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1. First production of X-rays at the ThomX high-intensity Compton source

Author

Jacquet, Marie, Alexandre, Patrick, Alkadi, Muath, Alves, Manuel, Amer, Manar, Amoudry, Loic, Auguste, Didier, Babigeon, Jean-Luc, Balcou, Philippe, Baltazar, Michel, Benabderrahmane, Chamseddine, el Fekih, Rachid Ben, Benoit, Alain, Berteaud, Philippe, Biagini, Marica, Blin, Alexandre, Bobault, Sébastien, Bonanzingamarco, Marco, Bonenfant, Jean, Bonis, Julien, Bouanani, Yazid, Bouaziz, Said, Bouvet, François, Bravin, Alberto, Bruni, Christelle, Bruyere, Cyril, Bzyl, Harold, Cassinari, Lodovico, Cassou, Kevin, Cayla, Jean-Noël, Chabaud, Thomas, Chaikovska, Iryna, Chance, Sophie, Chapelle, Christophe, Chaumat, Vincent, Chiche, Ronic, Cobessi, Alain, Cormier, Eric, Cornebise, Patrick, Couprie, Marie-Emmanuelle, Cuoq, Renaud, Dalifard, Olivier, Degallaix, Jérôme, Delerue, Nicolas, Del Net, William, Diaz, Antonio, Dietrich, Yannick, Diop, Massamba, Dorkel, Remy, Douillet, Denis, Drebot, Illya, Dugal, Jean-Phillipe, Dupraz, Kevin, Dupuy, Eric, El Ajjouri, Moussa, El Kamchi, Noureddine, El Khaldi, Mohamed, Elleaume, Hélène, Ergenlik, Ezgi, Estève, François, Favier, Pierre, Fernandez, Marco, Gamelin, Alexis, Garaut, Jean-François, Garolfi, Luca, Gauron, Philippe, Gauthier, Frédéric, Girault, Pascal, Gonnin, Alexandre, Grasset, Denis, Guerard, Eric, Guler, Hayg, Haissinski, Jacques, Hazemann, Jean-Louis, Helder, Dias, Herbeaux, Christian, Herry, Emmanuel, Hodeau, Jean-Louis, Horodynski, Jean-Michel, Hubert, Nicolas, Iaquaniello, Gregory, Jacquet, Philippe, Jeantet, Philippe, Jehanno, Didier, Jules, Eric, Kapoujyan, Grigor, Kubytskyi, Viacheslav, Labat, Marie, Labaye, François, Lacipière, Jerome, Lacroix, Mickaël, Lahéra, Eric, Langlet, Marc, Lebarillec, Titouan, Ledu, Jean-François, Le Duc, Géraldine, Le Guidec, Damien, Leluan, Bruno, Lepercq, Pierre, Lestrade, Alain, Letellier-cohen, Frédéric, Letrésor, Antoine, Lhermite, Jérôme, Liu, Xing, Lopes, Robert, Loulergue, Alexandre, Louvet, Marc, Mageur, Christophe, Marchand, Patrick, Marie, Rodolphe, Marrucho, Jean-Claude, Marteau, Fabrice, Martens, Aurélien, Mercadier, Gabriel, Mercier, Bruno, Michel, Christophe, Mistretta, Eric, Monard, Hugues, Moutardier, Alexandre, Muller, Didier, Nadji, Amor, Nadolski, Laurent, Nagaoka, Ryutaro, Neveu, Olivier, Nutarelli, Daniele, Omeich, Maher, Pedeau, Dominique, Peinaud, Yann, Perroux, Gilles, Pérus, Antoine, Petit, Sylvain, Petrilli, Yannick, Pichet, Marc, Pieyre, Bernard, Pinard, Laurent, Plaige, Eric, Pollina, Jean Pierre, Prévost, Christophe, Proux, Olivier, Ribeiro, Fernand, Robert, Pierre, Ros, Manuel, Roulet, Thomas, Roux, Raphael, Roy, Emmanuel, Rudnicky, Philippe, Salvia, Julien, Sebdaoui, Mourad, Sierra, Serge, Soskov, Viktor, Sreedharan, Rajesh, Susini, Jean, Taurigna-Quéré, Monique, Trochet, Stéphane, Vallerand, Cynthia, Variola, Alessandro, Veteran, José, Vitez, Olivier, Walter, Philippe, Wicek, François, Wurth, Sébastien, and Zomer, Fabian

Published
2024
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6. Reductive hydrothermal conversion of uranyl oxalates into UO2+x monitored by in situ XANES analyses.

