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Sulfur-nitrogen free radicals have been developed in the design of both organic magnets and conductors. Dithiazolyl (DTA) radicals are particularly promising in their application as organic magnets as they tend not to dimerize; it is crucial that they should be studied further for they might have interesting magnetic properties as their unpaired electrons do not spin-pair with neighbouring spins. Yet the synthesis of appropriate DTA radicals has proved synthetically more challenging than other thiazyl radicals. This talk will examine the effects of increasing the ring size on a series of benzo-fused dithiazolyls. The synthetic methodology, structures and magnetic properties of these derivatives will be discussed.

Incidence of AEs causing treatment discontinuation and SAEs (safety set). (DOCX 51 kb)

Patient disposition. (DOCX 51 kb)

In Beirut, space is not a static entity, it is both imagined and lived. This research provides a spatial analysis of Beirut and a class-based reinterpretation of space. In it, I identify two main groups that have two modes of operation in terms of city-spaces, the ‘Urbanistas’ and ‘the Biartis.’ The Urbanistas are an upper class-group that imagines a worldly Beirut part of a global order of capitalist cities, presenting this imaginare to a media audience. They reshape and command a limited enclave of the city with their focal point being the downtown and animate their lives in these spaces to ensure they are a reflection of the imaginaire. The Biartis are a lower-income group that lives Beirut in a diverse spatial sense. They reproduce and perform a spatial life that is detached from the image, from the branding and from the globalist order. Their lived experience of BeIrut becomes a form of counter-hegemonic bloc against the Urbanista imaginaire.