forming molecular clouds in our Galaxy will evaluate the importance of shocks to dissipate turbulent energy. The paper concludes with requirements for the telescope and instruments, and recommendations for the observing strategy., Comment: Accepted for publication in PASA; 19 pages, 8 figures, 1 table

Several rotational transitions of water have been identified toward evolved stars in the ground vibrational state as well as in the first excited state of the bending mode. In the latter vibrational state of water, the 658 GHz J = 1_1,0-1_0,1 rotational transition is often strong and seems to be widespread in late-type stars. Our main goals are to better characterize the nature of the 658 GHz emission, compare the velocity extent of the 658 GHz emission with SiO maser emission to help locate the water layers and, more generally, investigate the physical conditions prevailing in the excited water layers of evolved stars. Another goal is to identify new 658 GHz emission sources and contribute in showing that this emission is widespread in evolved stars. Eleven evolved stars were extracted from our mini-catalog of existing and potential 658 GHz sources for observations with the APEX telescope equipped with the SEPIA receiver. The 13CO J=6-5 line was placed in the same receiver sideband for simultaneous observation with the 658 GHz line of water. We have compared the 658 GHz line properties with our H2O radiative transfer models in stars and we have compared the velocity ranges of the 658 GHz and SiO J=2-1, v=1 maser lines. All stars show 658 GHz emission with a peak flux density in the range 50-70 Jy to 2000-3000 Jy. We have shown that the 658 GHz line is masing and we found that the 658 GHz velocity extent tends to be correlated with that of the SiO maser suggesting that both emission lines are excited in circumstellar layers close to the central star. Broad and stable line profiles are observed at 658 GHz. This could indicate maser saturation although we have tentatively provided first information on time variability at 658 GHz., Comment: 9 pages, 5 figures. Accepted in A&A

The formation of massive stars is still not well understood. Accumulating a large amount of mass infalling within a single entity in spite of radiation pressure is possible if, among several other conditions, enough thermal energy is released. Despite numerous water line observations, with the Herschel Space Observatory, in most of the sources observations were not able to trace the emission from the hot core around the newly forming protostellar object. We want to probe the physical conditions and water abundance in the inner layers of the host protostellar object NGC7538-IRS1 using a highly excited H2O line. Water maser models predict that several THz water masers should be detectable in these objects. We present SOFIA observations of the o-H2O 8(2,7)-7(3,4) line at 1296.41106 GHz and a 6(1,6)-5(2,3) 22 GHz e-MERLIN map of the region (first-ever 22 GHz images made after the e-MERLIN upgrade). In order to be able to constrain the nature of the emission - thermal or maser - we use near-simultaneous observations of the 22 GHz water maser performed with the Effelsberg radiotelescope and e-MERLIN. A thermal water model using the RATRAN radiative transfer code is presented based on HIFI pointed observations. Molecular water abundances are derived for the hot core. The H2O 8(2,7)- 7(3,4) line is detected toward NGC7538-IRS1 with one feature at the source velocity (-57.7 km/s) and another one at -48.4 km/s. We propose that the emission at the source velocity is consistent with thermal excitation and is excited in the innermost part of the IRS1a massive protostellar object's closest circumstellar environment. The other emission is very likely the first detection of a water THz maser line, pumped by shocks due to IRS1b outflow, in a star-forming region. Assuming thermal excitation of the THz line, the water abundance in NGC7538-IRS1's hot core is estimated to be 5.2x10^{-5} with respect to H2., Comment: accepted to A&A, 15 pages

During the transition from the Asymptotic Giant Branch (AGB) to Planetary Nebulae (PN), the circumstellar geometry and morphology change dramatically. Another characteristic of this transition is the high mass loss rate, that can be partially explained by radiation pressure and a combination of various factors like the stellar pulsation, the dust grain condensation and opacity in the upper atmosphere. The magnetic field can also be one of the main ingredients that shapes the stellar upper atmosphere and envelope. Our main goal is to investigate for the first time the spatial distribution of the magnetic field in the envelope of IRC+10216. More generally we intend to determine the magnetic field strength in the circumstellar envelope (CSE) of C-rich evolved stars, compare this field with previous studies for O-rich stars, and constrain the variation of the magnetic field with r the distance to the star's center. We use spectropolarimetric observations of the Stokes V parameter, collected with Xpol on the IRAM-30m radiotelescope, observing the Zeeman effect in seven hyperfine components of the CN J = 1-0 line. We use Crutcher's method to estimate the magnetic field. For C-rich evolved stars, we derive a magnetic field strength (B) between 1.6 and 14.2 mG while B is estimated to be 6 mG for the proto-PN (PPN) AFGL618, and an upper value of 8 mG is found for the PN NGC7027. These results are consistent with a decrease of B as 1/r in the environment of AGB objects, i.e., with the presence of a toroidal field. But this is not the case for PPN and PN stars. Our map of IRC+10216 suggests that the magnetic field is not homogeneously strong throughout or aligned with the envelope and that the morphology of the CN emission might have changed with time., Comment: 13 pages, accepted to A&A on May 11th 2017

