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We present results on simultaneous observations of Class~I methanol masers at 25, 36, and 44 GHz towards 22 Galactic targets carried out with the Effelsberg 100-m telescope. The study investigates relations between the hyperfine (HF) structure of the torsion-rotation transitions in CH3OH and maser activity. By analyzing the radial velocity shifts between different maser lines together with the patterns of the HF structure based on laboratory measurements and quantum-chemical calculations, we find that in any source only one specific HF transition forms the maser emission and that this transition changes from source to source. The physical conditions leading to this selective behavior are still unclear. Using accurate laboratory rest frequencies for the 25 GHz transitions, we have refined the centre frequencies for the HF multiplets at 36, 44, and 95 GHz: f_36 = (36169.2488 +/- 0.0002_stat +/- 0.0004_sys) MHz. f_44 = (44069.4176 +/- 0.0002_stat +/- 0.0004_sys) MHz, and f_95 = (95169.4414 +/- 0.0003_stat +/- 0.0004_sys) MHz. Comparison with previous observations of 44 GHz masers performed 6-10 years ago with a Korean 21-m KVN telescope towards the same targets confirms the kinematic stability of Class~I maser line profiles during this time interval and reveals a systematic radial velocity shift of 0.013 +/- 0.005 km/s between the two telescopes., Comment: 24 pages, 8 figures, 9 tables; accepted for publication in MNRAS

The nitrogen isotope ratio 14N/15N is a powerful tool to trace Galactic stellar nucleosynthesis and constraining Galactic chemical evolution. Previous observations have found lower 14N/15N ratios in the Galactic center and higher values in the Galactic disk. This is consistent with the inside-out formation scenario of our Milky Way. However, previous studies mostly utilized double isotope ratios also including 12C/13C, which introduces additional uncertainties. Here we therefore present observations of C14N and its rare isotopologue, C15N, toward a sample of star forming regions, measured by the IRAM 30 m and/or the ARO 12 m telescope at $\lambda$ ~3 mm wavelength. For those 35 sources detected in both isotopologues, physical parameters are determined. Furthermore we have obtained nitrogen isotope ratios using the strongest hyperfine components of CN and C15N. For those sources showing small deviations from Local Thermodynamical Equilibrium and/or self-absorption, the weakest hyperfine component, likely free of the latter effect, was used to obtain reliable 14N/15N values. Our measured 14N/15N isotope ratios from C14N and C15N measurements are compatible with those from our earlier measurements of NH3 and 15NH3 (Paper I), i.e., increasing ratios to a Galacticentric distance of ~9 kpc. The unweighted second order polynomial fit yields $\frac{{\rm C^{14}N}}{{\rm C^{15}N}} = (-4.85 \pm 1.89)\;{\rm kpc^{-2}} \times R_{\rm GC}^{2} + (82.11 \pm 31.93) \;{\rm kpc^{-1}} \times R_{\rm GC} - (28.12 \pm 126.62)$. Toward the outer galaxy, the isotope ratio tends to decrease, supporting an earlier finding by H13CN/HC15N. Galactic chemical evolution models are consistent with our measurements of the 14N/15N isotope ratio, i.e. a rising trend from the Galactic center region to approximately 9 kpc, followed by a decreasing trend with increasing $R_{\rm GC}$ toward the outer Galaxy., Comment: 34 pages, 9 figures, 6 tables

The kinetic temperature structure of the massive filament DR21 has been mapped using the IRAM 30 m telescope. This mapping employed the para-H$_2$CO triplet ($J_{\rm K_aK_c}$ = 3$_{03}$--2$_{02}$, 3$_{22}$--2$_{21}$, and 3$_{21}$--2$_{20}$) on a scale of $\sim$0.1 pc. By modeling the averaged line ratios of para-H$_{2}$CO with RADEX under non-LTE assumptions, the kinetic temperature of the dense gas was derived at a density of $n$(H$_{2}$) = 10$^{5}$ cm$^{-3}$. The para-H$_2$CO lines reveal significantly higher temperatures than NH$_3$ (1,1)/(2,2) and FIR wavelengths. The dense clumps appear to correlate with the notable kinetic temperature. Among the four dense cores (N44, N46, N48, and N54), temperature gradients are observed on a scale of $\sim$0.1-0.3 pc. This suggests that the warm dense gas is influenced by internal star formation activity. With the exception of N54, the temperature profiles of these cores were fitted with power-law indices ranging from $-$0.3 to $-$0.5. This indicates that the warm dense gas is heated by radiation emitted from internally embedded protostar(s) and/or clusters. While there is no direct evidence supporting the idea that the dense gas is heated by shocks resulting from a past explosive event in the DR21 region, our measurements toward the DR21W1 region provide compelling evidence that the dense gas is indeed heated by shocks originating from the western DR21 flow. Higher temperatures appear to be associated with turbulence. The physical parameters of the dense gas in the DR21 filament exhibit a remarkable similarity to the results obtained in OMC-1 and N113. This may imply that the physical mechanisms governing the dynamics and thermodynamics of dense gas traced by H$_{2}$CO in diverse star formation regions may be dominated by common underlying principles despite variations in specific environmental conditions. (abbreviated), Comment: 16 pages, 8 figures, 3 tabels. Accepted for publication by Astronomy & Astrophysics

Sulphur-bearing species are detected in various environments within Galactic star-forming regions and are particularly abundant in the gas phase of outflows and shocks, and photo-dissociation regions. In this work, we aim to investigate the nature of the emission from the most common sulphur-bearing species observable at millimetre wavelengths towards the nuclear starburst of the galaxy NGC 253. We intend to understand which type of regions are probed by sulphur-bearing species and which process(es) dominate(s) the release of sulphur into the gas phase. We used the high-angular resolution (1.6" or 27 pc) observations from the ALCHEMI ALMA Large Program to image several sulphur-bearing species towards the central molecular zone (CMZ) of NGC 253. We performed local thermodynamic equilibrium (LTE) and non-LTE large velocity gradient (LVG) analyses to derive the physical conditions of the gas in which S-bearing species are emitted, and their abundance ratios across the CMZ. Finally, we compared our results with previous ALCHEMI studies and a few selected Galactic environments. We found that not all sulphur-bearing species trace the same type of gas: strong evidence indicates that H2S and part of the emission of OCS, H2CS, and SO, are tracing shocks whilst part of SO and CS emission rather trace the dense molecular gas. For some species, such as CCS and SO2, we could not firmly conclude on their origin of emission. The present analysis indicates that the emission from most sulphur-bearing species throughout the CMZ is likely dominated by shocks associated with ongoing star formation. In the inner part of the CMZ where the presence of super star clusters was previously indicated, we could not distinguish between shocks or thermal evaporation as the main process releasing the S-bearing species., Comment: 44 pages, 20 figures, Accepted for publication in A&A

We present the results of a search for ammonia maser emission in 119 Galactic high-mass star-forming regions (HMSFRs) known to host 22 GHz H$_2$O maser emission. Our survey has led to the discovery of non-metastable NH$_3$ inversion line masers toward 14 of these sources. This doubles the number of known non-metastable ammonia masers in our Galaxy, including nine new very high excitation ($J,K$)~=~(9,6) maser sources. These maser lines, including NH$_3$ (5,4), (6,4), (6,5), (7,6), (8,6), (9,6), (9,8), (10,8), and (11,9), arise from energy levels of 342 K, 513 K, 465 K, 606 K, 834 K, 1090 K, 942 K, 1226 K, and 1449 K above the ground state. Additionally, we tentatively report a new metastable NH$_3$ (3,3) maser in G048.49 and an NH$_3$ (7,7) maser in G029.95. Our observations reveal that all of the newly detected NH$_3$ maser lines exhibit either blueshifted or redshifted velocities with respect to the source systemic velocities. Among the non-metastable ammonia maser lines, larger velocity distributions, offset from the source systemic velocities, are found in the ortho-NH$_3$ ($K=3n$) than in the para-NH$_3$ ($K\neq3n$) transitions., Comment: 14 pages, 4 tables, 9 figures. Accepted for publication in A&A

How galaxies regulate nuclear growth through gas accretion by supermassive black holes (SMBHs) is one of the most fundamental questions in galaxy evolution. One potential way to regulate nuclear growth is through a galactic wind that removes gas from the nucleus. It is unclear whether galactic winds are powered by jets, mechanical winds, radiation, or via magnetohydrodynamic (MHD) processes. Compact obscured nuclei (CONs) represent a significant phase of galactic nuclear growth. These galaxies hide growing SMBHs or unusual starbursts in their very opaque, extremely compact (r $<$ 100 pc) centres. They are found in approximately 30 % of the luminous and ultra-luminous infrared galaxy (LIRG and ULIRG) population. Here, we present high-resolution ALMA observations ($\sim$30 mas, $\sim$5 pc) of ground-state and vibrationally excited HCN towards ESO 320-G030 (IRAS 11506-3851). ESO 320-G030 is an isolated luminous infrared galaxy known to host a compact obscured nucleus and a kiloparsec-scale molecular wind. Our analysis of these high-resolution observations excludes the possibility of a starburst-driven wind, a mechanically or energy driven active galactic nucleus (AGN) wind, and exposes a molecular MDH wind. These results imply that the nuclear evolution of galaxies and the growth of SMBHs are similar to the growth of hot cores or protostars where gravitational collapse of the nuclear torus drives a MHD wind. These results mean galaxies are capable, in part, of regulating the evolution of their nuclei without feedback., Comment: 9 pages, 10 figures

The interstellar medium in the Milky Way's Central Molecular Zone (CMZ) is known to be strongly magnetised, but its large-scale morphology and impact on the gas dynamics are not well understood. We explore the impact and properties of magnetic fields in the CMZ using three-dimensional non-self gravitating magnetohydrodynamical simulations of gas flow in an external Milky Way barred potential. We find that: (1) The magnetic field is conveniently decomposed into a regular time-averaged component and an irregular turbulent component. The regular component aligns well with the velocity vectors of the gas everywhere, including within the bar lanes. (2) The field geometry transitions from parallel to the Galactic plane near $z=0$ to poloidal away from the plane. (3) The magneto-rotational instability (MRI) causes an in-plane inflow of matter from the CMZ gas ring towards the central few parsecs of $0.01-0.1$ M$_\odot$ yr$^{-1}$ that is absent in the unmagnetised simulations. However, the magnetic fields have no significant effect on the larger-scale bar-driven inflow that brings the gas from the Galactic disc into the CMZ. (4) A combination of bar inflow and MRI-driven turbulence can sustain a turbulent vertical velocity dispersion of $\sigma_z \simeq 5$ km s$^{-1}$ on scales of $20$ pc in the CMZ ring. The MRI alone sustains a velocity dispersion of $\sigma_z \simeq 3$ km s$^{-1}$. Both these numbers are lower than the observed velocity dispersion of gas in the CMZ, suggesting that other processes such as stellar feedback are necessary to explain the observations. (5) Dynamo action driven by differential rotation and the MRI amplifies the magnetic fields in the CMZ ring until they saturate at a value that scales with the average local density as $B \simeq 102 (n/10^3 cm^{-3})^{0.33}$ $\mu$G. Finally, we discuss the implications of our results within the observational context in the CMZ.