Author

Benarib, Sofian, Munoz, Maëva, Kieffer, Isabelle, Hazemann, Jean-Louis, Dacheux, Nicolas, and Clavier, Nicolas

Subjects
OXALATES, CHEMICAL systems, NUCLEAR fuels, OXIDATION states, URANIUM, IONS, CATIONS
Abstract

Hydrothermal conversion of actinide oxalates has recently gained attention as an innovative fabrication route for nuclear fuels but has remained mainly limited to tetra- or tri-valent cations. We report herein the reductive conversion of mixtures of uranyl and oxalate ions into UO2+x oxides under mild hydrothermal conditions (T = 250 °C). A multi-parametric study first led to specifying the optimal conditions in terms of pH, oxalate/U ratio and duration to provide a quantitative precipitation of uranium in the hyper-stoichiometric dioxide form with pH = 0.8; R = noxalate/nU = 3, and t = 72 hours. Particularly, pH was evidenced as a key parameter, with 3 different compounds obtained over a range of only 0.4 units. The mechanism leading to the formation of UO2+x was then investigated thanks to an in situ XANES study. Analysis of the supernatant showed that U(VI) was quickly reduced into U(IV) thanks to the presence of oxalates and/or their decomposition products in solution, following first-order kinetics. Tetravalent uranium was then hydrolysed, leading to the precipitation of UO2+x as the only crystalline phase. This study thus demonstrates that the hydrothermal conversion of actinide oxalates into oxides is an extremely versatile tool that can be implemented in a large variety of chemical systems, particularly in terms of the oxidation state of the cations initially present in solution. [ABSTRACT FROM AUTHOR]

Published
2024
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8. Novel high-pressure/high-temperature reactor cell for in situ and operando x-ray absorption spectroscopy studies of heterogeneous catalysts at synchrotron facilities

Author

Nassereddine, Abdallah, primary, Prat, Alain, additional, Ould-Chikh, Samy, additional, Lahera, Eric, additional, Proux, Olivier, additional, Delnet, William, additional, Costes, Anael, additional, Maurin, Isabelle, additional, Kieffer, Isabelle, additional, Min, Sophie, additional, Rovezzi, Mauro, additional, Testemale, Denis, additional, Cerrillo Olmo, Jose Luis, additional, Gascon, Jorge, additional, Hazemann, Jean-Louis, additional, and Aguilar Tapia, Antonio, additional

Published
2024
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11. The ThomX ICS source

Author

Dupraz, Kevin, Alkadi, Muath, Alves, Manuel, Amoudry, Loic, Auguste, Didier, Babigeon, Jean-Luc, Baltazar, Michel, Benoit, Alain, Bonis, Julien, Bonenfant, Jean, Bruni, Christelle, Cassou, Kevin, Cayla, Jean-Noël, Chabaud, Thomas, Chaikovska, Iryna, Chance, Sophie, Chaumat, Vincent, Chiche, Ronic, Cobessi, Alain, Cornebise, Patrick, Dalifard, Olivier, Delerue, Nicolas, Dorkel, Remy, Douillet, Denis, Dugal, Jean-Phillipe, El Kamchi, Noureddine, El Khaldi, Mohamed, Ergenlik, Ezgi, Favier, Pierre, Fernandez, Marco, Gamelin, Alexis, Garaut, Jean-Francois, Garolfi, Luca, Gauron, Philippe, Gauthier, Frédéric, Gonnin, Alexandre, Grasset, Denis, Guerard, Eric, Guler, Hayg, Haissinski, Jacques, Herry, Emmanuel, Iaquaniello, Gregory, Jacquet, Marie, Jules, Eric, Kubytskyi, Vlacheslav, Langlet, Marc, Le Barillec, Titouan, Ledu, Jean-François, Leguidec, Damien, Leluan, Bruno, Lepercq, Pierre, Letellier-Cohen, Frédéric, Marie, Rodolphe, Marrucho, Jean-Claude, Martens, Aurélien, Mageur, Christophe, Mercadier, Gabriel, Mercier, Bruno, Mistretta, Eric, Monard, Hugues, Moutardier, Alexandre, Neveu, Olivier, Nutarelli, Daniele, Omeich, Maher, Peinaud, Yann, Petrilli, Yann, Pichet, Marc, Plaige, Eric, Prévost, Christophe, Rudnicky, Philippe, Soskov, Viktor, Taurigna-Quéré, Monique, Trochet, Stéphane, Vallerand, Cynthia, Vitez, Olivier, Wicek, François, Wurth, Sébastien, Zomer, Fabian, Alexandre, Patrick, Ben El Fekih, Rachid, Berteaud, Philippe, Bouvet, François, Cuoq, Renaud, Diaz, Antonio, Dietrich, Yannick, Diop, Massamba, Pedeau, Dominique, Dupuy, Eric, Marteau, Fabrice, Helder, Dias, Hubert, Nicolas, Veteran, José, Labat, Marie, Lestrade, Alain, Letrésor, Antoine, Lopes, Robert, Loulergue, Alexandre, Louvet, Marc, Marchand, Patrick, El Ajjouri, Moussa, Muller, Didier, Nadji, Amor, Nadolski, Laurent, Nagaoka, Ryutaro, Petit, Sylvain, Pollina, Jean-Pierre, Ribeiro, Fernand, Ros, Manuel, Salvia, Julien, Bobault, Sébastien, Sebdaoui, Mourad, Sreedharan, Rajesh, Bouanai, Yazid, Hazemann, Jean-Louis, Hodeau, Jean-Louis, Roy, Emmanuel, Jeantet, Philippe, Lacipière, Jérôme, Robert, Pierre, Horodynski, Jean-Michel, Bzyl, Harold, Chapelle, Christophe, Biagini, Marica, Walter, Philippe, Bravin, Alberto, Del Net, William, Lahéra, Eric, Proux, Olivier, Elleaume, Hélène, and Cormier, Eric