We aim at characterizing the large-scale distribution of H2O in G327.3-0.6, a massive star-forming region made of individual objects in different evolutionary phases. We investigate variations of H2O abundance as function of evolution. We present Herschel continuum maps at 89 and 179 $\mu$m of the whole region and an APEX map at 350 {\mu}m of the IRDC. New spectral HIFI maps toward the IRDC region covering low-energy H2O lines at 987 and 1113 GHz are also presented and combined with HIFI pointed observations of the G327 hot core. We infer the physical properties of the gas through optical depth analysis and radiative transfer modeling. The continuum emission at 89 and 179 {\mu}m follows the thermal continuum emission at longer wavelengths, with a peak at the position of the hot core, a secondary peak in the Hii region, and an arch-like layer of hot gas west of the Hii region. The same morphology is observed in the 1113 GHz line, in absorption toward all dust condensations. Optical depths of ~80 and 15 are estimated and correspond to column densities of 10^15 and 2 10^14 cm-2, for the hot core and IRDC position. These values indicate an H2O to H2 ratio of 3 10^-8 toward the hot core; the abundance of H2O does not change along the IRDC with values of some 10^-8. Infall (over ~ 20") is detected toward the hot core position with a rate of 1-1.3 10^-2 M_sun /yr, high enough to overcome the radiation pressure due to the stellar luminosity. The source structure of the hot core region is complex, with a cold outer gas envelope in expansion, situated between the outflow and the observer, extending over 0.32 pc. The outflow is seen face-on and centered away from the hot core. The distribution of H2O along the IRDC is roughly constant with an abundance peak in the more evolved object. These water abundances are in agreement with previous studies in other massive objects and chemical models., Comment: Accepted by A&A

[Abridged] Do some environments favor efficient conversion of molecular gas into stars? To answer this, we need to be able to estimate the H2 mass. Traditionally, this is done using CO and a few assumptions but the Herschel observations in the FIR make it possible to estimate the molecular gas mass independently of CO. Previous attempts to derive gas masses from dust emission suffered from biases. Generally, dust surface densities, HI column densities, and CO intensities are used to derive a gas-to-dust ratio (GDR) and the local CO intensity to H2 column density ratio (XCO), sometimes allowing for an additional CO-dark gas component (Kdark). We tested earlier methods, revealing degeneracies among the parameters, and then used a Bayesian formalism to derive the most likely values for each of the parameters mentioned above as a function of position in the nearby low metallicity spiral galaxy M33. The data are from the IRAM 30m CO(2-1) line, high-resolution HI and Herschel dust continuum observations. Solving for GDR, XCO, and Kdark in macro pixels 500 pc in size, we find that (i) allowing for CO-dark gas significantly improves fits; (ii) Kdark decreases with galactocentric distance; (iii) GDR is slightly higher than initially expected and increases with galactocentric distance; (iv) the total amount of dark gas closely follows the radially decreasing CO emission, as might be expected if the dark gas is H2 where CO is photodissociated. The total amount of H2, including dark gas, yields an average XCO of twice the galactic value of 2e20 cm^-2/(K km/s), 55% of this traced directly through CO. The rather constant fraction of dark gas suggests that there is no large population of diffuse H2 clouds (unrelated to GMCs) without CO emission. Unlike in large spirals, we detect no systematic radial trend in XCO, possibly linked to the absence of a radial decrease in CO line ratios., Comment: Accepted for publication in Astronomy and Astrophysics