Compact obscured nuclei (CONs) are an extremely obscured (N$_{H2}$ >10$^{25}$ cm$^{-2}$) class of galaxy nuclei thought to exist in 20-40 per cent of nearby (ultra-)luminous infrared galaxies. While they have been proposed to represent a key phase of the active galactic nucleus (AGN) feedback cycle, the nature of these CONs - what powers them, their dynamics, and their impact on the host galaxy - remains unknown. This work analyses the large-scale optical properties of the local CON, NGC4418 (z=0.00727). We present new, targeted integral field unit observations of the galaxy with the Multi-Unit Spectroscopic Explorer (MUSE). For the first time, we map the ionised and neutral gas components of the galaxy, along with their dynamical structure, to reveal several previously unknown features of the galaxy. We confirm the presence of a previously postulated blueshifted outflow along the minor axis of NGC4418. We find this outflow to be decelerating and, for the first time, show it to extend bilaterally from the nucleus. We report the discovery of two further outflow structures: a redshifted southern outflow connected to a tail of ionised gas surrounding the galaxy and a blueshifted bubble to the north. In addition to these features, we find the [OIII] emission reveals the presence of knots across the galaxy, which are consistent with regions of the galaxy that have been photoionised by an AGN. Based on the properties of these features, we conclude that the CON in NGC4418 is most likely powered by AGN activity., Comment: 17 pages, 15 figures, accepted to A&A

Nuclear regions of ultraluminous and luminous infrared galaxies (U/LIRGs) are powered by starbursts and/or active galactic nuclei (AGNs). These regions are often obscured by extremely high columns of gas and dust. Molecular lines in the submillimeter windows have the potential to determine the physical conditions of these compact obscured nuclei (CONs). We aim to reveal the distributions of HCN and HCO$^+$ emission in local U/LIRGs and investigate whether and how they are related to galaxy properties. Using ALMA, we have conducted sensitive observations of the HCN J=3--2 and HCO$^+$ J=3--2 lines toward 23 U/LIRGs in the local Universe (z < 0.07) with a spatial resolution of ~0.3" (~50--400 pc). We detected both HCN and HCO$^+$ in 21 galaxies, only HCN in one galaxy, and neither in one galaxy. The global HCN/HCO$^+$ line ratios, averaged over scales of ~0.5--4 kpc, range from 0.4 to 2.3, with an unweighted mean of 1.1. These line ratios appear to have no systematic trend with bolometric AGN luminosity or star formation rate. The line ratio varies with position and velocity within each galaxy, with an average interquartile range of 0.38 on a spaxel-by-spaxel basis. In eight out of ten galaxies known to have outflows and/or inflows, we found spatially and kinematically symmetric structures of high line ratios. These structures appear as a collimated bicone in two galaxies and as a thin spherical shell in six galaxies. Non-LTE analysis suggests that the high HCN/HCO$^+$ line ratio in outflows is predominantly influenced by the abundance ratio. Chemical model calculations indicate that the enhancement of HCN abundance in outflows is likely due to high-temperature chemistry triggered by shock heating. These results imply that the HCN/HCO$^+$ line ratio can aid in identifying the outflow geometry when the shock velocity of the outflows is sufficiently high to heat the gas., Comment: 52 pages, 35 figures, accepted for publication in Astronomy & Astrophysics

Determining the evolution of the CNO isotopes in the interstellar medium (ISM) of starburst galaxies can yield important constraints on the ages of superstar clusters (SSCs), or on other aspects and contributing factors of their evolution. Due to the time-dependent nature of the abundances of isotopes within the ISM as they are supplied from processes such as nucleosynthesis or chemical fractionation, this provides the possible opportunity to probe the ability of isotopes ratios to trace the ages of high star forming regions, such as SSCs. The goal of this study is to investigate whether the isotopic variations in SSC regions within NGC253 are correlated with their different ages as derived from stellar population modelling. We have measured abundance ratios of CO, HCN and HCO$^+$ isotopologues in six regions containing SSCs within NGC253 using high spatial resolution (1.6",$\sim 28$pc) data from the ALCHEMI (ALma Comprehensive High-resolution Extragalactic Molecular Inventory) ALMA Large program. We have then analysed these ratios using RADEX radiative transfer modelling, with the parameter space sampled using the nested sampling Monte Carlo algorithm MLFriends. These abundance ratios were then compared to ages predicted in each region via the fitting of observed star formation tracers (such as Br$\gamma$) to starburst stellar population evolution models. We do not find any significant trend with age for the CO and HCN isotopologue ratios on the timescales for the ages of the SSC* regions observed. The driving factors of these ratios within SSCs could be the Initial Mass Function as well as possibly fractionation effects. To further probe these effects in SSCs over time a larger sample of SSCs must be observed spanning a larger age range., Comment: 44 pages, 43 Figures, Accepted for Publication to A&A

High precision mapping of H2O megamaser emission from active galaxies has revealed more than a dozen Keplerian H2O maser disks, which enable a ~4% uncertainty estimate of the Hubble constant as well as providing accurate masses for the central black holes. These disks often have well-defined inner and outer boundaries of maser emission on sub-parsec scales. In order to better understand the physical conditions that determine the inner and outer radii of a maser disk, we examine the distributions of gas density and X-ray heating rate in a warped molecular disk described by a power-law surface density profile. For a suitable choice of the disk mass, we find that the outer radius R_out of the maser disk predicted from our model can match the observed value, with R_out mainly determined by the maximum heating rate or the minimum density for efficient maser action, depending on the combination of the Eddington ratio, black hole mass, and disk mass. Our analysis also indicates that the inner radius for maser action is comparable to the dust sublimation radius, suggesting that dust may play a role in determining the inner radius of a maser disk. Finally, our model predicts that H2O gigamaser disks could exist at the centers of high-z quasars, with disk sizes of >~ 10-30 pc., Comment: Accepted by MNRAS, 17 pages, 8 figures, 2 tables

To investigate the relative amount of ejecta from high-mass versus intermediate-mass stars and to trace the chemical evolution of the Galaxy, we have performed with the IRAM 30m and the SMT 10m telescopes a systematic study of Galactic interstellar 18O/17O ratios toward a sample of 421 molecular clouds, covering a galactocentric distance range of 1-22 kpc. The results presented in this paper are based on the J=2-1 transition and encompass 364 sources showing both C18O and C17O detections. The previously suggested 18O/17O gradient is confirmed. For the 41 sources detected with both facilities, good agreement is obtained. A correlation of 18O/17O ratios with heliocentric distance is not found, indicating that beam dilution and linear beam sizes are not relevant. For the subsample of IRAM 30 m high-mass star-forming regions with accurate parallax distances, an unweighted fit gives 18O/17O = (0.12+-0.02)R_GC+(2.38+-0.13) with a correlation coefficient of R = 0.67. While the slope is consistent with our J=1-0 measurement, ratios are systematically lower. This should be caused by larger optical depths of C18O 2-1 lines, w.r.t the corresponding 1-0 transitions, which is supported by RADEX calculations and the fact that C18O/C17O is positively correlated with 13CO/C18O. After considering optical depth effects with C18O J=2-1 reaching typically an optical depth of 0.5, corrected 18O/17O ratios from the J=1-0 and J=2-1 lines become consistent. A good numerical fit to the data is provided by the MWG-12 model, including both rotating stars and novae., Comment: 17 pages, 11 figures, published in ApJS

We use spectra and maps of the $J=1-0$ and $J=2-1$ DCO$^{+}$, DCN, DNC, $\rm N_2D^+$ lines and $1_{11}-1_{01}$ ortho- and para-NH$_{2}$D lines, obtained with the IRAM-30m telescope, as well as observations of their hydrogenated isotopologues to study deuteration processes in five high-mass star-forming regions. The temperature was estimated from CH$_3$CCH lines, also observed with the IRAM-30m telescope, and from NH$_3$ lines, observed with the 100-m radio telescope in Effelsberg, as well as using the integrated intensity ratios of the $J=1-0$ H$^{13}$CN and HN$^{13}$C lines and their main isotopologues. Applying a non-LTE radiative transfer model with RADEX, the gas density and the molecular column densities were estimated. D/H ratios are $0.001-0.05$ for DCO$^{+}$, $0.001-0.02$ for DCN, $0.001-0.05$ for DNC and $0.02-0.4$ for NH$_{2}$D. The D/H ratios decrease with increasing temperature in the range of $\rm 20-40 \,K$ and slightly vary at densities $n(\rm H_2) \sim 10^4-10^6\, cm^{-3}$. The deuterium fraction of $\rm N_2H^{+}$ is $0.008-0.1$ at temperatures in the range of $\rm 20-25\, K$ and at a density of $\sim 10^5\, \rm cm^{-3}$. We also estimate relative abundances and find $ \sim 10^{-11}-10^{-9}$ for DCO$^{+}$ and DNC, $ \sim 10^{-11}-10^{-10}$ for $\rm N_2D^+$ and $ \sim 10^{-10}-10^{-8}$ for NH$_{2}$D. The relative abundances of these species decrease with increasing temperature. However, the DCN/H$_2$ ratio is almost constant ($\sim 10^{-10}$). The observational results agree with the predictions of chemical models (although in some cases there are significant differences)., Comment: 13 pages + appendix (25 pages total), 11 figures. Accepted for publication in MNRAS