Published
2020
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17. Modelling the Pb release during Portland cement alteration

Author

Benard, A., Rose, J., Hazemann, Jean-Louis, Proux, O., Trotignon, L., Borschneck, D., Nonat, A., Chateau, L., and Bottero, J. -Y.

Subjects
Condensed Matter - Materials Science
Abstract

Complex cementitious matrices undergo weathering with environmental exchange and can release metallic pollutants during alteration. The molecular mechanisms responsible for metal release are difficult to identify, though this is necessary if such processes are to be controlled. The present study determines and models the molecular mechanisms of Pb release during Portland cement leaching. As Pb release is strongly related to its speciation (i.e. atomic environment and the nature of bearing phases), the first objective of the present study was to investigate the evolution of Pb retention sites together with the evolution of the cement mineralogy during leaching. Complementary and efficient investigation tools were used, namely X-ray diffraction, micro-X-ray fluorescence and X-ray absorption fine structures. The second objective was to reproduce our results with a reactive transport code (CHESS/HYTEC) in order to test the proposed speciation model of Pb. Combined results indicate that in both the unaltered core and the altered layer of the leached cement, Pb(II) would be retained through C-S-H 'nano-structure', probably linked to a Q1 or Q2P silicate tetrahedra. Moreover in the altered layer, the presence of Fe atoms in the atomic environment of Pb is highly probable. Unfortunately little is known about Fe phases in cement, which makes the interpretation difficult. Can Fe- substituted hydrogranet (C3AH6) be responsible for Pb retention? Modelling results were consistent with Pb retention through C-S-H in layers and also in an additional, possibly Fe-containing, Pb-retention phase in the altered layer.

Published
2014
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22. Intracellular Fate of Sub-Toxic Concentration of Functionalized Selenium Nanoparticles in Aggressive Prostate Cancer Cells

Author

Bissardon, Caroline, primary, Proux, Olivier, additional, Gazze, Salvatore Andrea, additional, Filhol, Odile, additional, Toubhans, Benoît, additional, Sauzéat, Lucie, additional, Bouchet, Sylvain, additional, Lewis, Aled R., additional, Maffeis, Thierry, additional, Hazemann, Jean-Louis, additional, Bayat, Sam, additional, Cloetens, Peter, additional, Conlan, R. Steven, additional, Charlet, Laurent, additional, and Bohic, Sylvain, additional

Published
2023
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23. Structural relaxation around substitutional Cr3+ in pyrope garnet

Author

Juhin, Amélie, Calas, Georges, Cabaret, Delphine, Galoisy, Laurence, and Hazemann, Jean-Louis

Subjects
Condensed Matter - Materials Science
Abstract

The structural environment of substitutional Cr3+ ion in a natural pyrope Mg3Al2Si3O12 has been investigated by Cr K-edge Extended X-ray Absorption Fine Structure (EXAFS) and X-ray Absorption Near Edge Structure (XANES) coupled with first-principles computations. The Cr-O distance is close to that in knorringite Mg3Cr2Si3O12, indicating a full relaxation of the first neighbors. The local C3i symmetry of the octahedral Y site is retained during Cr-Al substitution. The second and third shells of neighbors (Mg and Si) relax only partially. Site relaxation is accommodated by strain-induced bond buckling, with angular tilts of the Si-centered tetrahedra around the Cr-centered octahedron, and by a radial deformation of the Mg-centered dodecahedra.