We carried out a millimeter wavelength line survey between 79 and 356 GHz with the IRAM-30m telescope to investigate the physical and chemical properties of the molecular envelope of the oxygen-rich AGB star IK Tau. We analysed the molecular lines detected using the population diagram technique to derive rotational temperatures and column densities. Additionally, we conducted a radiative transfer analysis of the SO$_2$ lines detected. For the first time in this source we detected rotational lines in the ground vibrational state of HCO$^+$, NS, NO, and H$_2$CO, as well as several isotopologues of molecules previously identified. We also detected several rotational lines in vibrationally excited states of SiS and SiO isotopologues, and rotational lines of H$_2$O ($\nu_{\mathrm{2}}$=2). We have also increased the number of rotational lines detected of molecules that were previously identified, enabling a detailed study of the molecular abundances and excitation temperatures. IK Tau displays a rich chemistry for an oxygen-rich circumstellar envelope. We highlight the detection of NS and H$_2$CO with fractional abundances of f(NS)$\sim$10$^{-8}$ and f(H$_2$CO)$\sim$[10$^{-7}$--10$^{-8}$]. Most of the molecules display rotational temperatures between 15 and 40 K. NaCl and SiS isotopologues display rotational temperatures higher than the average (~65 K). In the case of SO$_2$ a warm component with $T_{\mathrm{rot}}$$\sim$290 K is also detected. This SO$_2$ warm component is probably arising from the inner regions of the envelope (at $\sim$8$R_{*}$) where SO$_2$ has a fractional abundance of f(SO$_2$)$\sim$10$^{-6}$. This result should be considered for future investigation of the main formation channels of this, and other, parent species in the inner winds of O-rich AGB stars, which at present are not well reproduced by current chemistry models., Comment: 47 pages, 26 figures. Accepted for Astronomy and Astrophysics

Massive stars have a major influence on their environment yet their formation is difficult to study. W43 is a highly luminous galactic massive star forming region at a distance of 5.5 kpc and the MM1 part hosts a very massive dense core (1000 M$_{\odot}$ within 0.05 pc). We present new Herschel HIFI maps of the W43 MM1 region covering the main low-energy water lines at 557, 987, and 1113 GHz, their H$_2^{18}$O counterparts, and other lines such as $^{13}$CO(10-9) and C$^{18}$O(9-8) which trace warm gas. These water lines are, with the exception of line wings, observed in absorption. Herschel SPIRE and JCMT 450 $\mu$m data have been used to make a model of the continuum emission at these wavelengths. Analysis of the maps, and in particular the optical depth maps of each line and feature, shows that a velocity gradient, possibly due to rotation, is present in both the envelope and the protostellar core. Velocities increase in both components from SW to NE, following the general source orientation. While the H$_2$O lines trace essentially the cool envelope, we show that the envelope cannot account for the H$_2^{18}$O absorption, which traces motions close to the protostar. The core has rapid infall, 2.9 kms, as manifested by the H$_2^{18}$O absorption features which are systematically red-shifted with respect to the $^{13}$CO(10-9) emission line which also traces the inner material with the same angular resolution. Some H$_2^{18}$O absorption is detected outside the central core and thus outside the regions expected to be above 100 K - we attribute this to warm gas associated with the other massive dense cores in W43 MM1. Using the maps to identify absorption from cool gas on large scales, we subtract this component to model spectra for the inner envelope. Modeling the new spectra results in a lower water abundance, decreased from $8 10^{-8}$ to $8 10^{-9}$ , with no change in infall rate.

Betelgeuse is an M supergiant that harbors spots and giant granules at its surface and presents linear polarization of its continuum. We have previously discovered linear polarization signatures associated with individual lines in the spectra of cool and evolved stars. Here, we investigate whether a similar linearly polarized spectrum exists for Betelgeuse. We used the spectropolarimeter Narval, combining multiple polarimetric sequences to obtain high signal-to-noise ratio spectra of individual lines, as well as the least-squares deconvolution (LSD) approach. We have discovered the existence of a linearly polarized spectrum for Betelgeuse, detecting a rather strong signal (at a few times 10$^{-4}$ of the continuum intensity level), both in individual lines and in the LSD profiles. Studying its properties and the signal observed for the resonant \ion{Na}{i}\,D lines, we conclude that we are mainly observing depolarization of the continuum by the absorption lines. The linear polarization of the Betelgeuse continuum is due to the anisotropy of the radiation field induced by brightness spots at the surface and Rayleigh scattering in the atmosphere. We have developed a geometrical model to interpret the observed polarization, from which we infer the presence of two brightness spots and their positions on the surface of Betelgeuse. We show that applying the model to each velocity bin along the Stokes Q and U profiles allows the derivation of a map of the bright spots. We use the Narval linear polarization observations of Betelgeuse obtained over a period of 1.4 years to study the evolution of the spots. Our study of the linearly polarized spectrum of Betelgeuse provides a novel method for studying the evolution of brightness spots at its surface and complements quasi-simultaneous observations obtained with PIONIER at the VLTI., Comment: 13 pages, 10 figures, accepted for publication in Astronomy and Astrophysics