Sulfur isotope ratios have emerged as a promising tool for tracing stellar nucleosynthesis, quantifying stellar populations, and investigating the chemical evolution of galaxies. While extensively studied in the Milky Way, in extragalactic environments they remain largely unexplored. We focus on investigating the sulfur isotope ratios in the Large Magellanic Cloud (LMC) to gain insights into sulfur enrichment in this nearby system and to establish benchmarks for such ratios in metal-poor galaxies. We conducted pointed observations of CS and its isotopologues toward N113, one of the most prominent star-formation regions in the LMC, utilizing the Atacama Pathfinder EXperiment 12~m telescope. We present the first robust detection of C$^{33}$S in the LMC by successfully identifying two C$^{33}$S transitions on a large scale of $\sim$5 pc. Our measurements result in an accurate determination of the $^{34}$S/$^{33}$S isotope ratio, which is 2.0$\pm$0.2. Our comparative analysis indicates that the $^{32}$S/$^{33}$S and $^{34}$S/$^{33}$S isotope ratios are about a factor of 2 lower in the LMC than in the Milky Way. Our findings suggest that the low $^{34}$S/$^{33}$S isotope ratio in the LMC can be attributed to a combination of the age effect, low metallicity, and star formation history., Comment: 6 pages, 1 figures, 2 tables, accepted for publication in A&A, adjusted to the final version

Protonated hydrogen cyanide, HCNH$^{+}$, plays a fundamental role in astrochemistry because it is an intermediary in gas-phase ion-neutral reactions within cold molecular clouds. However, the impact of the environment on the chemistry of HCNH$^{+}$ remains poorly understood. With the IRAM-30 m and APEX-12 m observations, we report the first robust distribution of HCNH$^{+}$ in the Serpens filament and in Serpens South. Our data suggest that HCNH$^{+}$ is abundant in cold and quiescent regions, but is deficit in active star-forming regions. The observed HCNH$^{+}$ fractional abundances relative to H$_{2}$ range from $3.1\times 10^{-11}$ in protostellar cores to $5.9\times 10^{-10}$ in prestellar cores, and the HCNH$^{+}$ abundance generally decreases with increasing H$_{2}$ column density, which suggests that HCNH$^{+}$ coevolves with cloud cores. Our observations and modeling results suggest that the abundance of HCNH$^{+}$ in cold molecular clouds is strongly dependent on the H$_{2}$ number density. The decrease in the abundance of HCNH$^{+}$ is caused by the fact that its main precursors (e.g., HCN and HNC) undergo freeze-out as the number density of H$_{2}$ increases. However, current chemical models cannot explain other observed trends, such as the fact that the abundance of HCNH$^{+}$ shows an anti-correlation with that of HCN and HNC, but a positive correlation with that of N$_{2}$H$^{+}$ in the southern part of the Serpens South northern clump. This indicates that additional chemical pathways have to be invoked for the formation of HCNH$^{+}$ via molecules like N$_{2}$ in regions in which HCN and HNC freeze out. Both the fact that HCNH$^{+}$ is most abundant in molecular cores prior to gravitational collapse and the fact that low-$J$ HCNH$^{+}$ transitions have very low H$_{2}$ critical densities make this molecular ion an excellent probe of pristine molecular gas., Comment: 25 pages, 26 figures, accepted for publication in A&A

Cygnus X is one of the closest and most active high-mass star-forming regions in our Galaxy, making it one of the best laboratories for studying massive star formation. As part of the GLOSTAR Galactic plane survey, we performed large scale simultaneous H$_{2}$CO (1$_{1,0}$-1$_{1,1}$) spectral line and radio continuum imaging observations toward Cygnus X at $\lambda\sim$6 cm with the Karl G. Jansky Very Large Array and the Effelsberg-100 m radio telescope. Our Effelsberg observations reveal widespread H$_{2}$CO (1$_{1,0}$-1$_{1,1}$) absorption with a spatial extent of $\gtrsim$50 pc in Cygnus~X for the first time. On large scales of 4.4 pc, the relative orientation between local velocity gradient and magnetic field tends to be more parallel at H$_{2}$ column densities of $\gtrsim$1.8$\times 10^{22}$~cm$^{-2}$. On the smaller scale of 0.17 pc, our VLA+Effelsberg combined data reveal H$_{2}$CO absorption only toward three bright H{\scriptsize II} regions. Our observations demonstrate that H$_{2}$CO (1$_{1,0}$-1$_{1,1}$) is commonly optically thin. Kinematic analysis supports the assertion that molecular clouds generally exhibit supersonic motions on scales of 0.17-4.4 pc. We show a non-negligible contribution of the cosmic microwave background radiation in producing extended absorption features in Cygnus X. Our observations suggest that H$_{2}$CO ($1_{1,0}-1_{1,1}$) can trace molecular gas with H$_{2}$ column densities of $\gtrsim 5 \times 10^{21}$ cm$^{-2}$. The ortho-H$_{2}$CO fractional abundance with respect to H$_{2}$ has a mean value of 7.0$\times 10^{-10}$. A comparison of velocity dispersions on different linear scales suggests that the dominant $-3$ km s$^{-1}$ velocity component in the prominent DR21 region has nearly identical velocity dispersions on scales of 0.17-4.4 pc, which deviates from the expected behavior of classic turbulence., Comment: 27 pages, 23 figures, accepted for publication in A&A

We analyzed the 3-mm wavelength spectral line survey of 408 ATLASGAL clumps observed with the IRAM 30m-telescope, focusing on the class I methanol masers with frequencies near 84, 95 and 104.3 GHz. We detect narrow, maser-like features towards 54, 100 and 4 sources in the maser lines near 84, 95 and 104.3 GHz, respectively. Among them, fifty 84 GHz masers, twenty nine 95 GHz masers and four rare 104.3 GHz masers are new discoveries. The new detections increase the number of known 104.3 GHz masers from 5 to 9. The 95 GHz class I methanol maser is generally stronger than the 84 GHz maser counterpart. We find 9 sources showing class I methanol masers but no SiO emission, indicating that class I methanol masers might be the only signpost of protostellar outflow activity in extremely embedded objects at the earliest evolutionary stage. Class I methanol masers that are associated with sources that show SiO line wings are more numerous and stronger than those without such wings. The total integrated intensity of class I methanol masers is well correlated with the integrated intensity and velocity coverage of the SiO (2--1) emission. The properties of class I methanol masers are positively correlated with the bolometric luminosity, clump mass, peak H$_2$ column density of their associated clumps but uncorrelated with the luminosity-to-mass ratio, dust temperature, and mean H$_2$ volume density. We suggest that the properties of class I masers are related to shocks traced by SiO. Based on our observations, we conclude that class I methanol masers at 84 and 95 GHz can trace a similar evolutionary stage as H$_2$O maser, and appear prior to 6.7 and 12.2 GHz methanol and OH masers. Despite their small number, the 104.3 GHz class I masers appear to trace a short and more evolved stage compared to the other class I masers. [abridged], Comment: 23 pages, 27 figures, 8 tables, accepted for publication in A&A

The factor relating CO emission to molecular hydrogen column density, XCO, is still subject to uncertainty, in particular at low metallicity. Here, to quantify XCO at two different spatial resolutions, we exploit a dust-based method together with ALMA 12-m and ACA data and HI maps of three nearby metal-poor starbursts, NGC625, NGC1705, and NGC5253. Dust opacity at 250pc resolution is derived based on dust temperatures estimated by fitting two-temperature modified blackbodies to Herschel PACS data. By using the HI maps, we are then able to estimate dust-to-gas ratios in the atomic-gas dominated regions, and infer total gas column densities and H2 column densities as the difference with HI. Finally, from the ACA CO(1-0) maps, we derive XCO. We use a similar technique with 40 pc ALMA 12-m data for the three galaxies, but instead derive dust attenuation at 40 pc resolution from reddening maps based on VLT/MUSE data. At 250 pc resolution, XCO $\sim$ 10^22 - 10^23 cm^-2 / K.km/s, 5-1000 times the Milky Way value, with much larger values than would be expected from a simple metallicity dependence. Instead at 40 pc resolution, XCO again shows large variation, but is roughly consistent with a power-law metallicity dependence, given the Z $\sim$ 1/3 Zsun metal abundances of our targets. The large scatter in both estimations could imply additional parameter dependence, that we have investigated by comparing XCO with the observed velocity-integrated brightness temperatures, ICO, as predicted by recent simulations. Indeed, larger XCO is significantly correlated with smaller ICO, but with slightly different slopes and normalizations than predicted by theory. Such behavior can be attributed to the increasing fraction of CO-faint H2 gas with lower spatial resolution. This confirms the idea the XCO is multi-variate, depending not only on metallicity but also on CO brightness temperature and beam size., Comment: A&A, in press (16 figures, 1 appendix)

HNCO and SiO are well known shock tracers and have been observed in nearby galaxies, including the nearby (D=3.5 Mpc) starburst galaxy NGC 253. The simultaneous detection of these two species in regions where the star formation rate is high may be used to study the shock history of the gas. We perform a multi-line molecular study using these two shock tracers (SiO and HNCO) with the aim of characterizing the gas properties. We also explore the possibility of reconstructing the shock history in NGC 253's Central Molecular Zone (CMZ). Six SiO transitions and eleven HNCO transitions were imaged at high resolution $1''.6$ (28 pc) with the Atacama Large Millimeter/submillimeter Array (ALMA) as part of the ALCHEMI Large Programme. Both non-LTE radiative transfer analysis and chemical modelling were performed in order to characterize the gas properties, and to investigate the chemical origin of the emission. The non-LTE radiative transfer analysis coupled with Bayesian inference shows clear evidence that the gas traced by SiO has different densities and temperatures than that traced by HNCO, with an indication that shocks are needed to produce both species. Chemical modelling further confirms such a scenario and suggests that fast and slow shocks are responsible for SiO and HNCO production, respectively, in most GMCs. We are also able to infer the physical characteristics of the shocks traced by SiO and HNCO for each GMC. Radiative transfer and chemical analysis of the SiO and HNCO in the CMZ of NGC 253 reveal a complex picture whereby most of the GMCs are subjected to shocks. We speculate on the possible shock scenarios responsible for the observed emission and provide potential history and timescales for each shock scenario. Higher spatial resolution observations of these two species are required in order to quantitatively differentiate between scenarios.