Published
2007

24. XANES determination of chromium oxidation states in glasses: comparison with optical absorption spectroscopy

Author

Villain, Olivier, Calas, Georges, Galoisy, Laurence, Cormier, Laurent, and Hazemann, Jean-Louis

Subjects
Condensed Matter - Materials Science
Abstract

The oxidation state of chromium in glasses melted in an air atmosphere with and without refining agents was investigated by Cr K-edge X-ray Absorption Near-Edge Structure (XANES) and optical absorption spectroscopy. A good agreement in the relative proportion of Cr(III) and Cr(VI) is obtained between both methods. We show that the chemical dependence of the absorption coefficient of Cr(III) is less important in XANES than in optical absorption spectroscopy. The comparison of glasses melted under different conditions provides an indirect assessment of the molar extinction coefficient of Cr(VI) in glasses.

Published
2007

25. Structural relaxation around substitutional Cr3+ in MgAl2O4

Author

Juhin, Amélie, Calas, Georges, Cabaret, Delphine, Galoisy, Laurence, and Hazemann, Jean-Louis

Subjects
Condensed Matter - Materials Science
Abstract

The structural environment of substitutional Cr3+ ion in MgAl2O4 spinel has been investigated by Cr K-edge Extended X-ray Absorption Fine Structure (EXAFS) and X-ray Absorption Near Edge Structure (XANES) spectroscopies. First-principles computations of the structural relaxation and of the XANES spectrum have been performed, with a good agreement to the experiment. The Cr-O distance is close to that in MgCr2O4, indicating a full relaxation of the first neighbors, and the second shell of Al atoms relaxes partially. These observations demonstrate that Vegard's law is not obeyed in the MgAl2O4-MgCr2O4 solid solution. Despite some angular site distortion, the local D3d symmetry of the B-site of the spinel structure is retained during the substitution of Cr for Al. Here, we show that the relaxation is accomodated by strain-induced bond buckling, with angular tilts of the Mg-centred tetrahedra around the Cr-centred octahedron. By contrast, there is no significant alteration of the angles between the edge-sharing octahedra, which build chains aligned along the three four-fold axes of the cubic structure., Comment: 7 pages, 4 figures

Published
2007
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26. In situ measurements of density fluctuations and compressibility in silica glass as a function of temperature and thermal history

Author

Levelut, Claire, Faivre, Annelise, Parc, Rozenn Le, Champagnon, Bernard, Hazemann, Jean-Louis, and Simon, Jean-Paul

Subjects
Condensed Matter - Disordered Systems and Neural Networks
Abstract

In this paper, small-angle X-ray scattering measurements are used to determine the different compressibility contributions, as well as the isothermal compressibility, in thermal equilibrium in silica glasses having different thermal histories. Using two different methods of analysis, in the supercooled liquid and in the glassy state, we obtain respectively the temperature and fictive temperature dependences of the isotheraml compressibility. The values obtained in the glass and supercooled liquid states are very close to each other. They agree with previous determinations of the literature. The compressibility in the glass state slightly decreases with increasing fictive temperature. The relaxational part of the compressibility is also calculated and compared to previous determinations. We discussed the small differences between the different determinations.

Published
2005
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27. Characterization of the glass transition in vitreous silica by temperature scanning small-angle X-ray scattering

Author

Brüning, Ralf, Levelut, Claire, Faivre, Annelise, Parc, Rozenn Le, Simon, Jean-Paul, Bley, Françoise, and Hazemann, Jean-Louis

Subjects
Condensed Matter - Disordered Systems and Neural Networks
Abstract

The temperature dependence of the x-ray scattering in the region below the first sharp diffraction peak was measured for silica glasses with low and high OH content (GE-124 and Corning 7980). Data were obtained upon scanning the temperature at 10, 40 and 80 K/min between 400 K and 1820 K. The measurements resolve, for the first time, the hysteresis between heating and cooling through the glass transition for silica glass, and the data have a better signal to noise ratio than previous light scattering and differential thermal analysis data. For the glass with the higher hydroxyl concentration the glass transition is broader and at a lower temperature. Fits of the data to the Adam-Gibbs-Fulcher equation provide updated kinetic parameters for this very strong glass. The temperature derivative of the observed X-ray scattering matches that of light scattering to within 14%., Comment: EurophysicsLetters, in press