Hydrides are simple compounds containing one or a few hydrogen atoms bonded to a heavier atom. They are fundamental precursor molecules in cosmic chemistry and many hydride ions have become observable in high quality for the first time thanks to the Herschel Space Observatory. Ionized hydrides, such as CH+ and OH+, and also HCO+ that affect the chemistry of molecules such as water, provide complementary information on irradiation by far UV (FUV) or X-rays and gas temperature. The targeted lines of CH+, OH+, H2O+, C+ and CH are detected mostly in blue-shifted absorption. H3O+ and SH+ are detected in emission and only toward some high-mass objects. The observed line parameters and correlations suggest two different origins, related to gas entrained by the outflows and to the circumstellar envelope. The column density ratios of CH+/OH+ are estimated from chemical slab models, assuming that the H2 density is given by the specific density model of each object at the beam radius. For the low-mass YSOs the observed ratio can be reproduced for an FUV flux of 2-400 times the ISRF at the location of the molecules. In two high-mass objects, the UV flux is 20-200 times the ISRF derived from absorption lines, and 300-600 ISRF using emission lines. If the FUV flux required for low-mass objects originates at the central protostar, a substantial FUV luminosity, up to 1.5 L_sun, is required. There is no molecular evidence for X-ray induced chemistry in the low-mass objects on the observed scales of a few 1000 AU. For high-mass regions, the FUV flux required to produce the observed molecular ratios is smaller than the unattenuated flux expected from the central object(s) at the Herschel beam radius. This is consistent with an FUV flux reduced by circumstellar extinction or by bloating of the protostar., Comment: 40 pages, 97 figures, accepted by Astronomy and Astrophysics

We present Herschel/HIFI observations (WISH KP) of 14 water lines in a small sample of galactic massive protostellar objects: NGC6334I(N), DR21(OH), IRAS16272-4837, and IRAS05358+3543. We analyze the gas dynamics from the line profiles. Through modeling of the observations using RATRAN, we estimate outflow, infall, turbulent velocities, molecular abundances, and investigate any correlation with the evolutionary status of each source. The molecular line profiles exhibit a broad component coming from the shocks along the cavity walls associated with the protostars, and an infalling (or expansion for IRAS05358+3543) and passively heated envelope component, with highly supersonic turbulence likely increasing with the distance from the center. Accretion rates between 6.3 10^{-5} and 5.6 10^{-4} \msun yr^{-1} are derived from the infall observed in three of our sources. The outer water abundance is estimated to be at the typical value of a few 10^{-8} while the inner abundance varies from 1.7 10^{-6} to 1.4 10^{-4} with respect to H2 depending on the source. We confirm that regions of massive star formation are highly turbulent and that the turbulence likely increases in the envelope with the distance to the star. The inner abundances are lower than the expected 10^{-4} perhaps because our observed lines do not probe deep enough into the inner envelope, or because photodissociation through protostellar UV photons is more efficient than expected. We show that the higher the infall/expansion velocity in the protostellar envelope, the higher is the inner abundance, maybe indicating that larger infall/expansion velocities generate shocks that will sputter water from the ice mantles of dust grains in the inner region. High-velocity water must be formed in the gas-phase from shocked material., Comment: 31 pages, 15 figures, accepted in A&A main Journal on January 18th

Water probes the dynamics in young stellar objects (YSOs) effectively, especially shocks in molecular outflows. It is a key molecule for exploring whether the physical properties of low-mass protostars can be extrapolated to massive YSOs. As part of the WISH key programme, we investigate the dynamics and the excitation conditions of shocks along the outflow cavity wall as function of source luminosity. Velocity-resolved Herschel-HIFI spectra of the H2O 988, 752, 1097 GHz and 12CO J=10-9, 16-15 lines were analysed for 52 YSOs with bolometric luminosities (L_bol) ranging from <1 to >10^5 L_sun. The profiles of the H2O lines are similar, indicating that they probe the same gas. We see two main Gaussian emission components in all YSOs: a broad component associated with non-dissociative shocks in the outflow cavity wall (cavity shocks) and a narrow component associated with quiescent envelope material. More than 60% of the total integrated intensity of the H2O lines (L_H2O) comes from the cavity shock component. The H2O line widths are similar for all YSOs, whereas those of 12CO 10-9 increase slightly with L_bol. The excitation analysis of the cavity shock component, performed with the non-LTE radiative transfer code RADEX, shows stronger 752 GHz emission for high-mass YSOs, likely due to pumping by an infrared radiation field. As previously found for CO, a strong correlation with slope unity is measured between log(L_H2O) and log(L_bol), which can be extrapolated to extragalactic sources. We conclude that the broad component of H2O and high-J CO lines originate in shocks in the outflow cavity walls for all YSOs, whereas lower-J CO transitions mostly trace entrained outflow gas. The higher UV field and turbulent motions in high-mass objects compared to their low-mass counterparts may explain the slightly different kinematical properties of 12CO 10-9 and H2O lines from low- to high-mass YSOs., Comment: Abridged abstract, 31 pages, 18 figures, 12 tables, accepted in Astronomy & Astrophysics