With the IRAM 30 meter telescope, we performed observations of the $J$ = 2-1 transitions of CS, C$^{33}$S, C$^{34}$S, C$^{36}$S, $^{13}$CS, $^{13}$C$^{33}$S, and $^{13}$C$^{34}$S as well as the $J$ = 3-2 transitions of C$^{33}$S, C$^{34}$S, C$^{36}$S, and $^{13}$CS toward a large sample of 110 HMSFRs. We measured the $^{12}$C/$^{13}$C, $^{32}$S/$^{34}$S, $^{32}$S/$^{33}$S, $^{32}$S/$^{36}$S, $^{34}$S/$^{33}$S, $^{34}$S/$^{36}$S, and $^{33}$S/$^{36}$S abundance ratios with rare isotopologs of CS, thus avoiding significant saturation effects. With accurate distances obtained from parallax data, we confirm previously identified $^{12}$C/$^{13}$C and $^{32}$S/$^{34}$S gradients as a function of galactocentric distance (RGC). In the CMZ, $^{12}$C/$^{13}$C ratios are higher than suggested by a linear fit to the disk values as a function of RGC. While $^{32}$S/$^{34}$S ratios near the Galactic center and in the inner disk are similar, this is not the case for $^{12}$C/$^{13}$C, when comparing central values with those near RGC of 5 kpc. As was already known, there is no $^{34}$S/$^{33}$S gradient but the average ratio of 4.35~$\pm$~0.44 derived from the $J$ = 2-1 transition lines of C$^{34}$S and C$^{33}$S is well below previously reported values. A comparison between solar and local interstellar $^{32}$S/$^{34}$S and $^{34}$S/$^{33}$S ratios suggests that the Solar System may have been formed from gas with a particularly high $^{34}$S abundance. For the first time, we report positive gradients of $^{32}$S/$^{33}$S, $^{34}$S/$^{36}$S, $^{33}$S/$^{36}$S, and $^{32}{\rm S}/^{36}{\rm S}$ in our Galaxy. The predicted $^{12}$C/$^{13}$C ratios from the latest GCE models are in good agreement with our results. While $^{32}$S/$^{34}$S and $^{32}$S/$^{36}$S ratios show larger differences at larger RGC, $^{32}$S/$^{33}$S ratios show an offset across the entire inner 12 kpc of the Milky Way., Comment: HMSFRs: high-mass star-forming regions. CMZ: central molecular zone. GCE: Galactic chemical evolution. 68 pages, 12 tables, 18 figures. Accepted for publication in A&A

With the 30-m IRAM radio telescope, we observed several massive star forming regions at wavelengths of 3-4 and 2 mm. The temperature of the gas in the sources was estimated from the lines of CH$_{3}$CCH and from the transitions of the NH$_3$ molecule obtained during observations at the 100-m radio telescope in Effelsberg. As a result, a correlation between the integrated intensity ratios of the $J=1-0$ transitions of H$^{13}$CN and HN$^{13}$C and the kinetic temperature has been obtained. The obtained results allow us to propose the use of the intensity ratio H$^{13}$CN-HN$^{13}$C as a possible temperature indicator of interstellar clouds. We also compared the obtained estimates of the kinetic temperature with the dust temperature $T_{dust}$. As a result, no significant correlation was found., Comment: 16 pages, 7 figures, 2 tables, Accepted for publication in Astronomy Reports (2022)

We present observations of ammonia emission lines toward the interstellar filament WB~673 hosting the dense clumps WB~673, WB~668, S233-IR and G173.57+2.43. LTE analysis of the lines allows us to estimate gas kinetic temperature ($\lesssim$ 30~K in all the clumps), number density ($7-17\times10^3$~cm$^{-3}$), and ammonia column density ($\approx 1-1.5\times 10^{15}$~cm$^{-2}$) in the dense clumps. We find signatures of collapse in WB 673 and presence of compact spatially unresolved dense clumps in S233-IR. We reconstruct 1D density and temperature distributions in the clumps and estimate their ages using astrochemical modelling. Considering CO, CS, NH$_3$ and N$_2$H$^+$ molecules (plus HCN and HNC for WB~673), we find a chemical age of $t_{\rm chem}=1-3\times 10^5$~yrs providing the best agreement between the simulated and observed column densities in all the clumps. Therefore, we consider $t_{\rm chem}$ as the chemical age of the entire filament. A long preceding low-density stage of gas accumulation in the astrochemical model would break the agreement between the simulated and observed column densities. We suggest that rapid star formation over a $\sim 10^5$~yrs timescale take place in the filament., Comment: 10 pages, 7 figures, accepted for publication in MNRAS

We report the discovery of widespread maser emission in non-metastable inversion transitions of NH$_3$ toward various parts of the Sagittarius B2 molecular cloud/star forming region complex: We detect masers in the $J,K = $ (6,3), (7,4), (8,5), (9,6), and (10,7) transitions toward Sgr B2(M) and Sgr B2(N), an NH$_3$ (6,3) maser in Sgr B2(NS), and NH$_3$ (7,4), (9,6), and (10,7) masers in Sgr B2(S). With the high angular resolution data of the Karl G. Jansky Very Large Array (JVLA) in A-configuration we identify 18 maser spots. Nine maser spots arise from Sgr B2(N), one from Sgr B2(NS), five from Sgr B2(M), and three in Sgr B2(S). Compared to our Effelsberg single dish data, the JVLA data indicate no missing flux. The detected maser spots are not resolved by our JVLA observations. Lower limits to the brightness temperature are $>$3000~K and reach up to several 10$^5$~K, manifesting the lines' maser nature. In view of the masers' velocity differences with respect to adjacent hot molecular cores and/or UCH{\scriptsize II} regions, it is argued that all the measured ammonia maser lines may be associated with shocks caused either by outflows or by the expansion of UCH{\scriptsize II} regions. Overall, Sgr B2 is unique in that it allows us to measure many NH$_3$ masers simultaneously, which may be essential to elucidate their so far poorly understood origin and excitation., Comment: 17 pages, 14 figures, 7 tables. Accepted for publication in A&A Letter

Our aim is to measure the interstellar 14N/15N ratio across the Galaxy, to establish a standard data set on interstellar ammonia isotope ratios, and to provide new constraints on the Galactic chemical evolution. The (J, K ) = (1, 1), (2, 2), and (3, 3) lines of 14NH3 and 15NH3 were observed with the Shanghai Tianma 65 m radio telescope (TMRT) and the Effelsberg 100 m telescope toward a large sample of 210 sources. One hundred fourty-one of these sources were detected by the TMRT in 14NH3. Eight of them were also detected in 15NH3. For 10 of the 36 sources with strong NH3 emission, the Effelsberg 100 m telescope successfully detected their 15NH3(1, 1) lines, including 3 sources (G081.7522, W51D, and Orion-KL) with detections by the TMRT telescope. Thus, a total of 15 sources are detected in both the 14NH3 and 15NH3 lines. Line and physical parameters for these 15 sources are derived, including optical depths, rotation and kinetic temperatures, and total column densities. 14N/15N isotope ratios were determined from the 14NH3/15NH3 abundance ratios. The isotope ratios obtained from both telescopes agree for a given source within the uncertainties, and no dependence on heliocentric distance and kinetic temperature is seen. 14N/15N ratios tend to increase with galactocentric distance, confirming a radial nitrogen isotope gradient. This is consistent with results from recent Galactic chemical model calculations, including the impact of superasymptotic giant branch stars and novae.

Context: Methanol masers of Class I (collisionally-pumped) and Class II (radiatively-pumped) have been studied in great detail in our Galaxy in a variety of astrophysical environments such as shocks and star-forming regions and are helpful to analyze the properties of the dense interstellar medium. However, the study of methanol masers in external galaxies is still in its infancy. Aims: Our main goal is to search for methanol masers in the central molecular zone (CMZ; inner 500 pc) of the nearby starburst galaxy NGC 253. Methods: Covering a frequency range between 84 and 373 GHz ($\lambda$ = 3.6 to 0.8 mm) at high angular (1.6"$\sim$27 pc) and spectral ($\sim$8--9 km s$^{-1}$) resolution with the ALMA large program ALCHEMI, we have probed different regions across the CMZ of NGC 253. In order to look for methanol maser candidates, we employed the rotation diagram method and a set of radiative transfer models. Results: We detect for the first time masers above 84 GHz in NGC 253, covering an ample portion of the $J_{-1}\rightarrow(J-$ 1)$_{0}-E$ line series (at 84, 132, 229, and 278 GHz) and the $J_{0}\rightarrow(J-$ 1)$_{1}-A$ series (at 95, 146, and 198 GHz). This confirms the presence of the Class I maser line at 84 GHz, already reported but now being detected in more than one location. For the $J_{-1}\rightarrow(J-$ 1)$_{0}-E$ line series, we observe a lack of Class I maser candidates in the central star-forming disk. Conclusions: The physical conditions for maser excitation in the $J_{-1}\rightarrow(J-$ 1)$_{0}-E$ line series can be weak shocks and cloud-cloud collisions as suggested by shock tracers (SiO and HNCO) in bi-symmetric shock/active regions located in the outskirts of the CMZ. On the other hand, the presence of photodissociation regions due to a high star-formation rate would be needed to explain the lack of Class I masers in the very central regions., Comment: Accepted for publication in A&A. 29 pages, 17 figures (4 in Appendix)