Published
2005
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28. Understanding of the structure activity relationship of PtPd bimetallic catalysts prepared by surface organometallic chemistry and ion exchange during the reaction of iso-butane with hydrogen

Author

Al-Shareef, Reem, Harb, Moussab, Saih, Youssef, Ould-Chikh, Samy, Roldan, Manuel A., Anjum, Dalaver H., Guyonnet, Elodie, Candy, Jean-Pierre, Jan, Deng-Yang, Abdo, Suheil F., Aguilar-Tapia, Antonio, Proux, Olivier, Hazemann, Jean-Louis, and Basset, Jean-Marie

Published
2018
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29. Zeolite Synthesis in the Presence of Metallosiloxanes for the Quantitative Encapsulation of Metal Species for the Selective Catalytic Reduction (SCR) of NOx

Author

Khairova, Rushana, primary, Komaty, Sarah, additional, Dikhtiarenko, Alla, additional, Cerrillo, Jose L, additional, Veeranmaril, Sudheesh Kumar, additional, Telalovic, Selvedin, additional, Tapia, Antonio Aguilar, additional, Hazemann, Jean-Louis, additional, Ruiz-Martinez, Javier, additional, and Gascon, Jorge, additional

Published
2023
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35. Zeolite Synthesis in the Presence of Metallosiloxanes for the Quantitative Encapsulation of Metal Species for the Selective Catalytic Reduction (SCR) of NOx.

Author

Khairova, Rushana, Komaty, Sarah, Dikhtiarenko, Alla, Cerrillo, Jose Luis, Veeranmaril, Sudheesh Kumar, Telalović, Selvedin, Tapia, Antonio Aguilar, Hazemann, Jean‐Louis, Ruiz‐Martinez, Javier, and Gascon, Jorge

Subjects
CATALYTIC reduction, METALS, TRANSITION metals, METAL clusters, HYDROTHERMAL synthesis, ZEOLITES
Abstract

Metal encapsulation in zeolitic materials through one‐pot hydrothermal synthesis (HTS) is an attractive technique to prepare zeolites with a high metal dispersion. Due to its simplicity and the excellent catalytic performance observed for several catalytic systems, this method has gained a great deal of attention over the last few years. While most studies apply synthetic methods involving different organic ligands to stabilize the metal under synthesis conditions, here we report the use of metallosiloxanes as an alternative metal precursor. Metallosiloxanes can be synthesized from simple and cost‐affordable chemicals and, when used in combination with zeolite building blocks under standard synthesis conditions, lead to quantitative metal loading and high dispersion. Thanks to the structural analogy of siloxane with TEOS, the synthesis gel stabilizes by forming siloxane bridges that prevent metal precipitation and clustering. When focusing on Fe‐encapsulation, we demonstrate that Fe‐MFI zeolites obtained by this method exhibit high catalytic activity in the NH3‐mediated selective catalytic reduction (SCR) of NOx along with a good H2O/SO2 tolerance. This synthetic approach opens a new synthetic route for the encapsulation of transition metals within zeolite structures. [ABSTRACT FROM AUTHOR]

Published
2023
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36. Zeolite Synthesis in the Presence of Metallosiloxanes for the Quantitative Encapsulation of Metal Species for the Selective Catalytic Reduction (SCR) of NOx.

Author

Khairova, Rushana, Komaty, Sarah, Dikhtiarenko, Alla, Cerrillo, Jose Luis, Veeranmaril, Sudheesh Kumar, Telalović, Selvedin, Tapia, Antonio Aguilar, Hazemann, Jean‐Louis, Ruiz‐Martinez, Javier, and Gascon, Jorge

Subjects
CATALYTIC reduction, METALS, TRANSITION metals, METAL clusters, HYDROTHERMAL synthesis, ZEOLITES
Abstract