Column density (N) PDFs serve as a powerful tool to characterize the physical processes that influence the structure of molecular clouds. Star-forming clouds can best be characterized by lognormal PDFs for the lower N range and a power-law tail for higher N, commonly attributed to turbulence and self-gravity and/or pressure, respectively. We report here on PDFs obtained from observations of 12CO, 13CO, C18O, CS, and N2H+ in the Cygnus X North region and compare to a PDF derived from dust observations with the Herschel satellite. The PDF of 12CO is lognormal for Av~1-30, but is cut for higher Av due to optical depth effects. The PDFs of C18O and 13CO are mostly lognormal up for Av~1-15, followed by excess up to Av~40. Above that value, all CO PDFs drop, most likely due to depletion. The high density tracers CS and N2H+ exhibit only a power law distribution between Av~15 and 400, respectively. The PDF from dust is lognormal for Av~3-15 and has a power-law tail up to Av~500. Absolute values for the molecular line column densities are, however, rather uncertain due to abundance and excitation temperature variations. Taken the dust PDF face value, we 'calibrate' the molecular line PDF of CS to the one of the dust and determined an abundance [CS]/[H2] of 10^-9. The slopes of the power-law tails of the CS, N2H+, and dust PDFs are consistent with free-fall collapse of filaments and clumps. A quasi static configuration of filaments and clumps can possibly also account for the observed N-PDFs, as long as they have a sufficiently condensed density structure and external ram pressure by gas accretion is provided. The somehow flatter slopes of N2H+ and CS can reflect an abundance change and/or subthermal excitation at low column densities., Comment: Astronomy & Astrophysics in press

OH 231.8+4.2, a bipolar outflow around a Mira-type variable star, displays a unique molecular richness amongst circumstellar envelopes (CSEs) around O-rich AGB and post-AGB stars. We report line observations of the HCO+ and H13CO+ molecular ions and the first detection of SO+, N2H+, and (tentatively) H3O+ in this source. SO+ and H3O+ have not been detected before in CSEs around evolved stars. These data have been obtained as part of a full mm-wave and far-IR spectral line survey carried out with the IRAM 30 m radio telescope and with Herschel/HIFI. Except for H3O+, all the molecular ions detected in this work display emission lines with broad profiles (FWHM 50-90 km/s), which indicates that these ions are abundant in the fast bipolar outflow of OH 231.8. The narrow profile (FWHM 14 km/s) and high critical densities (>1e6cm-3 ) of the H3O+ transitions observed are consistent with this ion arising from denser, inner (and presumably warmer) layers of the fossil remnant of the slow AGB CSE at the core of the nebula. From rotational diagram analysis, we deduce excitation temperatures of Tex 10-20 K for all ions except for H3O+, which is most consistent with Tex 100 K. Although uncertain, the higher excitation temperature suspected for H3O+ is similar to that recently found for H2O and a few other molecules, which selectively trace a previously unidentified, warm nebular component.The column densities of the molecular ions reported here are in the range Ntot [1-8]x1e13 cm-2, leading to beam-averaged fractional abundances relative to H2 of X(HCO+) 1e-8, X(H13CO+) 2e-9, X(SO+) 4e-9, X(N2H+) 2e-9, and X(H3O+) 7e-9 cm-2. We have performed chemical kinetics models to investigate the formation of these ions in OH 231.8 as the result of standard gas phase reactions initiated by cosmic-ray and UV-photon ionization. (abridged)., Comment: 24 pages, 11 figures

