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Metal-free, luminescent, carbogenic nanomaterials (LCNMs) constitute a novel class of optical materials with low environmental impact. LCNMs, e.g., carbon dots (CDs), graphitic carbon nitride (g-C 3 N 4 ), and carbonized polymer microspheres (CPM) show strong blue/cyan emissions, but rather weak yellow/red emission. This has been a serious drawback in applying them to light-emitting and bio-imaging applications. Here, by integrating single-component LCNMs in photonic microcavities, the study spectroscopically engineers the coupling between photonic modes in these microcavities and optical transitions to "reconfigure" the emission spectra of these luminescent materials. Resonant photons are confined in the microcavity, which allows selective re-excitation of phosphors to effectively emit down-converted photons. The down-converted photons re-excite the phosphors and are multiply recycled, leading to enhanced yellow/red emissions and resulting in white-light emission (WLE). Furthermore, by adjusting photonic stop bands of microcavity components, color adaptable (cool, pure, and warm) WLE is flexibly generated, which precisely follows the black-body Planckian locus in the chromaticity diagram. The proposed approach offers practical low-cost chromaticity-adjustable WLE from single-component, luminescent materials without any chemical or surface modification, or elaborate machinery and processing, paving the way for practical WLE devices., (© 2024 The Author(s). Advanced Science published by Wiley‐VCH GmbH.)

Light-element-based fluorescent materials, colloidal graphene quantum dots, and carbon dots (CDs) have sparked an immense amount of scientific interest in the past decade. However, a significant challenge in practical applications has emerged concerning the development of solid-state fluorescence (SSF) materials. This study addresses this knowledge gap by exploring the unexplored photonic facets of C-based solid-state microphotonic emitters. The proposed synthesis approach focuses on carbonized polymer microspheres (CPMs) instead of conventional nanodots. These microspheres exhibit remarkable SSF spanning the entire visible spectrum from blue to red. The highly spherical shape of CPMs imparts built-in photonic properties in addition to its intrinsic CD-based attributes. Leveraging their excitation-dependent photoluminescence property, these microspheres exhibit amplified spontaneous emission, assisted by the whispering gallery mode resonance across the visible spectral region. Remarkably, unlike conventional semiconductor quantum dots or dye-doped microresonators, this single microstructure showcases adaptable resonant emission without structural/chemical modifications. This distinctive attribute enables a plethora of applications, including microcavity-assisted energy transfer for white light emission, highly sensitive chemical sensing, and secure encrypted anticounterfeiting measures. This interdisciplinary approach, integrating photonics and chemistry, provides a robust solution for light-element-based SSF with inherent photonic functionality and wide-ranging applications.

Methanol steam reforming (MSR) is a promising reaction that enables efficient production and safe transportation of hydrogen, but it requires a relatively high temperature to achieve high activity, leading to large energy consumption. Here, we report a plasmonic ZnCu alloy catalyst, consisting of plasmonic Cu nanoparticles with surface-deposited Zn atoms, for efficient solar-driven MSR without additional thermal energy input. Experimental results and theoretical calculations suggest that Zn atoms act not only as the catalytic sites for water reduction with lower activation energy but also as the charge transfer channel, pumping hot electrons into water molecules and subsequently resulting in the formation of electron-deficient Cu for methanol activation. These merits together with photothermal heating render the optimal ZnCu catalyst a high H 2 production rate of 328 mmol g catalyst -1 h -1 with a solar energy conversion efficiency of 1.2% under 7.9 Suns irradiation, far exceeding the reported conventional photocatalytic and thermocatalytic MSR. This work provides a potential strategy for efficient solar-driven H 2 production and various other energy-demanding industrial reactions through designing alloy catalysts.

Coherent light sources providing sub-wavelength confined modes are in ever more demand to face new challenges in a variety of disciplines. Scalability and cost-effective production of these systems are also highly desired. The use of ferroelectrics in functional optical platforms, on which plasmonic arrangements can be formed, is revealed as a simple and powerful method to develop coherent light sources with improved and novel functionalities at the nanoscale. Two types of sources with sub-diffraction spatial confinement and improved performances are presented: i) plasmon-assisted solid-state nanolasers based on the interaction between metallic nanostructures and optically active rare earth doped ferroelectric crystals and ii) nonlinear radiation sources based on quadratic frequency mixing processes that are enhanced by means of localized surface plasmon (LSP) resonances. The mechanisms responsible for the intensification of the radiation-matter interaction processes by LSP resonances are discussed in each case. The challenges, potential applications, and future perspectives of the field are highlighted., (© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)