We use ultrafast x-ray diffraction to quantify the transport of energy in laser-excited nanoscale Au/Ni bilayers. Electron transport and efficient electron-phonon coupling in Ni convert the laser-deposited energy in the conduction electrons within a few picoseconds into a strong non-equilibrium between hot Ni and cold Au phonons at the bilayer interface. Modeling of the subsequent equilibration dynamics within various two-temperature models confirms that for ultrathin Au films the thermal transport is dominated by phonons instead of conduction electrons because of the weak electron-phonon coupling in Au., Comment: 3 Figures

The wetting of soft polymer substrates brings in multiple complexities as compared to the wetting on rigid substrates. The contact angle of the liquid is no longer governed by Young's law, but is affected by the substrate's bulk and surface deformations. On top of that, elastic interfaces exhibit a surface energy that depends on how much they are stretched -- a feature known as the Shuttleworth effect (or as surface-elasticity). Here we present two models by which we explore the wetting of drops in the presence of a strong Shuttleworth effect. The first model is macroscopic in character and consistently accounts for large deformations via a neo-Hookean elasticity. The second model is based on a mesoscopic description of wetting, using a reduced description of the substrate's elasticity. While the second model is more empirical in terms of the elasticity, it enables a gradient dynamics formulation for soft wetting dynamics. We provide a detailed comparison between the equilibrium states predicted by the two models, from which we deduce robust features of soft wetting in the presence of a strong Shuttleworth effect. Specifically, we show that the (a)symmetry of the Shuttleworth effect between the "dry" and "wet" states governs horizontal deformations in the substrate. Our results are discussed in the light of recent experiments on the wettability of stretched substrates.

Gravitational collapse is one of the most important processes in high-mass star formation. Compared with the classic blue-skewed profiles, redshifted absorption against continuum emission is a more reliable method to detect inward motions within high-mass star formation regions. We aim to test if methanol transitions can be used to trace infall motions within high-mass star formation regions. Using the Effelsberg-100 m, IRAM-30 m, and APEX-12 m telescopes, we carried out observations of 37 and 16 methanol transitions towards two well-known collapsing dense clumps, W31C (G10.6-0.4) and W3(OH), to search for redshifted absorption features or inverse P-Cygni profiles. Redshifted absorption is observed in 14 and 11 methanol transitions towards W31C and W3(OH), respectively. The infall velocities fitted from a simple two-layer model agree with previously reported values derived from other tracers, suggesting that redshifted methanol absorption is a reliable tracer of infall motions within high-mass star formation regions. Our observations indicate the presence of large-scale inward motions, and the mass infall rates are roughly estimated to be $\gtrsim$10$^{-3}$ $M_{\odot}$yr$^{-1}$, which supports the global hierarchical collapse and clump-fed scenario. With the aid of bright continuum sources and the overcooling of methanol transitions leading to enhanced absorption, redshifted methanol absorption can trace infall motions within high-mass star formation regions hosting bright H{\scriptsize II} regions., Comment: 21 pages, 13 figures, 5 tables. Accepted for publication in A&A

Molecular maser lines are signposts of high-mass star formation, probing excitation and kinematics of very compact regions in the close environment of young stellar objects and providing useful targets for trigonometric parallax measurements. Only a few NH$_{3}$ (9,6) masers were known so far, and their origin is still poorly understood. Here we aim to find new NH$_{3}$ (9,6) masers to provide a better observational basis to study their role in high-mass star-forming regions. We carried out NH$_{3}$ (9,6) observations toward Cepheus A and G34.26$+$0.15 with the Effelsberg-100 m telescope and the Karl G. Janksy Very Large Array. We discovered new NH$_{3}$ (9,6) masers in Cep A and G34.26$+$0.15, which increases the number of high-mass star-forming regions hosting NH$_{3}$ (9,6) masers from five to seven. Long term monitoring (20 months) at Effelsberg shows that the intensity of the (9,6) maser in G34.26$+$0.15 is decreasing, while the Cep A maser remains stable. Compared to the Effelsberg data and assuming linear variations between the epochs of observation, the JVLA data indicate no missing flux. This suggests that the NH$_3$ (9,6) emission arises from single compact emission regions that are not resolved by the interferometric measurements. As JVLA imaging shows, the NH$_{3}$ (9,6) emission in Cep A originates from a sub-arcsecond sized region, slightly to the west of the peak position of the 1.36\,cm continuum object, HW2. In G34.26$+$0.15, three NH$_{3}$ (9,6) maser spots are observed: one is close to the head of the cometary ultracompact \h2 region C and the other two are emitted from a compact region to the west of the hypercompact \h2 region A. The newly found (9,6) masers appear to be related to outflows. Higher angular resolution of JVLA and VLBI observations are needed to provide more accurate positions and constraints for pumping scenarios., Comment: 10 pages, 6 figures, 3 tables. Publicated in A&A

We estimate limits on non-universal coupling of hypothetical hidden fields to standard matter by evaluating the fractional changes in the electron-to-proton mass ratio, mu = m_e/m_p, based on observations of ClassI methanol masers distributed in the Milky Way disk over the range of the galactocentric distances 4 < R < 12 kpc. The velocity offsets DeltaV = V44 - V95 measured between the 44 and 95 GHz methanol lines provide, so far, one of the most stringent constraints on the spatial gradient k_mu = d(Delta mu/mu)/dR < 2x10^-9 kpc-1 and the upper limit on Delta mu/mu < 2x10^-8, where Delta mu/mu = (mu_obs-mu_lab)/mu_lab. We also find that the offsets DeltaV are clustered into two groups which are separated by 0.022 +/- 0.003 km/s (1sigma C.L.). The grouping is most probably due to the dominance of different hyperfine transitions in the 44 and 95 GHz methanol maser emission. Which transition becomes favored is determined by an alignment (polarization) of the nuclear spins of the four hydrogen atoms in the methanol molecule. This result confirms that there are preferred hyperfine transitions involved in the methanol maser action., Comment: Accepted for publication in MNRAS, 7 pages text, 8 figures, 7 tables

Phosphorus (P) is a crucial element for life given its central role in several biomolecules. P-bearing molecules have been discovered in different regions of the Milky Way, but not yet towards an extragalactic environment. We have searched for P-bearing molecules towards the nearby starburst Galaxy NGC 253. Using observations from the ALMA Comprehensive High-resolution Extragalactic Molecular Inventory (ALCHEMI) project, we used the MADCUBA package to model the emission of P-bearing molecules assuming Local Thermodynamic Equilibrium (LTE) conditions. We have also performed a non-LTE analysis using SpectralRadex. We report the detection of a P-bearing molecule, phosphorus nitride (PN), for the first time in an extragalactic environment, towards two giant molecular clouds (GMCs) of NGC 253. The LTE analysis yields total PN beam-averaged column densities $N$=(1.20$\pm$0.09)$\times$10$^{13}$ cm$^{-2}$ and $N$=(6.5$\pm$1.6)$\times$10$^{12}$ cm$^{-2}$, which translate into abundances with respect to H$_2$ of $\chi$=(8.0$\pm$1.0)$\times$10$^{-12}$ and $\chi$=(4.4$\pm$1.2)$\times$10$^{-12}$. We derived a low excitation temperature of $T_{\rm ex}$=(4.4$\pm$1.3) K towards the GMC with the brightest PN emission, which indicates that PN is sub-thermally excited. The non-LTE analysis results in column densities consistent with the LTE values. We have also searched for other P-bearing molecules (PO, PH$_{3}$, CP and CCP), and upper limits were derived. The derived PO/PN ratios are $<$1.3 and $<$1.7. The abundance ratio between PN and the shock-tracer SiO derived towards NGC 253 follows the same trend previously found towards Galactic sources. Comparison of the observations with chemical models indicates that the derived molecular abundances of PN in NGC 253 can be explained by shock-driven chemistry followed by cosmic-ray-driven photochemistry., Comment: 14 pages, 14 figures, 4 tables. Accepted for publication in A&A

At a distance of 2.4kpc, W33 is an outstanding massive and luminous 10pc sized star forming complex containing quiescent infrared dark clouds as well as highly active infrared bright cloud cores heated by young massive stars. We report measurements of ammonia (NH$_3$) inversion lines in the frequency range 18--26GHz, obtained with the 40" resolution of the 100 m Effelsberg telescope. We have detected the ($J$, $K$)=(1,1), (2,2), (3,3), (4,4), (5,5), (6,6), (2,1) and (3,2) transitions. There is a maser line in the (3,3) transition towards W33 Main. Brightness temperature and line shape indicate no significant variation during the last $\sim$36yr. We have determined kinetic temperatures, column densities and other physical properties of NH$_3$ and the molecular clouds in W33. For the total-NH$_3$ column density, we find for 40"(0.5pc) sized regions 6.0($\pm$2.1)$\times$10$^{14}$, 3.5($\pm$0.1)$\times$10$^{15}$, 3.4($\pm$0.2)$\times$10$^{15}$, 3.1($\pm$0.2)$\times$10$^{15}$, 2.8($\pm$0.2)$\times$10$^{15}$ and 2.0($\pm$0.2)$\times$10$^{15}$cm$^{-2}$ at the peak positions of W33 Main, W33 A, W33 B, W33 Main1, W33 A1 and W33 B1, respectively. W33 Main has a total-NH$_3$ fractional abundance of 1.3($\pm$0.1)$\times$10$^{-9}$ at the peak position. High values of 1.4($\pm$0.3)$\times$10$^{-8}$, 1.6($\pm$0.3)$\times$10$^{-8}$, 3.4($\pm$0.5)$\times$10$^{-8}$, 1.6($\pm$0.5)$\times$10$^{-8}$ and 4.0($\pm$1.2)$\times$10$^{-8}$ are obtained at the central positions of W33 A, W33 B, W33 Main1, W33 A1, and W33 B1. From this, we confirm the already previously proposed different evolutionary stages of the six W33 clumps and find that there is no hot core in the region approaching the extreme conditions encountered in W51-IRS2 or Sgr B2. The ortho-to-para-NH$_3$ abundance ratios suggest that ammonia should have been formed in the gas phase or on dust grain mantles at kinetic temperatures of $\gtrsim$20K., Comment: 30 pages, 21 figures, accepted by A&A