We report the first detection of the J = 1 - 0 (102.6 GHz) rotational lines of CF+ (fluoromethylidynium ion) towards CygX-N63, a young and massive protostar of the Cygnus X region. This detection occurred as part of an unbiased spectral survey of this object in the 0.8-3 mm range, performed with the IRAM 30m telescope. The data were analyzed using a local thermodynamical equilibrium model (LTE model) and a population diagram in order to derive the column density. The line velocity (-4 km s-1) and line width (1.6 km s-1) indicate an origin from the collapsing envelope of the protostar. We obtain a CF+ column density of 4.10e11 cm-2. The CF+ ion is thought to be a good tracer for C+ and assuming a ratio of 10e-6 for CF+/C+, we derive a total number of C+ of 1.2x10e53 within the beam. There is no evidence of carbon ionization caused by an exterior source of UV photons suggesting that the protostar itself is the source of ionization. Ionization from the protostellar photosphere is not efficient enough. In contrast, X-ray ionization from the accretion shock(s) and UV ionization from outflow shocks could provide a large enough ionizing power to explain our CF+ detection. Surprisingly, CF+ has been detected towards a cold, massive protostar with no sign of an external photon dissociation region (PDR), which means that the only possibility is the existence of a significant inner source of C+. This is an important result that opens interesting perspectives to study the early development of ionized regions and to approach the issue of the evolution of the inner regions of collapsing envelopes of massive protostars. The existence of high energy radiations early in the evolution of massive protostars also has important implications for chemical evolution of dense collapsing gas and could trigger peculiar chemistry and early formation of a hot core., Comment: 6 pages

Water is a sensitive tracer of physical conditions in star-forming regions because of its large abundance variations between hot and cold regions. We use spectrally resolved observations of rotational lines of H$_2$O and its isotopologs with Herschel/HIFI to constrain the physical conditions of the water emitting region toward the high-mass protostar AFGL2591. We use analytical estimates and rotation diagrams to estimate T$_{ex}$ and column densities of H$_2$O of the envelope, the outflow, and a foreground cloud. Furthermore, we use the non-LTE radiative transfer code to estimate the temperature and volume density of the H$_2$O emitting gas. Assuming LTE, we estimate an T$_{ex}$ of 42 K and a column density of 2$\times$10$^{14}$ cm$^{-2}$ for the envelope and 45 K and 4$\times$10$^{13}$ cm$^{-2}$ for the outflow, in beams of 4" and 30", respectively. Non-LTE models indicate a kinetic temperature of 60-230 K and a volume density of 7$\times$10$^6$-10$^8$ cm$^{-3}$ for the envelope, and a kinetic temperature of 70-90 K and a gas density of 10$^7$-10$^8$ cm$^{-3}$ for the outflow. The o/p ratio of the foreground absorption is 1.9$\pm$0.4, suggesting a low temperature. In contrast, the o/p ratio seen in absorption by the outflow is 3.5$\pm$1.0, as expected for warm gas. The water abundance in the envelope is 10$^{-9}$, similar to the low values found for other high- and low-mass protostars, suggesting that this abundance is constant during the embedded phase of high-mass star formation. The water abundance in the outflow is 10$^{-10}$, which is 10$\times$ lower than in the envelope and in the outflows of high- and low-mass protostars. Since beam size effects can only increase this estimate by a factor of 2, we suggest that the water in the outflow is affected by dissociating UV radiation due to the low extinction in the outflow lobe., Comment: Accepted for publication in A&A

OH231.8+4.2 is a well studied O-rich CSE around an intermediate-mass evolved star that displays bipolar molecular outflows accelerated up to 400 km/s. OH231 also presents an exceptional molecular richness probably due to shock-induced chemical processes. We report the first detection in this source of HNCO, HNCS, HC3N and NO, with the IRAM-30m telescope in a sensitive mm-wavelength survey towards this target. HNCO and HNCS are also first detections in CSEs. The observed line profiles show that the emission arises in the massive central component of the envelope and at the base of the fast lobes. The NO profiles are broader than those of HNCO, HNCS, and HC3N, and most importantly, broader than the line profiles of 13CO. This indicates that the NO abundance is enhanced in the fast lobes relative to the slow, central parts. From LTE and non-LTE excitation analysis, we estimate beam-average rotational temperatures of 15-30 K (and, maybe, up to 55 K for HC3N) and fractional abundances of X(HNCO)=[0.8-1]E-7, X(HNCS)=[0.9-1]E-8, X(HC3N)=[5-7]E-9 and X(NO)=[1-2]E-6. NO is, therefore, amongst the most abundant N-bearing species in OH231. We have performed thermodynamical chemical equilibrium and chemical kinetics models to investigate the formation of these N-bearing species in OH231. The model underestimates the observed abundances for HNCO, HNCS, and HC3N by several orders of magnitude, which indicates that these molecules can hardly be products of standard UV-photon and/or cosmic-ray induced chemistry in OH231, and that other processes (e.g. shocks) play a major role in their formation. For NO, the model abundance is compatible with the observed average value. The new detections presented in this work corroborate the particularly rich chemistry of OH231, which is likely profoundly influenced by shock-induced processes, as proposed in earlier works., Comment: 22 pages, 14 figures. Published in A&A