Metal encapsulation in zeolitic materials through one‐pot hydrothermal synthesis (HTS) is an attractive technique to prepare zeolites with a high metal dispersion. Due to its simplicity and the excellent catalytic performance observed for several catalytic systems, this method has gained a great deal of attention over the last few years. While most studies apply synthetic methods involving different organic ligands to stabilize the metal under synthesis conditions, here we report the use of metallosiloxanes as an alternative metal precursor. Metallosiloxanes can be synthesized from simple and cost‐affordable chemicals and, when used in combination with zeolite building blocks under standard synthesis conditions, lead to quantitative metal loading and high dispersion. Thanks to the structural analogy of siloxane with TEOS, the synthesis gel stabilizes by forming siloxane bridges that prevent metal precipitation and clustering. When focusing on Fe‐encapsulation, we demonstrate that Fe‐MFI zeolites obtained by this method exhibit high catalytic activity in the NH3‐mediated selective catalytic reduction (SCR) of NOx along with a good H2O/SO2 tolerance. This synthetic approach opens a new synthetic route for the encapsulation of transition metals within zeolite structures. [ABSTRACT FROM AUTHOR]

Published
2023
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40. Understanding W/H-ZSM-5 Catalysts for the Dehydroaromatization of Methane

Author

Çağlayan, Mustafa, primary, Nassereddine, Abdallah, additional, Nastase, Stefan Adrian F., additional, Aguilar Tapia, Antonio, additional, Dikhtiarenko, Alla, additional, Chung, Sangho, additional, Shterk, Genrikh, additional, Shoinkhorova, Tuiana, additional, Hazemann, Jean-Louis, additional, Ruiz Martinez, Javier, additional, Cavallo, Luigi, additional, Ould-Chikh, Samy, additional, and Gascon, Jorge, additional

Published
2023
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43. Oxygen breath of subduction zones revealed by arsenic in serpentinite

Author

Pokrovski, Gleb, primary, Sanchez-Valle, Carmen, additional, Guillot, Stephane, additional, Borisova, Anastassia, additional, Munoz, Manuel, additional, Auzende, Anne Line, additional, Proux, Olivier, additional, Roux, Jacques, additional, Hazemann, Jean-Louis, additional, Testemale, Denis, additional, and Shvarov, Yuri, additional

Published
2023
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46. Sulfur radical species form gold deposits on Earth

Author

Pokrovski, Gleb S., Kokh, Maria A., Guillaume, Damien, Borisova, Anastassia Y., Gisquet, Pascal, Hazemann, Jean-Louis, Lahera, Eric, Del Net, William, Proux, Olivier, Testemale, Denis, Haigis, Volker, Jonchière, Romain, Seitsonen, Ari P., Ferlat, Guillaume, Vuilleumier, Rodolphe, Saitta, Antonino Marco, Boiron, Marie-Christine, and Dubessy, Jean

Published
2015

47. Contribution to the study of fission products release from nuclear fuels in severe accident conditions: effect of the pO2 on Cs, Mo and Ba speciation

Author

Le Gall Claire, Audubert Fabienne, Léchelle Jacques, Pontillon Yves, and Hazemann Jean-Louis

Subjects
Nuclear engineering. Atomic power, TK9001-9401
Abstract

The objective of this work is to experimentally investigate the effect of the oxygen potential on the fuel and FP chemical behaviour in conditions representative of a severe accident. More specifically, the speciation of Cs, Mo and Ba is investigated. These three highly reactive FP are among the most abundant elements produced through 235U and 239Pu thermal fission and may have a significant impact on human health and environmental contamination in case of a light water reactor severe accident. This work has set out to contribute to the following three fields: providing experimental data on Pressurized Water Reactor (PWR) MOX fuel behaviour submitted to severe accident conditions and related FP speciation; going further in the understanding of FP speciation mechanisms at different stages of a severe accident; developing a method to study volatile FP behaviour, involving the investigation of SIMFuel samples manufactured at low temperature through SPS. In this paper, a focus is made on the impact of the oxygen potential towards the interaction between irradiated MOX fuels and the cladding, the interaction between Mo and Ba under oxidizing conditions and the assessment of the oxygen potential during sintering.

Published
2020
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50. In situ X-ray absorption spectroscopy study of zinc and cadmium transport by S-rich fluids

Author

Bazarkina Elena F., Proux Olivier, Lahera Eric, Del Net William, and Hazemann Jean-Louis

Subjects
Environmental sciences, GE1-350
Abstract

This experimental and theoretical study is aimed at better quantifying the transport of Zn and Cd by hydrothermal fluids rich in sulfur by using in-situ X-ray absorption spectroscopy (XAS). We measured simultaneously fluorescence and transmission spectra of dissolved metal in NaHS-H2S, K2S2O3, Na2S2O3, K2S2O3-HCl aqueous solutions at 250-350°C and 600 bar. Here the first experimental results are presented. Possible sulfur speciation models for Zn and Cd are briefly discussed.

Published
2019
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