We used the Atacama Large Millimeter/submillimeter Array (ALMA), covering a nearly contiguous 289 GHz frequency range between 84.2 and 373.2 GHz, to image the continuum and spectral line emission at 1.6\arcsec ($\sim 28$ pc) resolution down to a sensitivity of $30-50$ mK. This article describes the ALMA Comprehensive High-resolution Extragalactic Molecular Inventory (ALCHEMI) Large Program. We focus on the analysis of the spectra extracted from the $15''$ ($\sim255$ pc) resolution ALMA Compact Array data. We model the molecular emission assuming local thermodynamic equilibrium with 78 species detected. Additionally, multiple hydrogen and helium recombination lines are identified. Spectral lines contribute 5 to 36\% of the total emission in frequency bins of 50 GHz. We report the first extragalactic detections of C$_2$H$_5$OH, HOCN, HC$_3$HO, and several rare isotopologues. Isotopic ratios of carbon, oxygen, sulfur, nitrogen and silicon were measure with multiple species. Infrared pumped vibrationaly excited HCN, HNC, and HC$_3$N emission, originating in massive star formation locations, is clearly detected at low resolution, while we do not detect it for HCO$^+$. We suggest high temperature conditions in these regions driving a seemingly "carbon-rich" chemistry which may also explain the observed high abundance of organic species close to those in Galactic hot cores. The $L_{vib}/L_{IR}$ ratio is used as a proxy to estimate a $3\%$ contribution from proto super star cluster to the global infrared emission. Measured isotopic ratios with high dipole moment species agree with those within the central kiloparsec of the Galaxy, while those derived from $\rm^{13}C^{18}O$ are a factor of 5 larger, confirming the existence of multiple ISM components within NGC 253 with different degrees of nucleosynthesis enrichment. ALCHEMI provides a template for early Universe galaxies., Comment: 60 pages, 32 figures, 15 tables, Accepted for publication at A&A

We mapped the kinetic temperature structure of two massive star-forming regions, N113 and N159W, in the Large Magellanic Cloud (LMC). We have used $\sim$1\hbox{$\,.\!\!^{\prime\prime}$}6\,($\sim$0.4\,pc) resolution measurements of the para-H$_2$CO\,$J_{\rm K_ aK_c}$\,=\,3$_{03}$--2$_{02}$, 3$_{22}$--2$_{21}$, and 3$_{21}$--2$_{20}$ transitions near 218.5\,GHz to constrain RADEX non-LTE models of the physical conditions. The gas kinetic temperatures derived from the para-H$_2$CO line ratios 3$_{22}$--2$_{21}$/3$_{03}$--2$_{02}$ and 3$_{21}$--2$_{20}$/3$_{03}$--2$_{02}$ range from 28 to 105\,K in N113 and 29 to 68\,K in N159W. Distributions of the dense gas traced by para-H$_2$CO agree with those of the 1.3\,mm dust and \emph{Spitzer}\,8.0\,$\mu$m emission, but do not significantly correlate with the H$\alpha$ emission. The high kinetic temperatures ($T_{\rm kin}$\,$\gtrsim$\,50\,K) of the dense gas traced by para-H$_2$CO appear to be correlated with the embedded infrared sources inside the clouds and/or YSOs in the N113 and N159W regions. The lower temperatures ($T_{\rm kin}$\,$<$\,50\,K) are measured at the outskirts of the H$_2$CO-bearing distributions of both N113 and N159W. It seems that the kinetic temperatures of the dense gas traced by para-H$_2$CO are weakly affected by the external sources of the H$\alpha$ emission. The non-thermal velocity dispersions of para-H$_2$CO are well correlated with the gas kinetic temperatures in the N113 region, implying that the higher kinetic temperature traced by para-H$_2$CO is related to turbulence on a $\sim$0.4\,pc scale. The dense gas heating appears to be dominated by internal star formation activity, radiation, and/or turbulence. It seems that the mechanism heating the dense gas of the star-forming regions in the LMC is consistent with that in Galactic massive star-forming regions located in the Galactic plane., Comment: Accepted for publication in A&A

Gas at high Galactic latitude is a relatively little-noticed component of the interstellar medium. In an effort to address this, forty-one Planck Galactic Cold Clumps at high Galactic latitude (HGal; $|b|>25^{\circ}$) were observed in $^{12}$CO, $^{13}$CO and C$^{18}$O J=1-0 lines, using the Purple Mountain Observatory 13.7-m telescope. $^{12}$CO (1-0) and $^{13}$CO (1-0) emission was detected in all clumps while C$^{18}$O (1-0) emission was only seen in sixteen clumps. The highest and average latitudes are $71.4^{\circ}$ and $37.8^{\circ}$, respectively. Fifty-one velocity components were obtained and then each was identified as a single clump. Thirty-three clumps were further mapped at 1$^\prime$ resolution and 54 dense cores were extracted. Among dense cores, the average excitation temperature $T_{\mathrm{ex}}$ of $^{12}$CO is 10.3 K. The average line widths of thermal and non-thermal velocity dispersions are $0.19$ km s$^{-1}$ and $0.46$ km s$^{-1}$ respectively, suggesting that these cores are dominated by turbulence. Distances of the HGal clumps given by Gaia dust reddening are about $120-360$ pc. The ratio of $X_{13}$/$X_{18}$ is significantly higher than that in the solar neighbourhood, implying that HGal gas has a different star formation history compared to the gas in the Galactic disk. HGal cores with sizes from $0.01-0.1$ pc show no notable Larson's relation and the turbulence remains supersonic down to a scale of slightly below $0.1$ pc. None of the HGal cores which bear masses from 0.01-1 $M_{\odot}$ are gravitationally bound and all appear to be confined by outer pressure., Comment: 35 pages, 13 figures

Observations of chemical species can provide an insight into the physical conditions of the emitting gas but it is important to understand how their abundances and excitation vary within different heating environments. C$_2$H is a molecule typically found in PDR regions of our own Galaxy but there is evidence to suggest it also traces other regions undergoing energetic processing in extragalactic environments. As part of the ALCHEMI ALMA large program, the emission of C$_2$H in the central molecular zone of the nearby starburst galaxy NGC 253 was mapped at 1.6 " (28 pc) resolution and characterized to understand its chemical origins. Spectral modelling of the N=1-0 through N=4-3 rotational transitions of C$_2$H was used to derive the C$_2$H column densities towards the dense clouds in NGC 253. Chemical modelling, including PDR, dense cloud, and shock models were then used to investigate the chemical processes and physical conditions that are producing the molecular emission. We find high C$_2$H column densities of $\sim 10^{15} cm^{-3}$ detected towards the dense regions of NGC 253. We further find that these column densities cannot be reproduced by assuming that the emission arises from the PDR regions at the edge of the clouds. Instead, we find that the C$_2$H abundance remains high even in the high visual extinction interior of these clouds and that this is most likely caused by a high cosmic-ray ionization rate., Comment: 18 pages, 13 figures, accepted for publication in A&A

Methanol is an important tracer to probe physical and chemical conditions in the interstellar medium of galaxies. Methanol is also the most sensitive target molecule for probing potential space-time variations of the proton-electron mass ratio, mu, a dimensionless constant of nature. We present an extensive ALMA study of the strongest submillimeter absorption lines of methanol [...] in the z=0.89 molecular absorber toward PKS1830-211, the only high-redshift object in which methanol has been detected. Our goals are to constrain the excitation of the methanol lines and to investigate the cosmological invariance of mu based on their relative kinematics. [...] We explore methanol excitation by running the non local thermal equilibrium radiative transfer code RADEX [...] The excitation analysis points to a cool (~10-20 K) and dense (~10^{4-5} cm-3) methanol gas. [...] In addition, we measure an abundance ratio A/E = 1.0 +/- 0.1, an abundance ratio CH3OH/H2 ~ 2 x 10^{-8}, and a 12CH3OH/13CH3OH ratio 62 +/- 3. Our analysis shows that the bulk velocities of the different transitions are primarily correlated with the observing epoch due to morphological changes in the background quasar's emission. There is a weaker correlation between bulk velocities and the lower level energies of the transitions, which could be a signature of temperature-velocity gradients in the absorbing gas. As a result, we do not find evidence for variations of mu, and we estimate Dmu/mu = (-1.8 +/- 1.2) x 10^{-7} at 1sigma from our multivariate linear regression. We set a robust upper limit | \Dmu/mu | < 3.6 x 10^{-7} (3sigma) for the invariance of mu at a look-back time of half the present age of the Universe. Our analysis highlights that systematics need to be carefully taken into account in future radio molecular absorption studies aimed at testing Dmu/mu below the 10^{-7} horizon. (Abridged), Comment: Accepted for publication in A&A