Context: Outflows are an important part of the star formation process as both the result of ongoing active accretion and one of the main sources of mechanical feedback on small scales. Water is the ideal tracer of these effects because it is present in high abundance in various parts of the protostar. Method: We present \textit{Herschel} HIFI spectra of multiple water-transitions towards 29 nearby Class 0/I protostars as part of the WISH Survey. These are decomposed into different Gaussian components, with each related to one of three parts of the protostellar system; quiescent envelope, cavity shock and spot shocks in the jet and at the base of the outflow. We then constrain the excitation conditions present in the two outflow-related components. Results: Water emission is optically thick but effectively thin, with line ratios that do not vary with velocity, in contrast to CO. The physical conditions of the cavity and spot shocks are similar, with post-shock H$_{2}$ densities of order 10$^{5}-$10$^{8}$\,cm$^{-3}$ and H$_{2}$O column densities of order 10$^{16}-$10$^{18}$\,cm$^{-2}$. H$_{2}$O emission originates in compact emitting regions: for the spot shocks these correspond to point sources with radii of order 10-200\,AU, while for the cavity shocks these come from a thin layer along the outflow cavity wall with thickness of order 1-30\,AU. Conclusions: Water emission at the source position traces two distinct kinematic components in the outflow; J shocks at the base of the outflow or in the jet, and C shocks in a thin layer in the cavity wall. Class I sources have similar excitation conditions to Class 0 sources, but generally smaller line-widths and emitting region sizes. We suggest that it is the velocity of the wind driving the outflow, rather than the decrease in envelope density or mass, that is the cause of the decrease in H$_{2}$O intensity between Class 0 and I., Comment: Abstract is abridged. Accepted to Astronomy & Astrophysics. 50 pages (21 excluding appendices), 15 figures and 7 tables in the main paper, 18 figures and 10 tables in the appendices. Table 4 updated to Corrigendum version

Very long baseline interferometry at millimetre/submillimetre wavelengths (mmVLBI) offers the highest achievable spatial resolution at any wavelength in astronomy. The anticipated inclusion of ALMA as a phased array into a global VLBI network will bring unprecedented sensitivity and a transformational leap in capabilities for mmVLBI. Building on years of pioneering efforts in the US and Europe the ongoing ALMA Phasing Project (APP), a US-led international collaboration with MPIfR-led European contributions, is expected to deliver a beamformer and VLBI capability to ALMA by the end of 2014 (APP: Fish et al. 2013, arXiv:1309.3519). This report focuses on the future use of mmVLBI by the international users community from a European viewpoint. Firstly, it highlights the intense science interest in Europe in future mmVLBI observations as compiled from the responses to a general call to the European community for future research projects. A wide range of research is presented that includes, amongst others: - Imaging the event horizon of the black hole at the centre of the Galaxy - Testing the theory of General Relativity an/or searching for alternative theories - Studying the origin of AGN jets and jet formation - Cosmological evolution of galaxies and BHs, AGN feedback - Masers in the Milky Way (in stars and star-forming regions) - Extragalactic emission lines and astro-chemistry - Redshifted absorption lines in distant galaxies and study of the ISM and circumnuclear gas - Pulsars, neutron stars, X-ray binaries - Testing cosmology - Testing fundamental physical constants, Comment: Replaced figures 2 and 3: corrected position SRT. Corrected minor typo in 5.1

In order to study the ISM and the interplay between the atomic and molecular components in a low-metallicity environment, we present a complete high angular and spectral resolution map and data cube of the 12CO(2-1) emission from the Local Group galaxy M33. Its metallicity is roughly half-solar, such that we can compare its ISM with that of the Milky Way with the main changes being the metallicity and the gas mass fraction. The data have a 12" angular resolution (50pc) with a spectral resolution of 2.6 km/s and a mean noise level of 20 mK per channel in antenna temperature. A radial cut along the major axis was also observed in the 12CO(1-0) line. The CO data cube and integrated intensity map are optimal when using HI data to define the baseline window and the velocities over which the CO emission is integrated. Great care was taken when building these maps, testing different windowing and baseline options and investigating the effect of error beam pickup. The total CO(2-1) luminosity is 2.8e7 K km/s pc2, following the spiral arms in the inner disk. There is no clear variation in the CO(2-1/1-0) intensity ratio with radius and the average value is roughly 0.8. The total molecular gas mass is estimated, using a N(H2)/Ico(1-0)=4e20 cm-2/(K km/s) conversion factor, to be 3.1e8 Msol. The CO spectra in the cube were shifted to zero velocity by subtracting the velocity of the HI peak from the CO spectra. Hence, the velocity dispersion between the atomic and molecular components is extremely low, independently justifying the use of the HI line in building our maps. Stacking the spectra in concentric rings shows that the CO linewidth and possibly the CO-HI velocity dispersion decrease in the outer disk. Using the CO(2-1) emission to trace the molecular gas, the probability distribution function of the H2 column density shows an excess at high column density above a log normal distribution., Comment: 14 pages, 14 figures, 2 tables, Accepted for publication in Astronomy & Astrophysics

