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A composite section, which reconstructs a continuous stratigraphic record from cores of multiple nearby holes, and its associated composite depth scale are important tools for analyzing sediment recovered from a drilling site. However, the standard technique for creating composite depth scales on drilling cruises does not correct for depth distortion within each core. Additionally, the splicing technique used to create composite sections often results in a 10-15% offset between composite depths and measured drill depths. We present a new automated compositing technique that better aligns stratigraphy across holes, corrects depth offsets, and could be performed aboard ship. By analyzing 618 cores from seven Ocean Drilling Program (ODP) sites, we estimate that ∼80% of the depth offset in traditional composite depth scales results from core extension during drilling and extraction. Average rates of extension are 12.4 ± 1.5% for calcareous and siliceous cores from ODP Leg 138 and 8.1 ± 1.1% for calcareous and clay-rich cores from ODP Leg 154. Also, average extension decreases as a function of depth in the sediment column, suggesting that elastic rebound is not the dominant extension mechanism. Copyright 2007 by the American Geophysical Union.

The investigation of triggers causing the onset and intensification of Northern Hemisphere Glaciation (NHG) during the late Pliocene is essential for understanding the global climate system, with important implications for projecting future climate changes. Despite their critical roles in the global climate system, influences of land-ocean interactions on high-latitude ice sheets remain largely unexplored. Here, we present a high-resolution Asian dust record from Ocean Drilling Program Site 1208 in the North Pacific, which lies along the main route of the westerlies. Our data indicate that atmosphere-land-ocean interactions affected aeolian dust emissions through modulating moisture and vegetation in dust source regions, highlighting a critical role of terrestrial systems in initiating the NHG as early as 3.6 Myr ago. Combined with additional multi-proxy and model results, we further show that westerly wind strength was enhanced, mainly at low-to-middle tropospheric levels, during major glacial events at about 3.3 and 2.7 Myr ago. We suggest that coupled responses of Earth's surface dynamics and atmospheric circulation in the Plio-Pleistocene likely involved feedbacks related to changes in paleogeography, ocean circulation, and global climate., (© 2024. The Author(s).)

The trigger, pace, and nature of the intensification of Northern Hemisphere Glaciation (iNHG) are uncertain, but can be probed by study of ODP Site 1208 North Pacific marine sediments. Herein, we present magnetic proxy data that indicate a 4-fold increase of dust between ~ 2.73 and ~ 2.72 Ma, with subsequent increases at the start of glacials thereafter, indicating a strengthening of the mid-latitude westerlies. Moreover, a permanent shift in dust composition after 2.72 Ma is observed, consistent with drier conditions in the source region and/or the incorporation of material which could not have been transported via the weaker Pliocene winds. The sudden increase in our dust proxy data, a coeval rapid rise in dust recorded by proxy dust data in the North Atlantic (Site U1313), and the Site 1208 shift in dust composition, suggest that the iNHG represents a permanent crossing of a climate threshold toward global cooling and ice sheet growth, ultimately driven by lower atmospheric CO 2 ., (© 2023. The Author(s).)

The Miocene Climatic Optimum (MCO) from ~17 to 14 million years ago (Ma) represents an enigmatic reversal in Cenozoic cooling. A synthesis of marine paleotemperature records shows that the MCO was a local maximum in global sea surface temperature superimposed on a period from at least 19 Ma to 10 Ma, during which global temperatures were on the order of 10°C warmer than at present. Our high-resolution global reconstruction of ocean crustal production, a proxy for tectonic degassing of carbon, suggests that crustal production rates were ~35% higher than modern rates until ~14 Ma, when production began to decline steeply along with global temperatures. The magnitude and timing of the inferred changes in tectonic degassing can account for the majority of long-term ice sheet and global temperature evolution since 20 Ma.

Alkenones are biomarkers produced solely by algae in the order Isochrysidales that have been used to reconstruct sea surface temperature (SST) since the 1980s. However, alkenone-based SST reconstructions in the northern high latitude oceans show significant bias towards warmer temperatures in core-tops, diverge from other SST proxies in down core records, and are often accompanied by anomalously high relative abundance of the C 37 tetra-unsaturated methyl alkenone (%C 37:4 ). Elevated %C 37:4 is widely interpreted as an indicator of low sea surface salinity from polar water masses, but its biological source has thus far remained elusive. Here we identify a lineage of Isochrysidales that is responsible for elevated C 37:4 methyl alkenone in the northern high latitude oceans through next-generation sequencing and lab-culture experiments. This Isochrysidales lineage co-occurs widely with sea ice in marine environments and is distinct from other known marine alkenone-producers, namely Emiliania huxleyi and Gephyrocapsa oceanica. More importantly, the %C 37:4 in seawater filtered particulate organic matter and surface sediments is significantly correlated with annual mean sea ice concentrations. In sediment cores from the Svalbard region, the %C 37:4 concentration aligns with the Greenland temperature record and other qualitative regional sea ice records spanning the past 14 kyrs, reflecting sea ice concentrations quantitatively. Our findings imply that %C 37:4 is a powerful proxy for reconstructing sea ice conditions in the high latitude oceans on thousand- and, potentially, on million-year timescales.