We present the first census of giant molecular clouds (GMCs) complete down to 10$^6 M_{\odot}$ and within the inner 4 kpc of the nearest giant elliptical and powerful radio galaxy, Centaurus A. We identified 689 GMCs using CO(1--0) data with 1" spatial resolution ($\sim 20$ pc) and 2 km/s velocity resolution obtained with the Atacama Large Millimeter/submillimeter Array (ALMA). The $I$(CO)-$N$(H$_2$) conversion factor based on the virial method is $X_{\rm CO}$ = $(2 \pm 1 )\times10^{20}$ cm$^{-2}$(K km/s)$^{-1}$ for the entire molecular disk, consistent with that of the disks of spiral galaxies including the Milky Way, and $X_{\rm CO}$ = $(5 \pm 2)\times10^{20}$ cm$^{-2}$(K km/s)$^{-1}$ for the circumnuclear disk (CND, within a galactocentric radius of 200 pc). We obtained the GMC mass spectrum distribution and find that the best-truncated power-law fit for the whole molecular disk, with index $\gamma \simeq -2.41 \pm 0.02$ and upper cutoff mass $\sim 1.3 \times 10^{7} M_{\odot}$, is also in agreement with that of nearby disk galaxies. A trend is found in the mass spectrum index from steep to shallow as we move to inner radii. Although the GMCs are in an elliptical galaxy, the general GMC properties in the molecular disk are as in spiral galaxies. However, in the CND, large offsets in the line-width-size scaling relations ($\sim$ 0.3 dex higher than those in the GMCs in the molecular disk), a different $X_{\rm CO}$ factor, and the shallowest GMC mass distribution shape ($\gamma = -1.1 \pm 0.2$) all suggest that there the GMCs are most strongly affected by the presence of the AGN and/or shear motions., Comment: 19 pages, 11 figures, 3 tables, accepted for publication in MNRAS

We searched for shocked carbon chain chemistry (SCCC) sources with C$_3$S abundances surpassing those of HC$_5$N towards the dark cloud L1251, using the Effelsberg telescope at K-band (18 -- 26\,GHz). L1251-1 and L1251-3 are identified as the most promising SCCC sources. The two sources harbor young stellar objects. We conducted mapping observations towards L1251-A, the western tail of L1251, at $\lambda$ $\sim$3\,mm with the PMO 13.7 m and the NRO 45 m telescopes in lines of C$_2$H, N$_2$H$^+$, CS, HCO$^+$, SO, HC$_3$N and C$^{18}$O as well as in CO 3--2 using the JCMT. The spectral data were combined with archival data including Spitzer and Herschel continuum maps for further analysis. Filamentary sub-structures labeled as F1 to F6 were extracted in L1251, with F1 being associated with L1251-A hosting L1251-1. The peak positions of dense gas traced by HCO$^+$ are misaligned relative to those of the dust clumps. Episodic outflows are common in this region. The twisted morphology of F1 and velocity distribution along L1251-A may originate from stellar feedback. SCCC in L1251-1 may have been caused by outflow activities originated from the infrared source IRS1. The signposts of ongoing SCCC and the broadened line widths of C$_3$S and C$_4$H in L1251-1 as well as the distribution of HC$_3$N are also related to outflow activities in this region. L1251-1 (IRS1) together with the previously identified SCCC source IRS3 demonstrate that L1251-A is an excellent region to study shocked carbon chain chemistry., Comment: 32 pages, 15 figures

We compare the relations among various integrated characteristics of ~25,000 low-redshift (z<1.0) compact star-forming galaxies (CSFGs) from Data Release 16 (DR16) of the Sloan Digital Sky Survey (SDSS) and of high-redshift (z>1.5) star-forming galaxies (SFGs) with respect to oxygen abundances, stellar masses M*, far-UV absolute magnitudes M(FUV), star-formation rates SFR and specific star-formation rates sSFR, Lyman-continuum photon production efficiencies (xi_ion), UV continuum slopes \beta, [OIII]5007/[OII]3727 and [NeIII]3868/[OII]3727 ratios, and emission-line equivalent widths EW([OII]3727), EW([OIII]5007), and EW(H\alpha). We find that the relations for low-z CSFGs with high equivalent widths of the H\beta emission line, EW(H\beta)>100A, and high-z SFGs are very similar, implying close physical properties in these two categories of galaxies. Thus, CSFGs are likely excellent proxies for the SFGs in the high-z Universe. They also extend to galaxies with lower stellar masses, down to ~10^6 Msun, and to absolute FUV magnitudes as faint as -14 mag. Thanks to their proximity, CSFGs can be studied in much greater detail than distant SFGs. Therefore, the relations between the integrated characteristics of the large sample of CSFGs studied here can prove very useful for our understanding of high-z dwarf galaxies in future observations with large ground-based and space telescopes., Comment: 20 pages, 14 figures, accepted for publication in Astronomy and Astrophysics

Some luminous and ultraluminous infrared galaxies (LIRGs and ULIRGs) host extremely compact and dusty nuclei. The intense infrared radiation arising from warm dust in these sources is prone to excite vibrational levels of molecules such as HCN. This results in emission from the rotational transitions of vibrationally excited HCN (HCN-vib), with the brightest emission found in compact obscured nuclei (CONs). We aim to establish how common CONs are in the local Universe, and whether their prevalence depends on the luminosity or other properties of the host galaxy. We have conducted an Atacama Large Millimeter/submillimeter Array (ALMA) survey of the rotational J=3-2 transition of HCN-vib in a sample of 46 far-infrared luminous galaxies. Compact obscured nuclei are identified in 38 percent of ULIRGs, 21 percent of LIRGs, and 0 percent of lower luminosity galaxies. We find no dependence on the inclination of the host galaxy, but strong evidence of lower IRAS 25 to 60 {\mu}m flux density ratios (f25/f60) in CONs compared to the rest of the sample. Furthermore, we find that CONs have stronger silicate features (s9.7{\mu}m) but similar PAH equivalent widths (EQW6.2{\mu}m) compared to other galaxies. In the local Universe, CONs are primarily found in (U)LIRGs. High resolution continuum observations of the individual nuclei are required to determine if the CON phenomenon is related to the inclinations of the nuclear disks. The lower f25/f60 ratios in CONs as well as the results for the mid-infrared diagnostics investigated are consistent with large dust columns shifting the nuclear radiation to longer wavelengths, making the mid- and far-infrared "photospheres" significantly cooler than the interior regions. To assess the importance of CONs in the context of galaxy evolution, it is necessary to extend this study to higher redshifts where (U)LIRGs are more common., Comment: 16 pages, 11 figures, Accepted for publication in Astronomy and Astrophysics

The Serpens filament, a prominent elongated structure in a relatively nearby molecular cloud, is believed to be at an early evolutionary stage, so studying its physical and chemical properties can shed light on filament formation and early evolution. The main goal is to address the physical and chemical properties as well as the dynamical state of the Serpens filament at a spatial resolution of $\sim$0.07 pc and a spectral resolution of $\lesssim$0.1~km~s$^{-1}$. We performed $^{13}$CO (1--0), C$^{18}$O (1--0), C$^{17}$O (1--0), $^{13}$CO (2--1), C$^{18}$O (2--1), and C$^{17}$O (2--1) imaging observations toward the Serpens filament with the Institut de Radioastronomie Millim{\'e}trique 30-m (IRAM-30 m) and Atacama Pathfinder EXperiment (APEX) telescopes. Widespread narrow $^{13}$CO (2--1) self-absorption is observed in this filament, causing the $^{13}$CO morphology to be different from the filamentary structure traced by C$^{18}$O and C$^{17}$O. Our excitation analysis suggests that the opacities of C$^{18}$O transitions become higher than unity in most regions, and this analysis confirms the presence of widespread CO depletion. Further we show that the local velocity gradients have a tendency to be perpendicular to the filament's long axis in the outskirts and parallel to the large-scale magnetic field direction. The magnitudes of the local velocity gradients decrease toward the filament's crest. The observed velocity structure can be a result of gravity-driven accretion flows. The isochronic evolutionary track of the C$^{18}$O freeze-out process indicates the filament is young with an age of $\lesssim$2 Myr. We propose that the Serpens filament is a newly-formed slightly-supercritical structure which appears to be actively accreting material from its ambient gas., Comment: 26 pages, 24 figures, 2 tables, accepted for publication in A&A; A 3D view of the C18O(2-1) cube can be found in https://gongyan2444.github.io/gallery.html

Measuring isotopic ratios is a sensitive technique used to obtain information on stellar nucleosynthesis and chemical evolution. We present measurements of the carbon and sulphur abundances in the interstellar medium of the central region of our Galaxy. The selected targets are the +50km/s Cloud and several l.o.s. clouds towards Sgr B2(N). Towards the +50km/s Cloud, we observed the J=2-1 rotational transitions of CS, C34S, 13CS, C33S, and 13C34S, and the J=3-2 transitions of CS and C34S with the IRAM-30m telescope, as well as the J=6-5 transitions of C34S and 13CS with the APEX 12m telescope, all in emission. The J=2-1 rotational transitions of CS, C34S, 13CS, and 13C34S were observed with ALMA in the envelope of Sgr B2(N), with those of CS and C34S also observed in the l.o.s. clouds towards Sgr B2(N), all in absorption. In the +50km/s Cloud we derive a 12C13C isotopic ratio of ~22.1, that leads, with the measured 13CS/C34S line intensity ratio, to a 32S/34S ratio of 16.3+3.0-2.4. We also derive the 32S/34S isotopic ratio more directly from the two isotopologues 13CS and 13C34S, which leads to an independent 32S/34S estimation of 16.3+2.1-1.7 and 17.9+-5.0 for the +50km/s Cloud and Sgr B2(N), respectively. We also obtain a 34S/33S ratio of ~4.3 in the +50 km/s Cloud. Previous studies observed a decreasing trend in the 32S/34S isotopic ratios when approaching the Galactic centre. Our result indicates a termination of this tendency at least at a galactocentric distance of 130-30+60 pc. This is at variance with findings based on 12C/13C, 14N/15N and 18O/17O isotope ratios, where the above-mentioned trend is observed to continue right to the central molecular zone. This can indicate a drop in the production of massive stars at the Galactic centre, in the same line as recent metallicity gradient studies, and opens the work towards a comparison with Galactic and stellar evolution models., Comment: 16 pages, 7 figures, accepted for publication by A&A