(Abridged) We study the response of the gas to energetic processes associated with high-mass star formation and compare it with studies on low- and intermediate-mass young stellar objects (YSOs) using the same methods. The far-IR line emission and absorption of CO, H$_2$O, OH, and [OI] reveals the excitation and the relative contribution of different species to the gas cooling budget. Herschel-PACS spectra covering 55-190 um are analyzed for ten high-mass star forming regions of various luminosities and evolutionary stages at spatial scales of ~10^4 AU. Radiative transfer models are used to determine the contribution of the envelope to the far-IR CO emission. The close environments of high-mass YSOs show strong far-IR emission from molecules, atoms, and ions. Water is detected in all 10 objects even up to high excitation lines. CO lines from J=14-13 up to typically 29-28 show a single temperature component, Trot~300 K. Typical H$_2$O temperatures are Trot~250 K, while OH has Trot~80 K. Far-IR line cooling is dominated by CO (~75 %) and to a smaller extent by OI (~20 %), which increases for the most evolved sources. H$_2$O is less important as a coolant for high-mass sources because many lines are in absorption. Emission from the envelope is responsible for ~45-85 % of the total CO luminosity in high-mass sources compared with only ~10 % for low-mass YSOs. The highest-J lines originate most likely from shocks, based on the strong correlation of CO and H$_2$O with physical parameters of the sources from low- to high-masses. Excitation of warm CO is very similar for all mass regimes, whereas H$_2$O temperatures are ~100 K higher for high-mass sources than the low-mass YSOs. Molecular cooling is ~4 times more important than cooling by [OI]. The total far-IR line luminosity is about 10$^{-3}$ and 10$^{-5}$ times lower than the dust luminosity for the low- and high-mass YSOs., Comment: 23 pages, 19 figures, 6 Tables. Accepted to Astronomy and Astrophysics

Aims. The aim of this paper is to study deuterated water in the solar-type protostars NGC1333 IRAS4A and IRAS4B, to compare their HDO abundance distribution with other star-forming regions, and to constrain their HDO/H2O ratios. Methods. Using the Herschel/HIFI instrument as well as ground-based telescopes, we observed several HDO lines covering a large excitation range (Eup/k=22-168 K) towards these protostars and an outflow position. Non-LTE radiative transfer codes were then used to determine the HDO abundance profiles in these sources. Results. The HDO fundamental line profiles show a very broad component, tracing the molecular outflows, in addition to a narrower emission component and a narrow absorbing component. In the protostellar envelope of NGC1333 IRAS4A, the HDO inner (T>100 K) and outer (T<100 K) abundances with respect to H2 are estimated at 7.5x10^{-9} and 1.2x10^{-11}, respectively, whereas, in NGC1333 IRAS4B, they are 1.0x10^{-8} and 1.2x10^{-10}, respectively. Similarly to the low-mass protostar IRAS16293-2422, an absorbing outer layer with an enhanced abundance of deuterated water is required to reproduce the absorbing components seen in the fundamental lines at 465 and 894 GHz in both sources. This water-rich layer is probably extended enough to encompass the two sources as well as parts of the outflows. In the outflows emanating from NGC1333 IRAS4A, the HDO column density is estimated at about (2-4)x10^{13} cm^{-2}, leading to an abundance of about (0.7-1.9)x10^{-9}. An HDO/H2O ratio between 7x10^{-4} and 9x10^{-2} is derived in the outflows. In the warm inner regions of these two sources, we estimate the HDO/H2O ratios at about 1x10^{-4}-4x10^{-3}. This ratio seems higher (a few %) in the cold envelope of IRAS4A, whose possible origin is discussed in relation to formation processes of HDO and H2O., Comment: 16 pages, 13 figures