The prevailing mid-latitude westerly winds, known as the westerlies, are a fundamental component of the climate system because they have a crucial role in driving surface ocean circulation 1 and modulating air-sea heat, momentum and carbon exchange 1-3 . Recent work suggests that westerly wind belts are migrating polewards in response to anthropogenic forcing 4,5 . Reconstructing the westerlies during past warm periods such as the Pliocene epoch, in which atmospheric carbon dioxide (CO 2 ) was about 350 to 450 parts per million 6 and temperatures were about 2 to 4 degrees Celsius higher than today 7 , can improve our understanding of changes in the position and strength of these wind systems as the climate continues to warm. Here we show that the westerlies were weaker and more poleward during the warm Pliocene than during glacial periods after the intensification of Northern Hemisphere glaciation (iNHG), which occurred around 2.73 million years ago 8 . Our results, which are based on dust and export productivity reconstructions, indicate that major ice sheet development during the iNHG was accompanied by substantial increases in dust fluxes in the mid-latitude North Pacific Ocean, especially compared to those in the subarctic North Pacific. Following this shift, changes in dust and productivity largely track the glacial-interglacial cycles of the late Pliocene and early Pleistocene epochs. On the basis of this pattern, we infer that shifts in the westerlies were primarily driven by variations in Plio-Pleistocene thermal gradients and ice volume. By combining this relationship with other dust records 9-11 and climate modelling results 12 , we find that the proposed changes in the westerlies were globally synchronous. If the Pliocene is predictive of future warming, we posit that continued poleward movement and weakening of the present-day westerlies in both hemispheres can be expected.

The timing and mechanisms of the eastern equatorial Pacific (EEP) cold tongue development, a salient feature of the tropical ocean, are intensely debated on geological time scales. Here, we reconstruct cold tongue evolution over the past 8 million years by computing changes in temperature gradient between the cold tongue and eastern Pacific warm pool. Results indicate that the cold tongue remained very weak between 8 and 4.3 million years ago, implying much weaker zonal temperature gradients prevailing during the late Miocene-Pliocene, but then underwent gradual intensification with apparently increasing sensitivity of the cold tongue to extratropical temperature changes. Our results reveal that the EEP cold tongue intensification was mainly controlled by extratropical climate.

Determining the timing and amplitude of tropical sea surface temperature (SST) change is an important part of solving the puzzle of the Plio-Pleistocene ice ages. Alkenone-based tropical SST records from the major ocean basins show coherent glacial-interglacial temperature changes of 1 degrees to 3 degrees C that align with (but slightly lead) global changes in ice volume and deep ocean temperature over the past 3.5 million years. Tropical temperatures became tightly coupled with benthic delta18O and orbital forcing after 2.7 million years. We interpret the similarity of tropical SST changes, in dynamically dissimilar regions, to reflect "top-down" forcing through the atmosphere. The inception of a strong carbon dioxide-greenhouse gas feedback and amplification of orbital forcing at approximately 2.7 million years ago connected the fate of Northern Hemisphere ice sheets with global ocean temperatures since that time.

The Pliocene warm interval has been difficult to explain. We reconstructed the latitudinal distribution of sea surface temperature around 4 million years ago, during the early Pliocene. Our reconstruction shows that the meridional temperature gradient between the equator and subtropics was greatly reduced, implying a vast poleward expansion of the ocean tropical warm pool. Corroborating evidence indicates that the Pacific temperature contrast between the equator and 32 degrees N has evolved from approximately 2 degrees C 4 million years ago to approximately 8 degrees C today. The meridional warm pool expansion evidently had enormous impacts on the Pliocene climate, including a slowdown of the atmospheric Hadley circulation and El Niño-like conditions in the equatorial region. Ultimately, sustaining a climate state with weak tropical sea surface temperature gradients may require additional mechanisms of ocean heat uptake (such as enhanced ocean vertical mixing).

Hydrogen isotope ratios (2H/H or D/H) of long-chain unsaturated ketones (alkenones) preserved in lake and marine sediments hold great promise for paleoclimate studies. However, compound-specific hydrogen isotope analysis of individual alkenones has not been possible due to chromatographic coelution of alkenones with the same carbon chain length but different numbers of double bonds. Published studies have only reported the deltaD values of the mixture of coeluting alkenones. We developed an efficient procedure to isolate individual alkenones based on double-bond numbers using silica gel impregnated with silver nitrate. The chromatographic procedure is simple, inexpensive, and highly reproducible, offers 87-100% sample recovery, and allows for the first time hydrogen isotopic measurement on individual alkenones. deltaD values of specific di-, tri- and tetraunsaturated C37 alkenones produced by an Emiliania huxleyi culture, as well as those isolated from Greenland lake sediments, differ consecutively by 43-65 per thousand. These findings suggest that alkenones with different numbers of carbon-carbon double bonds express significantly different deltaD values and that coelution of different alkenones may lead to erroneous source water deltaD reconstructions. Our alkenone isolation approach opens a new avenue for paleoclimate reconstructions using hydrogen isotope ratios of individual alkenones.