We present observations of $^{12}$C$^{32}$S, $^{12}$C$^{34}$S, $^{13}$C$^{32}$S and $^{12}$C$^{33}$S J=2$-$1 lines toward a large sample of massive star forming regions by using the Arizona Radio Observatory 12-m telescope and the IRAM\,30-m. Taking new measurements of the carbon $^{12}$C/$^{13}$C ratio, the $^{32}$S$/$$^{34}$S isotope ratio was determined from the integrated $^{13}$C$^{32}$S/$^{12}$C$^{34}$S line intensity ratios for our sample. Our analysis shows a $^{32}$S$/$$^{34}$S gradient from the inner Galaxy out to a galactocentric distance of 12\,kpc. An unweighted least-squares fit to our data yields $^{32}$S$/$$^{34}$S = (1.56 $\pm$ 0.17)$\rm D_{\rm GC}$ + (6.75 $\pm$ 1.22) with a correlation coefficient of 0.77. Errors represent 1$\sigma$ standard deviations. Testing this result by (a) excluding the Galactic center region, (b) excluding all sources with C$^{34}$S opacities $>$ 0.25, (c) combining our data and old data from previous study, and (d) using different sets of carbon isotope ratios leads to the conclusion that the observed $^{32}$S$/$$^{34}$S gradient is not an artefact but persists irrespective of the choice of the sample and carbon isotope data. A gradient with rising $^{32}$S$/$$^{34}$S values as a function of galactocentric radius implies that the solar system ratio should be larger than that of the local interstellar medium. With the new carbon isotope ratios we obtain indeed a local $^{32}$S$/$$^{34}$S isotope ratio about 10$\%$ below the solar system one, as expected in case of decreasing $^{32}$S$/$$^{34}$S ratios with time and increased amounts of stellar processing. However, taking older carbon isotope ratios based on a lesser amount of data, such a decrease is not seen. No systematic variation of $^{34}$S$/$$^{33}$S ratios along galactocentric distance was found., Comment: 28 pages, 11 figures, 5 tables. Accepted for publication in ApJ

We present results from Atacama Large Millimeter/submillimeter Array (ALMA) observations of CS from the nearby galaxy NGC 1068 ($\sim14$ Mpc). This Seyfert 2 barred galaxy possesses a circumnuclear disc (CND, $r\sim200$ pc) and a starburst ring (SB ring, $r\sim1.3$ kpc). These high-resolution maps ($\sim0.5$", $\sim35$ pc) allow us to analyse specific sub-regions in the galaxy and investigate differences in line intensity ratios and physical conditions, particularly those between the CND and SB ring. Local thermodynamic equilibrium (LTE) analysis of the gas is used to calculate CS densities in each sub-region, followed by non-LTE analysis conducted using the radiative transfer code RADEX to fit observations and constrain gas temperature, CS column density and hydrogen density. Finally, the chemical code UCLCHEM is used to reconstruct the gas, allowing an insight into its origin and chemical history. The density of hydrogen in the CND is found to be $\geq10^5$ cm$^{-2}$, although exact values vary, reaching $10^6$ cm$^{-2}$ at the AGN. The conditions in the two arms of the SB ring appear similar to one another, though the density found ($\sim10^4$ cm$^{-2}$) is lower than in the CND. The temperature in the CND increases from east to west, and is also overall greater than found in the SB ring. These modelling methods indicate the requirement for multi-phase gas components in order to fit the observed emission over the galaxy. A larger number of high resolution transitions across the SLED may allow for further constraining of the conditions, particularly in the SB ring., Comment: 32 pages, 19 figures, 6 tables, accepted for publication in MNRAS

Deuterium and lithium are light elements of high cosmological and astrophysical importance. In this work we report the first detection of deuterated molecules and a search for lithium hydride, 7LiH, at redshift z=0.89 in the spiral galaxy intercepting the line of sight to the quasar PKS1830-211. We used ALMA to observe several submillimeter lines of ND, NH2D, and HDO, and their related isotopomers NH2, NH3, and H2^18O, in absorption against the southwest image of the quasar, allowing us to derive XD/XH abundance ratios. The absorption spectra mainly consist of two distinct narrow velocity components for which we find remarkable differences. One velocity component shows XD/XH abundances that is about 10 times larger than the primordial elemental D/H ratio, and no variability of the absorption profile during the time span of our observations. [...] The second component has XD/XH abundances that are 100 times larger than the primordial D/H ratio, a deepening of the absorption by a factor of two within a few months, and a rich chemical composition, with relative enhancements of N2H+, CH3OH, SO2, and complex organic molecules. We therefore speculate that this component is associated with the analog of a Galactic dark cloud, while the first component is likely more diffuse. Our search for the 7LiH (1--0) line was unsuccessful and we derive an upper limit 7LiH/H2 = 4 x 10^-13 (3sigma) in the z=0.89 absorber toward PKS1830-211. Besides, with ALMA archival data, we could not confirm the previous tentative detections of this line in the z=0.68 absorber toward B0218+357; we derive an upper limit 7LiH/H2 = 5 x 10^-11 (3sigma), although this is less constraining than our limit toward PKS1830-211. We conclude that, as in the Milky Way, only a tiny fraction of lithium nuclei are possibly bound in LiH in these absorbers at intermediate redshift., Comment: Accepted for publication in A&A

We present a measurement of the Hubble constant made using geometric distance measurements to megamaser-hosting galaxies. We have applied an improved approach for fitting maser data and obtained better distance estimates for four galaxies previously published by the Megamaser Cosmology Project: UGC 3789, NGC 6264, NGC 6323, and NGC 5765b. Combining these updated distance measurements with those for the maser galaxies CGCG 074-064 and NGC 4258, and assuming a fixed velocity uncertainty of 250 km s$^{-1}$ associated with peculiar motions, we constrain the Hubble constant to be $H_0 = 73.9 \pm 3.0$ km s$^{-1}$ Mpc$^{-1}$ independent of distance ladders and the cosmic microwave background. This best value relies solely on maser-based distance and velocity measurements, and it does not use any peculiar velocity corrections. Different approaches for correcting peculiar velocities do not modify $H_0$ by more than ${\pm}1{\sigma}$, with the full range of best-fit Hubble constant values spanning 71.8-76.9 km s$^{-1}$ Mpc$^{-1}$. We corroborate prior indications that the local value of $H_0$ exceeds the early-Universe value, with a confidence level varying from 95-99% for different treatments of the peculiar velocities., Comment: 13 pages, 1 figure, accepted for publication in ApJL

As part of the survey component of the Megamaser Cosmology Project, we have discovered a disk megamaser system in the galaxy CGCG 074-064. Using the GBT and the VLA, we have obtained spectral monitoring observations of this maser system at a monthly cadence over the course of two years. We find that the systemic maser features display line-of-sight accelerations of ~4.4 km s$^{-1}$ yr$^{-1}$ that are nearly constant with velocity, while the high-velocity maser features show accelerations that are consistent with zero. We have also used the HSA to make a high-sensitivity VLBI map of the maser system in CGCG 074-064, which reveals that the masers reside in a thin, edge-on disk with a diameter of ~1.5 mas (0.6 pc). Fitting a three-dimensional warped disk model to the data, we measure a black hole mass of $2.42^{+0.22}_{-0.20} \times 10^7$ M$_{\odot}$ and a geometric distance to the system of $87.6^{+7.9}_{-7.2}$ Mpc. Assuming a CMB-frame recession velocity of $7308 \pm 150$ km s$^{-1}$, we constrain the Hubble constant to $H_0 = 81.0^{+7.4}_{-6.9}$ (stat.) $\pm 1.4$ (sys.) km s$^{-1}$ Mpc$^{-1}$., Comment: 22 pages, 6 figures, accepted for publication in ApJ

Almost all dwarf galaxies in the Local Group that are not satellites of the Milky Way or M31, belong to either one of two highly-symmetric planes. It is still a matter of debate, whether these planar structures are dynamically stable or whether they only represent a transient alignment. Proper motions, if they could be measured, could help to discriminate between these scenarios. Such motions could be determined with multi-epoch Very Long Baseline Interferometry (VLBI) of sources that show emission from water and methanol at frequencies of 22 and 6.7 GHz, respectively. We report searches for such masers. We have mapped three Local Group galaxies, NGC6822, IC1613 and WLM in the bands covering the water vapor and methanol lines. These systems are members of the two above mentioned planes of galaxies. We have produced deep radio continuum (RC) maps and spectral line cubes. The former have been used to identify star forming regions and to derive global galactic star formation rates (SFRs). These SFRs turn out to be lower than those determined at other wavelengths in two of our sources. This indicates that dwarf galaxies may follow predictions on the RC-SFR relation only in individual regions of enhanced radio continuum emission, but not when considering the entire optical body of the sources. No methanol or water maser emission has been confidently detected, down to line luminosity limits of ~0.004 and 0.01 solar luminosities, respectively. This finding is consistent with the small sizes, low SFRs and metallicities of these galaxies., Comment: 15 pages, 7 figures, accepted for publication by MNRAS. A high-resolution version of the paper can be found at the link http://erg.oa-cagliari.inaf.it/preprints/SRT_LGdwarfs_I.pdf

In order to search for further observational evidence of cloud-cloud collisions in one of the promising candidates, L1188, we carried out observations of multiple molecular lines toward the intersection region of the two nearly orthogonal filamentary molecular clouds in L1188. Based on these observations, we find two parallel filamentary structures, both of which have at least two velocity components being connected with broad bridging features. We also found a spatially complementary distribution between the two molecular clouds, as well as enhanced $^{13}$CO emission and $^{12}$CO self-absorption toward their abutting regions. At the most blueshifted velocities, we unveil a 1~pc-long arc ubiquitously showing $^{12}$CO line wings. We discover two 22 GHz water masers, which are the first maser detections in L1188. An analysis of line ratios at a linear resolution of 0.2 pc suggests that L1188 is characterised by kinetic temperatures of 13--23~K and H$_{2}$ number densities of 10$^{3}$--10$^{3.6}$ cm$^{-3}$. On the basis of previous theoretical predictions and simulations, we suggest that these observational features can be naturally explained by the scenario of a cloud-cloud collision in L1188, although an additional contribution of stellar feedback from low-mass young stellar objects cannot be ruled out., Comment: 17 pages, 15 figures, 2 tables, accepted for publication in A&A; for the draft showing figures with full resolution, see http://gongyan2444.github.io/pdf/l1188.pdf