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2. Quadratic Nonlinear Optical Properties of Correlated Chromophores: Cyclic 6,6'-Dinitro-1,1'-Binaphthyl-2,2'-Ethers

Author

Hendrickx, E.H.J., Boutton, C., Clays, K., Persoons, A.P., Es, van, J.J.G.S., Biemans, H.A.M., Meijer, E.W., Hendrickx, E.H.J., Boutton, C., Clays, K., Persoons, A.P., Es, van, J.J.G.S., Biemans, H.A.M., and Meijer, E.W.

Abstract

The first hyperpolarizability, , of a series of cyclic 6,6¿-dinitro-1,1¿-binaphthyl-2,2¿-ethers has been analyzed with hyper-Rayleigh scattering and electric-field-induced second-harmonic-generation and compared with the absorption data and semi-empirical calculations. The results show the critical dependence of on the conformation of the alkoxy donor and the dihedral angle of the binaphthyl unit.

Published
1997

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