A tropical Pacific climate state resembling that of a permanent El Niño is hypothesized to have ended as a result of a reorganization of the ocean heat budget approximately 3 million years ago, a time when large ice sheets appeared in the high latitudes of the Northern Hemisphere. We report a high-resolution alkenone reconstruction of conditions in the heart of the eastern equatorial Pacific (EEP) cold tongue that reflects the combined influences of changes in the equatorial thermocline, the properties of the thermocline's source waters, atmospheric greenhouse gas content, and orbital variations on sea surface temperature (SST) and biological productivity over the past 5 million years. Our data indicate that the intensification of Northern Hemisphere glaciation approximately 3 million years ago did not interrupt an almost monotonic cooling of the EEP during the Plio-Pleistocene. SST and productivity in the eastern tropical Pacific varied in phase with global ice volume changes at a dominant 41,000-year (obliquity) frequency throughout this time. Changes in the Southern Hemisphere most likely modulated most of the changes observed.

Many records of tropical sea surface temperature and marine productivity exhibit cycles of 23 kyr (orbital precession) and 100 kyr during the past 0.5 Myr (refs 1-5), whereas high-latitude sea surface temperature records display much more pronounced obliquity cycles at a period of about 41 kyr (ref. 6). Little is known, however, about tropical climate variability before the mid-Pleistocene transition about 900 kyr ago, which marks the change from a climate dominated by 41-kyr cycles (when ice-age cycles and high-latitude sea surface temperature variations were dictated by changes in the Earth's obliquity) to the more recent 100-kyr cycles of ice ages. Here we analyse alkenones from marine sediments in the eastern equatorial Pacific Ocean to reconstruct sea surface temperatures and marine productivity over the past 1.8 Myr. We find that both records are dominated by the 41-kyr obliquity cycles between 1.8 and 1.2 Myr ago, with a relatively small contribution from orbital precession, and that early Pleistocene sea surface temperatures varied in the opposite sense to local annual insolation in the eastern equatorial Pacific Ocean. We conclude that during the early Pleistocene epoch, climate variability at our study site must have been determined by high-latitude processes that were driven by orbital obliquity forcing.

Time series of alkenone unsaturation indices gathered along the California margin reveal large (4 degrees to 8 degrees C) glacial-interglacial changes in sea surface temperature (SST) over the past 550,000 years. Interglacial times with SSTs equal to or exceeding that of the Holocene contain peak abundances in the pollen of redwood, the distinctive component of the temperate rainforest of the northwest coast of California. In the region now dominated by the California Current, SSTs warmed 10,000 to 15,000 years in advance of deglaciation at each of the past five glacial maxima. SSTs did not rise in advance of deglaciation south of the modern California Current front. Glacial warming along the California margin therefore is a regional signal of the weakening of the California Current during times when large ice sheets reorganized wind systems over the North Pacific. Both the timing and magnitude of the SST estimates suggest that the Devils Hole (Nevada) calcite record represents regional but not global paleotemperatures, and hence does not pose a fundamental challenge to the orbital ("Milankovitch") theory of the Ice Ages.

Pacing of the marine carbon cycle by orbital forcing during the Pliocene and Pleistocene Ice Ages [past 2.5 million years (Myr)] is well known. As older deep-sea sediment records are being studied at greater temporal resolution, it is becoming clear that similar fluctuations in the marine carbon system have occurred throughout the late Mesozoic and Tertiary, despite the absence of large continental ice sheets over much of this time. Variations in both the organic and the calcium carbonate components of the marine carbon system seem to have varied cyclically in response to climate forcing, and carbon and carbonate time series appear to accurately characterize the frequency spectrum of ancient climatic change. For the past 35 Myr, much of the variance in carbonate content carries the "polar" signal of obliquity [41,000 years (41 kyr)] forcing. Over the past 125 Myr, there is evidence from marine sediments of the continued role of precessional (approximately 21 kyr) climatic cycles. Repeat patterns of sedimentation at about 100, 400, and 2,400 kyr, the modulation periods of precession, persistently enter into marine carbon cycle records as well. These patterns suggest a nonlinear response of climate and/or the sedimentation of organic carbon and carbonates to precessional orbital perturbations. Nonlinear responses of the carbon system may help to amplify relatively weak orbital insolation anomalies into more significant climatic perturbations through positive feedback effects. Nonlinearities in the carbon cycle may have transformed orbital-climatic cycles into long-wavelength features on time scales comparable to the residence times of carbon and nutrient elements in the ocean.